Claire E Welton, Eric W Reinheimer, Bradley W Smucker
{"title":"双（4,4'-联吡啶-1-ium）顺式-双-（1,2-二氰-2-硫-乙烯-1-硫-κ 2s，S'）铂酸盐（2-）。","authors":"Claire E Welton, Eric W Reinheimer, Bradley W Smucker","doi":"10.1107/S2414314625003839","DOIUrl":null,"url":null,"abstract":"<p><p>Crystals of the sulfinate-containing platinate salt, (C<sub>10</sub>H<sub>9</sub>N<sub>2</sub>)<sub>2</sub>[Pt(C<sub>4</sub>N<sub>2</sub>O<sub>2</sub>S<sub>2</sub>)<sub>2</sub>], were obtained from a solution of [Pt(4,4'-bpy)<sub>2</sub>(mnt)] after a long period with minimal light (4,4'-bpy is 4,4'-bi-pyridine and mnt is maleo-nitrile-dithiol-ate). In the crystals, the cations associate via C-H⋯O hydrogen bonds with hydrogen bonded (-H⋯) chains of pyridinium anions. The <i>cis</i>-geometry of the sulfinate around the square-planar platinum atom, coupled with a torsion of one of the rings of the pyridinium, engenders multiple hydrogen bonds between the sulfinate oxygen atoms and the pyridinium hydrogen atoms.</p>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 Pt 5","pages":"x250383"},"PeriodicalIF":0.0000,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12142385/pdf/","citationCount":"0","resultStr":"{\"title\":\"Bis(4,4'-bipyridin-1-ium) <i>cis</i>-bis-(1,2-di-cyano-2-sulfido-ethene-1-sulfinato-κ<sup>2</sup> <i>S</i>,<i>S</i>')platinate(2-).\",\"authors\":\"Claire E Welton, Eric W Reinheimer, Bradley W Smucker\",\"doi\":\"10.1107/S2414314625003839\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>Crystals of the sulfinate-containing platinate salt, (C<sub>10</sub>H<sub>9</sub>N<sub>2</sub>)<sub>2</sub>[Pt(C<sub>4</sub>N<sub>2</sub>O<sub>2</sub>S<sub>2</sub>)<sub>2</sub>], were obtained from a solution of [Pt(4,4'-bpy)<sub>2</sub>(mnt)] after a long period with minimal light (4,4'-bpy is 4,4'-bi-pyridine and mnt is maleo-nitrile-dithiol-ate). In the crystals, the cations associate via C-H⋯O hydrogen bonds with hydrogen bonded (-H⋯) chains of pyridinium anions. The <i>cis</i>-geometry of the sulfinate around the square-planar platinum atom, coupled with a torsion of one of the rings of the pyridinium, engenders multiple hydrogen bonds between the sulfinate oxygen atoms and the pyridinium hydrogen atoms.</p>\",\"PeriodicalId\":94324,\"journal\":{\"name\":\"IUCrData\",\"volume\":\"10 Pt 5\",\"pages\":\"x250383\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2025-05-23\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12142385/pdf/\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"IUCrData\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1107/S2414314625003839\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2025/5/1 0:00:00\",\"PubModel\":\"eCollection\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1107/S2414314625003839","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/5/1 0:00:00","PubModel":"eCollection","JCR":"","JCRName":"","Score":null,"Total":0}
Crystals of the sulfinate-containing platinate salt, (C10H9N2)2[Pt(C4N2O2S2)2], were obtained from a solution of [Pt(4,4'-bpy)2(mnt)] after a long period with minimal light (4,4'-bpy is 4,4'-bi-pyridine and mnt is maleo-nitrile-dithiol-ate). In the crystals, the cations associate via C-H⋯O hydrogen bonds with hydrogen bonded (-H⋯) chains of pyridinium anions. The cis-geometry of the sulfinate around the square-planar platinum atom, coupled with a torsion of one of the rings of the pyridinium, engenders multiple hydrogen bonds between the sulfinate oxygen atoms and the pyridinium hydrogen atoms.
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