{"title":"Experimental and Theoretical Insights into the Synergistic Corrosion Inhibition of AA2024 Aluminum Alloy by Nifuroxazide and Iodide Ions in HCl","authors":"Djouher Addadj, Abderrahmane Berchi, Brahim Idir, Baya Benfedda, Mustapha Djama, Lynda Benhaddad, Amel Kouache","doi":"10.1134/S2070205126700395","DOIUrl":"10.1134/S2070205126700395","url":null,"abstract":"<p>This study investigates, for the first time, the synergistic corrosion inhibition of AA2024 aluminum alloy in 1 M HCl using nifuroxazide (NFZ), an expired pharmaceutical compound, combined with iodide (I<sup>–</sup>) ions. Electrochemical measurements showed that NFZ acts mainly as a cathodic inhibitor, reaching only 32% efficiency when used alone at 1.2 mM. Adsorption studies showed that NFZ follows the Fowler–Guggenheim isotherm, indicating heterogeneous adsorption with repulsive lateral interactions. The addition of iodide ions dramatically enhanced this performance, achieving a maximum efficiency of ~97% at 1.2 mM NFZ + 1.2 mM KI. The synergism parameter confirmed a strong synergistic interaction between both inhibitors. The <span>(Delta G_{{text{ads}}}^{circ} )</span> values between −20 and −40 kJ/mol confirmed a spontaneous mixed physico-chemical adsorption mechanism, further supported by FTIR analysis which revealed frequency shifts of the C=O and NO<sub>2</sub> groups, confirming the coexistence of physical interactions and weak coordinate bonding between NFZ and the Al<sup>3+</sup> surface sites. Surface characterization by SEM, optical microscopy, and FTIR analysis confirmed the formation of a protective film on the aluminum surface. DFT calculations revealed that NFZ exists in its protonated form in acidic solution, with a fully positive electrostatic potential map that favours attraction with iodide ions. Molecular dynamics simulations confirmed that iodide reduces the inhibitor-surface distance from 3.5 to 3.0 Å and increases adsorption energy by 10.8%. Overall, this work demonstrates that the combination of an expired pharmaceutical compound with iodide ions represents an effective, sustainable, and low-cost strategy for the corrosion protection of aluminum alloys in aggressive acidic media.</p>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"62 3","pages":"686 - 700"},"PeriodicalIF":1.1,"publicationDate":"2026-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149176354","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. I. Lazarev, Yu. M. Golovin, E. Yu. Yanovskaya, A. A. Antipova, A. V. Krylov, M. I. Mikhailin
{"title":"Study of Structural Transformations of Hydrophilic Pores and Water State in the MA-41P Anion-Exchange Membrane Using IR Spectroscopy and Thermal Analysis","authors":"S. I. Lazarev, Yu. M. Golovin, E. Yu. Yanovskaya, A. A. Antipova, A. V. Krylov, M. I. Mikhailin","doi":"10.1134/S2070205126700565","DOIUrl":"10.1134/S2070205126700565","url":null,"abstract":"<p>An analysis was carried out of the structural transformations of macromolecules of the MA-41P anion-exchange membrane with a benzyltrimethylammonium group caused by ion exchange and static water absorption by means of IR spectroscopy in the NVPO mode and thermal analysis by thermogravimetry (TG) and differential scanning calorimetry (DSC). It is shown that hydroxyls (OH<sup>–</sup>) generated during the ion exchange process carry out a nucleophilic attack on proton of the methylene bridge CH<sub>2</sub> groups in benzyl R‒CH<sub>2</sub>–N<sup>+</sup>-positions by the mechanism of elimination with the formation of two products, H<sub>2</sub>O and R‒SN<sup>–</sup>‒N<sup>+</sup> (CH<sub>3</sub>)<sub>3</sub>, without destruction of trimethylammonium cation exchanger. The uncompensated negative charge on the carbon atom increases the hydrophilicity of the cation exchanger. Changes in water absorption are interpreted as an increase in the hydrophilicity of the pore surface and the formation of additional ion pairs in the cation exchanger. The phase composition of water in the pore space was analyzed using the method of deconvolution of OH-group stretching vibrations into five Gaussians. It is noted that the percentage of bound water does not change, while an increase in sorbed water occurs in the diffuse layer and solvation shells of ion pairs. Experimental data from TG and DSC showed that the degradation of anion–cation pairs is observed in the temperature range from 160 to 300°C, and the destruction of triethylammonium groups occurs in the range of ~300 to ~400°C. Free and bound water evaporates in the temperature range from 50 to 150°C.