{"title":"Membrane-coupled fungi reactor--an innovative approach to bioremediation of hazardous dye wastewater.","authors":"Faisal Ibney Hai, Kazuo Yamamoto, Kensuke Fukushi","doi":"","DOIUrl":"","url":null,"abstract":"<p><p>Owing to the inherent shortcomings of conventional biological dye effluent treatment processes, researchers have proposed diverse intriguing approaches that await practical implementation. This study demonstrates the feasibility of an innovative membrane-coupled fungi reactor. Preliminary batch tests revealed the noteworthy role of biosorption along with biodegradation in decoloration, and also confirmed excellent decoloration even in the presence of hardly biodegradable polyvinyl alcohol besides recalcitrant dye in the wastewater. Conversely, the continuous reactor achieved stable 97% total organic carbon (TOC) and 99% color removal with a hydraulic retention time (HRT) of 15 h. A marked decrease in the UV absorbance of the membrane permeate, and the detection of short-chain aliphatic acids in the permeate provided evidence of the subsequent biodegradation of the aromatic group following the breakdown of the color-imparting chromophoric group of the dye.</p>","PeriodicalId":87178,"journal":{"name":"Environmental sciences : an international journal of environmental physiology and toxicology","volume":"13 6","pages":"317-25"},"PeriodicalIF":0.0,"publicationDate":"2006-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"26530289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Toenail arsenic levels among residents in Amami-Oshima Island, Japan.","authors":"Hiromi Tabata, Muhammad Anwar, Sawako Horai, Tetsuo Ando, Atsuhiro Nakano, Junji Wakamiya, Chihaya Koriyama, Masanori Nakagawa, Katsushi Yamada, Suminori Akiba","doi":"","DOIUrl":"","url":null,"abstract":"<p><p>In order to evaluate the current arsenic exposure status and its determinants in Japan, we collected toenail samples from 212 subjects residing in a town with a population of 6,900 in Amami-Oshima Island in August 1999. We measured arsenic concentrations of the toenails using inductively coupled plasma mass spectrometry. In addition, we examined the association of arsenic levels with lifestyles and dietary habits, including the consumption of fish, seaweed, and rice. The mean toenail arsenic level was 0.41 ppm (95% confidence interval, 0.36-0.47), which was about 3-fold higher than those observed in other populations of mainland Kagoshima. Arsenic levels were elevated among current smokers (mean = 0.65; 95% confidence interval, 0.32-1.29) when compared with non-smokers (mean = 0.40; 95% confidence interval, 0.34-0.46), and among the residents consuming 4 bowls or more, of rice every day (mean = 1.97; 95% confidence interval, 0.25-15.75) when compared to residents consuming 3 bowls or less (mean = 0.39; 95% confidence interval, 0.34-0.45). Sex, age, alcohol intake, fish consumption, or seaweed consumption was not associated with toenail arsenic concentration. Further studies seem warranted to examine the cause of relatively high arsenic levels in our study area.</p>","PeriodicalId":87178,"journal":{"name":"Environmental sciences : an international journal of environmental physiology and toxicology","volume":"13 3","pages":"149-60"},"PeriodicalIF":0.0,"publicationDate":"2006-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"26176422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Seiichi Yoshida, Miki Yoshida, Isamu Sugawara, Ken Takeda
{"title":"Mice strain differences in effects of fetal exposure to diesel exhaust gas on male gonadal differentiation.","authors":"Seiichi Yoshida, Miki Yoshida, Isamu Sugawara, Ken Takeda","doi":"","DOIUrl":"","url":null,"abstract":"<p><p>We have shown that in ICR pregnant mice exposed to diesel exhaust (DE), mRNA expression of mällerian inhibiting substance (MIS) and a steroid hormone transcription factor (Ad4BP/SF-1), which are essential in male gonadal differentiation, decreases in a DE concentration-dependent manner. To further investigate whether these effects differ among strains, we conducted the present study in 3 different strains: ICR mice, ddY mice, and C57BL/6J mice. The response to DE exposure differed among the 3 strains. In C57BL/6J male fetuses, only MIS mRNA expression significantly decreased, and in ddY male fetuses, there was no change in either MIS or Ad4BP/SF-1 mRNA expression. Although there was no definite correlation between mouse strain characteristics and differences in the effects of DE, our findings suggest strain-related variations in DE sensitivity with respect to gene expression regulating male gonadal differentiation.</p>","PeriodicalId":87178,"journal":{"name":"Environmental sciences : an international journal of environmental physiology and toxicology","volume":"13 2","pages":"117-23"},"PeriodicalIF":0.0,"publicationDate":"2006-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"26101123","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Production of low-estrogen goldfish diet for in vivo endocrine disrupter test.","authors":"Makito Kobayashi, Hiroshi Ishibashi, Toshihisa Moriwaki, Tomohiko Koshiishi, Satoshi Ogawa, Takeru Matsumoto, Koji Arizono, Shugo Watabe","doi":"","DOIUrl":"","url":null,"abstract":"<p><p>A low-estrogenic diet for goldfish Carassius auatus was produced for an in vivo estrogen activity test, because commercial fish feed has estrogenic activity and may affect the results of estrogen assays. The newly produced diet (FD5) was formulated with defatted rice bran and casein, and did not contain any soybean meal or fish meal. Phytoestrogen contents (genistein, daidzein, equol, and coumestrol) of FD5 were measured by liquid chromatography-mass spectroscopy/mass spectroscopy (LC-MS/MS) and compared with those of the commercial trout diet (TD) and carp diet (CD). The genistein, daidzein, and coumestrol contents of TD and CD were much higher (5-2000 times) than those of FD5, but equol was detected only in FD5. Estrogenic activity of the fish diets was estimated in vitro by the yeast estrogen-screen assay (YES assay). The estrogenic activity was detected in TD and CD, but not in FD5. The in vivo estrogenic activity of the diets was examined by determining the production of vitellogenin in male goldfish. When male goldfish were fed TD or CD, plasma vitellogenin levels increased, but fish that were fed FD5 maintained low vitellogenin levels. These results indicate that FD5 produced in the present study has a low estrogenic activity, and FD5 would be suitable for the in vivo estrogen activity test using goldfish.