Inorganic Chemistry Frontiers最新文献_第6页

π-Stacked columnar assembly of a homoleptic 1,1′,2,2′-tetraphosphaferrocene derivative 同色1,1 ',2,2 ' -四磷二茂铁衍生物的π堆叠柱状组合

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-16 DOI: 10.1039/d6qi01772j

Ilya Alexandrovich Bezkishko,Almaz Zagidullin,Almaz Linarovich Zinnatullin,Mikhail Khrizanforov,Robert R. Fayzullin,Andrey V. Petrov,Olga Kataeva,Farit Vagizov,Miluykov Vasili,Evamarie Hey-Hawkins

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Far-Infrared Magnetospectroscopy (FIRMS): An Emerging Technique for Transition Metal (d Block) Chemistry 远红外磁光谱学（FIRMS）：过渡金属（d嵌段）化学的新兴技术

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-16 DOI: 10.1039/d6qi01351a

Mykhaylo Ozerov,Joshua Telser

{"title":"Far-Infrared Magnetospectroscopy (FIRMS): An Emerging Technique for Transition Metal (d Block) Chemistry","authors":"Mykhaylo Ozerov,Joshua Telser","doi":"10.1039/d6qi01351a","DOIUrl":"https://doi.org/10.1039/d6qi01351a","url":null,"abstract":"Vibrational (“IR”) spectroscopy is used for routine characterisation of organic and inorganic/organometallic complexes, chiefly in the mid-IR region (~3500 – 700 cm-1). The far-IR (FIR) region, namely below ~700 cm-1 is rarely considered except for “fingerprinting”, although metal-ligand vibrations of interest can occur in this spectral region. Electronic transitions in transition metal complexes would be considered to be at much higher energy, minimally in the near-IR region (above ~10 000 cm-1, wavelength of ~1000 nm). Yet in many cases of paramagnetic transition metal ion complexes, there are lower energy electronic transitions, between spin sublevels resulting from zero-field splitting (zfs), a phenomenon that is the consequence of spin-orbit coupling (SOC). Such transitions can be observed in the far-IR region and their identity confirmed and refined by application of an external magnetic field, hence far-infrared magnetospectroscopy (FIRMS). Spectroscopy of this type has been known for many years, but only recently has emerged as a crucial technique for understanding paramagnetic transition metal complexes with potential application in molecular magnetism and more broadly in quantum information science. Examples of mononuclear complexes of Ni2+, Co2+, and Fe2+, representing three different spin states (S = 1, 3/2, and 2, respectively), and a special case of S = 1/2 Ni+, are given in this Highlight to demonstrate the value of FIRMS in understanding electronic structure, particularly in cases of unusual geometry such as low coordination number (2- and 3-coordinate).","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"10 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148973501","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Correction: Solvent-free synthesis of rare-earth-doped zirconia ceramic nanofiber films with enhanced luminescence for anti-counterfeiting and warm white lighting 更正：无溶剂合成稀土掺杂氧化锆陶瓷纳米纤维薄膜，增强发光，用于防伪和暖白色照明

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-16 DOI: 10.1039/d6qi90079h

Chasina,Zhiping Fan,Xiao Ling,Yang Yang,Yilin Luo,Shuyu Yang,Zhaomeng Liu,Xiangtai Meng,Tingting Yang,Yang Liu,Ying Liu,Ranbo Yu,Jinrong Bao

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Intramolecular Strain Controlled Spin-Crossover in A Discrete Co II -Terpyridine based Metallo-Organic Circular Helicate 离散型Co -三吡啶基金属有机圆螺旋体分子内应变控制的自旋交叉

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-15 DOI: 10.1039/d6qi01577h

Tian Li,Sitao Bai,Wei-Quan Lin,Huoqing Chen,Yang Liu,Yuming Guan,Qixia Bai,Peiyang Su,Zhe Zhang,Pingshan Wang,Tun Wu

