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Zircon ZS - A Homogenous Natural Reference Material For U–Pb Age And O–Hf Isotope Microanalyses 锆石ZS -一种用于U-Pb年龄和O-Hf同位素微分析的均质天然标准物质
IF 3.4 2区 化学
Atomic Spectroscopy Pub Date : 2022-04-06 DOI: 10.46770/as.2022.033
Xiaoxiao Ling
{"title":"Zircon ZS - A Homogenous Natural Reference Material For U–Pb Age And O–Hf Isotope Microanalyses","authors":"Xiaoxiao Ling","doi":"10.46770/as.2022.033","DOIUrl":"https://doi.org/10.46770/as.2022.033","url":null,"abstract":": A well-formed natural zircon crystal ~10 g in weight from Sri Lanka was introduced as a reference material for the geochemical microanalysis of U–Pb–O–Hf isotopes. For the U–Pb system, a total of 96 secondary ion mass spectrometry (SIMS) and 174 laser-ablation inductively coupled plasma mass spectrometry analyses showed that zircon ZS was homogeneous within a ~20 μm area level. According to chemical abrasion isotope dilution thermal ionization mass spectrometry, the U–Pb system is concordant within the uncertainties, yielding a weighted mean 206 Pb/ 238 U age of 560.6 ± 1.3 Ma (2 standard deviation (SD), n = 18) and a weighted mean 207 Pb/ 206 Pb age of 561.1 ± 3.5 Ma (2SD, n = 18). The U and Th concentrations were 570 ± 40 μg g -1 (1SD) and 132 ± 28 μg g -1 (1SD), respectively. The homogeneity of the O isotopes was confirmed by 261 SIMS analyses, and that of Hf isotopes was determined by 100 laser-ablation multi-collector inductively coupled plasma mass spectrometry (MC–ICP–MS) analyses. A weighted mean δ 18 O value of 13.69‰ ± 0.11‰ (2SD, n = 12) obtained by laser fluorination isotope ratio mass spectrometry (IRMS) and a weighted mean 176 Hf/ 177 Hf value of 0.281668 ± 0.000010 (2SD, n = 7) by solution MC–ICP–MS are recommended as the best reference values for zircon ZS.","PeriodicalId":8642,"journal":{"name":"Atomic Spectroscopy","volume":null,"pages":null},"PeriodicalIF":3.4,"publicationDate":"2022-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42838977","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Micro-XRF Mapping Study On The Taphonomy Of A Jurassic Larval Salamander Fossil From Inner Mongolia Of China 内蒙古侏罗纪蝾螈幼体化石埋藏学的微xrf测图研究
IF 3.4 2区 化学
Atomic Spectroscopy Pub Date : 2022-03-05 DOI: 10.46770/as.2022.246
Xiao Li
{"title":"Micro-XRF Mapping Study On The Taphonomy Of A Jurassic Larval Salamander Fossil From Inner Mongolia Of China","authors":"Xiao Li","doi":"10.46770/as.2022.246","DOIUrl":"https://doi.org/10.46770/as.2022.246","url":null,"abstract":"","PeriodicalId":8642,"journal":{"name":"Atomic Spectroscopy","volume":null,"pages":null},"PeriodicalIF":3.4,"publicationDate":"2022-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48618976","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mineralogical And Geochemical Characterization At A Micro-Scale Of A New Natural Chalcopyrite Reference Material For In-Situ Fe Isotopic Ratio Analysis 一种用于原位铁同位素比分析的新型天然黄铜矿基准物的微尺度矿物学和地球化学特征
IF 3.4 2区 化学
Atomic Spectroscopy Pub Date : 2022-03-05 DOI: 10.46770/as.2022.186
Lei Chen
{"title":"Mineralogical And Geochemical Characterization At A Micro-Scale Of A New Natural Chalcopyrite Reference Material For In-Situ Fe Isotopic Ratio Analysis","authors":"Lei Chen","doi":"10.46770/as.2022.186","DOIUrl":"https://doi.org/10.46770/as.2022.186","url":null,"abstract":"","PeriodicalId":8642,"journal":{"name":"Atomic Spectroscopy","volume":null,"pages":null},"PeriodicalIF":3.4,"publicationDate":"2022-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44537730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Micro-XRF Analysis On The Relationship Between Pyrite And Uranium Mineralization In Sandstone-Hosted Uranium Deposits 砂岩型铀矿床黄铁矿与铀成矿关系的显微XRF分析
