ACS Applied Polymer Materials最新文献

{"title":"Eco-Friendly Hybrid Materials for Steel Protection Using a Water-Soluble Polyamic Acid as Chelating Agent","authors":"Chung-Ta Hsieh,&nbsp;Ying-Chi Huang,&nbsp;Tsung-Yu Yu,&nbsp;Kuan-Syun Wang,&nbsp;Yu-Wei Cheng,&nbsp;Chien-Hsin Wu* and Ru-Jong Jeng*,&nbsp;","doi":"10.1021/acsapm.5c0098910.1021/acsapm.5c00989","DOIUrl":"https://doi.org/10.1021/acsapm.5c00989https://doi.org/10.1021/acsapm.5c00989","url":null,"abstract":"<p >In this study, an environmentally friendly waterborne coating was developed as a corrosion inhibitor for mild steel (MS) through the synthesis of a polymeric dispersion. Initially, a water-soluble polyamic acid (PAmA) solution was synthesized utilizing ethylenediaminetetraacetic dianhydride and 2,2-(ethylenedioxy)bis(ethylamine). The incorporation of ether linkages and amic acid functional groups into the polymer backbone generates numerous polar sites, thereby facilitating the formation of a stable aqueous organosilane dispersion predominantly composed of 3-glycidoxypropyl trimethoxysilane (GPTMS), without the use of surfactants or additional salts. Additionally, 25 wt % of GPTMS can be replaced with tetraethyl orthosilicate (TEOS), which serves primarily as a crosslinking agent and a precursor for nanosilica, resulting in an aqueous organic/inorganic dispersion under optimized conditions. Comparative analyses with reference samples, such as polyacrylic acid dispersion, demonstrated a higher degree of condensation of 94.6% for the organic/inorganic dispersion in PAmA, as confirmed by Raman spectroscopy and ²⁹Si-NMR following sol-gel reactions. These results indicate the formation of extensive cross-linking sites and a silica network, which serves as passive layers, yielding a thermal decomposition temperature exceeding 380 °C for the organic/inorganic layer produced by the PAmA polymer. Notably, the application of the PAmA solution not only enhanced cross-linking density and facilitated the formation of a silica network for the organic/inorganic dispersion but also provided the formation of imide structures, leading to a robust sol-gel-derived hybrid coating system, consistent with findings from FTIR and DSC analyses. Consequently, this study demonstrates the successful development of an eco-friendly corrosion inhibitor that exhibits outstanding performance in salt spray tests and superior corrosion protection efficiency (η = 99.7%), as determined by electrochemical impedance spectroscopy for MS.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 10","pages":"6513–6522 6513–6522"},"PeriodicalIF":4.4,"publicationDate":"2025-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsapm.5c00989","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144114694","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis of Fatty Alcohol-Modified Maleic Anhydride Copolymer and Its Application in Shape-Stabilized Phase Change Materials","authors":"Qu Wang,&nbsp;Bingzheng Jiang,&nbsp;Dong Chen,&nbsp;Li Wang* and Wantai Yang*,&nbsp;","doi":"10.1021/acsapm.5c0032210.1021/acsapm.5c00322","DOIUrl":"https://doi.org/10.1021/acsapm.5c00322https://doi.org/10.1021/acsapm.5c00322","url":null,"abstract":"<p >The petrochemical industry produces many intermediate products rich in mixed olefinic fractions, which call for more efficient utilization. Herein, the self-stabilized precipitation polymerization was used to copolymerize C5 mixed olefins contained in light naphtha with maleic anhydride, giving light naphatha-based maleic anhydride copolymer PLNM. PLNM was grafted with fatty alcohols of different chain lengths by esterification reaction and subjected to amidation reaction with amino-terminated polyoxypropylene D230 to construct a 3D cross-linking network for shape-stabilized phase change materials (SSPCMs). The esterification kinetics were investigated in detail, which enabled the preparation of a series of fatty alcohol-modified PLNM (FMPLNM) bearing good compatibility with corresponding fatty alcohols above a critical esterification degree. The shape stability, thermal storage performance, cyclic stability, and thermal management performance of the light naphtha-based SSPCMs were assessed systematically. Thus, we have developed an efficient approach to converting “waste” olefins in light naphtha into high-value-added SSPCMs with good shape stability, high enthalpy efficiency, and outstanding thermal management performance.