Battery Energy最新文献

筛选
英文 中文
Binder-Free NiCo(PO4)3 Nanosheet Electrode for Supercapattery With Enhanced Ion Transport and Long-Term Stability 无粘结剂的NiCo(PO4)3纳米片超级电池电极具有增强离子传输和长期稳定性
Battery Energy Pub Date : 2026-04-12 DOI: 10.1002/bte2.70115
Usman Ahmed, Faiza Bibi, Adnan Younis, Fawad Ahmad, Seitkhan Azat, Arshid Numan, Fathalla Hamed
{"title":"Binder-Free NiCo(PO4)3 Nanosheet Electrode for Supercapattery With Enhanced Ion Transport and Long-Term Stability","authors":"Usman Ahmed,&nbsp;Faiza Bibi,&nbsp;Adnan Younis,&nbsp;Fawad Ahmad,&nbsp;Seitkhan Azat,&nbsp;Arshid Numan,&nbsp;Fathalla Hamed","doi":"10.1002/bte2.70115","DOIUrl":"https://doi.org/10.1002/bte2.70115","url":null,"abstract":"<p>Binder-free electrodes are emerging as a transformative solution in electrochemical energy storage systems, offering direct electron transport pathways and eliminating the limitations imposed by insulating binders. In this work, we report the synthesis of nickel-cobalt phosphate dihydrate (NCP) grown directly on nickel foam using a simple hydrothermal method carried out at 180°C for 12 h. This straightforward approach yielded a distinctive flake and nanosheet morphology, resulting in abundant electroactive sites, enlarged surface area, and open channels for rapid ion diffusion. Electrochemical investigation revealed the remarkable performance of the NCP electrode. Cyclic voltammetry (CV) demonstrated a specific capacity of 118.8 C/g (215 F/g) at 5 mV/s, while galvanostatic charge-discharge (GCD) measurements confirmed a specific capacity of 98.8 C/g (178.9 F/g) at 1 A/g within a 0.55 V potential window. To evaluate practical applicability, a supercapattery device was assembled using the binder-free NCP electrode as the positive electrode and activated carbon (AC) as the negative electrode. The NCP//AC device delivered a specific capacity of 87.7 C/g at 0.5 A/g. Most notably, the device demonstrated outstanding electrochemical stability, maintaining 92.9% capacity retention after 5000 cycles at 2 A/g. These findings highlight the efficacy of the hydrothermal approach and the synergistic role of Ni and Co in stabilizing the phosphate framework. The NCP electrode, with its unique nanosheet architecture, emerges as a promising candidate for next-generation, high-performance supercapattery.</p>","PeriodicalId":8807,"journal":{"name":"Battery Energy","volume":"5 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bte2.70115","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147686089","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Programming Ionic Landscapes: Ferroelectric Liquid Crystals, Dielectric Fields, and Process-Programmed Assembly for the Future of Solid-State Batteries 离子景观编程:铁电液晶、介电场和固态电池未来的过程编程组装
Battery Energy Pub Date : 2026-04-12 DOI: 10.1002/bte2.70117
Sijie Liu, Yuzhen Zhao, Le Zhou, Jianjun Chen, Kristiaan Neyts
{"title":"Programming Ionic Landscapes: Ferroelectric Liquid Crystals, Dielectric Fields, and Process-Programmed Assembly for the Future of Solid-State Batteries","authors":"Sijie Liu,&nbsp;Yuzhen Zhao,&nbsp;Le Zhou,&nbsp;Jianjun Chen,&nbsp;Kristiaan Neyts","doi":"10.1002/bte2.70117","DOIUrl":"https://doi.org/10.1002/bte2.70117","url":null,"abstract":"<p>Solid polymer electrolytes (SPEs) offer a compelling path toward next-generation all-solid-state batteries (ASSBs), but their practical application remains constrained by low ionic conductivity and poor interfacial stability. These limitations arise from the intrinsically low dielectric constant of polymer matrices that fail to effectively dissociate lithium salts. Meanwhile, the disordered ion pathways induce tortuous migration routes and nonuniform current density at electrode interfaces. This perspective introduces the concept of programming ionic transport, which integrates ferroelectric liquid crystals (LCs), dielectric field engineering, and process-programmed assembly to overcome these challenges. Ferroelectric LCs offer a unique combination of high dielectric anisotropy and programmable molecular order, enabling the creation of low-tortuosity ion highways with built-in polarization