Rare Metals最新文献

{"title":"Controlled multivalent-state vanadium electrolysis via a nitrogen-doped consumable anode","authors":"Yuzhen Chen, Ruijing Kong, Zepeng Lv, Shaolong Li, Yong Fan, Jilin He, Jianxun Song","doi":"10.1007/s12598-025-03611-5","DOIUrl":"https://doi.org/10.1007/s12598-025-03611-5","url":null,"abstract":"Vanadium is a strategically significant metal, indispensable to modern industries due to its unique physical and chemical properties. In this study, three dynamic optimisation challenges are addressed: controlling ionic valence states, regulating irregular product morphologies, and reducing carbon dioxide (CO2) emissions. A simple and innovative method for producing metallic vanadium via electrolysis of a nitrogen-doped vanadium consumable anode (VCxNyOz) is proposed and validated. The research compares the polarisation behaviour and reduction mechanisms of vanadium ions to metallic vanadium using two types of consumable anodes (VCxNyOz and VCxOy). Nitrogen doping stabilises the V2+ ion through sp2-hybridised C–N coordination, promoting the formation of a stable [VN6]3– octahedral complex via V–N bond interactions. The study demonstrates that the VCxNyOz anode effectively regulates the valence state of vanadium ions in molten salt systems, enabling a uniform dendritic morphology and achieving a 30% reduction in CO emissions compared to the VCxOy anode.","PeriodicalId":749,"journal":{"name":"Rare Metals","volume":"44 12","pages":"10967-10980"},"PeriodicalIF":0.0,"publicationDate":"2025-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147331654","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Boosted interfacial charge transfer on CoO/Zn0.5Cd0.5S for simultaneous photocatalytic H2 production and sewage purification","authors":"Deqian Zeng,&nbsp;Qingru Zeng,&nbsp;Yimin Liu,&nbsp;Yuezhou Wei,&nbsp;Jizhou Jiang","doi":"10.1007/s12598-025-03599-y","DOIUrl":"10.1007/s12598-025-03599-y","url":null,"abstract":"<div><p>Harnessing solar energy for simultaneous hydrogen evolution and sewage purification with organic contaminants via photocatalysis represents an effective strategy for sustainable energy conversion and environmental protection. In this work, an innovative 2D/0D CoO/Zn_0.5Cd_0.5S heterointerface catalyst was fabricated using a straightforward hybridization technique. The catalyst was used for photocatalytic hydrogen evolution in solutions with inorganic sacrificial agents (S²/SO₃^2–), ultrapure water, and Rhodamine B (RhB) dye. Remarkably, the optimized 2D/0D 5% CoO/Zn_0.5Cd_0.5S catalyst demonstrated an exceptional hydrogen evolution rate of 2688 μmol g⁻¹ h⁻¹ under visible-light irradiation, approximately 25-fold higher than that of pure Zn_0.5Cd_0.5S. Furthermore, it efficiently generates hydrogen while concurrently purifying RhB. The ultrathin CoO nanosheets uniformly disperse Zn_0.5Cd_0.5S nanoparticles, providing numerous catalytic active sites. In situ X-ray photoelectron spectroscopy analysis elucidates photogenerated electron transfer from layered CoO to Zn and Cd in Zn_0.5Cd_0.5S during photocatalysis. Photoluminescent spectra, femtosecond transient absorption (fs-TA) spectroscopy, photoelectrochemical measurements, ultraviolet photoelectron spectroscopy and first-principles calculations further confirm that the intrinsic electric field at the CoO/Zn_0.5Cd_0.5S heterointerface enhances photogenerated electron–hole separation and mobility. The outcomes of this research offer valuable insights into developing economical photocatalysts for efficient hydrogen production and concurrent sewage purification with organic pollutants.