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 10","pages":"5993–6002 5993–6002"},"PeriodicalIF":4.4,"publicationDate":"2025-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144114881","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Efficient Control of Swelling and Strength of Polyacrylamide/Polyacrylic Acid/Chitosan Hydrogels for NaF Release","authors":"Xinmeng Zhang*,&nbsp;Xunwei Wang and Peizhong Feng*,&nbsp;","doi":"10.1021/acsapm.5c0064910.1021/acsapm.5c00649","DOIUrl":"https://doi.org/10.1021/acsapm.5c00649https://doi.org/10.1021/acsapm.5c00649","url":null,"abstract":"<p >Topical fluoride administration has been widely recognized as an effective strategy for caries prevention. Hydrogels, owing to their unique hydrated networks and tunable physicochemical properties, have emerged as promising candidates for localized fluoride delivery. However, the controlled sustained release of fluoride ions (F^–) from hydrogels in moist environments continues to present significant technical challenges. In this study, we constructed a fluoride-loaded hydrogel system through a copolymerization strategy of chitosan (CS), acrylic acid (AA), and acrylamide (AM). The mesh size of the hydrogel was significantly reduced by the synergistic cross-linking effect of the hydrogen bond network and Zr⁴⁺-carboxyl coordination, thereby achieving the sustained release performance of F^–. Benefiting from the ion cross-linking sites provided by hydrated zirconium ions and the hydrogen bond interactions, the hydrogel shows remarkable property enhancements: tensile stress increases by 159% (from 0.37 to 0.96 MPa) while swelling ratio decreases by 97.4% (from 4600 to &lt;120%). The in vitro release experiment results showed that the cumulative release rate at 24 h decreased from 90 to 24%, effectively avoiding the initial burst release phenomenon and significantly prolonging the release time. The release mechanism was further investigated by fitting the in vitro release data to the zero-order model, the first-order model, and the Korsmeyer–Peppas model. The kinetic model fitting results indicated that the Peppas model had the best fitting effect, with a correlation coefficient (<i>R</i>²) of 0.9875 and a diffusion exponent <i>n</i> = 0.4060, suggesting that it conformed to the Fickian diffusion mechanism.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 10","pages":"6225–6239 6225–6239"},"PeriodicalIF":4.4,"publicationDate":"2025-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144114880","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Halogen-Free Poly(Ionic Liquid) Water-Based Lubricant Additive with Superior Viscosity-Building and Lubricating Properties","authors":"Yongbo Duan,&nbsp;Xiao Liu*,&nbsp;Pingxia Guo,&nbsp;Qiang Chen,&nbsp;Meirong Cai* and Feng Zhou,&nbsp;","doi":"10.1021/acsapm.5c0070310.1021/acsapm.5c00703","DOIUrl":"https://doi.org/10.1021/acsapm.5c00703https://doi.org/10.1021/acsapm.5c00703","url":null,"abstract":"<p >A protic poly(ionic liquid) (PPIL), PPDG, was synthesized by using a copolymer as the cationic component and halogen-free octanoylglycine as the anionic counterpart. The viscosity-enhancing and tribological properties of the PPDG additive were systematically characterized. In addition, scanning electron microscopy (SEM), electrical contact resistance (ECR), X-ray photoelectron spectroscopy (XPS), and time-of-flight secondary ion mass spectrometry (ToF-SIMS) analysis were employed to elucidate the lubrication mechanisms of PPDG. The results indicate that the addition of PPDG in deionized water significantly enhances the viscosity, anticorrosion, and tribological performance of the water-based lubricant. The coefficient of friction (COF) and wear volume (WV) of the water-based lubricant with 8% PPDG were reduced by approximately 68 and 75%, respectively, compared with deionized water. The synergistic action of the physical adsorption film and the tribochemical reaction film formed at the friction interface endows the lubricant with superior lubrication and anticorrosion properties. This type of PPIL lubricant additive is free of sulfur, phosphorus, and halogen elements, making it environmentally friendly. It demonstrates significant potential for application in fully synthetic water-based metalworking fluids or nonflammable hydraulic fluids.