{"title":"Bioinorganic Preparation of Hydroxyapatite and Rare Earth Substituted Hydroxyapatite for Biomaterials Applications.","authors":"Suha Q Al-Shahrabalee, Hussein Alaa Jaber","doi":"10.1155/2023/7856300","DOIUrl":"https://doi.org/10.1155/2023/7856300","url":null,"abstract":"Rare Earth elements in the lanthanide series are regarded as one of the finest options for the cationic substitution of calcium ions in hydroxyapatite (HA) because of their favorable impact on the biological characteristics of substituted HA. Neodymium and cerium were used to substitute 5% of calcium ions in HA, prepared via the wet precipitation method. Characterization tests for pure and substituted HA were conducted using XRD, FTIR, EDS, and FESEM. The results showed that changing part from calcium ions in hydroxyapatite to Nd and Ce ions altered its structure, composition, and morphology. Regarding the biological tests, the cytotoxicity test revealed a change in IC50 for both normal and cancer cell lines, where substitution part of the Ca ions with rare Earth elements led to increasing antitumor activity in comparison with HA without substitution; in addition, antibacterial and fungicide activity was evident for both HA and Nd-Ce/HA, with a modest increase in antibacterial activity of Nd-Ce/HA against S. epidermidis and E. coli in comparison with HA. These findings may shed light on the process by which Nd and Ce ions improve the biological characteristics of pure HA and the increased potential of these bioceramics.","PeriodicalId":8914,"journal":{"name":"Bioinorganic Chemistry and Applications","volume":"2023 ","pages":"7856300"},"PeriodicalIF":3.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9891820/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10652549","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Retracted: Research on Microseismic Source Location Method Based on Waveform Characteristics Monitored by Nanomaterial Sensor under the Background of Metal Oxide Polluted Environment.","authors":"Bioinorganic Chemistry And Applications","doi":"10.1155/2023/9840914","DOIUrl":"https://doi.org/10.1155/2023/9840914","url":null,"abstract":"<p><p>[This retracts the article DOI: 10.1155/2022/5479007.].</p>","PeriodicalId":8914,"journal":{"name":"Bioinorganic Chemistry and Applications","volume":"2023 ","pages":"9840914"},"PeriodicalIF":3.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10446981/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10072201","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Bioinorganic Nanoparticles for the Remediation of Environmental Pollution: Critical Appraisal and Potential Avenues.","authors":"Md Mominur Rahman, Limon Ahmed, Fazilatunnesa Anika, Anha Akter Riya, Sumaiya Khatun Kali, Abdur Rauf, Rohit Sharma","doi":"10.1155/2023/2409642","DOIUrl":"https://doi.org/10.1155/2023/2409642","url":null,"abstract":"<p><p>Nowadays, environmental pollution has become a critical issue for both developed and developing countries. Because of excessive industrialization, burning of fossil fuels, mining and exploration, extensive agricultural activities, and plastics, the environment is being contaminated rapidly through soil, air, and water. There are a variety of approaches for treating environmental toxins, but each has its own set of restrictions. As a result, various therapies are accessible, and approaches that are effective, long-lasting, less harmful, and have a superior outcome are extensively demanded. Modern research advances focus more on polymer-based nanoparticles, which are frequently used in drug design, drug delivery systems, environmental remediation, power storage, transformations, and other fields. Bioinorganic nanomaterials could be a better candidate to control contaminants in the environment. In this article, we focused on their synthesis, characterization, photocatalytic process, and contributions to environmental remediation against numerous ecological hazards. In this review article, we also tried to explore their recent advancements and futuristic contributions to control and prevent various pollutants in the environment.</p>","PeriodicalId":8914,"journal":{"name":"Bioinorganic Chemistry and Applications","volume":"2023 ","pages":"2409642"},"PeriodicalIF":3.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10110382/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"9383830","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Retracted: Assessing Deep Learning Techniques for the Recognition of Tropical Disease in Images from Parasitological Exams.","authors":"Bioinorganic Chemistry And Applications","doi":"10.1155/2023/9836730","DOIUrl":"https://doi.org/10.1155/2023/9836730","url":null,"abstract":"<p><p>[This retracts the article DOI: 10.1155/2022/2682287.].</p>","PeriodicalId":8914,"journal":{"name":"Bioinorganic Chemistry and Applications","volume":"2023 ","pages":"9836730"},"PeriodicalIF":3.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10469375/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10525626","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hoda A El-Ghamry, Rajaa O Al-Ziyadi, Fatmah M Alkhatib, Khadiga M Takroni, Abdalla M Khedr