fields. The spontaneous polarization of ferroelectric nematic phases can generate local electric fields that actively repel anions and guide lithium ions, potentially overcoming the limitations of conventional SPEs. To translate this molecular order into macroscopic device function, we highlight the critical role of advanced manufacturing techniques. Process-programmed assembly, including shear-induced alignment in 3D printing and electrospinning, provides a direct means to control alignment of LCs into designed architectures. The integration of material design and digital fabrication enables electrolytes with graded dielectric properties, hierarchical ion transport networks, and customized device geometries for ASSBs. We outline a roadmap for the future development of ASSBs that moves beyond facilitated ion transport toward actively programmed ion transport.</p>","PeriodicalId":8807,"journal":{"name":"Battery Energy","volume":"5 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-04-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bte2.70117","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147686987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced High-Rate Cycling Performance of Nickel-Rich Li[Ni0.88Co0.09Mn0.03]O2 Cathodes Through Sc2O3 Doping Sc2O3掺杂增强富镍Li[Ni0.88Co0.09Mn0.03]O2阴极的高速循环性能
Battery Energy Pub Date : 2026-04-03 DOI: 10.1002/bte2.70114
Parisa Mehdipour, Hossein Rostami, Tao Hu, Ali Margot Huerta-Flores, Pekka Tanskanen, Pekka Tynjälä, Ulla Lassi
{"title":"Enhanced High-Rate Cycling Performance of Nickel-Rich Li[Ni0.88Co0.09Mn0.03]O2 Cathodes Through Sc2O3 Doping","authors":"Parisa Mehdipour,&nbsp;Hossein Rostami,&nbsp;Tao Hu,&nbsp;Ali Margot Huerta-Flores,&nbsp;Pekka Tanskanen,&nbsp;Pekka Tynjälä,&nbsp;Ulla Lassi","doi":"10.1002/bte2.70114","DOIUrl":"https://doi.org/10.1002/bte2.70114","url":null,"abstract":"<p>Nickel-rich layered oxide cathodes are considered highly promising candidates for next-generation lithium-ion batteries (LIBs), owing to their high energy density. Nevertheless, their practical application remains constrained by limited cycling stability and rate capability. This study explores the influence of Sc<sub>2</sub>O<sub>3</sub> doping on the electrochemical performance and structural stability of LiNi<sub>0.88</sub>Co<sub>0.09</sub>Mn<sub>0.03</sub>O<sub>2</sub> (LNCM88). Sc<sub>2</sub>O<sub>3</sub> was incorporated at doping levels of 0.5, 1, and 2.5 wt%, and its effects were systematically investigated using several characterization techniques, including scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). These analyses confirmed successful Sc<sub>2</sub>O<sub>3</sub> incorporation without significant changes in the cathode morphology. Electrochemical characterizations showed that, although the initial capacity decreased with increasing Sc content, capacity retention and rate performance improved significantly. Notably, the sample doped with 1 wt% Sc<sub>2</sub>O<sub>3</sub> demonstrated a discharge capacity of 195.1 mAh g<sup>−1</sup> after 100 cycles at 0.1 C, with a retention rate of approximately 93.1%. These findings highlight the efficacy of Sc<sub>2</sub>O<sub>3</sub> doping as a viable strategy to enhance the electrochemical properties and commercial potential of nickel-rich layered cathodes in LIB applications. Full cell results revealed that the Sc<sub>2</sub>O<sub>3</sub>-doped LNCM88 delivers improved capacity retention, maintaining 83.2% at 1 C after 300 cycles, compared to only 76.4% for the undoped material under identical conditions. High-rate cycling results further demonstrate that 1 wt% Sc doping significantly enhances the durability of LNCM88, making it a promising strategy for improving the performance of nickel-rich layered cathode materials in high-power lithium-ion battery applications.</p>","PeriodicalId":8807,"journal":{"name":"Battery Energy","volume":"5 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bte2.70114","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147686726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Understanding Multiscale Lithium Transport Dynamics in Composite Si-C Electrodes: An Asymptotic Framework for GITT Experiments 理解复合Si-C电极中的多尺度锂输运动力学:GITT实验的渐近框架
