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4,4-Dimethyl-2-phenyl-4,5-di­hydro­pyrrolo­[2,3,4-kl]acridin-1(2H)-one 4 4-Dimethyl-2-phenyl-4 5-di-hydro-pyrrolo -[2、3、4-kl] acridin-1——(2 h)。
IUCrData Pub Date : 2025-04-01 DOI: 10.1107/S241431462500361X
Izarul Islam , Pijush Kanti Roy , Ennio Zangrando , Pran Gopal Karmaker , Harendra Nath Roy
{"title":"4,4-Dimethyl-2-phenyl-4,5-di­hydro­pyrrolo­[2,3,4-kl]acridin-1(2H)-one","authors":"Izarul Islam ,&nbsp;Pijush Kanti Roy ,&nbsp;Ennio Zangrando ,&nbsp;Pran Gopal Karmaker ,&nbsp;Harendra Nath Roy","doi":"10.1107/S241431462500361X","DOIUrl":"10.1107/S241431462500361X","url":null,"abstract":"<div><div>In the title compound, the pendant phenyl ring is twisted by 43.85 (1)° with respect to the acridine moiety. The extended structure features aromatic π–π stacking with a centroid-to-centroid distance of 3.489 (2) Å and weak C—H⋯O hydrogen bonds.</div></div><div><div>In the title compound, C<sub>22</sub>H<sub>18</sub>N<sub>2</sub>O, the pendant phenyl ring is twisted by 43.85 (1)° with respect to the acridine moiety, which has almost coplanar atoms apart from the <em>sp</em><sup>3</sup> carbon atoms. The extended structure features aromatic π–π stacking with a centroid-to-centroid distance of 3.489 (2) Å and weak C—H⋯O hydrogen bonds.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (234KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144065517","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
(E)-N-[4-(Di­ethyl­amino)-2-hy­droxy­benzyl­idene]-2,4,6-tri­methyl­benzenaminium nitrate (E) - n - [4 - (Di-ethyl-amino) 2-hy-droxy-benzyl-idene] 2, 4, 6-tri-methyl-benzenaminium硝酸盐。
IUCrData Pub Date : 2025-04-01 DOI: 10.1107/S2414314625002779
Segun D. Oladipo , Sizwe J. Zamisa , Robert C. Luckay
{"title":"(E)-N-[4-(Di­ethyl­amino)-2-hy­droxy­benzyl­idene]-2,4,6-tri­methyl­benzenaminium nitrate","authors":"Segun D. Oladipo ,&nbsp;Sizwe J. Zamisa ,&nbsp;Robert C. Luckay","doi":"10.1107/S2414314625002779","DOIUrl":"10.1107/S2414314625002779","url":null,"abstract":"<div><div>The crystal structure of a protonated Schiff base, isolated as its nitrate salt, exhibits a supra­molecular chain-like architecture that propagates along the crystallographic <em>b</em>-axis direction and features inter­molecular O—H⋯O and C—H⋯O hydrogen-bonding.</div></div><div><div>The crystal structure of the title salt, C<sub>20</sub>H<sub>27</sub>N<sub>2</sub>O<sup>+</sup>·NO<sub>3</sub><sup>−</sup>, has a cationic (<em>E</em>)-mesityl-<em>N</em>-[4-(di­ethyl­amino)­benzyl­idene]benzenaminium species and a nitrate counter-ion in the asymmetric-unit. In the crystal, alternating inter­molecular O—H⋯O and C—H⋯O hydrogen-bonding occurs between neighbouring protonated Schiff bases and nitrate ions within a supra­molecular, chain-like architecture that extends along the crystallographic <em>b</em>-axis direction.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (211KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144060079","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
2-[(5-Methyl-1,3,4-thia­diazol-2-yl)sulfan­yl]-N′-(4-nitro­benzyl­idene)acetohydrazide monohydrate 2 - [(5-Methyl-1 3 4-thia-diazol-2-yl) sulfan-yl] - n ' - (4-nitro-benzyl-idene) acetohydrazide一水。
