Materials Horizons最新文献

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Silicon anode modification strategies in solid-state lithium-ion batteries. 固态锂离子电池中的硅阳极改性策略。
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-05-01 DOI: 10.1039/d5mh00434a
Yang Deng, Xiaohan Feng, Zhonglin Qian, Jurui Ma, Yitao Ouyang, Weijie Li, Chao Han
{"title":"Silicon anode modification strategies in solid-state lithium-ion batteries.","authors":"Yang Deng, Xiaohan Feng, Zhonglin Qian, Jurui Ma, Yitao Ouyang, Weijie Li, Chao Han","doi":"10.1039/d5mh00434a","DOIUrl":"https://doi.org/10.1039/d5mh00434a","url":null,"abstract":"<p><p>The development and application of solid-state electrolytes in lithium-ion batteries (LIBs) have become mainstream in the industry of LIBs. Compared with liquid electrolytes, solid-state electrolytes offer higher safety and energy density and are expected to further broaden the application fields of lithium-ion batteries. Conventional solid-state lithium-ion batteries (SSLIBs) employ lithium metal as their anode, which raises new concerns about their safety and waste management. Therefore, silicon, with high safety, high theoretical capacity, low electrochemical plateau, and low handle cost, has become the most promising new-generation anode material. However, due to the volume expansion of silicon and the low contact with solid-state electrolytes, resulting in poor conductivity, the SSLIBs' capacity has not reached the expected level and the cycle performance is also poor. Therefore, further modification of silicon anodes has become one of the key points in the development of SSLIBs. This paper comprehensively expounds on the application and optimization of silicon anodes in SSLIBs. It proposes further optimization strategies, which focus on preventing the destruction of silicon and extending its lifespan. The strategies include (1) silicon with different morphologies; (2) the formation of amorphous silicon; and (3) silicon composites.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143955875","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In situ synchrotron X-ray diffraction for actuation in sodium bismuth titanate relaxor ferroelectrics. 钛酸铋钠弛豫铁电体的原位同步加速器x射线衍射驱动。
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-04-30 DOI: 10.1039/d5mh00388a
Yuxin Jia, Yongbo Fan, Lin Lei, Yao Su, Shuwen Zhu, Guangzhi Dong, Manuel Hinterstein, Qiang Li, Weijia Wang, Huiqing Fan
{"title":"<i>In situ</i> synchrotron X-ray diffraction for actuation in sodium bismuth titanate relaxor ferroelectrics.","authors":"Yuxin Jia, Yongbo Fan, Lin Lei, Yao Su, Shuwen Zhu, Guangzhi Dong, Manuel Hinterstein, Qiang Li, Weijia Wang, Huiqing Fan","doi":"10.1039/d5mh00388a","DOIUrl":"https://doi.org/10.1039/d5mh00388a","url":null,"abstract":"<p><p>Sodium bismuth titanate-based (NBT-based) ergodic relaxor ferroelectrics have garnered significant attention for actuator applications due to their fully reversible electrostrain behavior. In general, it is believed that the electrostain originates from three main aspects: electric field-induced phase transitions with volume changes, non-180° domain switching, and lattice stretching without volume changes. However, the individual contribution remains to be quantitatively understood. In this work, <i>in situ</i> synchrotron X-ray diffraction in different integration directions is performed to quantify the contributions of electric field-induced phase transition and non-180° domain switching to electrostrain for NBT-based ergodic relaxor ferroelectrics under external electric field. The calculated total strain is 0.41%, in which 0.038% results from volume strain related to the electric field-induced phase transition, while 0.127% is due to induced ferroelastic domain structures. The rest 0.245% is attributed to lattice stretching. The volume change caused directly by phase transition has a very limited effect on electrostrain, while the indirect effect of phase transition on strain (the domain switching of the ferroelectric phase) has a relatively large effect on electrostrain. This innovative work offers theoretical insights for optimizing NBT-based relaxor ferroelectric materials for actuator applications, contributing to better control of electrostrain.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143955850","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Covalent organic framework membranes for lithium extraction: facilitated ion transport strategies to enhance selectivity. 用于锂提取的共价有机框架膜:促进离子传输策略以提高选择性。
