Carolin A M Stein, Elisabetta Alberico, Anke Spannenberg, Matthias Beller, Henrik Junge
{"title":"(η<sup>4</sup>-Tri-methyl-ene-methane)(1,1,1-tris-{[bis-(4-meth-oxy-phen-yl)phosphan-yl]meth-yl}ethane)ruthenium(II) diethyl ether hemisolvate.","authors":"Carolin A M Stein, Elisabetta Alberico, Anke Spannenberg, Matthias Beller, Henrik Junge","doi":"10.1107/S2414314625005243","DOIUrl":null,"url":null,"abstract":"<p><p>The title compound, [Ru(C<sub>47</sub>H<sub>51</sub>O<sub>6</sub>P<sub>3</sub>)(C<sub>4</sub>H<sub>6</sub>)]·0.5C<sub>4</sub>H<sub>10</sub>O, consists of an Ru<sup>II</sup> atom coordinated by 1,1,1-tris-{[bis-(4-meth-oxy-phen-yl)phosphan-yl]meth-yl}ethane in κ<sup>3</sup>-coordination mode and an η<sup>4</sup>-coordinating tri-methyl-ene-methane ligand. The complex mol-ecule is co-crystallized with a diethyl ether solvent mol-ecule. A half diethyl ether mol-ecule was considered, whereas additional disordered solvent mol-ecules were removed from the diffraction data with the SQUEEZE procedure in <i>PLATON</i> [Spek (2015 ▸). <i>Acta Cryst</i>. C<b>71</b>, 9-18].</p>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 Pt 6","pages":"x250524"},"PeriodicalIF":0.0000,"publicationDate":"2025-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12230594/pdf/","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1107/S2414314625005243","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/6/1 0:00:00","PubModel":"eCollection","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
The title compound, [Ru(C47H51O6P3)(C4H6)]·0.5C4H10O, consists of an RuII atom coordinated by 1,1,1-tris-{[bis-(4-meth-oxy-phen-yl)phosphan-yl]meth-yl}ethane in κ3-coordination mode and an η4-coordinating tri-methyl-ene-methane ligand. The complex mol-ecule is co-crystallized with a diethyl ether solvent mol-ecule. A half diethyl ether mol-ecule was considered, whereas additional disordered solvent mol-ecules were removed from the diffraction data with the SQUEEZE procedure in PLATON [Spek (2015 ▸). Acta Cryst. C71, 9-18].
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