{"title":"乳胶丙烯酸酯聚合物的弛豫行为。聚合因素的影响。统计聚合物","authors":"T. R. Aslamazova, V. A. Kotenev, V. A. Lomovskoi","doi":"10.1134/S2070205124702320","DOIUrl":null,"url":null,"abstract":"<p>The review is devoted to generalizing the results of studies of the relaxation behavior of latex acrylate polymers used as a binder in composite coatings on surfaces of various chemical nature, and structure in order to clarify the temperature ranges of their elastic and inelastic (dissipative) properties at temperatures from –150 to +200°C. Part 1.1 analyzes experimental data on the spectrum of internal friction and temperature–frequency dependences of the oscillatory process in statistical latex polyacrylates in comparison with polyacrylates of the free radical type obtained using the method of dynamic relaxation spectroscopy, which demonstrates the prospect of using the method to describe the physicomechanical properties of acrylate copolymers of various monomeric composition.</p>","PeriodicalId":745,"journal":{"name":"Protection of Metals and Physical Chemistry of Surfaces","volume":"60 5","pages":"854 - 865"},"PeriodicalIF":0.8000,"publicationDate":"2025-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Relaxation Behavior of Latex Acrylate Polymers. 1. The Effect of Polymerization Factors. 1.1. Statistical Polymer\",\"authors\":\"T. R. Aslamazova, V. A. Kotenev, V. A. Lomovskoi\",\"doi\":\"10.1134/S2070205124702320\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>The review is devoted to generalizing the results of studies of the relaxation behavior of latex acrylate polymers used as a binder in composite coatings on surfaces of various chemical nature, and structure in order to clarify the temperature ranges of their elastic and inelastic (dissipative) properties at temperatures from –150 to +200°C. Part 1.1 analyzes experimental data on the spectrum of internal friction and temperature–frequency dependences of the oscillatory process in statistical latex polyacrylates in comparison with polyacrylates of the free radical type obtained using the method of dynamic relaxation spectroscopy, which demonstrates the prospect of using the method to describe the physicomechanical properties of acrylate copolymers of various monomeric composition.</p>\",\"PeriodicalId\":745,\"journal\":{\"name\":\"Protection of Metals and Physical Chemistry of Surfaces\",\"volume\":\"60 5\",\"pages\":\"854 - 865\"},\"PeriodicalIF\":0.8000,\"publicationDate\":\"2025-03-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Protection of Metals and Physical Chemistry of Surfaces\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1134/S2070205124702320\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"METALLURGY & METALLURGICAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Protection of Metals and Physical Chemistry of Surfaces","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1134/S2070205124702320","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
Relaxation Behavior of Latex Acrylate Polymers. 1. The Effect of Polymerization Factors. 1.1. Statistical Polymer
The review is devoted to generalizing the results of studies of the relaxation behavior of latex acrylate polymers used as a binder in composite coatings on surfaces of various chemical nature, and structure in order to clarify the temperature ranges of their elastic and inelastic (dissipative) properties at temperatures from –150 to +200°C. Part 1.1 analyzes experimental data on the spectrum of internal friction and temperature–frequency dependences of the oscillatory process in statistical latex polyacrylates in comparison with polyacrylates of the free radical type obtained using the method of dynamic relaxation spectroscopy, which demonstrates the prospect of using the method to describe the physicomechanical properties of acrylate copolymers of various monomeric composition.
期刊介绍：
Protection of Metals and Physical Chemistry of Surfaces is an international peer reviewed journal that publishes articles covering all aspects of the physical chemistry of materials and interfaces in various environments. The journal covers all related problems of modern physical chemistry and materials science, including: physicochemical processes at interfaces; adsorption phenomena; complexing from molecular and supramolecular structures at the interfaces to new substances, materials and coatings; nanoscale and nanostructured materials and coatings, composed and dispersed materials; physicochemical problems of corrosion, degradation and protection; investigation methods for surface and interface systems, processes, structures, materials and coatings. No principe restrictions exist related systems, types of processes, methods of control and study. The journal welcomes conceptual, theoretical, experimental, methodological, instrumental, environmental, and all other possible studies.
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