IUCrData Pub Date : 2025-04-01 DOI: 10.1107/S2414314625003645
Murugan Nidhishree , Sundaramoorthy Gomathi , Jeyaraman Selvaraj Nirmalram , Logesh Mathivathanan
{"title":"2-[(5-Methyl-1,3,4-thia­diazol-2-yl)sulfan­yl]-N′-(4-nitro­benzyl­idene)acetohydrazide monohydrate","authors":"Murugan Nidhishree ,&nbsp;Sundaramoorthy Gomathi ,&nbsp;Jeyaraman Selvaraj Nirmalram ,&nbsp;Logesh Mathivathanan","doi":"10.1107/S2414314625003645","DOIUrl":"10.1107/S2414314625003645","url":null,"abstract":"<div><div>In the title hydrate, the dihedral angle between the aromatic rings is 9.6 (3)°. In the crystal, N—H⋯O and O—H⋯N hydrogen bonds link the components into (101) sheets.</div></div><div><div>In the title hydrate, C<sub>12</sub>H<sub>11</sub>N<sub>5</sub>O<sub>3</sub>S<sub>2</sub>·H<sub>2</sub>O, the dihedral angle between the aromatic rings is 9.6 (3)°. In the crystal, N—H⋯O and O—H⋯N hydrogen bonds link the components into (101) sheets.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (184KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144056739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
CaCu1.424Fe0.576Si2
IUCrData Pub Date : 2025-04-01 DOI: 10.1107/S2414314625003256
Yangkun Dai , Yibo Liu , Marek Mihalkovic , Bin Wen , Lifeng Zhang , Changzeng Fan
{"title":"CaCu1.424Fe0.576Si2","authors":"Yangkun Dai ,&nbsp;Yibo Liu ,&nbsp;Marek Mihalkovic ,&nbsp;Bin Wen ,&nbsp;Lifeng Zhang ,&nbsp;Changzeng Fan","doi":"10.1107/S2414314625003256","DOIUrl":"10.1107/S2414314625003256","url":null,"abstract":"<div><div>A CaCu<sub>1.424</sub>Fe<sub>0.576</sub>Si<sub>2</sub> phase was obtained during high-pressure sinter­ing of an Si-rich quasicrystal composition prealloy with the nominal chemical com­position Si<sub>61</sub>Cu<sub>30</sub>Ca<sub>7</sub>Fe<sub>2</sub>. The obtained phase crystallizes in the space group <em>I</em>4/<em>mmm</em> (No. 139), with <em>a</em> = <em>b</em> = 4.041 Å and <em>c</em> = 10.010 Å.</div></div><div><div>A CaCu<sub>1.424</sub>Fe<sub>0.576</sub>Si<sub>2</sub> phase was obtained during high-pressure sinter­ing of an Si-rich quasicrystal composition prealloy with the nominal chemical com­position Si<sub>61</sub>Cu<sub>30</sub>Ca<sub>7</sub>Fe<sub>2</sub>. The obtained phase crystallizes in the space group <em>I</em>4/<em>mmm</em> (No. 139), with <em>a</em> = <em>b</em> = 4.041 Å and <em>c</em> = 10.010 Å. It is isotypic with CaCu<sub>2</sub>Si<sub>2</sub> (<em>a</em> = <em>b</em> = 4.06 Å and <em>c</em> = 9.91 Å) [Palenzona <em>et al.</em> (1986<span><span>#</span></span>). <em>J. Less-Common Met.</em><strong>119</strong>, 199–209] and CaFe<sub>2</sub>Si<sub>2</sub> (<em>a</em> = <em>b</em> = 3.94 Å and <em>c</em> = 10.19 Å) [Hlukhyy <em>et al.</em> (2012<span><span>#</span></span>). <em>Z. Anorg. Allg. Chem.</em><strong>638</strong>, 1619–1619]. It features a co-occupancy of Cu and Fe atoms with a ratio of the refined site-occupancy factors of 0.71 (15):0.29 (15).<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (93KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 4","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144056474","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
