Chemical Engineering Journal Advances最新文献

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Design and information interaction study of bio-based materials in the packaging field 包装领域生物基材料的设计和信息交互研究
IF 5.5
Chemical Engineering Journal Advances Pub Date : 2024-11-15 DOI: 10.1016/j.ceja.2024.100676
Ying Yao , Guo Cheng , Xuesong Xie
{"title":"Design and information interaction study of bio-based materials in the packaging field","authors":"Ying Yao ,&nbsp;Guo Cheng ,&nbsp;Xuesong Xie","doi":"10.1016/j.ceja.2024.100676","DOIUrl":"10.1016/j.ceja.2024.100676","url":null,"abstract":"<div><div>Based on the rapid and widespread application of fossil-based resources and global transportation, product packaging is crowding corners all around the world. Therefore, to meet modern needs, achieving a balance between intelligent interaction and the environmentally friendly sustainability and safety of materials has become an important consideration in contemporary packaging research. Given the environmental benefits of bio-based materials, this review aims to explore the utility of biomaterials in the packaging realm, particularly those derived from nature. By analyzing the characteristics of biomaterials, this review investigates the advantages and challenges of bio-based materials in packaging design, delves into the construction of their information interaction functions, and discusses their development potential in light of their renewable and degradable closed-loop properties. Meanwhile, from the expansion of material innovation, enhanced functionalities and interactive intelligence, scalability and cost efficiency, and cross-industry circular economy and collaboration, we offer some perspective in this review to provide theoretical insights for the sustainable development of intelligent packaging materials.</div></div>","PeriodicalId":9749,"journal":{"name":"Chemical Engineering Journal Advances","volume":"20 ","pages":"Article 100676"},"PeriodicalIF":5.5,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142653523","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fractional recovery of proteins and carbohydrates from secondary sludge from urban wastewater treatment plants 从城市污水处理厂二级污泥中分馏回收蛋白质和碳水化合物
IF 5.5
Chemical Engineering Journal Advances Pub Date : 2024-11-15 DOI: 10.1016/j.ceja.2024.100686
Angel Alejandro Filipigh , Elena M. Rojo , Andrea Natalia Pila , Silvia Bolado
{"title":"Fractional recovery of proteins and carbohydrates from secondary sludge from urban wastewater treatment plants","authors":"Angel Alejandro Filipigh ,&nbsp;Elena M. Rojo ,&nbsp;Andrea Natalia Pila ,&nbsp;Silvia Bolado","doi":"10.1016/j.ceja.2024.100686","DOIUrl":"10.1016/j.ceja.2024.100686","url":null,"abstract":"<div><div>The secondary sludge of wastewater treatment plants is an abundant and problematic bacterial biomass that accumulates nutrients from wastewater, mainly as proteins and carbohydrates. Recent studies have focused on energy recovery of this biomass by anaerobic digestion to produce biogas. However, fractional recovery of the sludge components could increase its value and provide the basis for a biorefinery based on this waste. Since ≈ 40-60% of the bacterial dry weight is protein, this biomass could be an important source of functional peptides or amino acids, and the carbohydrates could be used to produce bioplastics or biofuels. This study compares chemical, physical and biological hydrolysis methods and their sequential and assisted combinations to recover proteins and carbohydrates from sludge. Ultrasound-assisted alkaline treatment provided the highest protein solubilization yield (97.2%) with low degradation, resulting in peptide recovery yields of 75.1% with sizes from 70-215 kDa, 40% of essential amino acids and purity of 35.3% with NaOH 1M. The hydrothermal-alkaline combination almost completely solubilized the proteins but not the carbohydrates (77.4%) with high degradation (52.6%). The hydrothermal-acidic combination achieved high carbohydrate solubilization (94%) and recoveries of glucose (63.6%) and xylose (12.6%) but low protein recovery (43.7%) as small size peptides.</div></div>","PeriodicalId":9749,"journal":{"name":"Chemical Engineering Journal Advances","volume":"20 ","pages":"Article 100686"},"PeriodicalIF":5.5,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142697530","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative techno-economic and carbon footprint analysis of 2,3-butanediol production through aerobic and anaerobic bioconversion of carbon dioxide with green hydrogen 通过好氧和厌氧生物转化二氧化碳与绿色氢气生产 2,3-丁二醇的技术经济和碳足迹比较分析
