Tribology Letters最新文献

{"title":"Sliding on Slide-Ring Gels","authors":"Andrew R. Rhode,&nbsp;Iván Montes de Oca,&nbsp;Michael L. Chabinyc,&nbsp;Christopher M. Bates,&nbsp;Angela A. Pitenis","doi":"10.1007/s11249-024-01920-x","DOIUrl":"10.1007/s11249-024-01920-x","url":null,"abstract":"<div><p>Recent investigations have pointed to physical entanglements that greatly outnumber chemical crosslinks as key sources of energy dissipation and low friction in hydrogel networks. Slide-ring gels are an emerging class of hydrogels described by their mobile crosslinks, which are formed by rings topologically constrained to slide along linear polymer chains within the network. These materials have enjoyed decades of study by polymer chemists but have been underexplored by the tribology community. In this work, we synthesized a pseudo-rotaxane crosslinker from poly(ethylene glycol) diacrylate (PEG-diacrylate) and <i>α</i>-cyclodextrin-acrylate followed by hydrogel networks by connecting the sliding crosslinks with polyacrylamide chains. The mechanical and tribological properties of slide-ring hydrogels were investigated using a custom-built microtribometer. Slide-ring hydrogels exhibit unique behavior compared to conventional covalently crosslinked polyacrylamide hydrogels and offer a vast design space for future investigations.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":806,"journal":{"name":"Tribology Letters","volume":"72 4","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11249-024-01920-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142414447","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Preparation of Graphene and Its Tribological Properties Based on Deep Eutectic Solvent Stripping Method","authors":"Ting Li,&nbsp;Yun Chen,&nbsp;Rui Wang,&nbsp;Junhai Wang,&nbsp;Xinran Li,&nbsp;Lixiu Zhang","doi":"10.1007/s11249-024-01919-4","DOIUrl":"10.1007/s11249-024-01919-4","url":null,"abstract":"<div><p>Graphene (GP), when used as a lubricant additive, not only reduces the friction coefficient but also enhances wear resistance by forming a protective lubrication film. However, there are still several challenges in practical applications related to graphene preparation. Therefore, this study employs a novel type of ionic liquid deep eutectic solvent as an interlayer agent for graphene preparation and investigates its tribological properties when used as an additive. We used choline chloride/ethylene glycol deep eutectic solvent as the intercalation agent and successfully prepared graphene samples using liquid-phase exfoliation. The resulting graphene samples had a thickness of 4–5 layers. The peeling mechanism is analyzed through molecular dynamics simulations and characterization techniques such as Raman spectroscopy, XRD, SEM, and AFM. In friction experiments conducted with different mass fractions of 1.5 wt% DES and 0.05 wt% GP as lubricant additives, it is observed that the mixture exhibits optimal lubrication performance compared to base oil alone; specifically reducing average friction coefficient by 56.8% and depth of wear marks by 59.8%. This enhancement in friction performance can be attributed to both high wettability and synergistic effects between composite lubricants. Considering the wide range of available DESs and two-dimensional materials, these newly developed functional two-dimensional materials based on DES hold significant research potential.</p></div>","PeriodicalId":806,"journal":{"name":"Tribology Letters","volume":"72 4","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142413565","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Strongly Different Adhesion Reduction for 1D or 2D Random Fractal Roughness, and an Extension of the BAM Model to Anisotropic Surfaces","authors":"M. Ciavarella,&nbsp;F. Pérez-Ràfols","doi":"10.1007/s11249-024-01916-7","DOIUrl":"10.1007/s11249-024-01916-7","url":null,"abstract":"<div><p>The influence of roughness on adhesion has been studied since the time of Fuller and Tabor, but recently there has been debate about how roughness exactly seems to kill (but sometimes enhance!) adhesion, particularly with reference to the accepted model of fractal roughness. We show that the Persson–Tosatti criterion does not depend on anisotropy of the surface for a typical power law PSD if written in terms of rms roughness and magnification. Instead, a very simple extension of the Bearing Area Model (BAM) of Ciavarella to anisotropic fractal surface shows a weak but clear dependence on the anisotropy, with higher adhesion in the 1D case, showing better agreement than the Persson–Tosatti criterion to actual numerical results of Afferrante Violano and Dini. However, neither of the two models permit to capture the strong hysteresis found in experiments between loading and unloading, which is very likely to enhance adhesion more as we move from the isotropic to the full 1D case. This suggests the mechanism of load amplification along contact lines and the associated elastic instabilities, is not captured by either the Persson–Tosatti or the BAM model applied to anisotropic surfaces.