{"title":"Intramolecular Strain Controlled Spin-Crossover in A Discrete Co II -Terpyridine based Metallo-Organic Circular Helicate","authors":"Tian Li,Sitao Bai,Wei-Quan Lin,Huoqing Chen,Yang Liu,Yuming Guan,Qixia Bai,Peiyang Su,Zhe Zhang,Pingshan Wang,Tun Wu","doi":"10.1039/d6qi01577h","DOIUrl":"https://doi.org/10.1039/d6qi01577h","url":null,"abstract":"Discrete polynuclear spin-crossover (SCO) metallo-organic circular helicates are promising candidates for next-generation molecular switch and spintronic materials. Co II ion shows remarkable advantages in intrinsically fast spin transition dynamics and high stimulus sensitivity of the SCO behavior, in contrast to traditional Fe II ion. However, to the best of our knowledge, intrinsic SCO in discrete multinuclear Co II circular helicates remains unexplored due to small enthalpy and entropy changes in high-spin (HS) and low-spin (LS) state transition. Herein, a family of quadruple and triple circular helicates was assembled from ditopic-tpy (tpy= 2,2':6',2''-terpyridine) ligands (L1, L2) and transition metal ions (Fe II , Co II ). Strikingly, discrete and nonstrained triple circular helicate 6 reveals rare thermally induced SCO of Co II centers (T1/2 ≈ 100 K), confirmed by single crystal X-ray diffraction (SC-XRD), electron paramagnetic resonance (EPR), and variable temperature magnetic susceptibility measurements. Additionally, it spontaneously resolves from a racemic mixture into ΔΔΔ or ΛΛΛ enantiopure entities during crystallization. Conversely, the highly strained Co II quadruple circular helicate 5 shows no SCO and crystallizes as a racemate. This work establishes an effective ligand skeleton engineering strategy to tailor SCO properties via intramolecular strain modulation, providing a new platform for the design of supramolecular magnetic switch materials.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"14 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148964387","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Engineering Layered Double Hydroxides for Photocatalytic CO2 Reduction 光催化CO2还原的工程层状双氢氧化物

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-15 DOI: 10.1039/d6qi01621a

Ruya Ma,Dawen Dong,Xuyue Wang,Hongji Li,Pengcheng Yan,Gaopeng Liu,Xiangtong Zhou,Xianglin Zhu,Peipei Sun,Zhao Mo

{"title":"Engineering Layered Double Hydroxides for Photocatalytic CO2 Reduction","authors":"Ruya Ma,Dawen Dong,Xuyue Wang,Hongji Li,Pengcheng Yan,Gaopeng Liu,Xiangtong Zhou,Xianglin Zhu,Peipei Sun,Zhao Mo","doi":"10.1039/d6qi01621a","DOIUrl":"https://doi.org/10.1039/d6qi01621a","url":null,"abstract":"The extensive combustion of fossil fuels alongside rapid economic development has intensified global energy crisis and environmental challenges. Worldwide efforts are underway to mitigate climate change caused by excessive CO2 emissions through strategies such as CO2 capture, conversion, and utilization. Among them, artificial conversion of CO2 into syngas, oxygenates, methane, and other hydrocarbons presents a promising route for CO2 resource utilization, aligning with the goals of carbon peak and carbon neutrality. The rational design of advanced catalytic materials is crucial for enhancing the performance of artificial photosynthesis in CO2 reduction and achieving practical applications. Amongst the most promising materials for CO 2 capture and utilization, layered double hydroxides (LDHs) possess a unique two-dimensional layered structure, endowing them with excellent physical and chemical properties as energy materials. To address common limitations of conventional LDH photocatalystssuch as high recombination rates of photogenerated electron-hole pairs and low solar energy utilization efficiency-this review discusses strategies including morphology control, surface modification, compositing, and utilization of LDH precursors to improve the photocatalytic CO2 reduction performance of LDHs. This review provides a reference for promising design strategies and a comprehensive understanding of the mechanism of photocatalytic redox reactions.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"19 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148964395","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Biphase Nanocrystal-Amorphous Strategy for High Energy Storage in Thin Relaxor Ferroelectrics 超薄弛豫铁电体中高能量存储的双相纳米晶-非晶策略

