Inorganic Chemistry Frontiers最新文献

{"title":"The Role of Anionic Design in Modulating Material Properties: from SHG Switching to Ferroelastic Switching","authors":"Jiazi She, Yun-Hui Yu, Yan-Ran Weng, Yong Yu, Dan Lu, Ying Zhou, Hui-Peng Lv, Yong Ai","doi":"10.1039/d5qi01256b","DOIUrl":"https://doi.org/10.1039/d5qi01256b","url":null,"abstract":"Crystallographic engineering and chemical synthesis modification play crucial roles in modulating material properties and designing multifunctional materials, such as those with second-harmonic generation (SHG) switching and ferroelastic behaviors. Herein, we present the role of anion-based design in crystalline materials through anion H/F substitution. Specifically, the material [NMe<small>₄</small>][CH<small>₃</small>SO<small>₃</small>] exhibits a high phase transition temperature (<em>T</em><small>_c</small> = 462 K) and excellent SHG switching performance. The introduction of polyfluorinated substitutions results in a new organic ferroelastic material, [NMe<small>₄</small>][CF<small>₃</small>SO<small>_3]</small>, which exhibits ferroelastic phase transition at 309 K. The transition from the non-centrosymmetric [NMe<small>₄</small>][CH<small>₃</small>SO<small>₃</small>] to the centrosymmetric [NMe<small>₄</small>][CF<small>₃</small>SO<small>₃</small>] leads to a shift in material properties, transitioning from SHG switching to ferroelastic switching. Our findings underscore the importance of anion-based design in the development of advanced multifunctional phase-transition materials.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"9 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2025-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144594906","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Yolk@shell nanoreactor for heterogeneous Fenton reaction: A review of recent progress","authors":"Hongyan Liu, Heyu Gao, Xu Guo, Bingbing Li, Shuang Feng, Zixin Li, Tongjie Yao, Jie Wu","doi":"10.1039/d5qi00688k","DOIUrl":"https://doi.org/10.1039/d5qi00688k","url":null,"abstract":"Heterogeneous Fenton reaction was a promising technology to non-selectively degrade organic pollutants, providing a feasible solution to environment problems. The essential issue in Fenton reaction was the high efficient catalyst design, and the yolk@shell structure was usually functioned as the nanoreactor to boost activation efficiencies of H2O2 (or peroxymonosulfate (PMS)). In typical, a yolk@shell nanoreactor was constructed from a hollow shell and a movable core, which could transfer Fenton reaction performed in the bulk solution to the internal cavity. Benefiting from the confinement effect, the collision opportunity among various reactants was increased, the degradation rate was accelerated, the H2O2 (or PMS) utilization efficiency was boosted, the environmental tolerance of catalysts was improved, and the metal leaching was lowered. Therefore, yolk@shell nanoreactor provided an ideal platform for heterogeneous Fenton reaction. In addition, many methods could be adopted to tailor the yolk@shell nanoreactor for better catalytic performance, and this inspired researchers to design nanoreactor with optimized compositions and novel structures. At present, many reviews on either preparation and application of yolk@shell nanoreactor or recent development of heterogeneous Fenton reaction were reported, however, the strategies to improve the Fenton reaction based on yolk@shell nanoreactor have not been detailed discussed. This review have illustrated the recent progress on yolk@shell nanoreactor for heterogeneous Fenton reaction, and provided an comprehensive information on catalyst design, catalytic performance, catalytic mechanism, catalyst advantage, catalyst improvement method, aiming at catalyst with better performance.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"29 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2025-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144578027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhanced Stability in layered P2-Na0.67Fe0.5Mn0.5O2 cathode for Sodium Ion Batteries via Cu/Ti co-doping synergies engineering","authors":"Yihan Li, Anrui Feng, Na Chen, Tingfei Yang, Anqi Li, Yuanyuan Yang, Runze Liu, Xue Qin, Lijuan Zhang","doi":"10.1039/d5qi01070e","DOIUrl":"https://doi.org/10.1039/d5qi01070e","url":null,"abstract":"Co/Ni-free P2 type Fe/Mn-based layered oxide cathodes for sodium ion batteries have attracted much attention due to their low cost, high capacity, and environmental friendliness. However, it suffers from the Jahn-Teller (J-T) effect, transition metal migration, and irreversible oxygen loss, and the irreversible phase transition caused by these problems can lead to the deterioration of its crystal structure and the rapid decay of its capacity, which hinders its practical application. Herein, Cu/Ti co-doping P2-Na0.67Fe0.3Mn0.5Cu0.15Ti0.05O2 (NFMCTO) cathode material were prepared by sol-gel method. The doping of Ti4+ reduces the content of Mn3+, mitigates the J-T effect as well as the dissolution of Mn2+, and furthermore also excites the lattice oxygen oxidation reduction (ORR) to improve the capacity. Meanwhile, the introduction of highly reducing Cu2+ inhibits the migration of Fe3+ and realizes the