Natasha J. Chrisandina, Aovi A. Deshpande, Fahad M. Al-Fadhli, Eleftherios Iakovou, Mahmoud M. El-Halwagi, Efstratios N. Pistikopoulos
{"title":"Integration of risk, flexibility, and resilience in the optimization of water–energy nexus","authors":"Natasha J. Chrisandina, Aovi A. Deshpande, Fahad M. Al-Fadhli, Eleftherios Iakovou, Mahmoud M. El-Halwagi, Efstratios N. Pistikopoulos","doi":"10.1002/cjce.25316","DOIUrl":"10.1002/cjce.25316","url":null,"abstract":"<p>Co-location of power plants and desalination systems allows for a reduction in operational expense through energy integration. Furthermore, augmenting fossil-based power plants with solar energy provides a means of reducing the carbon footprint of electricity generation. It is also critical to protect the combined energy–water system against internal and external risk factors to maintain a reliable supply of both electricity and water. Therefore, a systematic approach for assessing and mitigating risks is needed. Because of the complex water–energy interactions, a superstructure representation is created and a quantitative risk assessment is conducted to show potential risk factors that target specific sub-systems. A surrogate model of the flexibility index analysis is built in order to optimize the superstructure for both cost and flexibility objectives. Finally, the generated design is simulated against disruption scenarios to obtain its resilience against various risk factors. This approach is applied to a case study on the Kuwait water–energy plant to show how the developed approach can help decision-makers create operational strategies to protect against risk in a cost-effective manner.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 1","pages":"28-41"},"PeriodicalIF":1.6,"publicationDate":"2024-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141114941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mitchell T. E. Zak, Nicolas A. R. Carunungan, Vladimiros G. Papangelakis, D. Grant Allen
{"title":"Desorption of rare earth elements biosorbed on Euglena mutabilis suspensions and biofilms","authors":"Mitchell T. E. Zak, Nicolas A. R. Carunungan, Vladimiros G. Papangelakis, D. Grant Allen","doi":"10.1002/cjce.25344","DOIUrl":"10.1002/cjce.25344","url":null,"abstract":"<p>Increasing demand for rare earth elements (REEs) has stimulated research on novel recovery methods from sources like industrial effluents. Our recent study demonstrated that algal biofilms are good candidates for the adsorption of REEs and that the extracellular polymeric substances (EPS) within the biofilm were a key accumulator of REEs. In this work, we measured the desorption kinetics, extents, and selectivity of REEs from the algae <i>Euglena mutabilis</i> in suspensions and biofilms using aqueous solutions of HCl at pH between 1.5 and 4, and Na<sub>2</sub>EDTA at pH 5. We examined the potential for reusing suspended and biofilm biomass for repeated adsorption–desorption cycles. The desorption kinetics were similar for suspensions and biofilms, with equilibrium being reached within 20 min. The extent of desorption was higher in biofilms with 86% and 95% desorption, compared to suspensions which had 72% and 74% desorption using HCl and Na<sub>2</sub>EDTA, respectively. We postulate that the difference between suspensions and biofilms is attributed to the binding sites in the EPS matrix of the biofilm being more readily protonated than those at the algal cell wall surface. Heavy REEs were found to preferentially desorb at pH 4 over lighter REEs. After 3 repeated adsorption–desorption cycles, the adsorption capacity of biofilms increased by 280% and 80% using HCl and Na<sub>2</sub>EDTA, respectively, compared to an 80% decrease in biosorption capacity for the suspension. The increase in biofilm biosorption capacity was attributed to the simultaneous desorption of divalent cations alongside REEs from the EPS increasing the number of available binding sites.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"102 12","pages":"4175-4182"},"PeriodicalIF":1.6,"publicationDate":"2024-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cjce.25344","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141114221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gang Yue, Yu Liu, Yong-hua Qin, Zong-ming Tian, Xin-mei Zhao, Xiao-xue Liu, Zhen Du, Xin-bo Zhang, Xu-qiang Guo
