Atmosphere最新文献

{"title":"Analysis of Volatile Organic Compounds from Compost.","authors":"Shastine K Berger, Rosario C Morales, Katherine McCown, Kylie Wilson, B Thomas Jobson, Nancy A C Johnston","doi":"10.3390/atmos16050591","DOIUrl":"10.3390/atmos16050591","url":null,"abstract":"<p><p>Many US states have adopted regulations to divert food waste from landfills to composts. While this may lower greenhouse emissions from landfills, volatile organic compound (VOC) emissions from compost may contain hazardous air pollutants or produce odors, posing potential public health concerns. Effective methods to analyze speciated VOCs in compost are needed to better understand VOC source generation. Here, a two-component compost sampling method was developed and employed consisting of a chilled impinger and pump apparatus to trap water-soluble VOCs, and dual sorbent tubes to capture hydrophobic VOCs in yard and food/yard waste compost. VOCs were measured via headspace gas-chromatography with flame ionization detection (HS-GC-FID) and thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS). Overall, there was higher VOC generation within higher temperature compost piles, with concentrations ranging up to 27,000 ppm for ethanol and 3,500 ppm for methanol. Alpha-Pinene and D-Limonene were seen in these piles with concentrations over 1600 ppb. Methanol and ethanol were more than one thousand times as concentrated in mixed food/yard waste than yard waste alone, while terpenes were seen in slightly higher concentrations for yard waste than the mixed food/yard waste. Methanol was observed higher than permissible indoor levels and may pose potential health risks.</p>","PeriodicalId":8580,"journal":{"name":"Atmosphere","volume":"16 5","pages":""},"PeriodicalIF":2.6,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC13268598/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148262941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Impact of Multiple HVAC Systems on Indoor Air VOC and Radon Concentrations from Vapor Intrusion During Seasonal Usage.","authors":"John H Zimmerman, Alan Williams, Brian Schumacher, Christopher Lutes, Rohit Warrier, Brian Cosky, Ben Thompson, Chase W Holton, Kate Bronstein","doi":"10.3390/atmos16040378","DOIUrl":"10.3390/atmos16040378","url":null,"abstract":"<p><p>Subsurface contamination can migrate upward into overlying buildings, exposing the buildings' inhabitants to contaminants that can cause detrimental health effects. This phenomenon is known as vapor intrusion (VI). When evaluating a building for VI, one must understand that seasonal and short-term variability are significant factors in determining the reasonable maximum exposure (RME) to the occupants. RME is a semi-quantitative term that refers to the lower portion of the high end of the exposure distribution-conceptually, above the 90th percentile exposure but less than the 98th percentile exposure. Samples were collected between December 2020 and April 2022 at six non-residential commercial buildings in Fairbanks, Alaska. The types of samples collected included indoor air (IA); outdoor air; subslab soil gas; soil gas; indoor radon; differential pressure; indoor and outdoor temperature; heating, ventilation, and air conditioning (HVAC) parameters; and other environmental factors. The buildings in close proximity to the volatile organic compound (VOC) source/release points presented less variability in indoor air concentrations of trichloroethylene (TCE) and tetrachloroethylene (PCE) compared to the buildings farther down gradient in the contaminated groundwater plume. The VOC data pattern for the source area buildings shows an outdoor air temperature-dominated behavior for indoor air concentrations in the summer season. HVAC system operations had less influence on long-term indoor air concentration trends than environmental factors, which is supported by similar indoor air concentration patterns independent of location within the plume. The use of soil temperature and indoor/outdoor temperatures as indicators and tracers (I&Ts) across the plume as predictors of the sampling period could produce a good estimation of the RME for the building occupants. These results, which show the use of soil temperature and indoor/outdoor temperatures as I&Ts, will help advance investigative methods for evaluation of VI in similar settings and thereby improve the protection of human health in indoor environments.</p>","PeriodicalId":8580,"journal":{"name":"Atmosphere","volume":"16 4","pages":"378"},"PeriodicalIF":2.3,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12180761/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144473952","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effects of the Geomagnetic Superstorms of 10–11 May 2024 and 7–11 October 2024 on the Ionosphere and Plasmasphere","authors":"Viviane Pierrard, Tobias Verhulst, Jean-Marie Chevalier, Nicolas Bergeot, Alexandre Winant","doi":"10.3390/atmos16030299","DOIUrl":"https://doi.org/10.3390/atmos16030299","url":null,"abstract":"On 10 May 2024 at 17 h:07 UTC, the simultaneous arrival of several solar coronal mass ejections (CMEs) generated the strongest geomagnetic storm of the last twenty years, with a minimum Dst = −412 