</p>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"62 3","pages":"493 - 499"},"PeriodicalIF":1.1,"publicationDate":"2026-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149176657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
K. I. Shaikhieva, R. Z. Galimova, A. A. Khubatkhuzin, Zh. A. Sapronova
{"title":"Adsorption of Copper Ions by Plasma-Modified Sorption Materials Based on Pea Pod Husks","authors":"K. I. Shaikhieva, R. Z. Galimova, A. A. Khubatkhuzin, Zh. A. Sapronova","doi":"10.1134/S2070205126700607","DOIUrl":"10.1134/S2070205126700607","url":null,"abstract":"<p>The process of adsorption of Cu<sup>2+</sup> ions by the native and modified pea pod husks is studied. The modification of the sorption material under study is executed with low-pressure high-frequency capacitively coupled plasma in an air atmosphere with the variation of the process parameters (power supplied to the electrodes of the plasmatron, time of plasma treatment). To determine the possible mechanism of interaction of the sorption materials with Cu<sup>2+</sup> ions, the obtained isotherms are processed using the Langmuir, Freundlich, Dubinin–Radushkevich, Temkin, Flory–Huggins, Harkins–Jura, and Frenkel–Halsey–Hill adsorption models. It is found that plasma treatment results in an increase in the sorption characteristics of the sorption material under study due to the appearance of various oxygen-containing groups on the surface of the adsorbent. Regression equations and values of the approximation ratios <i>R</i><sup>2</sup> of the obtained isotherms are calculated by the above adsorption models. The thermodynamic parameters (Gibbs energy, energy of adsorption) are determined which evidence the occurrence of a process of physical adsorption at the initial stage. The calculated values of the Biot parameter indicate the occurrence of a mixed diffusion adsorption process. Subsequent occurrence of a chemical interaction between Cu<sup>2+</sup> ions and functional groups in the composition of the biopolymers present in the composition of pea pod husks is shown by electron paramagnetic resonance.</p>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"62 3","pages":"466 - 473"},"PeriodicalIF":1.1,"publicationDate":"2026-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149176736","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zhi Huang, Zhihao Zhao, Man Liu, Muhan Li, Sisi Jiang, Yong Ma, Weijie An, Yun Gao, Chunling Li
{"title":"A Facile Preparation of Black Oxide Coating with Favorable Corrosion Resistance, Hydrogen Barrier Property, and Adhesion to Epoxy Resin","authors":"Zhi Huang, Zhihao Zhao, Man Liu, Muhan Li, Sisi Jiang, Yong Ma, Weijie An, Yun Gao, Chunling Li","doi":"10.1134/S2070205126700206","DOIUrl":"10.1134/S2070205126700206","url":null,"abstract":"<p>Hydrogen transportation pipelines require steels with enhanced hydrogen barrier properties. This study aims to develop a composite coating with integrated functions of corrosion resistance and hydrogen barrier. Firstly, a dense black oxide layer was chemically formed on X65 pipeline steel at room temperature by a modified blackening process. Then, the traditional epoxy resin was applied onto the surface of black oxide layer, obtaining a novel black oxide/epoxy resin composite coating. For the blackening process, the effects of surface pretreatment methods (untreated, polished, sandblasted) and blackening solution pH (1.5, 2.5, 3.5) on the microstructure, corrosion resistance and hydrogen barrier performance were investigated, as well as the adhesion strength of composite coating. Results show that corrosion resistance and hydrogen barrier performance of coatings depended on both blackening solution pH and pretreatment method, with polished substrates and pH 2.5 yielding optimal results. Additionally, the black oxide layer served as an effective adhesion-promoting interlayer, enhancing the bonding and durability of the composite coating. This novel black oxide/epoxy composite coating system offers valuable insights for designing hydrogen barrier coatings for pipeline steels.</p>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"62 2","pages":"344 - 352"},"PeriodicalIF":1.1,"publicationDate":"2026-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148856642","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Hayat Marmi, Saida Marmi, Abdelouahad Chala, Chahinez Siad