{"title":"Effect of ionic liquid on CH4 hydrate formation thermodynamics","authors":"Gang Yue, Yu Liu, Yong-hua Qin, Zong-ming Tian, Xin-mei Zhao, Xiao-xue Liu, Zhen Du, Xin-bo Zhang, Xu-qiang Guo","doi":"10.1002/cjce.25313","DOIUrl":"10.1002/cjce.25313","url":null,"abstract":"<p>In this work, experiment results of CH<sub>4</sub> hydrate formation pressure in four imidazole ionic liquid solutions have been determined. Hydrogen bond interaction between ionic liquids and water molecules has been simulated by conductor like screening model for real solvents model (COSMO-RS). Hydrogen bond energy has been calculated. Variation of hydrogen bond energy between ionic liquid and water molecules was obtained by COSMO-RS simulation. The inhibition effect of four ionic liquids on water activity was listed from strong to weak in order: [BMIm]Br > [BMIm]BF<sub>4</sub> > [BMIm]PF<sub>6</sub> > [OMIm]BF<sub>4</sub>. Compared with experimental results of CH<sub>4</sub> hydrate formation pressure in ionic liquid aqueous solution, hydrogen bond interaction between ionic liquid and water molecules obtained by COSMO-RS is basically consistent with experimental results of hydrate formation pressure in ionic liquid. The study could provide better theoretical basis for ionic liquid selection on gas hydrate study. The simulation would be better as one method to chose admirable ionic liquid in the area of hydrate additives usage.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"102 12","pages":"4440-4451"},"PeriodicalIF":1.6,"publicationDate":"2024-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141114772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The uniqueness of flexible and mouldable thermal insulation materials in thermal protection systems—A comprehensive review","authors":"Kamna Chaturvedi, Manish Dhangar, Ayushi Jaiswal, Avanish Kumar Srivastava, Sarika Verma","doi":"10.1002/cjce.25278","DOIUrl":"10.1002/cjce.25278","url":null,"abstract":"<p>In thermal control and safety systems, thermal insulation materials which are lightweight and flexible with hierarchical microstructures are commonly used nowadays. Flexible thermal insulation materials are designed to prevent heat transfer between two surfaces. These materials have various applications, from building insulation to automotive components, aerospace, and industrial processes. This review aims to provide an overview of flexible thermal insulation materials, their properties, and their applications. The most commonly used materials used for flexible thermal insulation are aerogels, ceramic fibres, and polymers. These materials are lightweight, durable, and have excellent thermal insulation properties and are also gaining popularity due to their unique characteristics. The insulation performance of flexible thermal insulation materials is influenced by thickness, density, porosity, and thermal conductivity factors. The choice of insulation material and its properties depend on the application site and the desired thermal insulation. The literature shows that nanofibrils-based insulating materials have low thermal conductivity values and can be excellent flexible thermal insulating materials. Using flexible thermal insulation materials is crucial in reducing energy consumption and dissipation, enhancing thermal efficiency, and improving sustainability in various industries.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"102 10","pages":"3372-3390"},"PeriodicalIF":1.6,"publicationDate":"2024-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140971580","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Omniphobic/superhydrophobic surface effect on oil and gas flow: A critical review","authors":"Mehedi Hasan, Baojiang Sun, Mihoubi Bahaeddine, Youran Liang, Moses Damulira, Litao Chen","doi":"10.1002/cjce.25310","DOIUrl":"10.1002/cjce.25310","url":null,"abstract":"<p>Flow assurance in the petroleum business of the oil and gas industry ensures the efficient and continuous flow of hydrocarbons from production facilities to consumers. Impurities in oil and gas can cause corrosion and erosion, hydrate formation, scaling, and fouling, resulting in flow limits and reduced operating efficiency. The significant flow assurance issues must be managed through systematic exploration of effective mitigation and management approaches. The objective of this paper is to highlight the latest research in the field of flow assurance, including the application of superhydrophobic or omniphobic coatings to prevent scale growth, asphaltene precipitation, wax deposition, and hydrate formation. This review will provide new perspectives into the basic mechanistic mechanisms of deposition and blockage in oil and gas production systems, assisting in the development of novel methods compared to the employment of commercial chemical or mechanical techniques. Overall, the flow assurance engineers will gain new perspectives from this study regarding how to deal with the risk of pipeline blockage caused by the problems mentioned earlier.