rac-4H,5H,6H,7H,8H,9H,10H,11H-Cyclo­deca­[d][1,2,3]selena­diazole-8-carb­oxy­lic acid rac-4H 5 h、6 h, 7 h, 8 h, h, 9 10 h, 11 h-cyclo-deca - [d] [1, 2, 3] selena-diazole-8-carb-oxy-lic酸
IUCrData Pub Date : 2025-03-01 DOI: 10.1107/S2414314625002421
Dieter Schollmeyer , Heiner Detert
{"title":"rac-4H,5H,6H,7H,8H,9H,10H,11H-Cyclo­deca­[d][1,2,3]selena­diazole-8-carb­oxy­lic acid","authors":"Dieter Schollmeyer ,&nbsp;Heiner Detert","doi":"10.1107/S2414314625002421","DOIUrl":"10.1107/S2414314625002421","url":null,"abstract":"<div><div>The chair-shaped mol­ecules in the crystal consist in two pairs of enanti­omers with two conformations (ratio 1:3), differing only in the position of two ring carbon atoms.</div></div><div><div>The chair-shaped mol­ecules in the title crystal, C<sub>11</sub>H<sub>16</sub>N<sub>2</sub>O<sub>2</sub>Se, consist of two pairs of enanti­omers with two conformations (ratio 1:3), differing only in the position of two ring carbon atoms. Two mol­ecules are connected <em>via</em> carb­oxy­lic acid hydrogen bridges.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (249KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143767676","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
2-Oxo-2H-chromen-7-yl tert-butyl­acetate 2-Oxo-2H-chromen-7-yl tert-butyl-acetate
IUCrData Pub Date : 2025-03-01 DOI: 10.1107/S2414314625001890
Hypolite Bazié , Eric Ziki , Sorgho Brahima , Veroarisinima Ratsimbazafy , Patrick Roge , Emmanuel Wenger , Abdoulaye Djandé , Claude Lecomte
{"title":"2-Oxo-2H-chromen-7-yl tert-butyl­acetate","authors":"Hypolite Bazié ,&nbsp;Eric Ziki ,&nbsp;Sorgho Brahima ,&nbsp;Veroarisinima Ratsimbazafy ,&nbsp;Patrick Roge ,&nbsp;Emmanuel Wenger ,&nbsp;Abdoulaye Djandé ,&nbsp;Claude Lecomte","doi":"10.1107/S2414314625001890","DOIUrl":"10.1107/S2414314625001890","url":null,"abstract":"<div><div>In the title compound, the dihedral angle between the 2<em>H</em>-chromen-2-one ring system and the <em>tert</em>-butyl­acetate moiety is 72.72 (9)°. In the crystal, the mol­ecules are connected through C—H⋯O hydrogen bonds, generating <em>C</em>(6) chains and <em>R</em><sub>2</sub><sup>2</sup>(20) loops that are reinforced by weak aromatic π–π stacking inter­actions.</div></div><div><div>In the title compound, C<sub>15</sub>H<sub>16</sub>O<sub>4</sub>, the dihedral angle between the 2<em>H</em>-chromen-2-one ring system and the <em>tert</em>-butyl­acetate moiety is 72.72 (9)°. In the crystal, the mol­ecules are connected through C—H⋯O hydrogen bonds, generating <em>C</em>(6) chains and <em>R</em><sub>2</sub><sup>2</sup>(20) loops that are reinforced by weak aromatic π–π stacking inter­actions. The H⋯H, H⋯O/O⋯H, H⋯C/C⋯H and C⋯C contacts contribute 50.6, 29.1, 8.5 and 6.8%, respectively, to the Hirshfeld surface.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (193KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143767672","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
(E)-1-(2-Hy­droxy­phen­yl)-3-(3-meth­oxy­phen­yl)prop-2-en-1-one (E) 1 - (2-Hy-droxy-phen-yl) 3 - (3-meth-oxy-phen-yl) prop-2-en-1-one
IUCrData Pub Date : 2025-03-01 DOI: 10.1107/S2414314625001828