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":749,"journal":{"name":"Rare Metals","volume":"44 12","pages":"10227 - 10242"},"PeriodicalIF":11.0,"publicationDate":"2025-10-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090920","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhanced interface coupling accelerates charge transfer of a MoO2−x/Bi2MoO6 Schottky junction for CO2 photoreduction to CH4","authors":"Ming Meng,&nbsp;Xi Wu,&nbsp;Qingqing Chai,&nbsp;Hucheng Zhou,&nbsp;Nan Qin,&nbsp;Honglei Yuan,&nbsp;Shufang Zhao,&nbsp;Jin Liu,&nbsp;Jun Li","doi":"10.1007/s12598-025-03629-9","DOIUrl":"10.1007/s12598-025-03629-9","url":null,"abstract":"<div><p>Artificial photosynthesis, converting CO₂ and H₂O into solar fuels, is considered as a strategic pathway to alleviate the greenhouse effect and the energy crisis. Nonetheless, in many heterojunction-based artificial photosynthetic systems, the CH₄ productivity is significantly limited by poor carrier transport, narrow spectral light absorption, and lacking suitable active sites for the eight-electron reaction. Herein, a MoO_2−<i>x</i>/Bi₂MoO₆ (MO/BWO) Schottky junction with a strong interfacial coupling effect was fabricated by a two-step hydrothermal strategy. The optimized MO/BMO Schottky junction delivered a CO₂-to-CH₄ photoreduction rate of 23.3 μmol g⁻¹ with 90.7% selectivity. In situ X-ray photoelectron spectroscopy and theoretical calculation demonstrated that BMO interacted with MO to produce a strong electron coupling effect and form a Schottky junction, which promoted the facilitated the directional migration of photogenerated electrons from BMO to MO with prolonging average photogenerated charge lifetime from 26.6 to 48.7 ps, but also effectively suppressed electron backflow through the Schottky barrier. Moreover, the coupling of MO with BMO significantly reduced the energy barrier of the rate-determining step. This work delves into the role of non-precious metal-based Schottky junction design in enhancing photocatalytic CO₂ reduction performance, providing new insights into co-catalyst as active sites for CH₄ generation in the CO₂ photoreduction process.</p><h3>Graphical abstract</h3><p>A MoO_2−<i>x</i>/Bi₂MoO₆ (MO/BWO) Schottky junction with strong interfacial coupling effect was fabricated, which enhances the facilitated the separation of photogenerated carriers charge lifetime; thus, facilitates photocatalytic CO₂ reduction activity.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":749,"journal":{"name":"Rare Metals","volume":"44 12","pages":"10271 - 10281"},"PeriodicalIF":11.0,"publicationDate":"2025-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090840","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Liquid metal-enabled energy generators for self-powered soft bioelectronics","authors":"Sheng-You Li,&nbsp;Kai-Ying Zhao,&nbsp;Guang-Tao Zan,&nbsp;Gwanho Kim,&nbsp;Ho-Yeon Kim,&nbsp;Eun-Ae Shin,&nbsp;Minji Kwon,&nbsp;Yeonji Kim,&nbsp;Jihye Jang,&nbsp;Jioh Yoo,&nbsp;Cheolmin Park","doi":"10.1007/s12598-025-03607-1","DOIUrl":"10.1007/s12598-025-03607-1","url":null,"abstract":"<div><p>Liquid metal-enabled energy generators (LMEGs) have emerged as promising technology for self-powered bioelectronics, offering an efficient solution to the challenges of power consumption in soft electronics. This review provides a comprehensive overview of the properties and process of liquid metals (LMs), focusing on their use in soft bioelectronics. We then discuss various types of LMEGs, including triboelectric nanogenerators (TENGs), piezoelectric nanogenerators (PENGs), electromagnetic generators (EMGs), hydrovoltaic generators (HEGs), thermoelectric generators (TEGs), and photovoltaic electric generators (PEGs), highlighting their recent research advancements. The unique properties of LMEGs make them ideal for integrating energy harvesting or self-powered sensing components into bioelectronics. Next, we provide a comprehensive summary of recent applications of LMEGs in wearable power sources, self-powered smart sensing, and biomedical devices. Finally, we outline future research directions, emphasizing the active roles and low-temperature operation of LMEGs, the broader adoption of self-healing capabilities, the advancement of functionalized LM–polymer composites, and system-level integration for practical applications.