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-04-30 DOI: 10.1039/d5mh00457h
Da Lei, Yongjie Zhu, Lan-Lan Lou, Zhong Liu
{"title":"Covalent organic framework membranes for lithium extraction: facilitated ion transport strategies to enhance selectivity.","authors":"Da Lei, Yongjie Zhu, Lan-Lan Lou, Zhong Liu","doi":"10.1039/d5mh00457h","DOIUrl":"https://doi.org/10.1039/d5mh00457h","url":null,"abstract":"<p><p>The surging global demand for lithium, driven by the proliferation of electric vehicles and energy storage technologies, has exposed significant limitations in conventional lithium extraction methods, including inefficiency and environmental harm. Covalent organic frameworks (COFs) have emerged as a promising platform to address this challenge and enable more sustainable lithium extraction, owing to their unique advantages such as precisely tunable pore sizes, robust stability, and the ability to incorporate functional binding sites for selective ion transport. This review focuses on structural design and functionalization strategies in COFs to optimize lithium-ion separation, highlighting how pore confinement effects, tailored interlayer stacking arrangements, and strategic functional group modifications can dramatically enhance Li<sup>+</sup> selectivity over competing ions present in brine solutions. A particular emphasis is placed on the fundamental energy barriers associated with lithium-ion transport. In particular, we discuss how appropriately designed pore environments and lithium-binding functional groups reduce the dehydration energy required for Li<sup>+</sup> to enter and traverse COF nanochannels, thereby facilitating faster and more selective Li<sup>+</sup> conduction. We also survey recent advancements in COF-based lithium separation technologies, such as high-performance COF membranes and sorbents for extracting lithium from brines and seawater, evaluating their potential, as well as remaining challenges, for sustainable industrial implementation. This review provides a comprehensive understanding of how advanced COF engineering can enable efficient and selective lithium-ion transport, offering valuable insights for the development of next-generation lithium extraction materials and technologies.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143951686","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An atomically precise alloy AgCu cuboid nanocluster with a cubic core: gram scale synthesis, total structure, electronic structure, and catalytic performance. 具有立方核的原子精密合金AgCu长方体纳米团簇:克级合成、总结构、电子结构和催化性能。
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-04-30 DOI: 10.1039/d4mh01324g
Abhijit Nag, Abdul Mannan Butt, Moon Young Yang, Praveen B Managutti, Bilal Masood Pirzada, M Infas H Mohideen, Ahmed L Abdelhady, Mohamed Abu Haija, Sharmarke Mohamed, Boris V Merinov, William A GoddardIII, Ahsanulhaq Qurashi
{"title":"An atomically precise alloy AgCu cuboid nanocluster with a cubic core: gram scale synthesis, total structure, electronic structure, and catalytic performance.","authors":"Abhijit Nag, Abdul Mannan Butt, Moon Young Yang, Praveen B Managutti, Bilal Masood Pirzada, M Infas H Mohideen, Ahmed L Abdelhady, Mohamed Abu Haija, Sharmarke Mohamed, Boris V Merinov, William A GoddardIII, Ahsanulhaq Qurashi","doi":"10.1039/d4mh01324g","DOIUrl":"https://doi.org/10.1039/d4mh01324g","url":null,"abstract":"<p><p>Although atomically precise noble metal nanoclusters (NMNCs) are highly desirable to unravel the size and structure-activity relationships in catalysis, their synthesis in a controlled way at the atomic level is challenging. Herein, we report the structure and gram scale synthesis of a highly symmetric 2-phenylethanethiol (PETH) and triphenylphosphine (PPh<sub>3</sub>)-protected AgCu alloy nanocluster (NC) [Ag<sub>4</sub>Cu<sub>28</sub>H<sub>6</sub>(PET)<sub>16</sub>Cl<sub>8</sub>(PPh<sub>3</sub>)<sub>8</sub>][BF<sub>4</sub>]<sub>2</sub> with a cuboid shape, denoted as Ag<sub>4</sub>Cu<sub>28</sub>. This was accomplished <i>via</i> a facile one-pot reduction method. The Ag<sub>4</sub>Cu<sub>28</sub> NC consists of an Ag<sub>4</sub>Cu<sub>4</sub> metal core, six hydrides, four Cu<sub>4</sub>Cl<sub>2</sub> units, eight PET ligands, and four Cu<sub>2</sub>(PET)<sub>2</sub>(PPh<sub>3</sub>)<sub>2</sub> motifs. High-resolution electrospray ionization mass spectrometry (HRESI MS) and density functional theory (DFT) calculations support this crystal structure. Moreover, Ag<sub>4</sub>Cu<sub>28</sub> exhibits excellent catalytic activity (<i>k</i> = 7.86 min<sup>-1</sup>) in the hydrogenation of hazardous nitroarenes. This intriguing NC delivers a unique opportunity to explore the gram scale synthesis of alloy nanoclusters and to expand the research on Cu and Ag-based NCs.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143953551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Reactive oxygen species-responsive prodrug nanomicelle-functionalized Lactobacillus rhamnosus probiotics for amplified therapy of ulcerative colitis. 活性氧物种响应的前药纳米微球功能化鼠李糖乳杆菌益生菌对溃疡性结肠炎的强化治疗。