nT, usually referred to as the Mother’s Day event. On 10 October 2024, the second strongest event of solar cycle 25 appeared with a Dst = −335 nT, preceded on 8 October by an event with a Dst = −153 nT. In the present work, with measurements of the vertical total electron content and with ionosonde observations from Europe, USA, and South Korea, we show that the ionization of the upper atmosphere shortly increased at the arrival of the CME for these different events, followed by a fast decrease at all latitudes. The ionization remained very low for more than a full day. While the recovery started at the beginning of the second day after the onset for both events in October, the sudden recovery in the middle of the second day on 12 May is much more unusual. The analysis of the observations at different latitudes and longitudes shows that the causes of the ionization variations during the superstorms were mainly due to strong perturbations in the ionospheric F layer, amplified by the plasmasphere’s influence on the vertical total electron content (VTEC). The erosion of the plasmasphere during these two strong events led to a plasmapause located at exceptionally low radial distances smaller than 2 Re (Earth’s radii) in the post-midnight sector and a rotating plume in the afternoon–dusk sector clearly visible in the BSPM plasmasphere model. It took several days after the storms to recover normal ionization rates.","PeriodicalId":8580,"journal":{"name":"Atmosphere","volume":"16 3","pages":"299-299"},"PeriodicalIF":0.0,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/2073-4433/16/3/299/pdf?version=1741087502","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147894505","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Development of Visualization Tools for Sharing Climate Cooling Strategies with Impacted Urban Communities.","authors":"Linda Powers Tomasso, Kachina Studer, David Bloniarz, Dillon Escandon, John D Spengler","doi":"10.3390/atmos16030258","DOIUrl":"10.3390/atmos16030258","url":null,"abstract":"<p><p>Intensifying heat from warming climates regularly concentrates in urban areas lacking green infrastructure in the form of green space, vegetation, and ample tree canopy cover. Nature-based interventions in older U.S. city cores can help minimize the urban heat island effect, yet neighborhoods targeted for cooling interventions may remain outside the decisional processes through which change affects their communities. This translational research seeks to address health disparities originating from the absence of neighborhood-level vegetation in core urban areas, with a focus on tree canopy cover to mitigate human susceptibility to extreme heat exposure. The development of LiDAR-based imagery enables communities to visualize the proposed greening over time and across seasons of actual neighborhood streets, thus becoming an effective communications tool in community-engaged research. These tools serve as an example of how visualization strategies can initiate unbiased discussion of proposed interventions, serve as an educational vehicle around the health impacts of climate change, and invite distributional and participatory equity for residents of low-income, nature-poor neighborhoods.</p>","PeriodicalId":8580,"journal":{"name":"Atmosphere","volume":"16 3","pages":""},"PeriodicalIF":2.6,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC13268589/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148262919","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Simulating the Fate of Dimethyl Sulfide (DMS) in the Atmosphere: A Review of Emission and Chemical Parameterizations.","authors":"Ernesto Pino-Cortés, Mariela Martínez, Katherine Gómez, Fernando González Taboada, Joshua S Fu, Golam Sarwar, Rafael P Fernandez, Sankirna D Joge, Anoop S Mahajan, Juan Höfer","doi":"10.3390/atmos16030350","DOIUrl":"10.3390/atmos16030350","url":null,"abstract":"<p><p>Numerical simulation studies of the dispersion of dimethyl sulfide (DMS) in the air have increased over the last two decades in parallel with the interest in understanding its role as a precursor of non-sea salt aerosols in the lower to middle levels of the troposphere. Here, we review recent numerical modeling studies that have included DMS emissions, their atmospheric oxidation mechanism, and their subsequent impacts on air quality at regional and global scales. In addition, we discuss the available methods for estimating sea-air DMS fluxes, including parameterizations and climatological datasets, as well as their integration into air quality models. At the regional level, modeling studies focus on the Northern Hemisphere, presenting a large gap in Antarctica, Africa, and the Atlantic coast of South America, whereas at the global scale, modeling studies tend to focus more on polar regions, especially the Arctic. Future studies must consider updated climatologies and parameterizations for more realistic results and the reduction in biases in numerical simulations analysis.