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meso-5,15-Bis[3-(iso­propyl­idenegalacto­pyran­oxy)phen­yl]-10,20-bis­(4-methyl­phen­yl)porphyrin meso-5, 15-Bis [3 - (iso-propyl-idenegalacto-pyran-oxy) phen-yl] -10年,20-bis——(4-methyl-phen-yl)卟啉。
IUCrData Pub Date : 2024-10-01 DOI: 10.1107/S2414314624010289
Mickey Vinodh , Fatemeh H. Alipour , Talal F. Al-Azemi
{"title":"meso-5,15-Bis[3-(iso­propyl­idenegalacto­pyran­oxy)phen­yl]-10,20-bis­(4-methyl­phen­yl)porphyrin","authors":"Mickey Vinodh ,&nbsp;Fatemeh H. Alipour ,&nbsp;Talal F. Al-Azemi","doi":"10.1107/S2414314624010289","DOIUrl":"10.1107/S2414314624010289","url":null,"abstract":"<div><div>The crystal structure, non-bonding inter­actions and packing features of a novel galactose conjugated porphyrin are presented and discussed.</div></div><div><div>The crystal structure of a glycosyl­ated porphyrin (<strong>P_Gal2</strong>) system, C<sub>70</sub>H<sub>70</sub>N<sub>4</sub>O<sub>12</sub>, where two iso­propyl­idene protected galactose moieties are attached to the <em>meso</em> position of a substituted tetra­aryl porphyrin is reported. This structure reveals that the parent porphyrin is planar, with the galactose moieties positioned above and below the porphyrin macrocycle. This orientation likely prevents porphyrin–porphyrin H-type aggregation, potentially enhancing its efficiency as a photosensitizer in photodynamic therapy. Notable non-bonding C—H⋯O and C—H⋯π inter­actions among adjacent <strong>P_Gal2</strong> systems are observed in this crystal network. Additionally, the tolyl groups of each porphyrin can engage in π–π inter­actions with the delocalized π-systems of neighboring porphyrins.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (265KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 10","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11660175/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142879250","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
1,4-Di­methyl­piperazine-2,3-dione
IUCrData Pub Date : 2024-10-01 DOI: 10.1107/S2414314624009362
Themmila Khamrang , C. Ponraj , Madhukar Hemamalini , G. Jerald Maria Antony , Dhandayutham Saravanan
{"title":"1,4-Di­methyl­piperazine-2,3-dione","authors":"Themmila Khamrang ,&nbsp;C. Ponraj ,&nbsp;Madhukar Hemamalini ,&nbsp;G. Jerald Maria Antony ,&nbsp;Dhandayutham Saravanan","doi":"10.1107/S2414314624009362","DOIUrl":"10.1107/S2414314624009362","url":null,"abstract":"<div><div>In the title compound, C<sub>6</sub>H<sub>10</sub>N<sub>2</sub>O<sub>2</sub>, the piperazine-2,3-dione ring adopts a half-chair conformation. In the crystal, the mol­ecules are linked by weak C—H⋯O hydrogen bonds, forming (010) sheets.</div></div><div><div>In the title compound, C<sub>6</sub>H<sub>10</sub>N<sub>2</sub>O<sub>2</sub>, the piperazine-2,3-dione ring adopts a half-chair conformation. In the crystal, the mol­ecules are linked by weak C—H⋯O hydrogen bonds, forming (010) sheets.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (210KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 10","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11660176/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142879257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
(Z)-N-(2,6-Di­methyl­phen­yl)-1-[(2-meth­oxy­phen­yl)amino]­methanimine oxide methanol monosolvate (Z)- n-(2,6-二甲基-苯基)-1-[(2-甲氧基-苯基)氨基]-甲基亚胺氧化甲醇单溶剂化物。
IUCrData Pub Date : 2024-10-01 DOI: 10.1107/S2414314624009891
David O. Juma , Sizwe J. Zamisa , Wisdom Munzeiwa , Bernard Omondi