Farid N. Naghiyev , Tuncer Hökelek , Victor N. Khrustalev , Anna Yu Zueva , Khammed A. Asadov , Alebel N. Belay , Ibrahim G. Mamedov
{"title":"(E)-1-(2-Hy­droxy­phen­yl)-3-(3-meth­oxy­phen­yl)prop-2-en-1-one","authors":"Farid N. Naghiyev ,&nbsp;Tuncer Hökelek ,&nbsp;Victor N. Khrustalev ,&nbsp;Anna Yu Zueva ,&nbsp;Khammed A. Asadov ,&nbsp;Alebel N. Belay ,&nbsp;Ibrahim G. Mamedov","doi":"10.1107/S2414314625001828","DOIUrl":"10.1107/S2414314625001828","url":null,"abstract":"<div><div>The title compound contains two almost coplanar phenyl rings and an intra­molecular O—H⋯O hydrogen bond.</div></div><div><div>In the title compound, C<sub>16</sub>H<sub>14</sub>O<sub>3</sub>, the phenyl rings are oriented at a dihedral angle of 3.82 (3)° and an intra­molecular O—H⋯O hydrogen bond closes an <em>S</em>(6) ring. In the crystal, weak C—H⋯O and C—H⋯π hydrogen bonds and aromatic π–π stacking occurs. A Hirshfeld surface analysis of the crystal structure indicates that the most important contributions for the crystal packing are from H⋯H (48.2%), H⋯O/O⋯H (20.0%), H⋯C/C⋯H (16.5%) and C⋯C (12.7%) inter­actions.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (177KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143767670","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
2-[3-(1H-Benzimidazol-2-yl)prop­yl]-1H-benzimidazol-3-ium 3,4,5-tri­hydroxy­benzoate trihydrate 2-[3-（1h -苯并咪唑-2-基）丙基]- 1h -苯并咪唑-3-ium 3,4,5-三羟基苯甲酸三水合物
IUCrData Pub Date : 2025-03-01 DOI: 10.1107/S2414314625002561
José Carlos Palacios Rodríguez , Angel Mendoza , Martha Sosa Rivadeneyra , Sylvain Bernès
{"title":"2-[3-(1H-Benzimidazol-2-yl)prop­yl]-1H-benzimidazol-3-ium 3,4,5-tri­hydroxy­benzoate trihydrate","authors":"José Carlos Palacios Rodríguez ,&nbsp;Angel Mendoza ,&nbsp;Martha Sosa Rivadeneyra ,&nbsp;Sylvain Bernès","doi":"10.1107/S2414314625002561","DOIUrl":"10.1107/S2414314625002561","url":null,"abstract":"<div><div>A layered crystal structure built up from alternating cationic and (anionic + water of crystallization) supra­molecular planes parallel to (100) is described for the title hydrated salt.</div></div><div><div>The characterized organic trihydrate title salt, C<sub>17</sub>H<sub>17</sub>N<sub>4</sub><sup>+</sup>·C<sub>7</sub>H<sub>5</sub>O<sub>5</sub><sup>−</sup>·3H<sub>2</sub>O or (H<em>L</em>)<sup>+</sup>(Gal)<sup>−</sup>·3H<sub>2</sub>O, with <em>L</em> = 1,3-bis­(1<em>H</em>-benzimidazol-2-yl)propane (C<sub>17</sub>H<sub>16</sub>N<sub>4</sub>) and HGal = 3,4,5-tri­hydroxy­benzoic acid (gallic acid, C<sub>7</sub>H<sub>6</sub>O<sub>5</sub>), crystallizes with two formulas per asymmetric unit. One-half of the cations in the crystal feature a bent shape, with the central propyl chain having a <em>gauche</em> conformation, and the other half is nearly linear, with a <em>trans</em> propyl chain. Both cations form two independent herringbone layers in the crystal, which allow efficient π–π inter­actions between aromatic rings of the benzimidazole moieties. These layers are parallel to (100), and anions and water mol­ecules of crystallization inter­calate between these cationic planes. All potential donor groups for hydrogen bonding (NH and OH groups) actually form hydrogen bonds, ensuring a good cohesion between layers of cations and anions, stacked along [100].<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (304KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143767675","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bis[(2-meth­oxy­phen­yl)di­phenyl­phosphane-κP](nitrito-κ2O,O′)silver(I) Bis ((2-meth-oxy-phen-yl) di-phenyl-phosphane -κP] (nitrito -κ2 O, O ')银(我)