IF 3.4 2区 化学
Atomic Spectroscopy Pub Date : 2022-03-05 DOI: 10.46770/as.2022.237
Hao Song
{"title":"Micro-XRF Analysis On The Relationship Between Pyrite And Uranium Mineralization In Sandstone-Hosted Uranium Deposits","authors":"Hao Song","doi":"10.46770/as.2022.237","DOIUrl":"https://doi.org/10.46770/as.2022.237","url":null,"abstract":"","PeriodicalId":8642,"journal":{"name":"Atomic Spectroscopy","volume":null,"pages":null},"PeriodicalIF":3.4,"publicationDate":"2022-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41840228","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-Precision Calcium Isotope Analysis On TIMS Using A Double Spike Technique: The Instrumental Drift And Its Correction TIMS高精度钙同位素双尖峰分析——仪器漂移及其校正
IF 3.4 2区 化学
Atomic Spectroscopy Pub Date : 2022-03-05 DOI: 10.46770/as.2023.043
Yongsheng He
{"title":"High-Precision Calcium Isotope Analysis On TIMS Using A Double Spike Technique: The Instrumental Drift And Its Correction","authors":"Yongsheng He","doi":"10.46770/as.2023.043","DOIUrl":"https://doi.org/10.46770/as.2023.043","url":null,"abstract":"","PeriodicalId":8642,"journal":{"name":"Atomic Spectroscopy","volume":null,"pages":null},"PeriodicalIF":3.4,"publicationDate":"2022-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49290744","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
LA-ICP-MS Imaging Analysis Of Gem-Quality Tourmaline: A Novel Method For Direct Identification Of Chromophore In Gemstone Samples 宝石级碧玺的LA-ICP-MS成像分析:一种直接鉴定宝石样品中发色团的新方法
IF 3.4 2区 化学
Atomic Spectroscopy Pub Date : 2022-03-05 DOI: 10.46770/as.2022.249
Tao Luo
{"title":"LA-ICP-MS Imaging Analysis Of Gem-Quality Tourmaline: A Novel Method For Direct Identification Of Chromophore In Gemstone Samples","authors":"Tao Luo","doi":"10.46770/as.2022.249","DOIUrl":"https://doi.org/10.46770/as.2022.249","url":null,"abstract":"The color of gemstones is a vital factor in the determination of their value in the gem market. The elemental content and local distribution of chromophores within gem samples play an important role in their coloration. In this study, the chemical compositions and two-dimensional (2D) element distributions within a gem-quality color-zoned tourmaline were investigated using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). The elemental distribution results indicated that major elements (i.e., B, Na, Mg, Al, Si, and Ca) were uniformly distributed in different color regions. Moreover, the contents of the transition elements Cr and V correlated well with the colors of the zoned tourmaline crystal. The highest concentrations of Cr and V were found in the intense green zones of the crystal, whereas the pale green regions contained lower concentrations of these elements. Furthermore, a strong correlation between the Cr distribution and complex color zones was observed. The visual results obtained using LA-ICP-MS imaging analysis clearly demonstrated that the presence of Cr and V contributed to the observed green color. In addition, Cr was determined to be the principal chromophore in the green-colored zoned tourmaline. The ultravioletvisible (UV–Vis) and near infrared (NIR) absorption spectra also indicated that the mixing of Cr as well as minor V caused the green color. The uniformity of the elemental distributions obtained using LA-ICP-MS imaging provides clear evidence that Cr can dominate the chromophore content in tourmaline. The results of this study clearly highlight the advantages of LA-ICP-MS imaging analysis as a novel and effective visual method to identify the chromophore contents in gemstone samples.","PeriodicalId":8642,"journal":{"name":"Atomic Spectroscopy","volume":null,"pages":null},"PeriodicalIF":3.4,"publicationDate":"2022-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44064292","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Application Of Collision Cell Technology In ICP-QMS For High-Purity Germanium And Germanium Dioxide Examination 碰撞电池技术在ICP-QMS高纯锗和二氧化锗检测中的应用