{"title":"Microstructure and Properties of Electrodeposited Ni–Cr Coatings Containing ZrO2 Particles","authors":"Hayat Marmi, Saida Marmi, Abdelouahad Chala, Chahinez Siad","doi":"10.1134/S2070205126700243","DOIUrl":"10.1134/S2070205126700243","url":null,"abstract":"<p>Ni—Cr—ZrO<sub>2</sub> nano-composites are electrodeposited from sulfate electrolyte and a comparison is made with Ni—ZrO<sub>2</sub> in terms of structure and properties. The coatings have been electrodeposited on cylindrical parts made of copper. The influence of the various experimental conditions has been considered by varying the concentration. The different electrodeposited layers are characterized by various analytical techniques: adhesion quality, corrosion resistance in sea water, Vickers microhardness, X-ray diffraction, morphology by scanning electron microscopy Followed by a microanalysis (EDX). The coatings prepared have a very good adhesion, are more resistant to corrosion, have a good hardness, an homogeneous and compact morphology and exhibit a high degree of co-deposition of particles incorporated in the nickel-chromium matrix.</p>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"62 2","pages":"299 - 306"},"PeriodicalIF":1.1,"publicationDate":"2026-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148856670","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Venkatesa Prabhu, Navuluri Padma Sravya, M Kavitha, S. Selvam, M. Murali, Ramya Maranan, S. Sathiyamurthy, Barun Haldar
{"title":"Cycling Stability and Specific Capacitance Performance of a Graphene-Embedded Polypyrrole-Based Supercapacitor","authors":"S. Venkatesa Prabhu, Navuluri Padma Sravya, M Kavitha, S. Selvam, M. Murali, Ramya Maranan, S. Sathiyamurthy, Barun Haldar","doi":"10.1134/S2070205126700280","DOIUrl":"10.1134/S2070205126700280","url":null,"abstract":"<p>This study examined graphene-embedded polypyrrole (PPy) composites with varying weight ratios of PPy to graphene (100 : 0, 90 : 10, 80 : 20, and 70 : 30). The composites were prepared via in situ chemical oxidative polymerization. They were thoroughly analyzed for their electrical, electrochemical, structural, thermal, and optical properties. Among the different compositions, the 80 : 20 ratio demonstrated the highest specific capacitance, energy density, and cycling stability. For this optimal composition, the sheet resistance was measured at 448.2 Ω/sq, optical transparency was at 47%, and electrical conductivity was 148.8 S/cm. The combined actions of PPy and graphene lead to better specific capacitance (782 F/g), optimum energy density behaviour (70.9 Wh/kg). This composition exhibited exceptional stability, retaining an impressive 93% of its initial capacitance even after enduring 5000 charge–discharge cycles. Thermogravimetric analysis demonstrated a significant initial decomposition temperature of 280°C, with a notable residual mass of 21%. Overall, the 80 : 20 composition strikes a remarkable balance of structural, electrical, electrochemical, thermal, and optical properties, establishing it as an exciting and highly promising candidate for high-performance, semi-transparent supercapacitor electrode applications.