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-15 DOI: 10.1039/d6qi01592a

HaiYing Li,Meng Yuan,Yuzhe Yang,Wenpeng Gao,Qianqian Yang,Yonghui Wu,Pengfei Song,Jianjun Tian,Linxing Zhang

{"title":"Biphase Nanocrystal-Amorphous Strategy for High Energy Storage in Thin Relaxor Ferroelectrics","authors":"HaiYing Li,Meng Yuan,Yuzhe Yang,Wenpeng Gao,Qianqian Yang,Yonghui Wu,Pengfei Song,Jianjun Tian,Linxing Zhang","doi":"10.1039/d6qi01592a","DOIUrl":"https://doi.org/10.1039/d6qi01592a","url":null,"abstract":"To address the inherent trade-off between polarization and breakdown strength in dielectric capacitors, herein, we propose a microstructural engineering strategy via biphase nanocrystal-amorphous design to tailor the phase evolution of ferroelectric thin films. Using the Bi 3.25 La 0.75 Ti 3 O 12 (BLTZ) system fabricated via a sol-gel process as a prototype, we demonstrate that the incorporation of Zr thermodynamically induces the precipitation of a cubic Pyrochlore phase from the layered Aurivillius matrix. This strategy successfully constructs a unique \"nanocrystal-amorphous\" composite architecture, where nanocrystals of both phases are firmly embedded within a random amorphous network. This specific microstructural configuration triggers a significant synergistic enhancement mechanism: the retained Aurivillius nanocrystals ensure high polarization, the Pyrochlore phase effectively mitigates hysteresis loss, and the random amorphous network acts as a robust barrier to charge transport, substantially suppressing leakage current and elevating breakdown strength. Consequently, the film exhibits superior performance surpassing similar counterparts: even at a thickness of only 190~200 nm, it achieves an ultra-high breakdown strength (E b ) of 4.72 MV/cm, yielding a recoverable energy density of 165.3 J/cm 3 with an efficiency of 74%, alongside excellent fatigue resistance. This work demonstrates that engineering multiphase coexistence and amorphous-wrapping structures via a simple substitution strategy offers an effective route for developing high-performance dielectric energy storage materials.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"75 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148957871","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Active Solvation Regulation Enabled by Sulfate-Intercalated LDH Interphase for Ultrastable Aqueous Zn Metal Anodes 硫酸盐-嵌入LDH界面相对超稳定锌金属水阳极的主动溶剂化调控

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-15 DOI: 10.1039/d6qi01508e

Linjiao Wei,Xiaoqi Liu,Xiaoan Yu,Guangnan Cheng,Fengjin Xie,Shuo Lyu,Dahai Zhang,Xianguo Li,Yu Zhang,Zi-Feng Yan

{"title":"Active Solvation Regulation Enabled by Sulfate-Intercalated LDH Interphase for Ultrastable Aqueous Zn Metal Anodes","authors":"Linjiao Wei,Xiaoqi Liu,Xiaoan Yu,Guangnan Cheng,Fengjin Xie,Shuo Lyu,Dahai Zhang,Xianguo Li,Yu Zhang,Zi-Feng Yan","doi":"10.1039/d6qi01508e","DOIUrl":"https://doi.org/10.1039/d6qi01508e","url":null,"abstract":"Aqueous zinc-ion batteries feature high safety and low cost, yet their commercialization is severely hindered by uncontrolled dendrite growth and detrimental side reactions at Zn anodes. Herein, a sulfate-intercalated Cu-Al layered double hydroxide (LDH) is proposed as an artificial interphase that synergistically combines steric sieving with zincophilic coordination to regulate the Zn 2+ desolvation and deposition. The sub-nanometer interlayer galleries of LDH (3.7 Å) physically sieve hydrated [Zn(H 2 O) 6 ] 2+ ions to promote partial pre-desolvation and guide uniform ion flux, suppressing water-induced side reactions.Meanwhile, the confined SO 4 2-anions within the galleries act as zincophilic anchors to reconstruct the interfacial solvation configuration, accelerating desolvation kinetics while restricting SO 4 2-migration. As a result, the Cu-Al LDH interphase enables dendrite-free and highly reversible Zn deposition with significantly suppressed side reactions. The Cu-Al LDH@Zn anode delivers an ultralong cycling lifespan exceeding 2500 h with an average Coulombic efficiency of 99.8%, and the Cu-Al LDH@Zn//NVO full cell maintains 87% capacity retention after 1000 cycles at 3 A g -1 . This work demonstrates that interlayer chemistry provides a powerful strategy for active solvation regulation, opening a new avenue toward durable and reversible aqueous batteries.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"28 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148957872","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Structural engineering of α-BaEuBOF borate oxyfluoride: circumventing concentration quenching for a highly efficient and thermally stable red phosphor α-BaEuBOF硼酸氧氟化物的结构工程：规避浓度猝灭，获得高效热稳定的红色荧光粉