IF 5.5
Chemical Engineering Journal Advances Pub Date : 2024-11-15 DOI: 10.1016/j.ceja.2024.100659
Fabio Bozzolo Lueckel , Felipe Scott , Germán Aroca
{"title":"Comparative techno-economic and carbon footprint analysis of 2,3-butanediol production through aerobic and anaerobic bioconversion of carbon dioxide with green hydrogen","authors":"Fabio Bozzolo Lueckel ,&nbsp;Felipe Scott ,&nbsp;Germán Aroca","doi":"10.1016/j.ceja.2024.100659","DOIUrl":"10.1016/j.ceja.2024.100659","url":null,"abstract":"<div><div>Renewable CO<sub>2</sub> and hydrogen have the potential to be the feedstocks of a decarbonized chemical industry, and biochemical conversions offer new alternatives for the industry. There are two options among chemolithotrophic bacteria capable of CO<sub>2</sub> fixation: under aerobic conditions, through the use of the Calvin-Benson-Basham cycle, known to produce large-chain compounds, and under anaerobic conditions, through the Wood-Ljungdahl pathway, known to produce short-chain organic molecules. Here, we report a comparison of both bioconversions, made at a simulated industrial scale, considering techno-economic and environmental variables, and using renewable CO<sub>2</sub> and H<sub>2</sub> as feedstocks. 2,3-butanediol, a mid-range chain compound that can be produced via both routes, was selected for comparison. The comparison was set up in Chile due to expected low-cost renewable hydrogen and renewable CO<sub>2</sub> availability. The assessment showed that the minimum selling price of 2,3-butanediol in the anaerobic case was higher (3.91 (USD kg<sup>−1</sup>)) than in the aerobic case (3.36 (USD kg<sup>−1</sup>)), with hydrogen being the largest expense in both processes (50 % and 70 % of total expenses respectively). Further, owing to metabolic restrictions, the anaerobic process required almost five times more CO<sub>2</sub> than the aerobic process to produce the same amount of 2,3-butanediol. A Monte Carlo analysis showed that in most scenarios the aerobic process was more economically favorable. In environmental terms, the aerobic process had a smaller carbon footprint in all the evaluated scenarios. Therefore, the results suggest that the aerobic process is a more suitable alternative to anaerobic bacteria-based processes for producing 2,3-butanediol from renewable CO<sub>2</sub> and hydrogen.</div></div>","PeriodicalId":9749,"journal":{"name":"Chemical Engineering Journal Advances","volume":"20 ","pages":"Article 100659"},"PeriodicalIF":5.5,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142653657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication and characterization of UV-curable thiol-functionalized siloxane elastomers with enhanced adhesion for flexible substrates 紫外线固化硫醇功能化硅氧烷弹性体的制备与表征,增强柔性基材的附着力
IF 5.5
Chemical Engineering Journal Advances Pub Date : 2024-11-15 DOI: 10.1016/j.ceja.2024.100679
Young-Hun Kim , Jongwon Kim , Jeong Ju Baek , Ki Cheol Chang , Baek Soo Park , Geun Yeol Bae , Won-Gun Koh , Gyojic Shin
{"title":"Fabrication and characterization of UV-curable thiol-functionalized siloxane elastomers with enhanced adhesion for flexible substrates","authors":"Young-Hun Kim ,&nbsp;Jongwon Kim ,&nbsp;Jeong Ju Baek ,&nbsp;Ki Cheol Chang ,&nbsp;Baek Soo Park ,&nbsp;Geun Yeol Bae ,&nbsp;Won-Gun Koh ,&nbsp;Gyojic Shin","doi":"10.1016/j.ceja.2024.100679","DOIUrl":"10.1016/j.ceja.2024.100679","url":null,"abstract":"<div><div>The rapid advancement of flexible and wearable devices has increased the demand for substrate materials with excellent elasticity, biocompatibility, and transparency. Polydimethylsiloxane (PDMS) is widely used in these applications due to its