{"title":"(Z)-N-(2,6-Di­methyl­phen­yl)-1-[(2-meth­oxy­phen­yl)amino]­methanimine oxide methanol monosolvate","authors":"David O. Juma ,&nbsp;Sizwe J. Zamisa ,&nbsp;Wisdom Munzeiwa ,&nbsp;Bernard Omondi","doi":"10.1107/S2414314624009891","DOIUrl":"10.1107/S2414314624009891","url":null,"abstract":"<div><div>The crystal structure of a zwitterionic unsymmetrical hy­droxy­formamidine methanol monosolvate is reported.</div></div><div><div>In the title solvate, C<sub>16</sub>H<sub>18</sub>N<sub>2</sub>O<sub>2</sub>·CH<sub>4</sub>O, the dihedral angles between the formamidine backbone and the pendant 2-meth­oxy­phenyl and 2,6-di­methyl­phenyl groups are 14.84 (11) and 81.61 (12)°, respectively. In the crystal, the components are linked by C—H⋯O, O—H⋯O and C—H⋯ π hydrogen bonds, generating a supra­molecular chain that extends along the crystallographic <em>a-</em>axis direction.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (212KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 10","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11660174/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142879242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
C-type Yb2Te3O9 C 型 Yb2Te3O9。
IUCrData Pub Date : 2024-09-01 DOI: 10.1107/S2414314624008885
Patrick Höss , Sheng-Chun Chou , Philip L. Russ , Ralf J. C. Locke , Thomas Schleid
{"title":"C-type Yb2Te3O9","authors":"Patrick Höss ,&nbsp;Sheng-Chun Chou ,&nbsp;Philip L. Russ ,&nbsp;Ralf J. C. Locke ,&nbsp;Thomas Schleid","doi":"10.1107/S2414314624008885","DOIUrl":"10.1107/S2414314624008885","url":null,"abstract":"<div><div>Yb<sub>2</sub>Te<sub>3</sub>O<sub>9</sub> is isotypic with Tm<sub>2</sub>Te<sub>3</sub>O<sub>9</sub> and Lu<sub>2</sub>Te<sub>3</sub>O<sub>9</sub> and crystallizes in the <em>C</em>-type modification of <em>Ln</em><sub>2</sub>Te<sub>3</sub>O<sub>9</sub> compounds.</div></div><div><div>The title compound, diytterbium enneaoxidotritellurate(IV), was obtained in its <em>C</em>-type crystal structure from the binary oxides at 1073 K using a CsCl flux. It crystallizes isotypically with <em>C</em>-type Tm<sub>2</sub>Te<sub>3</sub>O<sub>9</sub> and Lu<sub>2</sub>Te<sub>3</sub>O<sub>9</sub>, closing this gap of knowledge.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (180KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11451026/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142383071","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Di-μ-adipato-κ4O1,O1′:O6,O6′-bis­[(2,2′-di­pyridyl­amine-κ2N,N′)zinc(II)] trihydrate 二-μ-己二胺-κ4 O 1,O 1':O 6,O 6'-双-[(2,2'-二-吡啶基-胺-κ2 N,N')锌(II)]三水合物。
IUCrData Pub Date : 2024-09-01 DOI: 10.1107/S2414314624009064
Fatima Setifi , Zouaoui Setifi , Thang Pham Chien , Mohammad Hadi Al-Douh , Abderezak Addala
{"title":"Di-μ-adipato-κ4O1,O1′:O6,O6′-bis­[(2,2′-di­pyridyl­amine-κ2N,N′)zinc(II)] trihydrate","authors":"Fatima Setifi ,&nbsp;Zouaoui Setifi ,&nbsp;Thang Pham Chien ,&nbsp;Mohammad Hadi Al-Douh ,&nbsp;Abderezak Addala","doi":"10.1107/S2414314624009064","DOIUrl":"10.1107/S2414314624009064","url":null,"abstract":"<div><div>The title dinuclear and centrosymmetric complex mol­ecule exhibits a highly distorted octa­hedral O<sub>4</sub>N<sub>2</sub> coordination set about the central zinc(II) atom.</div></div><div><div>The title compound, [Zn<sub>2</sub>(C<sub>6</sub>H<sub>8</sub>O<sub>4</sub>)<sub>2</sub>(C<sub>10</sub>H<sub>9</sub>N<sub>3</sub>)<sub>2</sub>]·3H<sub>2</sub>O or {Zn<sub>2</sub>[(C<sub>5</sub>H<sub>4</sub>N)<sub>2</sub>NH]<sub>2</sub>[μ-(CH<sub>2</sub>)<sub>4</sub>(COO)<sub>2</sub>]<sub>2</sub>}·3H<sub>2</sub>O, was separ­ated from the solvothermal reaction of zinc(II) sulfate hepta­hydrate, 2,2′-di­pyridyl­amine and sodium adipate. The dinuclear metal complex has a centrosymmetric structure, with the Zn<sup>II</sup> atom adopting a highly distorted octa­hedral coordination sphere composed of four oxygen atoms from bridging adipato ligands and two pyridine nitro­gen atoms. In the crystal, the title compound aggregates into a tri-periodic supra­molecular structure through inter­molecular hydrogen-bonding networks of the form O—H⋯O and N—H⋯O.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (235KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11451035/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142383075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Redetermined structure of methyl 3-{4,4-di­fluoro-2-[2-(methoxy­car­bon­yl)­ethyl]-1,3,5,7-tetra­methyl-4-bora-3a,4a-di­aza-s-in­da­cen-6-yl}pro­pion­ate Redetermined structure of methyl 3-{4,4-di-fluoro-2-[2-(methoxy-car-bon-yl)-ethyl]-1,3,5,7-tetra-methyl-4-bora-3a,4a-di-aza-s-in-da-cen-6-yl}pro-pion-ate.