high multiplicity performance of the material by promoting electron-hole separation. Under the combined effect of Cu and Ti, NFMCTO shows a high initial discharge capacity of 207.2 mAh g-1 at a current density of 20 mA g-1, and superior rate performance (119.1 mAh g-1 at 400 mA g-1). Meanwhile, it still has 124.2 mAh g-1 capacity after 100 cycles at 200 mA g-1, and the capacity retention rate is increased from 51.1% to 77.1%. The In-situ XRD results confirm the reversible structural evolution of the modified material and alleviated phase transitions. The In-situ EIS and GITT results also indicate that NFMCTO has improved Na+ ion transfer kinetics through Cu/Ti synergism, which corresponds to the excellent rate performance of the material. Finally, the testing of the NFMCTO//HC full cell further confirms the promising application of NFMCTO. This work confirms the necessity of co-doping in doping modification, and the co-doping synergistic strategy provides a new idea for the subsequent study of Fe/Mn-based cathode materials on suppressing the J-T effect and irreversible oxygen loss under high voltage.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"39 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2025-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144568968","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Rapid Joule Heating Synthesis of Metal Single-Atom Materials: Theory, Devices Construction, and Functional Applications","authors":"Jiacheng Wang, Xinxing Shi, Zhenjie Cheng, Peng Du, Xiaohai Li, Lianli Jia, Jitang Zhang, Lili Zhang","doi":"10.1039/d5qi00777a","DOIUrl":"https://doi.org/10.1039/d5qi00777a","url":null,"abstract":"Joule heating (JH) synthesis has gained widespread application in dispersing atomic metals onto supports, thereby enhancing metal utilization efficiency and enabling precise control over the electronic structure at the atomic level. This method holds considerable promise for metal single-atom (SA) synthesis. This review aims to systematically investigate and summarize recent advancements in JH synthesis of metal SAs-based functional materials. It begins by clarifying the JH fundamental principles, including the methodology for calculating heating temperatures. After concluding an overview on the development of JH technique, it details the necessary equipment and systematically compare plate-type and tube-type heating apparatuses, highlighting their differences and respective application fields. The JH synthesis and traditional processes for SA materials synthesis are also compared to highlight the advantages of the JH technique. Furthermore, we conclude and compare various types of metal SAs along with their corresponding JH synthesis parameters and diverse functional applications in the fields of catalysis and electromagnetic wave adsorption. Finally, we provide a brief conclusion and outlook as well as emerging trends and challenges that could shape future research on metal SAs-based functional materials by rapid JH synthesis.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"9 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2025-07-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144568981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Boosting electrochemical urea synthesis via nitrous oxide and carbon oxide coupling over homonuclear dual-atom catalysts：a density functional study: A computational study","authors":"Song Lu, JIASHENG CHEN, Yi Ding, Jiadi Ying, Tiancun Liu, Qi Shen, Zhixin Yu","doi":"10.1039/d5qi00855g","DOIUrl":"https://doi.org/10.1039/d5qi00855g","url":null,"abstract":"Developing efficient electrocatalysts for urea synthesis is attracting increasing attention but remains challenging due to the lack of simplified mechanisms and suitable feedstock. In this work, we propose a novel mechanism for urea synthesis on dual transition metal atom-anchored graphitic carbon nitride (TM2@g-C₂N) through the co-reduction of CO and N2O using density functional theory (DFT) calculations. By employing a three-step screening strategy, we systematically investigated homonuclear dual-atom pairs embedded in g-C₂N for their catalytic activity, selectivity, and stability. Our results demonstrate that dual-atom pairs can be stably embedded into the hollow regions of g-C2N via nitrogen coordination, exhibiting superior electrochemical stability. In addition, dual-metal atoms significantly enhance the electrical conductivity of g-C2N, facilitating charge transfer. Notably, Fe2 and Co2@g-C2N emerge as promising candidates for electrocatalytic urea synthesis via CO and N2O coupling, with limiting potentials (UL) of −0.27 V and −0.35 V, respectively, following alternative mechanism. Meanwhile, Nb2@g-C2N is identified as an excellent catalyst for N2O reduction to NH3, achieving UL of −0.34 V within mixed mechanism. We further reveal that stable *NCON adsorption promotes subsequent hydrogenation steps, lowering the limiting potential for urea formation on Fe2@g-C2N. The adsorption of N2O and formation of *NCON on TM2@g-C2N are identified as critical steps, where the relatively strong interactions between active sites and intermediates correlate with high catalytic activity. This work expands the potential of dual-atom catalysts in enabling efficient urea production via N2O and CO co-reduction.