</p></div>","PeriodicalId":806,"journal":{"name":"Tribology Letters","volume":"72 4","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11249-024-01916-7.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142412490","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Friction Enhancement and Autoparametric Resonance","authors":"S. Yu. Krylov","doi":"10.1007/s11249-024-01918-5","DOIUrl":"10.1007/s11249-024-01918-5","url":null,"abstract":"<div><p>Recent intriguing experimental observations of atomic scale friction enhancement, that takes place at scanning velocities correspondent with the cantilever frequency and/or its fractions (1/<i>n</i>, <i>n</i> = 1, 2, 3, …), can be explained as the manifestation of an autoparametric resonance. Taking explicitly into account high flexibility of AFM tips, the developed theory reveals the autoparametric resonance to be a natural consequence of the rich dynamics of the combined tip–cantilever system. Besides the explanation of the observed friction force peaks, the theory predicts a dense multiplicity of smaller peaks to appear when the washboard frequency coincides with a rational part (m/n, with integer m and n) of the cantilever frequency. An important conclusion is made that the resonance enhancement of friction is independent of frequency of excited phonons, and it should manifest itself for any possible mechanism of frictional energy dissipation in the substrate, phononic, electronic, or any other.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":806,"journal":{"name":"Tribology Letters","volume":"72 4","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142252648","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Friction Coefficient Evolution of Si3N4 Binary Coating with a Stoichiometric Ratio of 57/43","authors":"C. H. Ortiz,&nbsp;J. M. Fuertes,&nbsp;M. Bejarano,&nbsp;V. Barrera,&nbsp;J. C. Caicedo","doi":"10.1007/s11249-024-01909-6","DOIUrl":"10.1007/s11249-024-01909-6","url":null,"abstract":"<div><p>Friction coefficient depends on various factors or surface characteristics during tribological testing, and this friction coefficient can be modified by altering the properties of one of the two contacting surfaces. It is crucial to monitor the friction coefficient continuously, not only at the conclusion of the test. This research examined the evolution of friction coefficient of silicon nitride (Si₃N₄) coating and H13 steel over different sliding distances (250, 500, 750, 1000 m). The study assessed surface wear and oxidation through three-dimensional profilometry and SEM/EDX. The findings indicated a reduction in friction coefficient by 22%, a decrease in wear rate by 88%, and a reduction in wear volume by 87% when comparing the silicon nitride coated steel to the uncoated steel. Furthermore, the changes in friction coefficient provided insights into the timing of the complete fracture of the hard coating.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":806,"journal":{"name":"Tribology Letters","volume":"72 4","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11249-024-01909-6.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142252647","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Molecular Simulation of Contact/Separation Behavior of Platinum Surfaces with Adsorbed Acetylenes","authors":"Chunhong Li,&nbsp;Fangli Duan","doi":"10.1007/s11249-024-01917-6","DOIUrl":"10.1007/s11249-024-01917-6","url":null,"abstract":"<div><p>Ambient hydrocarbons adsorbed on the contact surface of nanoelectromechanical (NEM) switches would impact its performance. In this study, we utilized reactive molecular dynamics simulations to investigate the cyclic contact/separation process of Pt(111)/C₂H₂/Pt(111) systems. Our results demonstrate that substrate damage decreases as acetylene coverage increases from sub-monolayer to multilayer. This suppression occurs due to the presence of acetylene molecules, which can suppress direct (Pt–Pt connection) and indirect (Pt–(C_<i>x</i>)–Pt-like connection) interfacial bonding between the two substrates, depending on their coverage. Moreover, we observed the formation of