</p>","PeriodicalId":87178,"journal":{"name":"Environmental sciences : an international journal of environmental physiology and toxicology","volume":"13 2","pages":"125-36"},"PeriodicalIF":0.0,"publicationDate":"2006-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"26101124","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Solidification and stabilization of fly ash from mixed hazardous waste incinerator using ordinary Portland cement.","authors":"Agamuthu Pariatamby, Chitra Subramaniam, Satoshi Mizutani, Hiroshi Takatsuki","doi":"","DOIUrl":"","url":null,"abstract":"<p><p>Fly ash samples from a mixed hazardous waste (MHW) incinerator were subjected to solidification and stabilization (S/S) studies using ordinary Portland cement (OPC) as the binder. Additives (i.e., activated carbon and rice husk) were also homogenized with the binder and waste to determine the effectiveness of the immobilization of heavy metals. The toxicity characteristics leaching procedure (TCLP), Japanese Leaching Test (JLT-13) and the American Nuclear Test 16.1 (modified) ANS 16.1 were used to gauge the leaching of heavy metals from the solidified matrixes. Compressibility strength of the solidified matrixes was also tested using the American Standard Testing Material (ASTM) test procedure for the compressive strength of hydraulic cement mortars.</p>","PeriodicalId":87178,"journal":{"name":"Environmental sciences : an international journal of environmental physiology and toxicology","volume":"13 5","pages":"289-96"},"PeriodicalIF":0.0,"publicationDate":"2006-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"26356388","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Estimation and control of atmospheric emissions of chloroform and dichloromethane due to laboratory activity.","authors":"Tadashi Nomura, Satoshi Mizutani, Yasufumi Suzuki, Nobuhisa Watanabe, Hiroshi Takatsuki","doi":"","DOIUrl":"","url":null,"abstract":"<p><p>In Japanese universities, the management of chemical reagents has become an important issue in preserving the environment and the health of students and researchers. It is thus necessary to estimate the levels of chemical emissions into the environment and to measure working-environment chemical levels in laboratories. However, there are many laboratories in universities using many chemical reagents for their own needs. Hence, it is difficult for universities to quantitate the amount of chemicals on campus, and there is a lack of information about laboratory environment chemical levels. In this study, the material balance of chloroform and dichloromethane (DCM) in Kyoto University was examined, and the emission rates of chloroform and DCM were estimated to be 37-50% and 50-70%, respectively. These chemicals were thought to be volatilized mainly through reduced-pressure distillation. However, it was found that there was a loss of chemicals due to volatility, which researchers were unaware of, such as that during solvent recovery under reduced pressure and volatilization from containers of organic waste liquid. On the other hand, working-environment chemical levels were measured in several laboratories which used chloroform and DCM frequently. Even in such laboratories, the average concentrations of these chemicals were approximately 1 ppm at most measurement points.</p>","PeriodicalId":87178,"journal":{"name":"Environmental sciences : an international journal of environmental physiology and toxicology","volume":"13 4","pages":"219-34"},"PeriodicalIF":0.0,"publicationDate":"2006-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"26356490","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Estimating ambient concentration and cancer risk for 1,3-butadiene in Japan.","authors":"Kazuaki Mita, Haruyuki Higashino, Hiroshi Yoshikado, Junko Nakanishi","doi":"","DOIUrl":"","url":null,"abstract":"<p><p>A detailed assessment of 1,3-butadiene exposure was performed for the purpose of risk assessment in Japan. The concentration of 1,3-butadiene and the 1,3-butadiene-exposure-related lifetime excess cancer risk in the general environment and in the vicinity of industrial point sources were estimated using two different types of diffusion models: the National Institute of Advanced Industrial Science and Technology-atmospheric dispersion model for exposure and risk assessment (AIST-ADMER) model ver. 1.0 for the estimation of regional scale concentrations and the Ministry of Economy, Trade and Industry - low rise industrial source dispersion (METI-LIS) model ver. 2.01 for the estimation of local concentrations near industrial sources. The calculated results indicate that the annual mean concentrations of 1,3-butadiene in residential areas are generally less than 0.5 microg/m(3), but in a few area near industrial point sources they exceed 1.7 microg/m(3), corresponding to a lifetime excess cancer risk of 10(-5). Using data on exposure concentrations and cancer unit risk, the lifetime excess cancer risk for persons exposed to 1,3-butadiene in Japan was evaluated. The results indicate that an extremely small number of people have a risk of developing 1,3-butadiene-exposure-related cancer that is greater than 10(-5), while that of most of the population in Japan is between 10(-5) and 10(-6). The total 1,3-butadiene-exposure-related cancer risk in Japan was calculated as 2.0 cases/year. A large proportion of the cancer risk was associated with general environmental areas. However, the individual risks of the population living in the vicinity of industrial point sources were significantly higher than those of the population living in the general environment.