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"46 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2025-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144566368","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Outstanding Reviewers for Inorganic Chemistry Frontiers in 2024","authors":"","doi":"10.1039/D5QI90053K","DOIUrl":"10.1039/D5QI90053K","url":null,"abstract":"<p >We would like to take this opportunity to thank all of <em>Inorganic Chemistry Frontiers</em>’ reviewers for helping to preserve quality and integrity in chemical science literature. We would also like to highlight the Outstanding Reviewers for <em>Inorganic Chemistry Frontiers</em> in 2024.</p>","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":" 15","pages":" 4543-4543"},"PeriodicalIF":6.1,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144566373","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"New Encapsulated bis Cyclometalated Ir(III) Complexes with Very Potent Anticancer PDT Activity","authors":"Cristina Bermejo, Carlos Gonzalo-Navarro, Juan Angel Gallego Organero, Ana María Rodríguez, Lucia Santos, Elisenda Zafon, J. Carlos Lima, Artur J. Moro, Mònica Iglesias, Pedro Tavares, Daniel Martínez, Blanca R. Manzano, Anna Massaguer, Gema Dura","doi":"10.1039/d5qi00775e","DOIUrl":"https://doi.org/10.1039/d5qi00775e","url":null,"abstract":"Photodynamic therapy (PDT) has emerged as a promising approach to cancer treatment, due to its ability to reduce side effects. In the search for luminescent iridium [Ir(C^N)<small>₂</small>(N^N)]<small>⁺</small> complexes with high ability to generate ROS (reactive oxygen species) under irradiation, we employed C^N ligands with high π-expansion (pbpz (4,9,14-triazadibenzo[a,c]anthracene), <strong>1</strong>, or pbpn (4,9,16-triazadibenzo[a,c]naphthacene), <strong>3</strong>) that should lead to long excited state lifetimes. The photophysical properties were significantly influenced by the degree of C^N ligand π-expansion. Complex <strong>1</strong> exhibited a long fluorescence lifetime, matching the triplet lifetime observed in TAS, indicating delayed fluorescence. In contrast, the additional ring in complex <strong>3</strong> generated two near-HOMO orbitals, increasing the excited states LC character and reducing spin-orbit coupling (SOC) and intersystem crossing (ISC). They exhibited a notable ability to generate <small>¹</small>O<small>₂</small> and O<small>₂</small><small>^•−</small>. TD-DFT studies nicely explained the differentiated photophysical properties. Both complexes exhibited significant phototoxicity against human cancer cells in both monolayer and multicellular spheroids models, with complex <strong>1</strong> exhibiting higher effect. They effectively photogenerated intracellular ROS, including O<small>₂</small><small>^•−</small>. The mitochondrial accumulation of <strong>1</strong> and its disruption of mitochondrial functions was verified. Wound healing and clonogenic assays demonstrated their potential as antimetastatic agents. In general, complexes encapsulation significantly facilitated their cellular accumulation and increased photocytotoxic indexes, with <strong>NP1</strong> achieving one of the highest IC<small>₅₀</small> reported in iridium chemistry. Furthermore, the NP showed good anticancer activity even in 3D models. Thus, <strong>1</strong> and <strong>3</strong> and specially <strong>NP1</strong> show great promise as type I and II PDT agents with theragnostic potential.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"97 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144566375","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Crosslinked ion-conducting hybrid coating layers for robust artificial solid-electrolyte interphase towards high-performance silicon anodes","authors":"Yuhui Weng, Xingyu Sun, Siying Li, Zhuoying Wu, Ziwei Chen, Yongqun Ma, Zefan Zheng, Feng Lin, Ming Zhang, Kejun Zhang, Min Ling, Keli Yang, Chengdu Liang, Jun Chen","doi":"10.1039/d5qi01119a","DOIUrl":"https://doi.org/10.1039/d5qi01119a","url":null,"abstract":"High-capacity silicon (Si)-based anodes have been recognized as particularly promising candidates for high-energy-density lithium-ion batteries (LIBs). Rational design and tailoring of an artificial interface for Si anodes can effectively mitigate volume expansion, suppress detrimental side reactions, and enhance lithium-ion (Li<small>⁺</small>) diffusion kinetics—three critical factors widely acknowledged as fundamental prerequisites for enabling long-term cycling stability and fast-charging capabilities. Therefore, we introduced an organic/inorganic composite interface design strategy combining high elasticity and ion-conductive properties. Lithium metasilicate (LMS) not only functions as an effective protective layer and Li<small>⁺</small> conductor but also inhibits lithium hexafluorophosphate (LiPF<small>₆</small>) hydrolysis to suppress the generation of corrosive hydrofluoric acid (HF). When integrated with carboxyl-rich polyacrylic acid (PAA), the nanocomposite coating layer demonstrates high elasticity to accommodate volume expansion, establishes continuous Li<small>⁺</small> diffusion pathways, and promotes the formation of a robust lithium fluoride (LiF)-rich artificial solid-electrolyte interphase (SEI). Consequently, the as-developed Si@PL-10 electrode demonstrates significantly enhanced cycling performance (2297 mAh g<small>⁻¹</small> after 200 cycles at 1 A g<small>⁻¹</small>) and high-rate capability (1854 mAh g<small>⁻¹</small> at 6 A g<small>⁻¹</small>). This work provides valuable insights for designing scalable multifunctional coatings for high-performance Si anodes.