{"title":"Metal Chelates of Sulfafurazole Azo Dye Derivative: Synthesis, Structure Affirmation, Antimicrobial, Antitumor, DNA Binding, and Molecular Docking Simulation.","authors":"Hoda A El-Ghamry, Rajaa O Al-Ziyadi, Fatmah M Alkhatib, Khadiga M Takroni, Abdalla M Khedr","doi":"10.1155/2023/2239976","DOIUrl":"https://doi.org/10.1155/2023/2239976","url":null,"abstract":"<p><p>A series of divalent and one trivalent metal chelates of the azo ligand resulting from coupling of sulfafurazole diazonium chloride with resorcinol have been designed and synthesized. Structure investigation of the isolated chelates have been achieved by applying spectroscopic and analytical tools which collaborated to assure the formation of the metal chelates in the molar ratios of 1L: 1M for Ni(II), Co(II), and Fe(III) chelates, where Cu(II) and Zn(II) complexes formed in the ratio 2L : 1M. The geometrical arrangement around the metal canters was concluded from UV-Vis spectra to be octahedral for all metal chelates. The attachment of the ligand to the metal ions took place through the azo group nitrogen and o-hydroxyl oxygen through proton displacement leading to the ligand being in monobasic bidentate binding mode. Antimicrobial and antitumor activities of the interested compounds have been evaluated against alternative microorganisms and cancer cells, respectively, in a trial to investigate their extent of activity in addition to docking studies. The mode of interaction of the compounds with SS-DNA has been examined by UV-Vis spectra and viscosity studies.</p>","PeriodicalId":8914,"journal":{"name":"Bioinorganic Chemistry and Applications","volume":"2023 ","pages":"2239976"},"PeriodicalIF":3.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10234726/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"9950902","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Retracted: Clinical Diagnostic Value of Quantitative Hepatitis B Virus Core Antibody Test in Chronic Viral Hepatitis B.","authors":"Bioinorganic Chemistry And Applications","doi":"10.1155/2023/9857473","DOIUrl":"https://doi.org/10.1155/2023/9857473","url":null,"abstract":"<p><p>[This retracts the article DOI: 10.1155/2021/3720571.].</p>","PeriodicalId":8914,"journal":{"name":"Bioinorganic Chemistry and Applications","volume":"2023 ","pages":"9857473"},"PeriodicalIF":3.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10447072/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10072194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Retracted: A Study on <i>Glycyrrhiza glabra</i>-Fortified Bread: Predicted Glycemic Index and Bioactive Component.","authors":"Bioinorganic Chemistry And Applications","doi":"10.1155/2023/9828939","DOIUrl":"https://doi.org/10.1155/2023/9828939","url":null,"abstract":"<p><p>[This retracts the article DOI: 10.1155/2022/4669723.].</p>","PeriodicalId":8914,"journal":{"name":"Bioinorganic Chemistry and Applications","volume":"2023 ","pages":"9828939"},"PeriodicalIF":3.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10447055/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10072198","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Retracted: Beta-Sitosterol Facilitates GLUT4 Vesicle Fusion on the Plasma Membrane via the Activation of Rab/IRAP/Munc 18 Signaling Pathways in Diabetic Gastrocnemius Muscle of Adult Male Rats.","authors":"Bioinorganic Chemistry And Applications","doi":"10.1155/2023/9859160","DOIUrl":"https://doi.org/10.1155/2023/9859160","url":null,"abstract":"<p><p>[This retracts the article DOI: 10.1155/2022/7772305.].</p>","PeriodicalId":8914,"journal":{"name":"Bioinorganic Chemistry and Applications","volume":"2023 ","pages":"9859160"},"PeriodicalIF":3.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10469747/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10506596","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Assessment of Structural, Optical, and Antibacterial Properties of Green Sn(Fe : Ni)O<sub>2</sub> Nanoparticles Synthesized Using <i>Azadirachta indica</i> Leaf Extract.","authors":"Abeer S Aloufi","doi":"10.1155/2023/5494592","DOIUrl":"https://doi.org/10.1155/2023/5494592","url":null,"abstract":"<p><p>Metal oxide nanoparticles have attained notable recognition due to their interesting physicochemical properties. Although these nanoparticles can be synthesized using a variety of approaches, the biological method involving plant extracts is preferred since it provides a simple, uncomplicated, ecologically friendly, efficient, rapid, and economical way for synthesis. In this study, the <i>Azadirachta indica</i> leaf extract was used as a reducing agent, and a green process was used to synthesize tin(ferrous: nickel)dioxide (Sn(Fe : Ni)O<sub>2</sub>) nanoparticles. The synthesized nanoparticles were subjected to characterization by using X-ray diffraction (XRD), energy-dispersive X-ray (EDX) spectroscopy analysis, field emission scanning electron microscopy (FESEM), Fourier transform infrared (FTIR) spectroscopy, dynamic light scattering (DLS), and photoluminescence (PL) measurement. Furthermore, Sn(Fe : Ni)O<sub>2</sub> nanoparticles were analyzed for their antimicrobial activity against Gram-positive and Gram-negative organisms including <i>Staphylococcus aureus, Streptococcus pneumoniae, Bacillus subtilis, Klebsiella pneumoniae, Escherichia coli</i>, and <i>Pseudomonas aeruginosa</i> bacterial strains. XRD patterns revealed that Sn(Fe : Ni)O<sub>2</sub> nanoparticles exhibited a tetragonal structure. The hydrodynamic diameter of the nanoparticles was 143 nm, as confirmed by the DLS spectrum. The FESEM image showed the spherical form of the synthesized nanoparticles. Chemical composites and mapping analyses were performed through the EDAX spectrum. The Sn-O-Sn and Sn-O stretching bands were 615 cm<sup>-1</sup> and 550 cm<sup>-1</sup> in the FTIR spectrum, respectively. Various surface defects of the synthesized Sn(Fe : Ni)O<sub>2</sub> nanoparticles were identified by photoluminescence spectra. Compared to traditional antibiotics like amoxicillin, the inhibition zone revealed that Sn(Fe : Ni)O<sub>2</sub> nanoparticles displayed remarkable antibacterial activity against all tested organisms, indicating the valuable potential of nanoparticles in the healthcare industry.</p>","PeriodicalId":8914,"journal":{"name":"Bioinorganic Chemistry and Applications","volume":"2023 ","pages":"5494592"},"PeriodicalIF":3.8,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9928506/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10731199","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}