advantageous properties. However, its inherently low surface energy limits its adhesion in high-stretchability contexts. To address this issue, various surface modification techniques have been developed, but these methods often alter the intrinsic properties of PDMS or introduce complexities in the manufacturing process. This study proposes elastomers based on ultraviolet (UV)-curable siloxane resins, which retain outstanding flexibility and transparency while significantly enhancing adhesion properties. UV-curable siloxanes were synthesized to prepare elastomers that were evaluated for their mechanical, thermal, and surface properties in comparison with PDMS. Results indicate that the prepared elastomers can be rapidly cured under UV exposure, achieving storage moduli 6 and 37 times higher than those of PDMS at 25 °C and 100 °C, respectively. Furthermore, thermal conductivity improved by 60 %, and the coefficient of thermal expansion was reduced by 26 %, demonstrating superior mechanical stability across diverse conditions. Adhesion properties were also markedly enhanced, as shown by peel-test adhesion strength that was 7 times greater than that of conventional PDMS.</div></div>","PeriodicalId":9749,"journal":{"name":"Chemical Engineering Journal Advances","volume":"20 ","pages":"Article 100679"},"PeriodicalIF":5.5,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142653520","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bio-inspired microstructures for high-performance and self-powered E-skin technologies 用于高性能自供电电子皮肤技术的生物启发微结构
IF 5.5
Chemical Engineering Journal Advances Pub Date : 2024-11-15 DOI: 10.1016/j.ceja.2024.100664
Husam A. Neamah , Al-Gburi Mousa
{"title":"Bio-inspired microstructures for high-performance and self-powered E-skin technologies","authors":"Husam A. Neamah ,&nbsp;Al-Gburi Mousa","doi":"10.1016/j.ceja.2024.100664","DOIUrl":"10.1016/j.ceja.2024.100664","url":null,"abstract":"<div><div>The advancement of electronic skin (e-skin) technology has transitioned from fictional narratives to real-world applications due to breakthroughs in microelectronics. Current e-skin designs utilize advanced materials and microfabrication techniques. Recent developments focus on integrating biomimetic microstructures, such as pyramids, domes, and nanofibers, to enhance sensor performance. These structures improve sensitivity, flexibility, and durability. Innovations include self-powered sensors using piezoelectric materials like PVDF and ZnO, as well as multi-mode e-skins combining capacitive and piezoelectric sensors, stretchable electrodes, and self-healing materials. E-skin technology has applications in wearable devices, healthcare, robotics, and human-machine interfaces. This review, using the PRISMA methodology, examines advancements in tactile sensors, highlighting the role of biomimetic microstructures. These structures provide additional functionalities such as freeze resistance, corrosion resistance, self-cleaning, and degradability, optimizing overall sensor performance. Continued research and innovation are moving e-skin technology towards human-like tactile sensing with improved performance, flexibility, and self-sufficiency. This review summarizes the latest developments in biomimetic microstructures for tactile sensors and their application prospects in human detection and human-machine interaction devices.</div></div>","PeriodicalId":9749,"journal":{"name":"Chemical Engineering Journal Advances","volume":"20 ","pages":"Article 100664"},"PeriodicalIF":5.5,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142653522","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimizing the screening process for inhibitory aptamers specific to folate receptor alpha on an integrated, shear force-controlling microfluidic system 在剪切力控制集成微流控系统上优化叶酸受体α特异性抑制性适配体的筛选过程
IF 5.5
Chemical Engineering Journal Advances Pub Date : 2024-11-15 DOI: 10.1016/j.ceja.2024.100681
Yi-Cheng Tsai , Yang-Sheng Shao , Chih-Hung Wang , Keng-Fu Hsu , Gwo-Bin Lee