</p>","PeriodicalId":87178,"journal":{"name":"Environmental sciences : an international journal of environmental physiology and toxicology","volume":"13 1","pages":"1-13"},"PeriodicalIF":0.0,"publicationDate":"2006-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"26011381","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A novel on-site system for the treatment of pharmaceutical laboratory wastewater by supercritical water oxidation.","authors":"Teerada Ruamchat, Rumiko Hayashi, Somkiat Ngamprasertsith, Yoshito Oshima","doi":"","DOIUrl":"","url":null,"abstract":"<p><p>For the on-site treatment of laboratory waste, we have been developing a compact-sized reaction system for the treatment of laboratory wastewater using supercritical water oxidation (SCWO) technology. Pharmaceutical laboratory wastewater is one of the most difficult wastewaters to treat because of its high concentration of halogenated organic compounds. We proposed a new cascade process in which two reactors are consecutively combined, carrying out hydrolysis in the first reactor followed by SCWO in the second reactor, for the complete removal of halogenated organic compounds. Dichloromethane was chosen as a representative model of chlorinated compounds. There have been many previous studies on the hydrolysis of dichloromethane, which results in the coproduction of formaldehyde and HCl. However, there has been less investigation on the kinetics of formaldehyde oxidation in supercritical water. In this study, we focus on the oxidation of formaldehyde in supercritical water with and without a catalyst. As a result, formaldehyde can be completely decomposed at 400 degrees C and 25 MPa within a very short contact time in a heterogeneous system with a MnO(2) catalyst.</p>","PeriodicalId":87178,"journal":{"name":"Environmental sciences : an international journal of environmental physiology and toxicology","volume":"13 5","pages":"297-304"},"PeriodicalIF":0.0,"publicationDate":"2006-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"26415317","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Investigation of the management of industrial safety and health at an educational research institution.","authors":"Yasuyuki Fujita, Hiroyasu Yamasaki, Hajime Matsushima","doi":"","DOIUrl":"","url":null,"abstract":"<p><p>Following the incorporation of national universities, the Industrial Safety and Health Law became applicable to universities. A questionnaire survey was conducted on 93 national universities in order to ascertain the current management of industrial safety and health at incorporated national universities. The present findings indicate that each university has established a managerial organization in accordance with the Industrial Safety and Health Law; however, it is important for such organizations to maintain and improve safety management. Therefore, the implementation of a safety and health management system in conjunction with the managerial organization required by the Industrial Safety and Health Law is recommended as a method of enhancing safety management at university laboratories.</p>","PeriodicalId":87178,"journal":{"name":"Environmental sciences : an international journal of environmental physiology and toxicology","volume":"13 4","pages":"235-40"},"PeriodicalIF":0.0,"publicationDate":"2006-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"26356381","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Identification of subjects for social responsibility education at universities and the present activity at the university of Tokyo.","authors":"Risuke Karima, Yoshito Oshima, Kazuo Yamamoto","doi":"","DOIUrl":"","url":null,"abstract":"<p><p>The management of corporate social responsibility (CSR) has recently become a critical concern for companies in advanced countries. For universities, there is a requirement to contribute to the promotion of CSR, resulting in graduates who have sufficient cognition of and a good attitude towards CSR. In addition, universities have social responsibilities, which can be called \"University Social Responsibility (USR).\" On the basis of the concepts of the guidelines for CSR in the \"Green Paper,\" which was presented by the European Committee (EC) in 2001, we provide a perspective here on what factors dictate the establishment of education programs for social responsibilities at universities. These factors include an outline of the concepts and the significance of CSR, social ethics and the morals of higher education and research, compliances, human resource management, human rights, safety and health in academic settings, and various concerns regarding environmental safety and preservation. Additionally, through the concept postulated here for social responsible education, in this paper, we introduce the present activity at the University of Tokyo (UT) in terms of the education program for CSR and USR, proposing that the future establishment of university-wide education programs based on the concept of CSR and the value of sustainability is required at UT.</p>","PeriodicalId":87178,"journal":{"name":"Environmental sciences : an international journal of environmental physiology and toxicology","volume":"13 6","pages":"327-37"},"PeriodicalIF":0.0,"publicationDate":"2006-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"26530290","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}