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-14 DOI: 10.1039/d6qi01290f

Huiyi Zhang,Li Li,Bo Zhao,Yaozu Li,Bingbing Zhang,Cuimiao Zhang,Guang Jia,Ying Wang

{"title":"Structural engineering of α-BaEuBOF borate oxyfluoride: circumventing concentration quenching for a highly efficient and thermally stable red phosphor","authors":"Huiyi Zhang,Li Li,Bo Zhao,Yaozu Li,Bingbing Zhang,Cuimiao Zhang,Guang Jia,Ying Wang","doi":"10.1039/d6qi01290f","DOIUrl":"https://doi.org/10.1039/d6qi01290f","url":null,"abstract":"Red phosphors play a crucial role in enhancing the lighting quality and color rendering index of phosphor-converted white light-emitting diodes (pc-WLEDs). However, the development of robust and high-performance red phosphors remains a pivotal challenge due to their low absorption efficiency and pronounced concentration/thermal quenching. Herein, we propose a fluorination strategy to design red-emitting phosphors with non-concentration-quenching and anti-thermal-quenching properties. The as-synthesized α-BaEuBO3F2 exhibits an intense and concentration-quenching free red emission centered at 612 nm with a relatively high quantum efficiency of 78.8% under the optimal 393 nm blue light excitation. Impressively, this red-emitting α-BaEuBO3F2 phosphor demonstrates superior thermal stability in the elevated temperature range of 150–270 °C (maintaining >90% intensity), outperforming conventional red Y2O3:Eu3+ phosphors. In addition, the application of this red α-BaEuBO3F2 phosphor in a pc-WLED has been demonstrated, yielding warm white light with color coordinates at (0.3425, 0.3325), a color rendering index (CRI) of 82.49, and a correlated color temperature (CCT) of 5000 K. Our findings not only present a compelling red-emitting candidate for high-quality pc-WLEDs but also provide a structural roadmap for circumventing concentration quenching in inorganic luminescent materials.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"15 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148957873","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Molecular mechanism for the altered hydroxyl radical production pathway from peroxynitrous acid-generating SIN-1 by sulfhydryl compounds: an ESR spin-trapping study 巯基化合物改变过氧亚硝酸生成sin1产生羟基自由基途径的分子机制：ESR自旋俘获研究

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-14 DOI: 10.1039/d6qi01866a

Li Qin,Xin-Ru Lin,Cui-Qing Liu,Ran Li,Lu Zhang,Jie Shao,Chun-Hua Huang,Li Mao,Ben-Zhan Zhu