</p>","PeriodicalId":8580,"journal":{"name":"Atmosphere","volume":"16 3","pages":"350"},"PeriodicalIF":2.3,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC12180756/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144473951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Role of Atmospheric Circulation Patterns in Water Storage of the World’s Largest High-Altitude Landslide-Dammed Lake","authors":"Xi Deng, Yizhen Li, Jingjing Zhang, Lingxin Kong, Jilili Abuduwaili, Majid Gulayozov, Anvar Kodirov, Long Ma","doi":"10.3390/atmos16020209","DOIUrl":"https://doi.org/10.3390/atmos16020209","url":null,"abstract":"This study reconstructed the annual lake surface area (LSA) and absolute lake water storage (LWS) changes of Lake Sarez, the world’s largest high-altitude landslide-dammed lake, from 1992 to 2023 using multi-source remote sensing data. All available Landsat images were used to extract the LSA using an improved multi-index threshold method, which incorporates a slope mask and threshold adjustment to enhance the boundary delineation accuracy (Kappa coefficient = 0.94). By combining the LSA with high-resolution DEM and the GLOBathy bathymetry dataset, the absolute LWS was reconstructed, fluctuating between 12.3 × 109 and 12.8 × 109 m3. A water balance analysis revealed that inflow runoff (IRO) was the primary driver of LWS changes, contributing 54.57%. The cross-wavelet transform and wavelet coherence analyses showed that the precipitation (PRE) and snow water equivalent (SWE) were key climatic factors that directly influenced the variability of IRO, impacting the interannual water availability in the lake, with PRE having a more sustained impact. Temperature indirectly regulated IRO by affecting SWE and potential evapotranspiration. Furthermore, IRO exhibited different resonance periods and time lags with various atmospheric circulation factors, with the Pacific Decadal Oscillation and North Atlantic Oscillation having the most significant influence on its interannual variations. These findings provide crucial insights into the hydrological behavior of Lake Sarez under climate change and offer a novel approach for studying water storage dynamics in high-altitude landslide-dammed lakes, thereby supporting regional water resource management and ecological conservation.","PeriodicalId":8580,"journal":{"name":"Atmosphere","volume":"16 2","pages":"209-209"},"PeriodicalIF":0.0,"publicationDate":"2025-02-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147919811","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Investigation of the Ionospheric Response on Mother’s Day 2024 Geomagnetic Superstorm over the European Sector","authors":"Krishnendu Sekhar Paul, Haris Haralambous, Mefe Moses, Christina Oikonomou, Stelios M. Potirakis, Nicolas Bergeot, Jean-Marie Chevalier","doi":"10.3390/atmos16020180","DOIUrl":"https://doi.org/10.3390/atmos16020180","url":null,"abstract":"The present study examines the negative ionospheric response over Europe during two geomagnetic storms on 10–13 May 2024, known as the Mother’s Day geomagnetic superstorm. The first storm, with a peak SYM-H value of −436 nT, occurred in the interval 10–11 May, while the second, less intense storm (SYM-H~−103 nT), followed in the interval 12–13 May. Using data from four European locations, temporal and spatial variations in ionospheric parameters (TEC, foF2, and hmF2) were analyzed to investigate the morphology of the strong negative response. Sharp electron density (Ne) depletion is associated with the equatorward displacement of the Midlatitude Ionospheric Trough (MIT), confirmed by Swarm satellite data. A key finding was the absence of foF2 and hmF2 values over all ionosonde stations during the recovery phase of the storms, likely due to the coupling between the Equatorial Ionization Anomaly (EIA) crests and the auroral ionosphere influenced by the intense uplift of the F layer. Relevant distinct features such as Large-scale Travelling Ionospheric Disturbance (LSTID) signatures and Spread F were also noted, particularly during the initial and main phase of the first storm over high midlatitude regions. Regional effects varied, with high European midlatitudes exhibiting different features compared to lower European latitude areas.","PeriodicalId":8580,"journal":{"name":"Atmosphere","volume":"16 2","pages":"180-180"},"PeriodicalIF":0.0,"publicationDate":"2025-02-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147918104","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Association of Cardiovascular Disease Mortality and Ambient Temperature Variation in Shanghai, China: Beyond Air Quality Index PM_2.5.","authors":"Qi Li, Shizhen Li, Ting Zhai, Shan Jin, Chunfang Wang, Bo Fang, Tian Xia","doi":"10.3390/atmos16020119","DOIUrl":"10.3390/atmos16020119","url":null,"abstract":"<p><p>Evidence from megacity registry data regarding the independent association between ambient temperature and cardiovascular disease (CVD) mortality, after accounting for Particulate Matter 2.5 (PM_2.5), remains scarce. In this study, we collected 308,116 CVD mortality cases in Shanghai from 2015 to 2020. The distributed lag non-linear model (DLNM) was utilized. The daily PM_2.5 concentration was transformed using a natural spline (ns) function and integrated into the model for adjustment. The DLNM analysis revealed that the exposure-response curve between daily temperature and CVD mortality approximated an inverted \"J\" shape, consistent for both women and men. The minimum mortality temperature (MMT) for total CVD mortality was 25 °C, with an MMT of 26 °C for females and 24 °C for males. The highest relative risk (RR) of CVD mortality was 2.424 [95% confidence interval (95% CI): 2.035, 2.887] at the lowest temperature of -6.1 °C, with 2.244 (95% CI: 1.787, 2.818) for female and 2.642 (95% CI: 2.100, 3.326) for male. High temperatures exert acute and short-term effects, with the peak risk occurring on the day of exposure. In contrast, the risk from low temperature peaks on day 3 of the lag time and subsequently declines until days 16-21. This study offers evidence-based support for the prevention of temperature-induced CVD mortality.