IUCrData Pub Date : 2024-09-01 DOI: 10.1107/S2414314624008848
Dieter Schollmeyer , Matthias Jochen , Heiner Detert
{"title":"Redetermined structure of methyl 3-{4,4-di­fluoro-2-[2-(methoxy­car­bon­yl)­ethyl]-1,3,5,7-tetra­methyl-4-bora-3a,4a-di­aza-s-in­da­cen-6-yl}pro­pion­ate","authors":"Dieter Schollmeyer ,&nbsp;Matthias Jochen ,&nbsp;Heiner Detert","doi":"10.1107/S2414314624008848","DOIUrl":"10.1107/S2414314624008848","url":null,"abstract":"<div><div>In the title compound, a highly fluorescent boron–dipyrromethene dye, the methyl­propionate moieties have different conformations. In the crystal, weak C—H⋯F and C—H⋯O inter­actions link the mol­ecules.</div></div><div><div>In the title compound, C<sub>21</sub>H<sub>27</sub>BF<sub>2</sub>N<sub>2</sub>O<sub>4</sub>, a highly fluorescent boron–dipyrromethene dye, the methyl­propionate moieties have different conformations. In the crystal, weak C—H⋯F and C—H⋯O inter­actions link the mol­ecules. Some optical properties are presented.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (186KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11451027/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142383169","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
(E)-1-(3,4-Di­meth­oxy­phen­yl)-3-(1,3-diphenyl-1H-pyrazol-4-yl)prop-2-en-1-one (E)-1-(3,4-Di-meth-oxy-phen-yl)-3-(1,3-diphenyl-1H-pyrazol-4-yl)prop-2-en-1-one.
IUCrData Pub Date : 2024-09-01 DOI: 10.1107/S2414314624008666
Jiha Sung
{"title":"(E)-1-(3,4-Di­meth­oxy­phen­yl)-3-(1,3-diphenyl-1H-pyrazol-4-yl)prop-2-en-1-one","authors":"Jiha Sung","doi":"10.1107/S2414314624008666","DOIUrl":"10.1107/S2414314624008666","url":null,"abstract":"<div><div>The crystal structure of a pyrazole chalcone is reported.</div></div><div><div>In the title compound, C<sub>26</sub>H<sub>22</sub>N<sub>2</sub>O<sub>3</sub>, the dihedral angle between the benzene and pyrazole rings of the chalcone unit is 88.3 (1)°. The pyrazole ring has two attached phenyl rings that form dihedral angles with the pyrazole ring of 22.6 (2) and 40.0 (1)°. In the crystal, pairwise C—H⋯O hydrogen bonds generate <em>R</em><sup>2</sup><sub>2</sub>(20) inversion dimers.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (250KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11451031/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142383349","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
(1R,2S,4aR,6S,8R,8aS)-1-(3-Hy­droxy­propano­yl)-1,3,6,8-tetra­methyl-1,2,4a,5,6,7,8,8a-octa­hydronaphthalene-2-carb­oxy­lic acid (1R,2S,4aR,6S,8R,8aS)-1-(3-Hy-droxy-propano-yl)-1,3,6,8-tetra-methyl-1,2,4a,5,6,7,8,8a-octa-hydronaphthalene-2-carb-oxy-lic acid.