IUCrData Pub Date : 2025-03-01 DOI: 10.1107/S2414314625001932
Frederick P. Malan , Kariska Potgieter , Reinout Meijboom
{"title":"Bis[(2-meth­oxy­phen­yl)di­phenyl­phosphane-κP](nitrito-κ2O,O′)silver(I)","authors":"Frederick P. Malan ,&nbsp;Kariska Potgieter ,&nbsp;Reinout Meijboom","doi":"10.1107/S2414314625001932","DOIUrl":"10.1107/S2414314625001932","url":null,"abstract":"<div><div>The synthesis and single-crystal structure description of a silver(I) diphenyl-2-meth­oxy­phenyl­phosphine nitrite complex is described.</div></div><div><div>The mol­ecular structure of the title Ag<sup>I</sup> complex, [Ag(NO<sub>2</sub>)(C<sub>19</sub>H<sub>17</sub>OP)<sub>2</sub>], is described, where a distorted tetra­hedral coordination environment for the Ag<sup>I</sup> atom is apparent within a O<sub>2</sub>P<sub>2</sub> donor set as the nitrito anion coordinates in a bidentate mode. A fairly large angle for P—Ag—P [129.126 (16)°] is noted. The O—Ag—O chelate angle is = 50.38 (6)° and the P—Ag—O angles lie in the range 99.51 (5) to 118.45 (6)°. In the crystal, C—H⋯O inter­actions are evident.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (432KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143767678","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chlorido­{2-[(4-chloro­phen­yl)imino­meth­yl]pyridine-κ2N,N′}(η6-toluene)­ruthenium(II) hexa­fluoridophosphate Chlorido - {2 - [(4-chloro-phen-yl) imino-meth-yl]吡啶-κ2 N, N '}(η6-toluene)钌(II) hexa-fluoridophosphate
IUCrData Pub Date : 2025-03-01 DOI: 10.1107/S2414314625001038
Joel Gichumbi , Holger B. Friedrich , Sizwe J. Zamisa
{"title":"Chlorido­{2-[(4-chloro­phen­yl)imino­meth­yl]pyridine-κ2N,N′}(η6-toluene)­ruthenium(II) hexa­fluoridophosphate","authors":"Joel Gichumbi ,&nbsp;Holger B. Friedrich ,&nbsp;Sizwe J. Zamisa","doi":"10.1107/S2414314625001038","DOIUrl":"10.1107/S2414314625001038","url":null,"abstract":"<div><div>The crystal structure of an arene ruthenium(II) complex bearing a bidentate Schiff base ligand is reported.</div></div><div><div>The asymmetric unit of the title compound, [RuCl(C<sub>7</sub>H<sub>8</sub>)(C<sub>12</sub>H<sub>9</sub>ClN<sub>2</sub>)]PF<sub>6</sub>, contains two cationic ruthenium(II) complexes and two [PF<sub>6</sub>]<sup>−</sup> anions. One of the anions exhibits disorder over two positions. The ruthenium complex adopts a piano-stool geometry, with chelating Schiff base and chlorido ligands occupying three coordination sites, and the arene ring serving as the ‘seat’.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (278KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143767674","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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