</p>","PeriodicalId":8580,"journal":{"name":"Atmosphere","volume":"16 2","pages":""},"PeriodicalIF":2.5,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11845240/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143481993","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Research on the Detection Model of Kernel Anomalies in Ionospheric Space Electric Fields","authors":"Xingsu Li, Zhong Li, Jianping Huang, Ying Han, Yumeng Huo, Junjie Song, Bo Hao","doi":"10.3390/atmos16020160","DOIUrl":"https://doi.org/10.3390/atmos16020160","url":null,"abstract":"Research has found kernel anomaly regions in the power spectrum images of ionospheric electric fields in space, which are widely distributed. To effectively detect these kernel abnormal regions, this paper proposes a new kernel abnormal region detection method, KANs-Unet, based on KANs and U-net networks. The model embeds the KAN-Conv convolutional module based on KANs in the encoder section, introduces the feature pyramid attention module (FPA) at the junction of the encoder and decoder, and introduces the CBAM attention mechanism module in the decoder section. The experimental results show that the improved KANs-Unet model has a mIoU improvement of about 10% compared to the PSPNet algorithm and an improvement of about 7.8% compared to the PAN algorithm. It has better detection performance than the currently popular semantic segmentation algorithms. A higher evaluation index represents that the detected abnormal area is closer to the label value (i.e., the detected abnormal area is more complete), indicating better detection performance. To further investigate the characteristics of kernel anomaly areas and the differences in features during magnetic storms, the author studied the characteristics of kernel anomaly areas during two different intensities of magnetic storms: from November 2021 to October 2022 and from 1 May 2024 to 13 May 2024 (large magnetic storm), and from 11 October 2023 to 23 October 2023 (moderate magnetic storm). During a major geomagnetic storm, the overall distribution of kernel anomaly areas shows a parallel trend with a band-like distribution. The spatial distribution of magnetic latitudes is relatively scattered, especially in the southern hemisphere, where the magnetic latitudes are wider. Additionally, the number of orbits with kernel anomaly areas during ascending increases, especially during peak periods of major geomagnetic storms. The overall spatial distribution of moderate geomagnetic storms does not change significantly, but the global magnetic latitude distribution is relatively concentrated.","PeriodicalId":8580,"journal":{"name":"Atmosphere","volume":"16 2","pages":"160-160"},"PeriodicalIF":0.0,"publicationDate":"2025-01-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147917010","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Simultaneous Catalytic Oxidation of Benzene and Toluene over Pd-CeZrOx Catalysts","authors":"Xing Xin, Yixin Wang, Meiping Hao, Zhe Li, Dandan Liu, Kezhou Yan","doi":"10.3390/atmos15111301","DOIUrl":"https://doi.org/10.3390/atmos15111301","url":null,"abstract":"Since actual industrial emissions contain a wide range of volatile organic compounds, studies into the simultaneous catalytic degradation of multi-component VOCs are essential. This work developed Pd-CeZrOx samples for the simultaneous elimination of benzene and toluene. Firstly, CeZrOx supports were synthesized using several methods (co-precipitation, CTAB template co-precipitation, and sol–gel method). Pd active species were then added into the 1.0Pd-CeZrOx samples using the impregnation procedure. XRD, BET, NH3-TPD, Raman, EPR, XPS, and H2-TPR were utilized to analyze the as-prepared Pd-CeZrOx samples. The catalytic performance tests reveal that the performance of 1.0Pd-CeZrOx-CTAB outperforms that of 1.0Pd-CeZrOx-PM and 1.0Pd-CeZrOx-CASG, and 1.0Pd-CeZrOx-CTAB displays superior catalytic activity for both benzene and toluene oxidation. The improved redox properties, the abundant surface oxygen vacancies, and the surface Pd2+ species of the 1.0Pd-CeZrOx-CTAB sample may be responsible for the simultaneous degradation activity of benzene and toluene.","PeriodicalId":8580,"journal":{"name":"Atmosphere","volume":"15 11","pages":"1301-1301"},"PeriodicalIF":0.0,"publicationDate":"2024-10-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.mdpi.com/2073-4433/15/11/1301/pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147903386","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}