chain-like oligomers after multiple contact/separation simulations in the monolayer model, much more significantly compared with the sub-monolayer and multilayer models. These oligomers arise from polymerization reactions among fragmented acetylene molecules, primarily formed through acetylene dehydrogenation. In the sub-monolayer model, numerous transferred Pt atoms at the interface hinder bonding between acetylene fragments, whereas in the multilayer model, only a few acetylene fragments form during the contact process, due to the well-organized and dense acetylene layer adsorbed on the substrate surfaces. These insights shed light on the atomic-scale mechanisms underlying substrate damage and chain-like oligomers formation in metal NEM switches.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":806,"journal":{"name":"Tribology Letters","volume":"72 4","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142221002","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Newly Developed Heavy-Haul Wheel Steel with Excellent Rolling Contact Fatigue Performance Assessed by an Innovative Vision System","authors":"Ting-wei Zhou,&nbsp;Hai Zhao,&nbsp;Hang Yuan,&nbsp;Zhen-lin Xu,&nbsp;Yi-zhu He,&nbsp;Shi-huai Su,&nbsp;Dong-fang Zeng","doi":"10.1007/s11249-024-01914-9","DOIUrl":"10.1007/s11249-024-01914-9","url":null,"abstract":"<div><p>As railway transportation advances towards higher speeds and increased axle loads, the fatigue damage between wheels and rails has become more severe, significantly limiting the service life and safety of trains. Therefore, developing upgrade wheel-rail materials with enhanced contact fatigue properties has been considered an effective approach to avoid damage. This study reports a newly developed heavy-haul wheel steel with a superior rolling contact fatigue performance and the fatigue damage of wheel was studied by a novel RCF tester with a vision system. The results indicate that the newly developed heavy-haul wheel steel (NW) consists of smaller pearlite layer spacing and reduced proeutectoid ferrite. The NW steel demonstrates outstanding fatigue resistance in both oil and dry conditions, with a fatigue life 2.7 times longer than CL65 wheel steel and superior performance compared to most typical wheel steels. With increasing in pearlite content and decreasing in pearlitic interlamellar spacing, the fatigue damage degree of wheels under oil or dry contact conditions decreases obviously, leading to a significant enhancement in fatigue life. Properly controlling the pearlite content and the interlamellar spacing can optimize the fatigue properties of wheel materials. The vision system observed that the average area and perimeter of the defects gradually increased on the sample surface. The shape of the defect became more rounded under oil contact conditions but showed the opposite result in dry contact. When subjected to cyclic loading, surface cracks propagated along various paths after initiation, eventually forming different morphologies of peeling. The results will not only help optimize wheel materials for heavy-haul railways, but also offer an effective means for analyzing damage evolution in wheel-rail contact.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":806,"journal":{"name":"Tribology Letters","volume":"72 4","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142221004","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Multiscale Parametrization Of a Friction Model For Metal Cutting Using Contact Mechanics, Atomistic Simulations, And Experiments","authors":"Hannes Holey,&nbsp;Florian Sauer,&nbsp;Prasanth Babu Ganta,&nbsp;Leonhard Mayrhofer,&nbsp;Martin Dienwiebel,&nbsp;Volker Schulze,&nbsp;Michael Moseler","doi":"10.1007/s11249-024-01906-9","DOIUrl":"10.1007/s11249-024-01906-9","url":null,"abstract":"<div><p>In this study, we developed and parametrized a friction model for finite element (FE) cutting simulations of AISI4140 steel, combining experimental data and numerical simulations at various scales. Given the severe thermomechanical loads during cutting, parametrization of friction models based on analogous experiments has been proven difficult, such that the cutting process itself is often used for calibration. Instead, our model is based on the real area of contact between rough surfaces and the stress required to shear adhesive micro contacts. We utilized microtextured cutting tools and their negative imprint on chips to orient chip and tool surfaces, enabling the determination of a combined surface roughness. This effective roughness was then applied in contact mechanics calculations using