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 10","pages":"6240–6249 6240–6249"},"PeriodicalIF":4.4,"publicationDate":"2025-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144114777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Polyimide/Metal–Organic Framework-5 Separator with Excellent Electrolyte Wettability and Thermal Stability for High Performance Lithium-Ion Battery","authors":"Xiaoyan Song*,&nbsp;Wanchun Huang,&nbsp;Hao Wang,&nbsp;Yi Ming Lu and Jinfeng Xing,&nbsp;","doi":"10.1021/acsapm.5c0079310.1021/acsapm.5c00793","DOIUrl":"https://doi.org/10.1021/acsapm.5c00793https://doi.org/10.1021/acsapm.5c00793","url":null,"abstract":"<p >The safety and performance of lithium-ion batteries (LIBs) are closely related to the separator. Commercial polyolefin separators hinder electrochemical performance and may result in safety issues at high temperatures due to insufficient thermal stability and electrolyte wettability. In this work, a polyimide (PI)/metal–organic framework-5 (MOF-5) composite separator was prepared via in situ polymerization and electrospinning. The tensile strength of the PI/MOF-5 composite membrane was superior to that of the PI membrane by 104%. The outstanding flame retardancy of the PI/MOF-5 composite separator significantly enhances the safety of lithium-ion batteries, especially in high-temperature environments. The PI/MOF-5 separator demonstrated a high number of lithium-ion transferences (<i>t</i>_Li⁺ = 0.79). The cell using the PI/MOF-5 separator exhibited excellent cycling performance, with an initial discharge capacity of 174.7 mA h/g at a current density of 0.5 C, which is 140.8 and 46.6% higher than that of the LIB coin cell with a polypropylene (PP) separator and PI separator, respectively. After 200 cycles at a current density of 0.5 C, the specific discharge capacity of the battery using the PI/MOF-5 separator still maintained 89.02% of the initial specific discharge capacity, which is higher than that of the PP and PI separators. Consequently, the outstanding properties of the PI/MOF-5 composite separator indicate its potential in high-performance lithium-ion batteries.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 10","pages":"6312–6325 6312–6325"},"PeriodicalIF":4.4,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144114617","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis of Triphenylamine-Based Hyper-Branched Polymers via Cobalt-Catalyzed [2 + 2 + 2] Cycloaddition Polymerization of Alkynes and Their Conductive Properties","authors":"Yuga Tsunoda,&nbsp;Kouta Ibe and Sentaro Okamoto*,&nbsp;","doi":"10.1021/acsapm.5c0099110.1021/acsapm.5c00991","DOIUrl":"https://doi.org/10.1021/acsapm.5c00991https://doi.org/10.1021/acsapm.5c00991","url":null,"abstract":"<p >Hyperbranched polymers bearing triphenylamine (TPA) moieties in the polymer backbone are synthesized via cobalt-catalyzed [2 + 2 + 2] cycloaddition copolymerization of TPA-based diynes and internal monoalkyne monomers. The resulting polymers are soluble in organic solvents, exhibit good thermal stability, and exist in a solid amorphous-like morphology. Hole-only devices made from these polymers exhibit electrical conductivity that is suitable for use as hole injection and transport materials.