{"title":"Optimizing the screening process for inhibitory aptamers specific to folate receptor alpha on an integrated, shear force-controlling microfluidic system","authors":"Yi-Cheng Tsai ,&nbsp;Yang-Sheng Shao ,&nbsp;Chih-Hung Wang ,&nbsp;Keng-Fu Hsu ,&nbsp;Gwo-Bin Lee","doi":"10.1016/j.ceja.2024.100681","DOIUrl":"10.1016/j.ceja.2024.100681","url":null,"abstract":"<div><div>Folate receptor alpha (FRα) has been regarded as a promising target for ovarian cancer (OvCa) therapy. This work focused on improving the identification of inhibitory aptamers that specifically target and block FRα. A new integrated microfluidic system (IMS) was designed to automate the entire systematic evolution of ligands by exponential enrichment (SELEX), precisely controlling the washing shear force from 62.7 nN to 451.7 nN that gradually washed away low-affinity aptamers, allowing high-affinity, high-specificity, single-stranded DNA aptamers to be screened within 15 h, which is significantly shorter than conventional process (weeks to months) while consuming 50 % less samples and reagents. Furthermore, screened aptamers significantly inhibited OvCa progression, achieving 20 % higher wound recovery in wound-healing tests when compared with an anti-cancer drug targeting FRα. In summary, precisely controlled shear force by IMS could optimize aptamers screening with high affinity/specificity towards FRα, which inhibited OvCa cell growth, suggesting their applicability as promising candidates for onco-therapy.</div></div>","PeriodicalId":9749,"journal":{"name":"Chemical Engineering Journal Advances","volume":"20 ","pages":"Article 100681"},"PeriodicalIF":5.5,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142697958","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of the functionalization on the performance of graphene oxide-based membranes in the desalination and wastewater treatment: A new classification of functionalizing material 功能化对基于氧化石墨烯的膜在海水淡化和废水处理中的性能的影响:功能化材料的新分类
IF 5.5
Chemical Engineering Journal Advances Pub Date : 2024-11-15 DOI: 10.1016/j.ceja.2024.100684
Martin Ayala-Claveria , Carlos Carlesi , Julieta Puig , Gianni Olguin
{"title":"Effects of the functionalization on the performance of graphene oxide-based membranes in the desalination and wastewater treatment: A new classification of functionalizing material","authors":"Martin Ayala-Claveria ,&nbsp;Carlos Carlesi ,&nbsp;Julieta Puig ,&nbsp;Gianni Olguin","doi":"10.1016/j.ceja.2024.100684","DOIUrl":"10.1016/j.ceja.2024.100684","url":null,"abstract":"<div><div>Graphene oxide membranes have emerged as cutting-edge materials in desalination and wastewater treatment technologies due to valuable attributes such as ready accessibility, mechanical strength, chemical affinity, high water permeability, and pollutant selectivity. However, a significant challenge arises from the distortion of the nanochannels responsible for water transport due to the hydration of oxidized groups over the graphene oxide nanoplates. This compromises selectivity and alters water transport dynamics. To surmount this drawback, innovative strategies involve the incorporation of additives, or crosslinkers, into the graphene oxide matrix to stabilize these critical nanochannels. This comprehensive review investigates the performance of graphene oxide membranes for desalination and wastewater treatment, where graphene oxide was functionalized through crosslinker integration. A novel classification based on the connector element is considered for relating the crosslinker nature and performance in water treatment, accompanied by a statistical analysis highlighting key factors influencing the performance. It was found that additives based on metallic connectors offer a high likelihood of obtaining high performance while incorporating oxygen-based additives shows the highest performance. Furthermore, the hydrophobic character of the selective graphene oxide layer arises as the key factor in determining the final performance in water depuration.</div></div>","PeriodicalId":9749,"journal":{"name":"Chemical Engineering Journal Advances","volume":"20 ","pages":"Article 100684"},"PeriodicalIF":5.5,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142697529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-sensitivity detection of copper ions in water via cellulose nanomaterial nano-antennas and DFT studies 通过纤维素纳米材料纳米天线和 DFT 研究高灵敏度检测水中的铜离子