IF 3.4 2区 化学
Atomic Spectroscopy Pub Date : 2022-03-05 DOI: 10.46770/as.2022.247
T. Guselnikova
{"title":"Application Of Collision Cell Technology In ICP-QMS For High-Purity Germanium And Germanium Dioxide Examination","authors":"T. Guselnikova","doi":"10.46770/as.2022.247","DOIUrl":"https://doi.org/10.46770/as.2022.247","url":null,"abstract":"","PeriodicalId":8642,"journal":{"name":"Atomic Spectroscopy","volume":null,"pages":null},"PeriodicalIF":3.4,"publicationDate":"2022-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42627540","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Matrix Volatilization ICP-OES And ICP-MS For Trace Elements Analysis In High-Purity Tellurium Materials 基体挥发ICP-OES和ICP-MS用于高纯碲材料中微量元素分析
IF 3.4 2区 化学
Atomic Spectroscopy Pub Date : 2022-03-05 DOI: 10.46770/as.2022.248
N. S. Medvedev
{"title":"Matrix Volatilization ICP-OES And ICP-MS For Trace Elements Analysis In High-Purity Tellurium Materials","authors":"N. S. Medvedev","doi":"10.46770/as.2022.248","DOIUrl":"https://doi.org/10.46770/as.2022.248","url":null,"abstract":"","PeriodicalId":8642,"journal":{"name":"Atomic Spectroscopy","volume":null,"pages":null},"PeriodicalIF":3.4,"publicationDate":"2022-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47013353","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Determination Of Sr Isotope Ratios In Biogenic Carbonates Using LA–MC-ICP–MS: A Case Study Of Chinese Mitten Crabs LA-MC-ICP-MS测定生物成因碳酸盐Sr同位素比率——以中华绒螯蟹为例
IF 3.4 2区 化学
Atomic Spectroscopy Pub Date : 2022-03-05 DOI: 10.46770/as.2022.135
F. Huang
{"title":"Determination Of Sr Isotope Ratios In Biogenic Carbonates Using LA–MC-ICP–MS: A Case Study Of Chinese Mitten Crabs","authors":"F. Huang","doi":"10.46770/as.2022.135","DOIUrl":"https://doi.org/10.46770/as.2022.135","url":null,"abstract":"","PeriodicalId":8642,"journal":{"name":"Atomic Spectroscopy","volume":null,"pages":null},"PeriodicalIF":3.4,"publicationDate":"2022-03-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48117038","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
The Chang’e-5 Lunar Samples Stimulate The Development Of Microanalysis Techniques 嫦娥五号月球样品推动了微量分析技术的发展
IF 3.4 2区 化学
Atomic Spectroscopy Pub Date : 2022-02-25 DOI: 10.46770/as.2022.010
Jinhua Li, Wei Yang, Xiong-Yao Li, Yong He
{"title":"The Chang’e-5 Lunar Samples Stimulate The Development Of Microanalysis Techniques","authors":"Jinhua Li, Wei Yang, Xiong-Yao Li, Yong He","doi":"10.46770/as.2022.010","DOIUrl":"https://doi.org/10.46770/as.2022.010","url":null,"abstract":"Jin-Hua Li,* Wei Yang,* Xiong-Yao Li,* and Yong-Sheng He* a Key Laboratory of Earth and Planetary Physics, Institute of Geology and Geophysics, Innovation Academy for Earth Science, Chinese Academy of Sciences (IGGCAS), Beijing 100029, P.R. China b Center for Lunar and Planetary Sciences, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, P.R. China c State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Beijing 100083, P.R. China","PeriodicalId":8642,"journal":{"name":"Atomic Spectroscopy","volume":null,"pages":null},"PeriodicalIF":3.4,"publicationDate":"2022-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45550607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
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