IUCrData最新文献_第4页

Poly[bis(μ4-oxalato)potassium(I)praseodymium(III)] 保利(bis(μ4-oxalato)钾(I)镨(III)]。

IUCrData Pub Date : 2025-07-01 DOI: 10.1107/S2414314625006078

Kanthida Kummoon , Sakchai Laksee , Kittipong Chainok

引用次数: 0

6-Chloro-3-[4-(hexyloxy)phenyl]-[1,2,4]triazolo[4,3-b]pyridazine 6-Chloro-3 - [4 - (hex-yloxy) phen-yl] -[1、2、4]triazolo哒嗪(4 3 b)。

IUCrData Pub Date : 2025-07-01 DOI: 10.1107/S2414314625005668

Jasmin Preis , Dieter Schollmeyer , Heiner Detert

{"title":"6-Chloro-3-[4-(hexyloxy)phenyl]-[1,2,4]triazolo[4,3-b]pyridazine","authors":"Jasmin Preis , Dieter Schollmeyer , Heiner Detert","doi":"10.1107/S2414314625005668","DOIUrl":"10.1107/S2414314625005668","url":null,"abstract":"<div><div>Molecules of the title compound, C17H19ClN4O, are essentially planar, the dihedral angles between the planes of the tetraazaindene ring system and the benzene ring and between the benzene ring and the hexyloxy chain being 1.56 (10)° and 5.02 (17)°, respectively. In the crystal, pairs of molecules are connected via π–π interactions between the phenyl ring and the triazolopyridazine moiety.</div></div><div><div>Molecules of the title compound, C17H19ClN4O, are essentially planar, the dihedral angles between the planes of the tetraazaindene ring system and the benzene ring and between the benzene ring and the hexyloxy chain being 1.56 (10)° and 5.02 (17)°, respectively. In the crystal, pairs of molecules are connected via π–π interactions between the phenyl ring and the triazolopyridazine moiety.<blockquote><div><figure><img><ol><li>Download: Download high-res image (190KB)</li><li>Download: Download full-size image</li></ol></figure></div></blockquote></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 7","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144801540","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

2-{[(1S,2S)-1-Hydroxy-1-phenylpropan-2-yl](methyl)amino}-N-(3-methylphenyl)acetamide 2 - {((1 s, 2 s) 1-hy-droxy-1-phenyl-propan-2-yl)(甲基)氨基}- n -乙酰胺(3-methyl-phen-yl)。

IUCrData Pub Date : 2025-07-01 DOI: 10.1107/S2414314625005784

Sarvinoz Bobonazarova , Batirbay Torambetov , Dilnoza Burieva , Anvar Abdushukurov , Shakhnoza Kadirova , Rasul Ya Okmanov , Mukhriddin Yusufov

引用次数: 0

Bis[N,N-bis(diphenylphosphanyl)cyclohexanamine-κ2P,P′]dichloridocobalt(III) tris(μ-diphenylphosphinato-κ2O:O′)bis[chloridocobaltate(II)]–dichloromethane–diethyl ether (1/1.189/0.811) 双-[N，N-双-（二苯基-膦基）环六氨基-κ 2P，P']二氯化钴（III）三-（μ-二苯基-膦酸-κ 2O:O'）二-[氯戊酸盐（II）]-二氯甲烷-二乙基醚（1/1.189/0.811）。

IUCrData Pub Date : 2025-07-01 DOI: 10.1107/S2414314625006327

Sizwe J. Zamisa , Adesola A. Adeleke , Dunesha Naicker , Holger B. Friedrich , Bernard Omondi

{"title":"Bis[N,N-bis(diphenylphosphanyl)cyclohexanamine-κ2P,P′]dichloridocobalt(III) tris(μ-diphenylphosphinato-κ2O:O′)bis[chloridocobaltate(II)]–dichloromethane–diethyl ether (1/1.189/0.811)","authors":"Sizwe J. Zamisa , Adesola A. Adeleke , Dunesha Naicker , Holger B. Friedrich , Bernard Omondi","doi":"10.1107/S2414314625006327","DOIUrl":"10.1107/S2414314625006327","url":null,"abstract":"<div><div>The solvated title compound has a cationic CoIII-aminodiphosphine and a dimeric CoII-diphenylphosphonate anionic species.</div></div><div><div>The DCM-Et2O solvated title compound, [CoCl2(C30H31NP2)2][Co2(C12H10O2P)3Cl2]·1.189CH2Cl2·0.811C4H10O or [CoCl2{Ph2PN(C6H11)PPh2}2][Co2{Ph2PO2}3Cl2]·1.189DCM·0.811Et2O, is a combination of a cationic CoIII-aminodiphosphine and a dimetallic CoII-diphenylphosphonate anionic species. The asymmetric unit features one half of the cationic and anionic species with solvent molecules in the outer coordination sphere. The metal centre of the cation is located on an inversion center, while the anion is disordered around an inversion center. The cyclohexanyl moiety of the aminodiphosphine ligand exhibits two-component rotational disorder along the N—C bond, the moiety’s major component occupancy refined to 71.1 (7)%. The dichloromethane and diethyl ether solvate molecules are disordered with each other and were modelled with 59.4 (3)% and 40.6 (3)% site occupancies in the asymmetric unit, respectively. Intermolecular C—H⋯π hydrogen-bonding patterns form infinite supramolecular sheets extending parallel to (110). C—H⋯Cl and C—H⋯O hydrogen bonds were also found in the crystal packing of the title compound.<blockquote><div><figure><img><ol><li>Download: Download high-res image (353KB)</li><li>Download: Download full-size image</li></ol></figure></div></blockquote></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 7","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144801541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