</p><h3>Graphic abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":749,"journal":{"name":"Rare Metals","volume":"44 12","pages":"9297 - 9335"},"PeriodicalIF":11.0,"publicationDate":"2025-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090843","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"High-entropy effects enhance atomic displacements to manipulate thermal/oxygen ionic transport properties of ordered RE3MO7 ceramics","authors":"Guiyu Xue, Jiankun Wang, Chenyu Li, Cheng Xu, Chao Li, Lin Chen, Jing Feng","doi":"10.1007/s12598-025-03625-z","DOIUrl":"https://doi.org/10.1007/s12598-025-03625-z","url":null,"abstract":"The high-entropy engineering has emerged as a novel method for manipulating various properties of ceramics. Herein, the enhancement of atomic displacements was shown to effectively tailor the thermal/oxygen ionic conductivities of high-entropy ceramics (HECs). Although RE3MO7 (RE represents rare-earth elements; M is Ta or Nb) ceramics have been widely studied for use in thermal barrier coatings and solid oxide fuel cells, their application scope can be broadened through the effective manipulation of the thermal/oxygen ionic conductivities. Herein, (Sm1/5Eu1/5Gd1/5Dy1/5Ho1/5)3Ta1/2Nb1/2O7 HECs are designed and synthesized. These ceramics exhibit lower thermal conductivity and higher oxygen ionic conductivity than pristine ordered RE3MO7 ceramics. Characterization results prove that high-entropy effects in the prepared material enhance atomic displacement parameters (ADPs), causing an increase in the oxygen ionic conductivity by a factor of 10 and enhancement in the phonon scattering rate, thereby reducing thermal conductivity by increasing ADPs. The ADPs can act as an indicator of the anharmonic vibration strength of the lattice, affecting the thermal/oxygen ionic conductivity and thermal expansion coefficient. Furthermore, in nano-indentation tests, (Sm1/5Eu1/5Gd1/5Dy1/5Ho1/5)3Ta1/2Nb1/2O7 HECs show high hardness (11.8 GPa), toughness (2.0 MPa·m1/2), and modulus (215.0 GPa), which are beneficial for structural/functional applications. Overall, the obtained results indicate that thermal/oxygen ionic transport mechanisms can be used to further improve the properties and thereby expand the application scope of various HECs.","PeriodicalId":749,"journal":{"name":"Rare Metals","volume":"44 12","pages":"10660-10671"},"PeriodicalIF":0.0,"publicationDate":"2025-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147333302","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"MOF-derived SnSe/carbon composite anode materials for Li-ion and Na-ion batteries","authors":"Nesrin Bugday,&nbsp;Wentao Deng,&nbsp;Ozgur Duygulu,&nbsp;Guoqiang Zou,&nbsp;Hongshuai Hou,&nbsp;Xiaobo Ji,&nbsp;Sedat Yaşar","doi":"10.1007/s12598-025-03568-5","DOIUrl":"10.1007/s12598-025-03568-5","url":null,"abstract":"<div><p>Metal selenides (MSs) are attracted considerable interest as potential anode electrode materials for Li-ion/Na-ion batteries (LIBs/SIBs) owing to their elevated theoretical capacity and superior conductivity. Nevertheless, their potential is constrained by inadequate capacity retention and inferior longevity, principally due to volumetric expansion and undesirable structural failure caused by the insertion and extraction of comparatively large Li⁺/Na⁺ ions during charging and discharging. Therefore, three different composites containing SnSe and one more metal selenide are synthesized using metal–organic framework (MOF) to enhance the accommodation of Li/Na ions and provide adequate ion routes. The Co₃Se₄/SnSe<i>@</i>NPC material demonstrates exceptional cyclic stability and rate capability as anode material for LIBs and SIBs (603 mAh g⁻¹ after 1000 cycles at 2 A g⁻¹ (for LIBs) and 296 mAh g⁻¹ after 1000 cycles at 2 A g⁻¹ (for SIBs)). This electrochemical performance enhancement may be attributed to the improved conductivity of the composite structure and introduction of SnSe, which facilitates the transfer of electrons within the structure. In addition, selenium- and nitrogen-doped mesoporous carbon architectures facilitate electrolyte penetration in active materials, enhance contact area, promote effective diffusion of Li⁺ or Na⁺ within the composite, and mitigate volume expansion during the charge–discharge cycle. Consequently, the Co₃Se₄/SnSe<i>@</i>NPC composite offers a novel perspective on the advancement of anode materials for LIBs and SIBs.