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 10","pages":"6552–6560 6552–6560"},"PeriodicalIF":4.4,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144114555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Halloysite Nanoclay Reinforced Biobased Polyurethane Nanocomposite Polymer Electrolyte","authors":"Atika Alhanish,&nbsp;KaiLing Chai,&nbsp;Nurul Ilham Adam,&nbsp;Nurul Akmaliah Dzulkurnain,&nbsp;Khairiah Haji Badri,&nbsp;Ubaidah Syafiq and Mohd Sukor Su’ait*,&nbsp;","doi":"10.1021/acsapm.4c0420410.1021/acsapm.4c04204","DOIUrl":"https://doi.org/10.1021/acsapm.4c04204https://doi.org/10.1021/acsapm.4c04204","url":null,"abstract":"<p >Developing polyurethane (PU) with enhanced physicochemical properties through cost-effectiveness and a sustainable approach is currently a significant challenge. This challenge aims to address the shortcomings of conventional options. In this study, a series of biobased PU nanocomposites derived from crop oil, incorporating natural halloysite clay nanotubes (HNTs) as filler, shows promising potential to reduce dependency on petroleum derivatives harness. A monoester polyol was prepared via the polyesterification of crop oil to prepare biobased PU nanocomposite polymeric films with different HNT content (0, 2, 4, 6, and 8 wt %). The obtained films were characterized by their chemical functional groups and interactions, morphology, thermal, mechanical, and electrochemical properties. Fourier transform infrared spectroscopy analysis confirmed the formation of urethane linkage in PU and the interaction between PU chains and HNTs. Scanning electron microscope showed well homogeneity and dispersion of HNTs. The presence of HNTs also affected the mobility of PU chains, a reduction in crystallinity and glass transition temperature (<i>T</i>_g) were confirmed by X-ray diffraction and differential scanning calorimetry, respectively. This was revealed also by the enhancement of thermal stability and mechanical properties compared to neat PU. At 6 wt % HNT, maximum tensile strength was 153% higher compared to neat PU while Young’s modulus increased by 443% than neat PU at 2 wt %. The key findings demonstrated that adding HNTs enhanced the estimated ionic conductivity and dielectric properties. Dielectric relaxation peaks with non-Debye relaxation behavior were observed for all samples. The highest electric and dielectric performance was recorded for the sample with 6 wt % of HNTs attributed to the well dispersion of the individual and partial agglomerates. These findings indicate a promising nanocomposite polymer electrolyte host with proper mechanical stability to withstand the electrode stack pressure and stresses caused by dimensional changes in the rechargeable batteries.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 10","pages":"5884–5897 5884–5897"},"PeriodicalIF":4.4,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144114521","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Influence of Grafting Density and the Ionic Environment on the Structure of Zwitterionic Brushes","authors":"Judith Witte,&nbsp;Alexandros Koutsioubas,&nbsp;Samantha Micciulla,&nbsp;Laura Roxana Stingaciu,&nbsp;Mariano Andrés Paulin,&nbsp;Margarethe Dahl,&nbsp;Christian Fettkenhauer,&nbsp;Joerg Lahann,&nbsp;Olaf Holderer and Stefan Wellert*,&nbsp;","doi":"10.1021/acsapm.4c0287910.1021/acsapm.4c02879","DOIUrl":"https://doi.org/10.1021/acsapm.4c02879https://doi.org/10.1021/acsapm.4c02879","url":null,"abstract":"<p >Zwitterionic polymer brushes possess a high potential for applications as surface coatings, e.g., in antifouling applications. Their complex association behavior due to the coexistence of oppositely charged groups on the same monomeric unit allows for a broad variation of polarity, hydrophilicity, and the antipolyelectrolyte effect with the variation of the surrounding environment. In this study, planar polysulfobetaine brushes were investigated with neutron reflectometry (NR) and neutron spin–echo spectroscopy under grazing incidence (GINSES) to explore the brush structure and its inner dynamics perpendicular to the substrate. In particular, the effects of the substrate–initiator system and ionic strength on the structure were investigated with neutron reflectometry and a swelling by a factor of 3–5 was found in the presence of aqueous NaCl and MgCl₂ solutions compared to the dry state. During the data analysis, the applicability of a model-free evaluation was also demonstrated for the investigated polysulfobetaine brushes. Furthermore, it was found with GINSES that in contrast to neutral brushes, these polysulfobetaine brushes do not show the typical concentration fluctuations in the nanosecond time range when partially swollen with salt-free water.