IF 5.5
Chemical Engineering Journal Advances Pub Date : 2024-11-15 DOI: 10.1016/j.ceja.2024.100675
Arwa Alharbi , Abdullah A.A. Sari , Ali H. Alessa , Razan M. Snari , Hatun H. Alsharief , Ibrahim S.S. Alatawi , E.F.M. El-Zaidia , Nashwa M. El-Metwaly
{"title":"High-sensitivity detection of copper ions in water via cellulose nanomaterial nano-antennas and DFT studies","authors":"Arwa Alharbi ,&nbsp;Abdullah A.A. Sari ,&nbsp;Ali H. Alessa ,&nbsp;Razan M. Snari ,&nbsp;Hatun H. Alsharief ,&nbsp;Ibrahim S.S. Alatawi ,&nbsp;E.F.M. El-Zaidia ,&nbsp;Nashwa M. El-Metwaly","doi":"10.1016/j.ceja.2024.100675","DOIUrl":"10.1016/j.ceja.2024.100675","url":null,"abstract":"<div><div>The widespread occurrence of copper in water presents serious health hazards, requiring improvement of a method to monitor and remove copper ions in the field. In this study, a fresh approach is introduced that incorporates Cellulose Nanomaterials (CNMs) with a unique rod-like structure, offering a large surface area that is perfect for adsorbing cupral, a Cu(II) ion probe. By using this arrangement, toxic copper can be rapidly and visibly detected. Without any special tools, it's easy to see the color change from off-white to brown. The copper nano-antenna (CNA) has an impressively high sensitivity, detecting as low as 2.5 × 10–7 M through image analysis and 4.3 × 10–8 M with spectrophotometric methods. The values fall significantly below the WHO drinking water guidelines of 2 ppm. The CNA's ability to detect at low thresholds and be easily regenerated makes it an effective tool for initial water testing. According to the findings, the CNA could be a promising solution for enhancing safety in drinking water by allowing real-time visualization of copper ions, with only 5 mg required for measurements. Computational analysis has been conducted to study the structural properties of copper and its copper complex (Cu(CNA)<sub>2</sub>). There is a significant-close agreement between the theoretical and experimental results. The developed CNA material was tested in various environmental and real samples for detecting Cu<sup>2+</sup> ions, especially in water and whitening cream samples showing the material application for real-world applications.</div></div>","PeriodicalId":9749,"journal":{"name":"Chemical Engineering Journal Advances","volume":"20 ","pages":"Article 100675"},"PeriodicalIF":5.5,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142653525","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fine-tuning CO2 separation of mixed matrix membranes by constructing efficient transport pathways through the addition of hybrid porous 2D nanosheets 通过添加混合多孔二维纳米片构建高效传输途径,微调混合基质膜的二氧化碳分离性能
IF 5.5
Chemical Engineering Journal Advances Pub Date : 2024-11-15 DOI: 10.1016/j.ceja.2024.100685
Adel Hosseinkhani , Mohammadreza Omidkhah , Abtin Ebadi Amooghin
{"title":"Fine-tuning CO2 separation of mixed matrix membranes by constructing efficient transport pathways through the addition of hybrid porous 2D nanosheets","authors":"Adel Hosseinkhani ,&nbsp;Mohammadreza Omidkhah ,&nbsp;Abtin Ebadi Amooghin","doi":"10.1016/j.ceja.2024.100685","DOIUrl":"10.1016/j.ceja.2024.100685","url":null,"abstract":"<div><div>In this research, the effect of adding PEG 400 and synthesized rGO<img>NiO hybrid nanocomposite to Pebax® to design the Pebax® 1657/PEG 400/rGO<img>NiO ternary mixed matrix membrane (MMM) for CO<sub>2</sub>/CH<sub>4</sub> and CO<sub>2</sub>/N<sub>2</sub> separation, has been evaluated. For this purpose, neat membrane, Pebax® 1657/PEG 400 blend membranes and Pebax® 1657/PEG400/rGO<img>NiO based MMMs were fabricated. In the next step, gas separation performance tests were performed on the membranes at 35 °C and operating pressure of 2 to 10 bar, and gas separation properties were evaluated. Also, FTIR-ATR, XRD, FESEM, DSC, TGA, TEM, and tensile analyses were employed. The obtained results indicate the uniform dispersion of rGO<img>NiO nanocomposite in the polymer matrix and the proper adhesion between rGO<img>NiO nanocomposite and polymer chains due to the modification of the hydrophilicity by polyethylene glycol (PEG), which led to the preparation of a ternary MMM without defects. It significantly improved the separation performance of the membranes compared to the neat membrane. Gas permeability results demonstrated that the optimized blend membrane was obtained at 30 wt.