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-04-29 DOI: 10.1039/d5mh00114e
Xinyue Zhang, Shuyun Liu, Rui Xin, Wenxiu Hu, Qiqi Zhang, Qian Lu, Lu Han
{"title":"Reactive oxygen species-responsive prodrug nanomicelle-functionalized <i>Lactobacillus rhamnosus</i> probiotics for amplified therapy of ulcerative colitis.","authors":"Xinyue Zhang, Shuyun Liu, Rui Xin, Wenxiu Hu, Qiqi Zhang, Qian Lu, Lu Han","doi":"10.1039/d5mh00114e","DOIUrl":"https://doi.org/10.1039/d5mh00114e","url":null,"abstract":"<p><p>Characterized by elevated reactive oxygen species (ROS) and disrupted gut flora, ulcerative colitis (UC) affects millions of patients worldwide. Probiotic therapy is commonly utilized in clinical practice to modulate intestinal flora and ameliorate colitis symptoms. Nonetheless, oral probiotics encounter challenges such as limited bioactivity, brief retention time, intricate pathological conditions, and singular efficacy. Here we designed plant-derived 18β-glycyrrhetinic acid (18β-GA) prodrug nanomicelles with ROS and inflammation-resolving capabilities, as well as anti-depressant effects, to protect probiotics and amplify their therapeutic effects in alleviating UC and UC-associated depression-like behaviors. Upon oral administration to UC lesion sites, prodrug nanomicelles can be dissociated by excessive ROS and release 18β-GA to attenuate colonic inflammatory responses and oxidative stress, which in turn provided a favorable microenvironment for LGG to repair intestinal barrier integrity and restore the gut microbiota. The synergistic therapeutic effects of STG nanomicelles and LGG alleviated UC-associated depression-like behavior by suppressing the activation of microglia and reducing neuroinflammation. This study introduces a promising strategy for oral nanomedicine with satisfactory therapeutic outcomes for the treatment of inflammatory diseases by integrating naturally derived small-molecule drugs with probiotics.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143953425","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modeling and design of 3D printed hyperelastic lattice metamaterials with bionic S-shaped stress-strain behaviors. 具有仿生s形应力-应变行为的3D打印超弹性晶格超材料建模与设计。
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-04-28 DOI: 10.1039/d4mh01582g
Le Dong, Mengjie Zhang, Dong Wang
{"title":"Modeling and design of 3D printed hyperelastic lattice metamaterials with bionic S-shaped stress-strain behaviors.","authors":"Le Dong, Mengjie Zhang, Dong Wang","doi":"10.1039/d4mh01582g","DOIUrl":"https://doi.org/10.1039/d4mh01582g","url":null,"abstract":"<p><p>Lattice metamaterials made of stiff polymers, ceramics, and metals have been extensively designed to reproduce the mechanical behaviors of biological tissues, holding promising applications in biomedical devices and tissue engineering. However, lattice metamaterials composed of soft materials have been far less explored due to challenges posed by material nonlinearity and large deformations. Here, hyperelastic lattice metamaterials with curved microstructures are fabricated by 3D printing elastomers and are developed to mimic bionic S-shaped stress-strain behaviors. We propose a design framework for 3D printed hyperelastic lattice metamaterials that integrates digital geometry generation, hierarchical mechanics modeling, and validation by finite element (FE) simulations and experiments. The microstructures are modeled through deriving a Timoshenko-type beam theory governed by hyperelastic strain energy potentials. The model is then combined with the deformation and equilibrium analysis considering non-rigid connections between microstructures to predict the mechanical responses of hyperelastic lattice metamaterials. Using the developed design framework, programmable S-shaped stress-strain behaviors and high fracture strains (over 800%) are achieved. We demonstrate S-shaped stress-strain curves that match skeletal and cardiac muscles and highly stretchable lattice sensors for remote controls. This study provides design methods and theoretical guidelines for hyperelastic lattice metamaterials, holding promise for robotic sensors with bionic performance and functionality.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143957165","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrazine-assisted water electrolysis system: performance enhancement and application expansion. 肼辅助水电解系统:性能提升与应用拓展。