2-(10-Phenylanthracen-9-yl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine (2) - 10-Phenyl-anthracen-9-yl 2, 3-di-hydro-1H-naphtho - [1, 8-de][1、3、2]di-aza-borinine。

IUCrData Pub Date : 2025-07-01 DOI: 10.1107/S2414314625005759

Fanyi Meng , Shimin Zhou

引用次数: 0

(η4-Trimethylenemethane)(1,1,1-tris{[bis(4-methoxyphenyl)phosphanyl]methyl}ethane)ruthenium(II) diethyl ether hemisolvate （η - 4-三甲基-甲烷）（1,1,1-三-{[双-（4-甲氧基-苯基）磷基]甲基基}乙烷）钌（II）二乙醚半磺酸盐。

IUCrData Pub Date : 2025-06-01 DOI: 10.1107/S2414314625005243

Carolin A. M. Stein , Elisabetta Alberico , Anke Spannenberg , Matthias Beller , Henrik Junge

引用次数: 0

2,3,4,6-Tetra-O-acetyl-1-[(dimethylcarbamothioyl)sulfanyl]-β-d-galactopyranose 2、3、4,6-Tetra-O-acetyl-1 - [(dimethylcarbamothioyl) sulfanyl] -β-d-galacto-pyran-ose。

IUCrData Pub Date : 2025-06-01 DOI: 10.1107/S2414314625005449

Reham A. Mohamed-Ezzat , Galal H. Elgemeie , Peter G. Jones

引用次数: 0

rac-4,5-trans-Dibromo-9,9-dichloro-cis-bicyclo[6.1.0]nonane rac-4,5-trans-Di-bromo-9,9-di-chloro-cis-bi-cyclo (6.1.0 nona-ne) .

IUCrData Pub Date : 2025-06-01 DOI: 10.1107/S2414314625005735

Heiner Detert , Dieter Schollmeyer

引用次数: 0

3-(4-Fluorophenyl)imidazo[1,2-a]pyridine-2-carbaldehyde 3 - (4-Fluoro-phen-yl) imidazo (1,2-a pyridine-2-carbaldehyde) .

IUCrData Pub Date : 2025-06-01 DOI: 10.1107/S241431462500553X

Firudin I. Guseinov , Aida I. Samigullina , Tuncer Hökelek , Sahil Z. Hamidov , Jamal Lasri , Khudayar I. Hasanov , Narmina A. Guliyeva , Alebel N. Belay

引用次数: 0

Tris(2,2′-bipyridine)iron(II) tris(dicyanomethylidene)methanediide 三(2,2’-bi-pyridine)铁(II)三- (di-cyano-methylidene) methane-diide。

IUCrData Pub Date : 2025-06-01 DOI: 10.1107/S2414314625005036

Said Abdelghafour Messalti , Fatima Setifi , Uwe Böhme , Zouaoui Setifi , Mohammad Hadi Al-Douh

{"title":"Tris(2,2′-bipyridine)iron(II) tris(dicyanomethylidene)methanediide","authors":"Said Abdelghafour Messalti , Fatima Setifi , Uwe Böhme , Zouaoui Setifi , Mohammad Hadi Al-Douh","doi":"10.1107/S2414314625005036","DOIUrl":"10.1107/S2414314625005036","url":null,"abstract":"<div><div>The asymmetric unit of the title compound, [Fe(C10H8N2)3][C{C(CN)2}3], contains an iron–bipyridyl unit and one third of two crystallographic independent tris(dicyanomethylidene)methanediide units. In the crystal, hydrogen bonds between cations and anions form complex layers parallel to (001). These are supplemented by hydrogen bonds perpendicular to the former, leading to a three-dimensional network.</div></div><div><div>The asymmetric unit of the title compound, [Fe(C10H8N2)3][C{C(CN)2}3], contains an iron–bipyridyl unit and one third of two crystallographic independent tris(dicyanomethylidene)methanediide units. As a result of crystallographic site symmetry the ratio of cations to anions is 1:1. The tris(2,2′-bipyridine)iron(II) cation has threefold symmetry. The two crystallographic independent tris(dicyanomethylidene)methanediide ions are disordered over two atomic sites having equal occupancy. The anions have 3 symmetry. In the crystal, hydrogen bonds between cations and anions form complex layers parallel to (001). These are supplemented by hydrogen bonds perpendicular to the former, leading to a three-dimensional network.<blockquote><div><figure><img><ol><li>Download: Download high-res image (307KB)</li><li>Download: Download full-size image</li></ol></figure></div></blockquote></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144593360","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0