a penetration hardness model informed by indentation hardness measurements. Consistent with Bowden and Tabor theory, we observed that the fractional contact area increased linearly with the applied normal load, and the effective roughness remained insensitive to cutting fluid application. Additionally, we calculated the required shear stress as a function of normal load using DFT-based molecular dynamics simulations for a tribofilm formed at the interface, with its composition inferred from ex-situ XPS depth profiling of the cutting tools. Our friction model demonstrated good agreement with experimental results in two-dimensional FE chip forming simulations of orthogonal cutting processes, evaluated by means of cutting force, passive force, and contact length prediction. This work presents a proof of concept for a physics-based approach to calibrate constitutive models in metal cutting, potentially advancing the use of multiscale and multiphysical simulations in machining.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":806,"journal":{"name":"Tribology Letters","volume":"72 4","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11249-024-01906-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142221092","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Electronic Properties and Friction Characteristics of GeSe/SnS Heterostructures Based on the DFT Theoretical Calculations","authors":"Xing’an Cao,&nbsp;Peipei Xu,&nbsp;Xiushuo Zhang,&nbsp;Haixiang Huan,&nbsp;Linzhen Zhou,&nbsp;Chunwei Zhang","doi":"10.1007/s11249-024-01913-w","DOIUrl":"10.1007/s11249-024-01913-w","url":null,"abstract":"<div><p>Constructing van der Waals (vdW) heterostructures offers a feasible approach for enhancing the electronic properties and obtaining superlubricity of various electromechanical devices. Here, the electronic and frictional properties of GeSe/SnS heterostructures were investigated through first-principle calculations based on density function theory. The GeSe/SnS bilayer with AC stacking configuration revealed a direct band structure with a gap value of about 0.95 eV and a standard typical type-II band alignment. Within the GeSe/SnS vdW heterostructure, AC stacking setup demonstrates a more uniform potential energy surface (PES) than AB stacking arrangement, verified by a lower friction barrier. The peak PES value of the GeSe/SnS heterostructure in AC stacking is merely 0.0016 eV. The weak vdW interaction between the adjacent layers in vdW heterostructure and smooth PES are responsible for reducing potential energy fluctuations and friction. The investigation on the friction characteristics of GeSe/SnS vdW heterostructure with AC stacking configuration provides valuable insights for understanding the atomic-scale friction behavior in two-dimensional (2D) materials.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":806,"journal":{"name":"Tribology Letters","volume":"72 4","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142221094","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effect of Water on Wear of DLC Coatings in High Temperature and Pressurized Ethanol","authors":"T. Tokoroyama,&nbsp;S. Horikawa,&nbsp;J. Mimata,&nbsp;N. Umehara,&nbsp;M. Murashima","doi":"10.1007/s11249-024-01910-z","DOIUrl":"10.1007/s11249-024-01910-z","url":null,"abstract":"<div><p>The friction and wear characteristics of a-C:H:Si and a-C:H coatings in an ethanol environment at 120 °C and 10 MPa focusing on the effects of water and dissolved oxygen in ethanol were investigated. The friction tests were conducted using an autoclave chamber, with gases (oxygen or nitrogen) and ethanol–water mixtures (0 and 6 vol.%). The wear acceleration of a-C:H:Si took place when it slid in ethanol with 6 vol.% water and pressurized by oxygen, thus the specific wear rate was the highest, approximately 1.8 × 10⁻⁷ mm³/Nm. The reason of this wear acceleration was assumed the effect of hardness reduction due to oxidation of the a-C:H:Si, so the O/C ratio by AES and the hardness of topmost surface by AFM nano-scratch were investigated. As a result, the higher O/C ratio showed higher specific wear rate due to the hardness reduction from 13.3 to 6.0 GPa. These findings highlight the role of water and dissolved oxygen in accelerating wear of a-C:H:Si coatings.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":806,"journal":{"name":"Tribology Letters","volume":"72 4","pages":""},"PeriodicalIF":2.9,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11249-024-01910-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142221093","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}