% of PEG 400, and the optimized ternary MMM was obtained at 30 wt.% of PEG 400 and 0.75 wt.% of rGO<img>NiO. Pebax® 1657/PEG (30 wt.%)/rGO<img>NiO (0.75 wt.%) with CO<sub>2</sub> permeability of 442.37 barrer showed 258 % improvement compared to the neat membrane at 10 bar Moreover, the excellent CO<sub>2</sub>/CH<sub>4</sub> and CO<sub>2</sub>/N<sub>2</sub> selectivity of 121.32 (495.29 % improvement) and 510.45 (713.59 % improvement) were reported for the optimized ternary MMM, respectively. Finally, the fabricated membranes surpassed Robeson's upper bound limit, indicating their potential for real gas separation situations.</div></div>","PeriodicalId":9749,"journal":{"name":"Chemical Engineering Journal Advances","volume":"20 ","pages":"Article 100685"},"PeriodicalIF":5.5,"publicationDate":"2024-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142697959","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Numerical simulation of magnetically driven nanomaterial rotating flow configured by convective-radiative cone with chemical reaction
IF 5.5
Chemical Engineering Journal Advances Pub Date : 2024-11-12 DOI: 10.1016/j.ceja.2024.100682
Cyrus Raza Mirza , Muhammad Salman Kausar , Muhammad Nasir , M. Waqas , Nurnadiah Zamri , Iskandar Shernazarov , S.U. Khan , Nidhal Ben Khedher
{"title":"Numerical simulation of magnetically driven nanomaterial rotating flow configured by convective-radiative cone with chemical reaction","authors":"Cyrus Raza Mirza ,&nbsp;Muhammad Salman Kausar ,&nbsp;Muhammad Nasir ,&nbsp;M. Waqas ,&nbsp;Nurnadiah Zamri ,&nbsp;Iskandar Shernazarov ,&nbsp;S.U. Khan ,&nbsp;Nidhal Ben Khedher","doi":"10.1016/j.ceja.2024.100682","DOIUrl":"10.1016/j.ceja.2024.100682","url":null,"abstract":"<div><div>Indeed, nanoliquids have acquired substantial consideration in heat transference field because of their inimitable thermal attributes and favorable application likelihoods. In contrast to orthodox liquids, the haphazard movement of nanoparticles within nanoliquid strengthens fluid turbulence, accomplishes superior thermal effectiveness and declines thermal resistance. Nanoliquids have ample utilization, for illustration, solar energy, electronic chips, automotive radiators and heat exchangers etc. This communication reports chemically reactive electro-magnetized nanomaterial dissipative flow confined by rotating cone. Flow expressions include thermo-solutal buoyancy, varying viscosity and magneto-hydrodynamics. Radiative heat, thermophoresis, viscous dissipation, Brownian diffusion, thermal source and first order chemical reaction are pondered to model transport expressions. Relevant variables are introduced to transfigure partial differential mathematical expressions to mathematical ordinary ones. Numerical outcomes for non-dimensional mathematical expressions are reported via bvp4c algorithm in MATLAB. The comprehensive results featuring dimensionless quantities are explored through graphs and arithmetic representations. It is evaluated that escalating values of variable viscosity, Prandtl number and unsteady parameter decline temperature but temperature is improved as a consequence of progressive variation in radiation parameter, Eckert number, thermophoresis parameter, heat generating and Brownian diffusive variables. The study is relevant to cooling industry, electroconductive, thermal collector and nano-materials processing.</div></div>","PeriodicalId":9749,"journal":{"name":"Chemical Engineering Journal Advances","volume":"21 ","pages":"Article 100682"},"PeriodicalIF":5.5,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142748018","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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