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"64 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144566372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Unveiling the Relationship Between the Shortest Mn-Mn Distance in Manganese Halide Hybrids and Their Photoluminescence and Scintillation Properties","authors":"Jiali Fan, Haibo Li, Hua Tong, Zhennan Zhou, Wei Liu, Gangfeng Ouyang","doi":"10.1039/d5qi01136a","DOIUrl":"https://doi.org/10.1039/d5qi01136a","url":null,"abstract":"Organic-inorganic hybrid manganese halides (OIMnHs) attract much attention in solid state lighting and X-ray imaging due to their eco-friendliness and outstanding photo/radioluminescent (PL/RL) properties. It is reported that their luminescent performance is closely related to the distances of Mn centers. However, further research on their relationship is still needed, especially for their scintillation properties. In this work, four novel 0D OIMnHs (ted-Cn-ted)MnBr4 (ted = triethylenediamine, n = 7-10) were synthesized using tailored (ted-Cn-ted)2+ cations. Benefiting from the large molecule size and rigidity of the cations, the [MnBr4]2− units are effectively separated, bringing the compounds about high PL quantum yields (PLQYs) and light yields. More importantly, after analyzing the synthesized compounds and the reported samples, the positive correlation between the shortest Mn-Mn distance in these OIMnHs and their PLQYs and light yields is unveiled, and OIMnHs with distances in the 9-11 Å range exhibit both superior PLQYs and light yields. Besides, a WLED device is fabricated employing (ted-C10-ted)MnBr4, achieving high-quality illumination with 94% National Television Standards Committee (NTSC) color gamut coverage. This work not only deepens the understanding of structure-property relationships in OIMnHs, but also provides a theoretical foundation for designing advanced luminescent materials with high quantum efficiency and scintillation properties.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"1 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2025-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144566739","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Mechanistic Insights into MnOx-Cocatalyzed Piezophotocatalytic Dye Degradation over S-Scheme MnOx/BiFeO3 Heterojunctions","authors":"Yuxing Chu, Yekang Zheng, Jiating Xu, Ruoyu Dong, Feng Zhu, Kaiqi Wang, Ying Wu, Yiming He","doi":"10.1039/d5qi01226k","DOIUrl":"https://doi.org/10.1039/d5qi01226k","url":null,"abstract":"MnOx is commonly used as an oxidative cocatalyst to promote charge carrier separation, yet, its underlying mechanism remains incompletely understood. In this study, MnOx nanoparticles were deposited onto the surface of BiFeO3 nanosheets via a photodeposition method, and their promoting effects in piezocatalytic and piezo-photocatalytic reactions were systematically investigated. The synthesized MnOx/BiFeO3 composites exhibited enhanced catalytic performance in RhB degradation. In the piezocatalytic system, the optimized MnOx/BiFeO3 catalyst achieved a degradation rate constant of 0.78 h⁻¹, approximately 4.6 times that of pure BiFeO3. Under simultaneous ultrasonic vibration and light irradiation, the rate constant further increased to 1.4 h⁻¹, representing 1.8 times and 1.4 times the rates observed under individual piezocatalytic and photocatalytic conditions, respectively. Comprehensive characterization techniques were employed to elucidate the mechanism behind the enhanced performance. The results reveal that MnOx modification induces interfacial stress, enhancing the piezoelectric response of BiFeO3. Moreover, an S-scheme heterojunction is formed at the MnOx/BiFeO3 interface, wherein holes in the valence band of BiFeO3 recombine with electrons from MnOx, effectively promoting charge separation and transport while preserving the strong redox capability of both charge carriers. The synergistic piezo-photocatalytic effect of MnOx/BiFeO3 is attributed to the global piezoelectric potential of BiFeO3, which extends the spatial range of interfacial charge separation within the S-scheme heterojunction. Additionally, the high-density photogenerated electron-hole pairs produced under light irradiation effectively supplement the intrinsic charge carriers. This study not only clarifies the potential mechanism by which MnOx functions as a hole-trapping cocatalyst, but also highlights the unique advantages of S-scheme heterojunctions in the field of piezo-photocatalysis, offering valuable insights for the design of efficient piezocatalytic materials.","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":"11 1","pages":""},"PeriodicalIF":7.0,"publicationDate":"2025-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144533747","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}