</p></div>","PeriodicalId":749,"journal":{"name":"Rare Metals","volume":"44 12","pages":"9920 - 9937"},"PeriodicalIF":11.0,"publicationDate":"2025-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090871","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Carbon quantum dot modified W18O49 electrode enables smart energy storage device with a self-diagnosis character","authors":"Jun-Kai Li,&nbsp;Kai-Zhao Wang,&nbsp;Jin Shi,&nbsp;Ya-Fei Wang,&nbsp;Zhao-Wei Sun,&nbsp;Feng Liu,&nbsp;Kai-Jun Wang,&nbsp;Jia-Le Wu,&nbsp;Chen Zhu,&nbsp;Hyeona Park,&nbsp;Jang-Yeon Hwang,&nbsp;Jin Hu,&nbsp;Shi-Zhao Xiong","doi":"10.1007/s12598-025-03601-7","DOIUrl":"10.1007/s12598-025-03601-7","url":null,"abstract":"<div><p>In Monitoring the health state of energy storage devices, including batteries and supercapacitors, is of significance to ensure safety and potential endurance for electric vehicles or other usage. However, electrochemical parameters measured from a battery or supercapacitor usually bring very less information about potential fault or failure of electrodes at the material level. Herein, W₁₈O₄₉ is synthesized to build a smart electrode with high specific capacity, which is also used as an indicator with self-diagnosis character. The flexible carbon quantum dot modified W₁₈O₄₉ electrode is loaded on carbon cloth, revealing failure by irreversibility of discoloration. An irreversible electrochromism from indigo to cyan or dark, along with cycling, is observed when the electrode is used in a supercapacitor or in a lithium battery. The mechanism is revealed as cations preferentially diffuse in tunneling of W₁₈O₄₉ rather than the (010) face. This irreversibly changes the crystal structure and valence state of W, inducing the electrochromic effect with decayed performance of the electrode. The smart electrode is further demonstrated in a transparent pouch-type full cell, delivering excellent flexibility, good performance, and visual chromogenic effect. Our work provides a novel perspective on the design of smart energy storage devices with a function of self-diagnosis for future applications.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":749,"journal":{"name":"Rare Metals","volume":"44 12","pages":"10133 - 10143"},"PeriodicalIF":11.0,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090842","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Transformative applications of artificial intelligence in lithium battery materials science: advancements and future prospects","authors":"Guangcun Shan,&nbsp;Zejian Ding,&nbsp;Liujiang Xi,&nbsp;Hongbin Zhao,&nbsp;Jiliang Zhang,&nbsp;Jijian Xu","doi":"10.1007/s12598-025-03617-z","DOIUrl":"10.1007/s12598-025-03617-z","url":null,"abstract":"<div><p>Artificial intelligence (AI) technologies have transformed the field of materials science by enabling efficient data-driven approaches for property prediction and material discovery. Here, we provide an in-depth analysis of AI applications in materials science, focusing on data collection, property prediction, material discovery, and autonomous experimentation. We summarize the primary data sources and increased utility of large language models, which have significantly expedited the material discovery process. Additionally, we examine the application of AI to predict the key properties, emphasizing the transformative role of AI for lithium batteries. Although numerous challenges persist, advancements in AI-driven tools and methodologies provide avenues for accelerating innovation in materials science.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":749,"journal":{"name":"Rare Metals","volume":"44 12","pages":"9747 - 9762"},"PeriodicalIF":11.0,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090841","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Past, present, prospect: AI-driven evolution of low-dimensional material design for sustainable environmental solutions","authors":"Bo-Ru Su,&nbsp;Jian-Qiao Liu,&nbsp;Dan Zhao,&nbsp;Di Wu,&nbsp;Chu-Qiao Hu,&nbsp;Pei-Lun Qiu,&nbsp;Ya-Nan Zhang,&nbsp;Ce Fu,&nbsp;Qian-Ru Zhang","doi":"10.1007/s12598-025-03631-1","DOIUrl":"10.1007/s12598-025-03631-1","url":null,"abstract":"<div><p>Low-dimensional materials have attracted significant interest