{"title":"Molecular mechanism for the altered hydroxyl radical production pathway from peroxynitrous acid-generating SIN-1 by sulfhydryl compounds: an ESR spin-trapping study","authors":"Li Qin,Xin-Ru Lin,Cui-Qing Liu,Ran Li,Lu Zhang,Jie Shao,Chun-Hua Huang,Li Mao,Ben-Zhan Zhu","doi":"10.1039/d6qi01866a","DOIUrl":"https://doi.org/10.1039/d6qi01866a","url":null,"abstract":"It is commonly believed that the decomposition of peroxynitrous acid could readily generate hydroxyl radicals (˙OH). However, neither ˙OH nor methyl radicals (˙CH3) could be detected from peroxynitrous acid using the electron spin resonance (ESR) spin trapping method with 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) as the spin-trapping agent either in the absence or presence of dimethyl sulfoxide (DMSO). In this study, we chose 3-morpholinosydnonimine N-ethylcarbamide (SIN-1) to selectively produce peroxynitrous acid and found that when the well-known thiol antioxidant glutathione (GSH) was present, both ˙OH and secondary ˙CH3 (from DMSO) could be unequivocally detected from SIN-1. Further investigation revealed that the GSH-mediated generation of ˙OH and ˙CH3 was closely dependent not only on the production of superoxide anion radical (O2˙−) via thiyl radical formation during the oxidation reaction of GSH with SIN-1 but also on the spin-trapping agent DMPO. Analogous results were observed for several other sulfhydryl compounds (RSH) and spin-trapping agents. Interestingly, we found that ˙CH3 could also be produced from the typical O2˙−-generating systems (xanthine/xanthine oxidase and KO2/crown ether) with DMPO/DMSO. Taken together, the mechanism for ˙OH generation from SIN-1/DMPO/RSH was proposed: RSH could react with peroxynitrous acid generated from SIN-1 decomposition to produce a large amount of O2˙−via thiyl radical formation, which could be trapped by DMPO to form the unstable DMPO–OOH adduct that subsequently decomposed to yield ˙OH. This study discovered a unique ˙OH-generating pathway, which could not only better explain previous findings but also might have significant chemical, biomedical, and toxicological implications for future research on the interaction of sulfhydryl compounds and peroxynitrous acid, especially in the presence of spin trapping agents.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"39 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148957876","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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An Acetyl-triggered Pentacarbonyl Chromium CORM for Redox-Responsive Hepatic Protection 乙酰触发的五羰基铬CORM用于氧化还原反应性肝脏保护

IF 7 1区化学

Inorganic Chemistry Frontiers Pub Date : 2026-09-14 DOI: 10.1039/d6qi01635a

Xiao Zhang,Xin Zhang,Yuting Wan,Li Yu,Liangshuo Hu,Wei-Qiang Zhang,Bo Wang,Kallol Ray,Yong-Min Lee,Wonwoo Nam

{"title":"An Acetyl-triggered Pentacarbonyl Chromium CORM for Redox-Responsive Hepatic Protection","authors":"Xiao Zhang,Xin Zhang,Yuting Wan,Li Yu,Liangshuo Hu,Wei-Qiang Zhang,Bo Wang,Kallol Ray,Yong-Min Lee,Wonwoo Nam","doi":"10.1039/d6qi01635a","DOIUrl":"https://doi.org/10.1039/d6qi01635a","url":null,"abstract":"Carbon monoxide-releasing molecules (CORMs) with stimulus-responsive release kinetics and high aqueous solubility are critical for translating therapeutic potential of CO to clinical applications. Herein, we report CORM-501, a low-molecularweight (LMW) Cr-based CORM engineered with an acetyl redox trigger that mediates selective CO release in oxidatively stressed physiological microenvironments. Single-crystal X-ray diffraction elucidates the molecular structure of CORM-501 as a tetramethylammonium salt of the anionic pentacarbonyl chromium acetylate complex [(CO)5CrC(=O)CH3] -, stabilized by a distinctive threefold intermolecular C-H...O hydrogen-bonding network. This structural architecture endows CORM-501 with exceptional aqueous solubility, sustained CO release kinetics (t1/2>6 h), and robust hepatoprotective activity in a rat model of hepatic ischemia-reperfusion injury (IRI). In direct benchmarking, CORM-501 outperforms commercial CORM-2 and CORM-401 in both CO delivery profile and in vivo IRI protection efficacy, establishing acetyl-triggered pentacarbonyl chromium complexes as a versatile and clinically relevant platform for next-generation therapeutic CORM design.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"76 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2026-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148957868","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0