Battery Energy Pub Date : 2026-03-28 DOI: 10.1002/bte2.70107
E. Jane, M. Higuera, F. Varas
{"title":"Understanding Multiscale Lithium Transport Dynamics in Composite Si-C Electrodes: An Asymptotic Framework for GITT Experiments","authors":"E. Jane,&nbsp;M. Higuera,&nbsp;F. Varas","doi":"10.1002/bte2.70107","DOIUrl":"https://doi.org/10.1002/bte2.70107","url":null,"abstract":"<p>This work presents an asymptotic analysis of lithium transport phenomena during a galvanostatic intermittent titration technique (GITT) pulse-relaxation cycle in electrodes combining composite silicon-carbon (Si-C) aggregates and graphite particles. The study demonstrates that asymptotic techniques offer both physical insight into the complex interplay of transport mechanisms—namely, lithium exchange between silicon and graphite, diffusion within active particles, and exchange between graphite and composite particles—and contribute to efficient parameter identification. A key challenge in characterising composite Si-C electrodes via GITT lies in the presence of very disparate time scales associated with the relevant transport phenomena. This fact results in a cell behaviour during the GITT test completely different with respect to homogeneous electrodes. The asymptotic framework developed here explains how the interplay among these transport phenomena affects the observed cell voltage during the experiments and why GITT tests must be adapted for reliable identification of blended electrode parameters, providing guidance for the design of such adapted experiments. Although applied here to a single pulse-relaxation cycle, the methodology is general and can be extended to other operating conditions or composite electrode systems.</p>","PeriodicalId":8807,"journal":{"name":"Battery Energy","volume":"5 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bte2.70107","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147615271","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Black Phosphorus-Based Nanocomposites as Anode Materials for Lithium-Ion Batteries: A Comprehensive Review 黑磷基纳米复合材料作为锂离子电池负极材料的研究进展
Battery Energy Pub Date : 2026-03-27 DOI: 10.1002/bte2.70110
Md Shamsul Islam, Konok Chandra Bhowmik, Sabit Ara Orpa, Md. Aminul Islam, Md. Arafat Rahman
{"title":"Black Phosphorus-Based Nanocomposites as Anode Materials for Lithium-Ion Batteries: A Comprehensive Review","authors":"Md Shamsul Islam,&nbsp;Konok Chandra Bhowmik,&nbsp;Sabit Ara Orpa,&nbsp;Md. Aminul Islam,&nbsp;Md. Arafat Rahman","doi":"10.1002/bte2.70110","DOIUrl":"https://doi.org/10.1002/bte2.70110","url":null,"abstract":"<p>Black phosphorus (BP) is a layered and two-dimensional substance that has been discussed as an anode material for lithium-ion batteries (LIBs) due to its exceptionally large theoretical capacity, anisotropic electrochemical characteristics, and bandgap control. However, pristine BP suffers from problems such as significant volume expansion, capacity fading, and low coulombic efficiency. To overcome these challenges, researchers have explored BP incorporated with various nanocomposites to not only improve structural stability and conductivity of BP, but also suppress its environmental degradation and optimize its electrochemical performance. This review focuses on modification strategies such as carbon-based hybridization, metal doping, and heterostructure engineering to address these challenges. It also systematically compares the strategy of synthesis of the BP-based nanocomposites, such as high-energy ball milling machine, chemical vapor deposition, liquid exfoliation, and their combination with various reinforcements. The electrochemical behavior of these composites, such as specific capacities, rate capability, cycling stability, among others are evaluated and compared, and the results are summarized in a tabular form to make them clear. In addition, this review explains how the BP-based nanocomposites can be used to transform the LIB technology while identifying key research directions to advance the versatility of these composites in real-world applications.</p>","PeriodicalId":8807,"journal":{"name":"Battery Energy","volume":"5 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bte2.70110","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147615255","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Stereoscopic Serpentine Channel-Based Cold Plate Design for Enhanced Liquid Cooling of EV Batteries 基于立体蛇形通道的电动汽车电池强化液冷冷板设计