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 10","pages":"5807–5819 5807–5819"},"PeriodicalIF":4.4,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsapm.4c02879","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144114616","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Highly Stable, Tough, Adhesive, Anticorrosive, and Antifouling Waterborne Polyurethane from Synergistic Perfluoroalcohol-Polysiloxane Modifications","authors":"Mingfei Li,&nbsp;Yujie Yang,&nbsp;Weifeng Jiang,&nbsp;Yi Yang* and Jingcheng Hao*,&nbsp;","doi":"10.1021/acsapm.5c0075910.1021/acsapm.5c00759","DOIUrl":"https://doi.org/10.1021/acsapm.5c00759https://doi.org/10.1021/acsapm.5c00759","url":null,"abstract":"<p >Waterborne polyurethanes (WPUs) have found extensive potential applications in industrial fields owing to their facile preparation and eco-friendliness. However, their relatively low hydrophobicity and mechanical strength normally make them nonideal for acting as protective coatings for solid surfaces, as well as adhesive materials for under-water operations. Here, we report one kind of WPU-based material synergistically modified with perfluoroalcohol and polysiloxane. The as-prepared WPU products can not only exhibit long-term colloidal stability after synthesis using a stepwise polymerization method but also readily be processed into functional coatings after directly spreading onto various solid substrates. The resultant polymeric thin films possess good thermal stability, strong hydrophobicity, and high mechanical strength. And all of these properties can be effectively tuned by controlling their internal silicon contents. The excellent hydrophobic and mechanical performances also enable them to act as efficient anticorrosive, antifouling, and under-water adhesive materials for solid surfaces. Our work may provide useful guidance for creating versatile and relatively clean polymeric coatings.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 10","pages":"6272–6283 6272–6283"},"PeriodicalIF":4.4,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144114615","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Scavenger Resin Enabling Simplification of Complicated Living Anionic Polymerization","authors":"Jiye Yang,&nbsp;Dayin Sun,&nbsp;Anqi Gu,&nbsp;Zhendong Wen,&nbsp;Yan Wang and Zhenzhong Yang*,&nbsp;","doi":"10.1021/acsapm.5c0095410.1021/acsapm.5c00954","DOIUrl":"https://doi.org/10.1021/acsapm.5c00954https://doi.org/10.1021/acsapm.5c00954","url":null,"abstract":"<p >Since Szwarc first proposed living anionic polymerization in Nature (1956), this method has proven to be the most powerful approach for large-scale synthesis of nearly uniform polymers with tunable compositions and microstructures. Eliminating various impurities toward the absolute purification of reagents and vessels is a prerequisite for living polymerization. Conventional purification methods are laborious and highly specific for the reagents, significantly limiting the potential of the anionic polymerization. Herein, we develop a facile and universal purification method by the anionic initiating scavenger resin that eliminates impurities via self-sacrificial reactions, substantially simplifying the process. For representative synthesized homopolymers, the degree of polymerization (DP) shows a strict linear correlation with monomer/initiator molar ratios (R) according to DP = R while maintaining low dispersity indices (<i>Đ</i> ≈ 1.03). The living anionic polymerization also enables scalable production of nearly uniform copolymers through designed one-batch sequential polymerization. This large-scale synthesis of composition-controlled polymers with a narrow distribution advances the fundamental understanding of structure-performance relationships and supports the precise construction of uniform self-assembled nanostructures.</p>","PeriodicalId":7,"journal":{"name":"ACS Applied Polymer Materials","volume":"7 10","pages":"6493–6499 6493–6499"},"PeriodicalIF":4.4,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144114559","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}