</p>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"62 2","pages":"307 - 317"},"PeriodicalIF":1.1,"publicationDate":"2026-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148856707","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Schiff Base Derived Lanthanide(III) Complexes with Emphasis on Structural and Biological Studies","authors":"Kirandeep Kaur, Meenakshi Patyal, Apoorva Katoch, Nidhi Gupta, Simarjeet Kaur","doi":"10.1134/S2070205126700218","DOIUrl":"10.1134/S2070205126700218","url":null,"abstract":"<p>The macrocyclic octaaza-bis-α-diimine complex was synthesized through the condensation of dione dihydrazone with an acid. Through the reaction of this complex with lanthanide chloride, [Ln(C<sub>36</sub>H<sub>34</sub>N<sub>10</sub>O<sub>4</sub>)Cl] complexes were formed, where Ln represents La(III), Ce(III), or Yb(III). Thorough spectral characterization was conducted on both the ligand and its respective metal complexes. Infrared spectroscopy, energy-dispersive X-ray spectroscopy (EDS), and elemental analysis were employed to confirm the successful synthesis of the complexes and accurately identify their constituent elements. The stability of the metal-ligand complex was evaluated through thermogravimetric analysis (TGA). Additionally, fractal analysis was performed on the ligand lanthanide (III) complex. The cube counting method revealed that the fractal dimension (<i>D</i><sub>f</sub>) value followed the order of La > Ce > Yb, indicating that lanthanum exhibited the highest surface roughness. Consequently, La demonstrated the greatest antibacterial and antifungal properties, attributable to its rough surface. The enhanced biological activity of the La(III) complexes can be attributed to the presence of surface roughness. Furthermore, due to the structural modification of the metal complexes into nanostructures, the antimicrobial activities exhibited by the metal complexes surpassed those of the ligands. Notably, the La(III) nanosized complex displayed excellent antimicrobial activity. The results of these evaluations are presented and discussed in detail within this paper.</p>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"62 2","pages":"281 - 289"},"PeriodicalIF":1.1,"publicationDate":"2026-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148856747","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Occurrence and Corrosion-Related Activity of Sulfate-Reducing Bacteria in Oil-Contaminated Soils of the Bibi-Heybat OGPD","authors":"Nargiz F. Sultanova, Elshan F. Sultanov","doi":"10.1134/S2070205126700322","DOIUrl":"10.1134/S2070205126700322","url":null,"abstract":"<p>Sulfate-reducing bacteria (SRB) are major contributors to microbiologically influenced corrosion (MIC) in oil and gas production systems due to their ability to generate hydrogen sulfide (H<sub>2</sub>S) during dissimilatory sulfate reduction. Although SRB have been extensively studied in reservoirs and produced waters, oil-contaminated soils remain insufficiently investigated despite their potential to serve as long-term microbial sources of sulfide and corrosion activity. This study investigates the occurrence, abundance, metabolic activity, and corrosion-related effects of sulfate-reducing bacteria in oil-contaminated soil samples collected from the Bibi-Heybat OGPD. Soil samples were enriched and cultivated under anaerobic conditions using selective Postgate B medium. SRB abundance was determined by culture-based methods, sulfide production was quantified iodometrically, and the corrosive aggressiveness of soil-derived aqueous extracts was evaluated gravimetrically using carbon steel coupons. Molecular identification of representative isolates was carried out by partial 16S rRNA gene sequencing. The results demonstrated significant SRB populations ranging from 10<sup>4</sup> to 10<sup>6</sup> cells g<sup>–1</sup> dry soil, with <i>Desulfovibrio</i> species dominating the microbial community. Active sulfate reduction was confirmed by sulfide accumulation reaching approximately 400 mg L<sup>–1</sup> after 7 days of incubation. Higher SRB abundance was associated with slightly alkaline soil pH and increased corrosion rates, indicating that oil-contaminated soils represent an important and previously underestimated corrosion risk factor in oilfield environments. The obtained results contribute to understanding the microbial diversity and corrosion potential of subsurface environments associated with offshore oil extraction.</p>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"62 2","pages":"424 - 434"},"PeriodicalIF":1.1,"publicationDate":"2026-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148856704","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