IUCrData Pub Date : 2024-09-01 DOI: 10.1107/S241431462400885X
Christo J. Botha , Gerda Fouche , Frederick P. Malan
{"title":"(1R,2S,4aR,6S,8R,8aS)-1-(3-Hy­droxy­propano­yl)-1,3,6,8-tetra­methyl-1,2,4a,5,6,7,8,8a-octa­hydronaphthalene-2-carb­oxy­lic acid","authors":"Christo J. Botha ,&nbsp;Gerda Fouche ,&nbsp;Frederick P. Malan","doi":"10.1107/S241431462400885X","DOIUrl":"10.1107/S241431462400885X","url":null,"abstract":"<div><div>The single-crystal structure elucidation of diplodiatoxin, a toxic metabolite of <em>Diplodia maydis</em>, is described.</div></div><div><div>The mol­ecular structure of C<sub>18</sub>H<sub>28</sub>O<sub>4</sub>, (+)-diplodiatoxin, is described, whereby the absolute configuration of the structure of diplodiatoxin has been confirmed by single-crystal X-ray diffraction. Diplodiatoxin crystallizes in the chiral <em>P</em>4<sub>3</sub>2<sub>1</sub>2 space group with one mol­ecule in the asymmetric unit.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (422KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11451037/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142383350","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ti4Fe2C0.82O0.18 Ti4Fe2C0.8O0.18。
IUCrData Pub Date : 2024-09-01 DOI: 10.1107/S2414314624008903
Huizi Liu , Changzeng Fan , Bin Wen , Lifeng Zhang
{"title":"Ti4Fe2C0.82O0.18","authors":"Huizi Liu ,&nbsp;Changzeng Fan ,&nbsp;Bin Wen ,&nbsp;Lifeng Zhang","doi":"10.1107/S2414314624008903","DOIUrl":"10.1107/S2414314624008903","url":null,"abstract":"<div><div>Ti<sub>4</sub>Fe<sub>2</sub>C<sub>0.82</sub>O<sub>0.18</sub> is the first example where C and O atoms co-occupy the same site in filled Ti<sub>2</sub>Fe structures.</div></div><div><div>The phase with composition Ti<sub>4</sub>Fe<sub>2</sub>C<sub>0.82</sub>O<sub>0.18</sub>, tetra­titanium diiron carbide oxide, was unexpectedly synthesized by high-pressure sinter­ing (HPS) of a stoichiometric mixture with nominal composition Ti<sub>2</sub>Fe. The Ti<sub>4</sub>Fe<sub>2</sub>C<sub>0.82</sub>O<sub>0.18</sub> phase crystallizes in the <em>Fd</em><blockquote><div><figure><img></figure></div></blockquote><em>m</em> space group and can be considered as the Ti<sub>2</sub>Fe structure filled with C and O atoms co-occupying the same octa­hedral void [occupancy ratio 0.82 (7):0.18 (7)]. The Ti<sub>4</sub>Fe<sub>2</sub>C<sub>0.82</sub>O<sub>0.18</sub> phase is isotypic with Ti<sub>4</sub>Ni<sub>2</sub>C and Ti<sub>4</sub>Fe<sub>2</sub>O<sub>0.407</sub>, and is the first example where C and O atoms co-occupy the same site in filled Ti<sub>2</sub>Fe structures.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (272KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11451028/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142383170","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
catena-Poly[[(8-amino­quinoline)­cobalt(II)]-di-μ-azido] 链-多[[(8-氨基-喹啉)-钴(II)]-二-μ-叠氮]。
IUCrData Pub Date : 2024-09-01 DOI: 10.1107/S2414314624008496
Fatima Setifi , Zouaoui Setifi , David K. Geiger , Mohammed Hadi Al-Douh , Abderezak Addala
{"title":"catena-Poly[[(8-amino­quinoline)­cobalt(II)]-di-μ-azido]","authors":"Fatima Setifi ,&nbsp;Zouaoui Setifi ,&nbsp;David K. Geiger ,&nbsp;Mohammed Hadi Al-Douh ,&nbsp;Abderezak Addala","doi":"10.1107/S2414314624008496","DOIUrl":"10.1107/S2414314624008496","url":null,"abstract":"<div><div>[Co(C<sub>9</sub>H<sub>8</sub>N<sub>2</sub>)(N<sub>3</sub>)<sub>2</sub>]<sub>n</sub> exhibits a distorted octa­hedral coordination geometry. Bridging azide ligands result in chains along [100].</div></div><div><div>The title coordination polymer, [Co(N<sub>3</sub>)<sub>2</sub>(C<sub>9</sub>H<sub>8</sub>N<sub>2</sub>)]<sub>n</sub>, was synthesized solvothermally. The Co<sup>II</sup> atom exhibits a distorted octa­hedral [CoN<sub>6</sub>] coordination geometry with a bidentate 8-amino­quinoline ligand and four azide ligands. Bridging azide ligands result in chains extending along [100]. N—H⋯N hydrogen bonds join the chains to give an extended structure with sheets parallel to (002).<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (267KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"9 9","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11451032/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142383072","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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