Battery Energy Pub Date : 2026-03-26 DOI: 10.1002/bte2.70109
Anoop Kanjirakat, Rahul Saldanha, Pramod G. K., Dolfred Vijay Fernandes
{"title":"Stereoscopic Serpentine Channel-Based Cold Plate Design for Enhanced Liquid Cooling of EV Batteries","authors":"Anoop Kanjirakat,&nbsp;Rahul Saldanha,&nbsp;Pramod G. K.,&nbsp;Dolfred Vijay Fernandes","doi":"10.1002/bte2.70109","DOIUrl":"https://doi.org/10.1002/bte2.70109","url":null,"abstract":"<p>This study examines the cooling performance of lithium-ion (Li-ion) batteries in electric vehicles, emphasizing the importance of maintaining temperatures below 35°C to ensure efficiency and safety. A simulation-based approach is used to study battery pack cooling using a liquid coolant (deionized water) within a cold plate system, focusing on a 16-cell battery pack connected in series-parallel. A novel stereoscopic-serpentine cold plate design is implemented. The thermal response of the battery pack is evaluated under constant and worldwide harmonized light vehicles test cycle (WLTC Class 3 drive) discharge rates. The inlet temperature and inlet flow velocities of the liquid coolant are varied. The simulation results for the stereoscopic-serpentine cold plate design are compared with those for the traditional serpentine bottom cold plate design. The new design improved coolant flow and effectively reduced temperature differences in the battery pack. The findings highlight that lowering the coolant temperature is significantly more effective for reducing the battery temperature than increasing the coolant flow speed, with a 1% decrease in coolant temperature leading to a 7.1% reduction in the maximum battery temperature, compared with a mere 0.21% reduction from a 1% increase in coolant flow speed.</p>","PeriodicalId":8807,"journal":{"name":"Battery Energy","volume":"5 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bte2.70109","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147615282","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multi-Phase Synergy Enhances Lithium-Ion Storage Performance of Transition Metal Oxalates 多相协同作用增强过渡金属草酸盐锂离子存储性能
Battery Energy Pub Date : 2026-03-24 DOI: 10.1002/bte2.70103
Liying Xue, Stefanie Arnold, Jean Gustavo de Andrade Ruthes, Oliver Janka, Chaochao Dun, Volker Presser
{"title":"Multi-Phase Synergy Enhances Lithium-Ion Storage Performance of Transition Metal Oxalates","authors":"Liying Xue,&nbsp;Stefanie Arnold,&nbsp;Jean Gustavo de Andrade Ruthes,&nbsp;Oliver Janka,&nbsp;Chaochao Dun,&nbsp;Volker Presser","doi":"10.1002/bte2.70103","DOIUrl":"https://doi.org/10.1002/bte2.70103","url":null,"abstract":"<p>Transition metal oxalates have been proven to be a promising electrode material for lithium-ion batteries. Here, we have designed a series of multi-phase transition metal oxalates with different structures and compositions by simply adjusting the proportions of five transition metal elements. Among them, the multi-phase mixture (<i>M</i>C<sub>2</sub>O<sub>4</sub>·2H<sub>2</sub>O - CuC<sub>2</sub>O<sub>4</sub> - <i>M</i>C<sub>2</sub>O<sub>4</sub>·2H<sub>2</sub>O, <i>M</i> = Mn, Fe, Co, Ni, Cu) provides a more stable framework for the material during lithiation and delithiation, effectively alleviating the structural collapse during the cycling process. In addition, the electron transport and fast charge compensation processes of multiple electrochemically active metal pairs also contribute to the improvement of performance. Therefore, the multi-phase transition metal oxalate TMOx-2 electrode with an additional CuC<sub>2</sub>O<sub>4</sub> phase exhibits high reversible capacity and long-term cycling stability. After 400 cycles at 100 and 500 mA/g, the specific discharge capacities are 827 mAh/g and 498 mAh/g, respectively. Constructing multi-metal, multi-phase systems by combining different transition metals enables control over potential, reaction pathways, and stability of high-performance electrodes.