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"102 12","pages":"4241-4266"},"PeriodicalIF":1.6,"publicationDate":"2024-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140967867","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synthesis of low cost cathode electrocatalyst Pt-Ni/CAB using DMSO as a solvent for low temperature proton exchange membrane fuel cell application","authors":"Abhay Pratap Singh, Hiralal Pramanik","doi":"10.1002/cjce.25306","DOIUrl":"10.1002/cjce.25306","url":null,"abstract":"<p>In the present study, low cost platinum based bimetallic electrocatalyst Pt-Ni/C<sub>AB</sub> with varying Pt to Ni atomic ratios 3:1, 1:1, and 1:3 were successfully synthesized for oxygen reduction reaction (ORR) of the developed proton exchange membrane fuel cell (PEMFC). The solvothermal process was adopted for the synthesis of Pt-Ni(3:1)/C<sub>AB</sub>, Pt-Ni(1:1)/C<sub>AB</sub>, and Pt-Ni(1:3)/C<sub>AB</sub> using dimethyl sulfoxide (DMSO) as solvent at a temperature of 190°C which is very close to the boiling point. The Pt-Ni/C<sub>AB</sub> exhibited the highest activity for the ORR in half-cell and single cell PEMFC performance. The electrocatalysts Pt-Ni(1:3)/C<sub>AB</sub> appeared with smallest crystalline FCC structures having crystallite size of 8.33 nm. The transmission electron microscopy (TEM) analysis also show that the Pt-Ni(1:3)/C<sub>AB</sub> has smallest particle size of 1.67 ± 0.45 nm. The cyclic voltammetry (CV) analysis shows Pt-Ni(1:3)/C<sub>AB</sub> electrocatalyst offers less activation loss at ORR peak at a potential of 0.16 V as compared to Pt-Ni(3:1)/C<sub>AB</sub> (ORR peak – 0.12) and Pt-Ni(1:1)/C<sub>AB</sub> (ORR peak – 0.11). The synthesized Pt-Ni(1:3)/C<sub>AB</sub> produced a maximum power density of 18.86 mW/cm<sup>2</sup> at a maximum current density of 44.8 mA/cm<sup>2</sup> with an open-circuit voltage of 0.914 V at a room temperature of 33°C. The power density improved around 1.34 times when the cell temperature was raised from 33 to 70°C. The Pt-Ni(1:3)/C<sub>AB</sub> cathode electrocatalyst could be used as economical to substitute costly commercial pure platinum based electrocatalyst.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"102 11","pages":"4007-4025"},"PeriodicalIF":1.6,"publicationDate":"2024-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140971203","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The effect of PVP and PVA on hydrate formation kinetics of ethane and propane mixture in the presence of kaolin nanoparticles","authors":"J. Kiani, P. Gholami, F. Makenali, M. Bahrami","doi":"10.1002/cjce.25305","DOIUrl":"10.1002/cjce.25305","url":null,"abstract":"<p>The blockage of gas transmission pipelines due to gas hydrates poses a significant challenge for the gas industry. Low-dosage hydrate inhibitors (LDHI) are utilized to influence the kinetics of hydrate formation, including nucleation, growth, and/or agglomeration. In the current study, a series of batch, isochoric, and isothermal tests were carried out to investigate the impacts of two LDHIs, poly N-vinylpyrrolidone (PVP) and polyvinyl alcohols (PVA). This study examined the influence of these inhibitors on nucleation and growth of ethane+propane mixture in the presence of kaolin nanoparticles. In laboratory studies and using pure constituents, the rate of hydrate formation is low to investigate the inhibitors effect. To enhance the rate of hydrate formation, kaolin nanoparticles were utilized as they serve as a suitable representative for solid minerals commonly found in pipelines. The gas phase's compositional change were measured using a gas chromatograph. The results revealed that the growth stage of mixed-gas exhibited two distinct steps, attributed to the formation of two different structures known as structure II and structure I. During the first step, structure II was formed, and the cavities were occupied by both gas components. In the second stage, structure I was formed by ethane. The effect of temperature on the induction time (nucleation rate) and the growth rate during the second stage was lower than that at the first stage. The increase in PVA concentration resulted in an increase in the induction time and a decrease in the rate of growth during the first stage. The performance of PVA was found to be affected by temperature. Lower temperatures resulted in the formation of less foam, providing improved performance for PVA at −0.5°C. PVP had a stronger impact on induction time and both growth steps compared to PVA, indicating stronger inhibitory impact of PVP on nucleation of hydrates initiated by propane and the growth of both propane and ethane hydrates.