O. V. Solovtsova, I. V. Ponomarev, A. E. Grinchenko, E. V. Khozina, I. E. Men’shchikov, A. A. Fomkin, M. A. Erokhin, A. E. Belov, V. A. Mavrov, N. I. Filatov, A. V. Shkolin
{"title":"Study of Applicability of MOF ZrBDC-NH2 for the Direct Carbon Dioxide Capture Process","authors":"O. V. Solovtsova, I. V. Ponomarev, A. E. Grinchenko, E. V. Khozina, I. E. Men’shchikov, A. A. Fomkin, M. A. Erokhin, A. E. Belov, V. A. Mavrov, N. I. Filatov, A. V. Shkolin","doi":"10.1134/S2070205126700383","DOIUrl":"10.1134/S2070205126700383","url":null,"abstract":"<p>The present work focuses on the results of the study of adsorption of carbon dioxide and nitrogen onto the synthesized metal-organic framework polymer (MOF) ZrBDC-NH<sub>2</sub>. The isotherms were recorded at temperatures of 243, 273, 293, and 333 K within the pressure range of 0 to 120 kPa. The isotherms of individual gas adsorption were calculated using the Dubinin–Radushkevich (D–R) equation within the framework of the theory of volume filling of micropores (TVFM). The IAST method was used to predict the adsorption of the binary CO<sub>2</sub>/N<sub>2</sub> mixture with the gas component ratio of 0.04/99.96 vol %. The differential molar isosteric heat of CO<sub>2</sub> adsorption and the separation coefficients were evaluated. The applicability of ZrBDC-NH<sub>2</sub> MOF for the direct adsorption removal of carbon dioxide from the air was assessed.</p>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"62 2","pages":"197 - 206"},"PeriodicalIF":1.1,"publicationDate":"2026-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148856748","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Probing of Transition Metals Microencapsulation via Hybrid Boron Nitride Nanomaterial towards Optimal Performance of Energy Storage in Nanoelectronics Devices","authors":"Fatemeh Mollaamin","doi":"10.1134/S2070205126700255","DOIUrl":"10.1134/S2070205126700255","url":null,"abstract":"<p>An investigation gives insights into the nature of the transition metal (TM)–boron electronic interaction in boron-bearing intermetallics and its effects on surface hydrogen adsorption and energy storage activity. This article wants to investigate the hydrogen storage increase through doping of Cr, Ni, Zn, Mo, Pd, Cd on the boron nitride nanocage. Based on NQR analysis, nickel, and palladium with atomic charges of 0.2658 and 0.3266 C on the complexes of Ni@BN and Pd@BN, respectively, have shown much more tendency for H<sub>2</sub> adsorption than other complexes. The results of NMR spectroscopy have exhibited that the efficiency of electron admitting for implanting atoms on the [Cr, Ni, Zn, Mo, Pd, Cd]@BN through H<sub>2</sub> adsorption can be ordered as: Ni > Pd <span>( gg )</span> Cr > Mo ≈ Zn > Cd. Regarding thermodynamic properties, it was indicated that for hydrogen sites in H<sub>2</sub> molecules, the consistencies of heteroclusters of decorated elements of Cr, Ni, Zn, Mo, Pd, Cd can be brought up as: Ni@BN > Pd@BN <span>( gg )</span> Cr@BN > Mo@BN ≈ Zn@BN > Cd@BN complexes. In addition, the hydrogen adsorption on transition metals doping BN heterocluster has been estimated through density of states analysis of total density of state (TDOS), partial density of states (PDOS), overlap partial density of states (OPDOS) and localized orbital locator analysis (LOL). Thus, the transition metal implanted BN can be used for designing novel materials for H<sub>2</sub> adsorption and sensing applications. Strong hybridization between the <i>d</i> orbitals of TM and the <i>sp</i> orbitals of boron exists in a family of six TM–boron intermatallics (TM@B), and hydrogen atoms adsorb more weakly to the metal-terminated intermetallic surfaces than to the corresponding pure metal surfaces.</p>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"62 2","pages":"265 - 280"},"PeriodicalIF":1.1,"publicationDate":"2026-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148856703","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}