for their unique properties, including high surface area, confined but tunable electronics and superior catalysis, making them ideal for environmental applications. Their potential to address key challenges in solar energy conversion and in-situ remediation highlights their importance in advancing environmental sustainability. However, traditional methods of low-dimensional material design face significant obstacles, such as scalability limitations, high computational costs, and the inherent difficulty in accurate prediction of material properties, underscoring the need for innovative approaches. Here, we demonstrate an AI-driven evolution of low-dimensional material design for sustainable environmental solutions, from the traditional techniques in the past, through the present transition to computational approaches, to the prospect where AI-enabled strategies exhibit the supremacy. This review covers properties of low-dimensional materials and the fundamental design principles, emphasizing the pivotal role of deep learning in optimizing and accelerating design of advanced functional materials. Further explorations focus on their applications for sustainable environmental solutions, including pollution remediation, water purification, nitrogen fixation, CO₂ reduction as well as hydrogen and hydrogen peroxide production. Ultimately, the key challenges and future trends are identified in the aspects of algorithm, intelligence and scalability for environmental applications. This work offers a comprehensive overview on the evolution pathway of design strategies for low-dimensional materials driven by AI methodology, demonstrating transformative insights that not only accelerate the discovery of low-dimensional materials, but also motivate the environmental applications in various domains.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":749,"journal":{"name":"Rare Metals","volume":"44 12","pages":"9671 - 9701"},"PeriodicalIF":11.0,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090979","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Emerging Fe-based catalysts for heterogeneous Fenton-like reactions: from nanoparticles to clusters and single-atom catalysts","authors":"Jiang-Feng Li,&nbsp;Yu-Xuan Shi,&nbsp;Li-Shuang Wei,&nbsp;Sang Sang,&nbsp;Xiao-Xin Xia,&nbsp;Sheng-You Li,&nbsp;Yu-Zhen Liu,&nbsp;Kai-Ying Zhao,&nbsp;Guang-Tao Zan","doi":"10.1007/s12598-025-03612-4","DOIUrl":"10.1007/s12598-025-03612-4","url":null,"abstract":"<div><p>Heterogeneous Fenton-like technology, a prominent advanced oxidation process, has gained widespread use in wastewater treatment for the removal of contaminants. The performance of this technology is highly dependent on the catalyst materials employed. Iron-based catalysts have attracted considerable attention due to their tunable properties, low cost, and environmental friendliness. However, challenges such as inadequate catalytic activity and the dissolution of iron species have limited their practical effectiveness. To address these challenges, various novel iron-based materials have been developed, ranging from diverse iron compounds to iron-based composites on different substrates, and from iron nanoparticles to iron clusters and single-atom catalysts (SACs). This review systematically examines the latest advancements in heterogeneous iron-based catalysts, focusing on two main categories: iron-based nanoparticle catalysts and iron-based clusters/SACs. We delve into the relationship between catalyst structures and catalytic performance in Fenton-like reactions, such as the nature of the substrate, catalyst size, and the interfacial interaction between the catalyst and the substrate. By emphasizing recent progress and existing limitations, this review aims to provide valuable insights for the future development and application of high-performance heterogeneous catalysts for Fenton-like reactions.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":749,"journal":{"name":"Rare Metals","volume":"44 12","pages":"9588 - 9636"},"PeriodicalIF":11.0,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"146090997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}