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"102 11","pages":"3994-4006"},"PeriodicalIF":1.6,"publicationDate":"2024-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140969116","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Understanding two-phase flow behaviour: CFD Assessment of silicone oil–air and water–air in an intermediate vertical pipe","authors":"Prantik Mondal, Sandip Kumar Lahiri, Kartik Chandra Ghanta","doi":"10.1002/cjce.25311","DOIUrl":"10.1002/cjce.25311","url":null,"abstract":"<p>The study utilized computational fluid dynamics (CFD) simulations employing the volume of fluid (VOF) model to analyze silicone oil–air flows in a vertical pipe with a diameter of 67 mm. Various structured meshes ensured grid independence, and the <i>k</i>-<i>ε</i> realizable model addressed turbulence. The analysis characterized bubbly to annular flows, involving the evaluation of flow patterns, radial void fractions, void fraction time series, probability density functions (PDFs), power spectral densities (PSDs), and mean void fractions. Results indicated a transition from bubbly to annular flow with increasing gas velocities and notable changes in radial void fraction profiles. Void fraction exhibited significant variations with distinct flow patterns at constant liquid velocity. PDFs identified flow regimes, and PSDs revealed frequency patterns. CFD results were validated against experiments, demonstrating good agreement. The validated CFD model was utilized to investigate radial gas velocities and pressure drops, revealing a shift from uniform velocity distributions to irregular patterns and a decrease in total pressure drop with an increase in gas superficial velocity. The model was also applied to a water-air system to explore two-phase flow behaviour. The impact of superficial gas velocity on flow patterns and radial void fractions was studied through numerical analysis and compared with the silicone oil-air system. Results showed that at extreme gas velocities (0.06 and 5.53 m/s), silicone oil exhibited bubbly and annular flows, while water displayed cap bubbly and churn flows. The significant variation in radial void fraction at these velocities emphasized the impact of fluid properties.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"102 12","pages":"4416-4439"},"PeriodicalIF":1.6,"publicationDate":"2024-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140973064","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
José Roberto Nunhez, Harry Van den Akker, Vivek Vinayak Ranade
{"title":"Process design in chemical engineering CFD symposium","authors":"José Roberto Nunhez, Harry Van den Akker, Vivek Vinayak Ranade","doi":"10.1002/cjce.25285","DOIUrl":"10.1002/cjce.25285","url":null,"abstract":"","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"102 8","pages":"2648-2649"},"PeriodicalIF":1.6,"publicationDate":"2024-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140929841","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect analysis on passive and active regeneration performance of catalytic diesel particulate filters at the equilibrium point in the presence of ash layer","authors":"Chao Zhong, Shaoli Wang, Bo Chen, Guohai Jia, Chenxi Wu, Hongyan Zuo","doi":"10.1002/cjce.25302","DOIUrl":"10.1002/cjce.25302","url":null,"abstract":"<p>Catalytic diesel particulate filters (CDPF) form the main post-processing devices for the diesel engines. Particulates trapped by CDPF can be oxidized by nitrogen dioxide (NO<sub>2</sub>) and oxygen (O<sub>2</sub>). The CDPF passive and active regeneration model on platinum-based catalyst in the presence of ash layer, including the mass, momentum, and enthalpy balances of the gas and the solid phase, the gas diffusion, and the kinetic of the soot oxidation reaction is performed and validated by the bench test. The effects of different temperatures on CDPF passive and active regeneration at the equilibrium point are analyzed. Further, the effective analysis of ash loading and ash layer distribution on the equilibrium state is conducted. The research on CDPF passive and active regeneration at the equilibrium point in the presence of ash layer provides a theoretical basis for CDPF application.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"102 10","pages":"3437-3447"},"PeriodicalIF":1.6,"publicationDate":"2024-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140929771","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}