Carolin A. M. Stein , Elisabetta Alberico , Anke Spannenberg , Matthias Beller , Henrik Junge
{"title":"(η4-Trimethylenemethane)(1,1,1-tris{[bis(4-methoxyphenyl)phosphanyl]methyl}ethane)ruthenium(II) diethyl ether hemisolvate","authors":"Carolin A. M. Stein , Elisabetta Alberico , Anke Spannenberg , Matthias Beller , Henrik Junge","doi":"10.1107/S2414314625005243","DOIUrl":null,"url":null,"abstract":"<div><div>In the title complex, the Ru<sup>II</sup> atom is coordinated by a 1,1,1-tris{[bis(4-methoxyphenyl)phosphanyl]methyl}ethane ligand in κ<sup>3</sup>-coordination mode and an η<sup>4</sup>-coordinating trimethylenemethane ligand.</div></div><div><div>The title compound, [Ru(C<sub>47</sub>H<sub>51</sub>O<sub>6</sub>P<sub>3</sub>)(C<sub>4</sub>H<sub>6</sub>)]·0.5C<sub>4</sub>H<sub>10</sub>O, consists of an Ru<sup>II</sup> atom coordinated by 1,1,1-tris{[bis(4-methoxyphenyl)phosphanyl]methyl}ethane in κ<sup>3</sup>-coordination mode and an η<sup>4</sup>-coordinating trimethylenemethane ligand. The complex molecule is co-crystallized with a diethyl ether solvent molecule. A half diethyl ether molecule was considered, whereas additional disordered solvent molecules were removed from the diffraction data with the SQUEEZE procedure in <em>PLATON</em> [Spek (2015<span><span>#</span></span>). <em>Acta Cryst</em>. C<strong>71</strong>, 9–18].<blockquote><div><span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (267KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></blockquote></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 6","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S241431462500046X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract
In the title complex, the RuII atom is coordinated by a 1,1,1-tris{[bis(4-methoxyphenyl)phosphanyl]methyl}ethane ligand in κ3-coordination mode and an η4-coordinating trimethylenemethane ligand.
The title compound, [Ru(C47H51O6P3)(C4H6)]·0.5C4H10O, consists of an RuII atom coordinated by 1,1,1-tris{[bis(4-methoxyphenyl)phosphanyl]methyl}ethane in κ3-coordination mode and an η4-coordinating trimethylenemethane ligand. The complex molecule is co-crystallized with a diethyl ether solvent molecule. A half diethyl ether molecule was considered, whereas additional disordered solvent molecules were removed from the diffraction data with the SQUEEZE procedure in PLATON [Spek (2015#). Acta Cryst. C71, 9–18].
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