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-04-28 DOI: 10.1039/d5mh00118h
Hao-Yu Wang, Zhong-Yong Yuan
{"title":"Hydrazine-assisted water electrolysis system: performance enhancement and application expansion.","authors":"Hao-Yu Wang, Zhong-Yong Yuan","doi":"10.1039/d5mh00118h","DOIUrl":"https://doi.org/10.1039/d5mh00118h","url":null,"abstract":"<p><p>Powered by renewable energy sources, water electrolysis has emerged as a highly promising technology for energy conversion, attracting significant attention in recent years, but it faces severe challenges, especially at the anode. Accordingly, hydrazine-assisted water electrolysis, incorporating the electro-oxidation of hydrazine at the anode, holds great promise for greatly reducing the input voltage and optimizing the system by application expansion. In this review, we present an in-depth overview of hydrazine-assisted water electrolysis, introducing its reaction mechanisms, basic parameters, specific advantages compared with conventional water electrolysis and other hybrid water electrolysis systems, strategies for developing efficient electrocatalysts with enhanced electrocatalytic performances, and especially its potential application expansion. An analysis of its technical and economic aspects, feasibility studies, mechanistic investigations, and relevant comparisons are also presented for providing a deeper insight into hydrazine-assisted water electrolysis. Finally, the potential avenues and opportunities for future research on hydrazine-assisted water electrolysis are discussed.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143955319","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances in photocatalytic H2O2 production: modification strategies of 2D materials and in situ application of H2O2. 光催化生产H2O2的最新进展:二维材料的改性策略和H2O2的原位应用。
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-04-28 DOI: 10.1039/d5mh00295h
Guangyuan Chen, Chenyang Lin, Fangchong Han, Haotian Zhang, Shijian Zhou, Fu Yang, Yan Kong, Edison Huixiang Ang
{"title":"Recent advances in photocatalytic H<sub>2</sub>O<sub>2</sub> production: modification strategies of 2D materials and <i>in situ</i> application of H<sub>2</sub>O<sub>2</sub>.","authors":"Guangyuan Chen, Chenyang Lin, Fangchong Han, Haotian Zhang, Shijian Zhou, Fu Yang, Yan Kong, Edison Huixiang Ang","doi":"10.1039/d5mh00295h","DOIUrl":"https://doi.org/10.1039/d5mh00295h","url":null,"abstract":"<p><p>Environmental pollution and the energy crisis are two major problems that threaten human health and restrict industrial development. Hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) is a green oxidant and clean energy widely used in sterilization, degradation of pollutants and as an energy carrier, which is one of the important strategies to solve these two major problems. In recent years, solar-driven photocatalytic production of H<sub>2</sub>O<sub>2</sub> has gained significant attention and been extensively studied. Two dimensional (2D) material photocatalysts offer promising prospects and distinct advantages for H<sub>2</sub>O<sub>2</sub> production. However, their performance is hindered by challenges such as rapid electron-hole recombination, wide bandgaps, and slow reaction kinetics. Additionally, the high solubility of H<sub>2</sub>O<sub>2</sub> in water and its tendency to decompose easily make it difficult to recover from solutions containing sacrificial agents, thereby restricting its practical applications. To the best of our knowledge, there are few reviews focused on the photocatalytic production of H<sub>2</sub>O<sub>2</sub> using 2D material composite catalysts and its <i>in situ</i> applications. This review provides a detailed discussion of various strategies, including introducing vacancy defects, elemental doping, heterojunction engineering, functionalization and multi-strategy coupling, to improve the photocatalytic performance of 2D material composite photocatalysts. Furthermore, this review highlights the <i>in situ</i> applications of H<sub>2</sub>O<sub>2</sub> produced through photocatalysis in diverse fields, including water purification, sterilization, and pharmaceutical intermediate synthesis. It concludes by outlining the key challenges in the photocatalytic production of H<sub>2</sub>O<sub>2</sub> and proposing practical solutions.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144053016","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Filling core-shell microneedles with pressurized oxygen-embedded particles (POPs) to improve photodynamic therapy. 用加压氧包埋粒子(pop)填充核-壳微针以改善光动力治疗。