</p>","PeriodicalId":8807,"journal":{"name":"Battery Energy","volume":"5 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bte2.70103","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147568576","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Intraparticular Heterogeneity Limits Capacity in Lithium–Sulfur Batteries With Carbonate Electrolyte 碳酸盐电解质锂硫电池的粒子内非均质性限制了电池容量
Battery Energy Pub Date : 2026-03-24 DOI: 10.1002/bte2.70111
Ayca Senol Gungor, Jean-Marc von Mentlen, Francisco Javier García-Soriano, Christian Zaubitzer, Milivoj Plodinec, Jean G. A. Ruthes, Sven Dunkel, Volker Presser, Alen Vizintin, Vanessa Wood, Christian Prehal
{"title":"Intraparticular Heterogeneity Limits Capacity in Lithium–Sulfur Batteries With Carbonate Electrolyte","authors":"Ayca Senol Gungor,&nbsp;Jean-Marc von Mentlen,&nbsp;Francisco Javier García-Soriano,&nbsp;Christian Zaubitzer,&nbsp;Milivoj Plodinec,&nbsp;Jean G. A. Ruthes,&nbsp;Sven Dunkel,&nbsp;Volker Presser,&nbsp;Alen Vizintin,&nbsp;Vanessa Wood,&nbsp;Christian Prehal","doi":"10.1002/bte2.70111","DOIUrl":"https://doi.org/10.1002/bte2.70111","url":null,"abstract":"<p>The formation of a stable cathode-electrolyte interphase (CEI) is critical for the performance of lithium–sulfur (Li–S) batteries with carbonate-based electrolytes, as it suppresses parasitic polysulfide reactions and enables solid-state sulfur conversion. In nanoporous carbon hosts, the CEI together with nanopore confinement plays a key role in capacity retention and long-term cycling. Yet, its spatial formation, stability, and contribution to electrochemical performance remain poorly understood, partly due to challenges in characterization caused by beam and air sensitivity. Here, we employ cryogenic transmission electron microscopy (cryo-TEM) with electron energy loss spectroscopy and energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy and electrochemical testing together with galvanostatic intermittent titration technique measurements to elucidate how carbon particle size affects CEI formation and electrochemical performance. We find that the CEI is not a uniform surface film but extends heterogeneously into the particle bulk. Mass transport during the first discharge dictates CEI development, and larger particles suffer from inactive regions due to the preferential CEI formation only in the outer regions of the particles. During extended cycling, charge transfer resistance at confined CEI/active material/carbon interfaces emerges as the dominant performance-limiting factor. These findings show that particle size controls CEI formation during initial discharge, offering guidance for designing carbon hosts from nano- to micrometer length scales in Li–S battery cathodes.</p>","PeriodicalId":8807,"journal":{"name":"Battery Energy","volume":"5 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bte2.70111","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147568578","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Beyond Lattice Softness: The Polarizability of Anion-Cluster and Paddle-Wheel Effect in Solid-State Electrolyte 超越晶格柔软:固态电解质中阴离子簇的极化性和桨轮效应
Battery Energy Pub Date : 2026-03-07 DOI: 10.1002/bte2.70102
Shipeng Liang, Yuqin Xiong, Tong Wu