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-04-28 DOI: 10.1039/d5mh00253b
Weijiang Yu, Junzhe Fu, Yonghang Chen, Yixian Mu, Qiao Jin, Youxiang Wang, Jian Ji
{"title":"Filling core-shell microneedles with pressurized oxygen-embedded particles (POPs) to improve photodynamic therapy.","authors":"Weijiang Yu, Junzhe Fu, Yonghang Chen, Yixian Mu, Qiao Jin, Youxiang Wang, Jian Ji","doi":"10.1039/d5mh00253b","DOIUrl":"https://doi.org/10.1039/d5mh00253b","url":null,"abstract":"<p><p>Photodynamic therapy (PDT) represents a spatiotemporal and minimally invasive treatment for superficial diseases. Enhancing the delivery efficiency of photosensitizers and elevating oxygen levels at the lesion site are two established strategies for improving its effectiveness. Here, we introduce a strategy involving the release of pressurized oxygen to drive photosensitizer diffusion, which is incorporated into a core-shell microneedle (MN) system to improve PDT. This MN system comprises a polyvinylpyrrolidone shell and methylene blue (MB) photosensitizer loaded core particles containing pressurized oxygen bubbles. Upon insertion, the aqueous tissue environment triggers the dissolution of particles within the MNs, enabling the rapid release of oxygen, thereby promoting the diffusion of MB. <i>In vitro</i> experiments demonstrate that these particles could effectively accelerate the release and diffusion of MB. The released oxygen could relieve hypoxia and increase the generation of reactive oxygen species (ROS) of PDT. In a mouse melanoma model, the MN system enhances tumor growth inhibition induced by PDT and mitigates tumor metastasis. This innovative system offers an autonomous, safe, and convenient approach for localized gas delivery and drug diffusion, potentially creating new avenues for efficiently combining gas and other therapies for superficial diseases.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143953350","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Retaining superior electrochromic performance by effective suppression of ion trapping upon cycling. 通过有效抑制循环时的离子捕获,保持优越的电致变色性能。
IF 12.2 2区 材料科学
Materials Horizons Pub Date : 2025-04-28 DOI: 10.1039/d5mh00229j
Renfu Zhang, Qingjiao Huang, Zhexuan Ou, Tooba Afaq Khan, Menghan Yin, Er Gao, Jiawei Sun, Rui-Tao Wen
{"title":"Retaining superior electrochromic performance by effective suppression of ion trapping upon cycling.","authors":"Renfu Zhang, Qingjiao Huang, Zhexuan Ou, Tooba Afaq Khan, Menghan Yin, Er Gao, Jiawei Sun, Rui-Tao Wen","doi":"10.1039/d5mh00229j","DOIUrl":"https://doi.org/10.1039/d5mh00229j","url":null,"abstract":"<p><p>Smart windows based on electrochromic technology play a key role in decarbonization. However, cathodic electrochromic electrodes suffer from ion trapping induced performance degradation upon long-term cycling. Here, we present guidelines for designing electrolytes and preventing ion trapping to achieve optimal durability. Specifically, by controlling the solvation energy of the salts in the electrolyte, anions can be prevented from penetrating the cation-solvent sheath, thereby inhibiting their involvement in the ion trapping process. Therefore, cycling stability is significantly extended, <i>i.e.</i>, no observed degradation after 1000 cycles. Following this concept, we further reveal that for the degraded electrodes which cannot be restored in an electrolyte with relatively weak cation-solvent interaction, they can be successfully recovered by switching to an electrolyte with strong cation-solvent interaction. Our work not only provides strategies to suppress the ion trapping and prolong the cycling stability of electrochromic electrodes, but also evokes the importance of electrode-electrolyte interaction to the electrochromic community.</p>","PeriodicalId":87,"journal":{"name":"Materials Horizons","volume":" ","pages":""},"PeriodicalIF":12.2,"publicationDate":"2025-04-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143955936","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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