{"title":"Beyond Lattice Softness: The Polarizability of Anion-Cluster and Paddle-Wheel Effect in Solid-State Electrolyte","authors":"Shipeng Liang,&nbsp;Yuqin Xiong,&nbsp;Tong Wu","doi":"10.1002/bte2.70102","DOIUrl":"https://doi.org/10.1002/bte2.70102","url":null,"abstract":"<p>The polarizability of anionic frameworks has emerged as a powerful yet under‑recognized descriptor for understanding ion transport in solid‑state electrolytes. Recent studies reveal that polarizable anions and tetrahedral clusters, such as PS<sub>4</sub>, govern lattice softness, phonon responses, and electron‑cloud deformation, collectively shaping the energy landscape for cation migration. In this Perspective, we revisit the role of anionic polarizability across sulfide, halide, oxide, and mixed‑anion systems, highlighting how local tetrahedral dynamics complement global lattice effects. We further propose that the widely debated paddle‑wheel effect may, in essence, originate from the intrinsic polarizability‑driven vibrational and rotational behavior of anion clusters. By synthesizing emerging experimental and computational insights, this work outlines a unified framework linking anion‑cluster polarizability to ion‑transport mechanisms. Such a viewpoint aims to guide the rational design of solid electrolytes that balance structural stability, lattice responsiveness, and high ionic conductivity for next‑generation solid‑state batteries.</p>","PeriodicalId":8807,"journal":{"name":"Battery Energy","volume":"5 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bte2.70102","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147614841","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Intelligent Battery Systems: System-Level Integration of Data-Driven Learning, Optimisation and Predictive Management 智能电池系统:数据驱动学习、优化和预测管理的系统级集成
Battery Energy Pub Date : 2026-03-07 DOI: 10.1002/bte2.70099
Divine Senanu Ametefe, Nur Sabahiah Abdul Sukor, Dah John, George Dzorgbenya Ametefe, Abdulmalik Adozuka Aliu, Macaulay M. Owen, Salaudeen Taofeek Olaidey
{"title":"Intelligent Battery Systems: System-Level Integration of Data-Driven Learning, Optimisation and Predictive Management","authors":"Divine Senanu Ametefe,&nbsp;Nur Sabahiah Abdul Sukor,&nbsp;Dah John,&nbsp;George Dzorgbenya Ametefe,&nbsp;Abdulmalik Adozuka Aliu,&nbsp;Macaulay M. Owen,&nbsp;Salaudeen Taofeek Olaidey","doi":"10.1002/bte2.70099","DOIUrl":"https://doi.org/10.1002/bte2.70099","url":null,"abstract":"<p>The rapid expansion of electrified energy systems has transformed batteries from passive storage components into critical infrastructure assets. This shift has intensified persistent challenges related to degradation, safety and lifecycle uncertainty. A growing body of literature examines the use of artificial intelligence (AI) and machine learning (ML) in battery modelling and management. However, most extant studies emphasise individual algorithms or isolated prediction tasks. The reliable deployment of intelligence on operational battery system receives limited attention. This perspective addresses this limitation by examining intelligent battery systems from a system-level standpoint. Intelligence is approached as an outcome of coordinated integration across sensing, learning, optimisation and management functions, rather than as an isolated algorithmic feature. Recent advances in data acquisition, performance optimisation, lifecycle modelling and predictive management are examined within a unified battery management architecture. Attention is given to practical deployment constraints, including sensing fidelity, data representativeness, interpretability, scalability and compatibility with embedded control systems. Evidence from fast charging studies and grid-scale deployments highlights both the potential of AI-driven approaches and the structural barriers that restrict translation from laboratory settings to real-world operation. The analysis highlights the role of early and diverse sensing, physics-informed learning, uncertainty-aware decision processes and deployment-oriented model design in shaping dependable system-level intelligence. The paper concludes by identifying research priorities that align algorithmic development with safety, sustainability and operational feasibility, positioning intelligent battery systems as adaptive assets within future energy infrastructures.</p>","PeriodicalId":8807,"journal":{"name":"Battery Energy","volume":"5 2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-03-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/bte2.70099","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147614817","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信
小红书