发布求助
文献互助 智能选刊 最新文献

Nature synthesis最新文献

筛选
英文 中文
Geometric frustration in morphologically chiral nanoribbons of layered perovskites 层状钙钛矿手性纳米带的几何挫折
Nature synthesis Pub Date : 2026-09-29 DOI: 10.1038/s44160-026-01167-5
Wenhao Shao, Zhichen Nian, Yuan Lu, Hanjun Yang, Yi Yu, Brett M. Savoie, Letian Dou
{"title":"Geometric frustration in morphologically chiral nanoribbons of layered perovskites","authors":"Wenhao Shao, Zhichen Nian, Yuan Lu, Hanjun Yang, Yi Yu, Brett M. Savoie, Letian Dou","doi":"10.1038/s44160-026-01167-5","DOIUrl":"https://doi.org/10.1038/s44160-026-01167-5","url":null,"abstract":"Twisting and chiral growth are unusual in crystals and rarely observed in layered materials. Here we show that layered achiral metal-halide perovskites spontaneously form twisted and helical ribbons. Microscopy, diffraction and molecular dynamics simulations reveal that hydrogen-bonded organic networks within the lattice generate mismatched strains, causing ribbons to bend and twist when the strain is released, similar to the chiral opening of seed pods. This mismatch, known as geometric frustration, originates from crystal symmetry and can be tuned through molecular doping. Controlling growth kinetics twists nearly all ribbons towards one direction, giving bulk samples chiroptical activity. Statistical and mechanical analyses show that ribbon shape is governed by intrinsic elastic strain and geometric constraints; modulating them enables a continuous transition from twisted to helical ribbons. Our results show how molecular-scale interactions can generate macroscopic chiral shapes, providing a route to control chiral morphologies in layered two-dimensional materials.","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149087896","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Accelerated polymer design outpaces resistance 加速聚合物设计超过了阻力
IF 22.6
Nature synthesis Pub Date : 2026-09-29 DOI: 10.1038/s44160-026-01169-3
Jet-Sing M. Lee
{"title":"Accelerated polymer design outpaces resistance","authors":"Jet-Sing M. Lee","doi":"10.1038/s44160-026-01169-3","DOIUrl":"10.1038/s44160-026-01169-3","url":null,"abstract":"","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":"5 10","pages":"1484-1484"},"PeriodicalIF":22.6,"publicationDate":"2026-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149126005","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sustainable pyrrole synthesis 可持续吡咯合成
IF 22.6
Nature synthesis Pub Date : 2026-09-28 DOI: 10.1038/s44160-026-01174-6
Peter W. Seavill
{"title":"Sustainable pyrrole synthesis","authors":"Peter W. Seavill","doi":"10.1038/s44160-026-01174-6","DOIUrl":"10.1038/s44160-026-01174-6","url":null,"abstract":"","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":"5 10","pages":"1485-1485"},"PeriodicalIF":22.6,"publicationDate":"2026-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149125998","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Author Correction: Chemical reactivity from the perspective of enthalpic coupling 作者更正：从焓偶联的角度看化学反应性
IF 22.6
Nature synthesis Pub Date : 2026-09-28 DOI: 10.1038/s44160-026-01196-0
Chelsey Brien, Andrei K. Yudin
{"title":"Author Correction: Chemical reactivity from the perspective of enthalpic coupling","authors":"Chelsey Brien, Andrei K. Yudin","doi":"10.1038/s44160-026-01196-0","DOIUrl":"10.1038/s44160-026-01196-0","url":null,"abstract":"","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":"5 10","pages":"1660-1660"},"PeriodicalIF":22.6,"publicationDate":"2026-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.nature.comhttps://www.nature.com/articles/s44160-026-01196-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149125999","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hierarchically porous metal–organic frameworks with red topology for hydrogen and methane storage 层次多孔金属有机框架与红色拓扑为氢和甲烷储存
Nature synthesis Pub Date : 2026-09-28 DOI: 10.1038/s44160-026-01163-9
Xu Chen, Lik Hong Wee, Mohammad Reza Alizadeh Kiapi, Christos Tampaxis, Jiarui Fan, Hamish W. MacLeod, Yan Zheng, Benjamin J. Moore, Pascal Manuel, Fabio Orlandi, Luke L. Keenan, Enci Zhang, Mehrdad Asgari, Dhruv Menon, Georgia Charalambopoulou, Tom Willhammar, Sihai Yang, William Shepard, Yong Cui, Theodore Steriotis, David Fairen-Jimenez
{"title":"Hierarchically porous metal–organic frameworks with red topology for hydrogen and methane storage","authors":"Xu Chen, Lik Hong Wee, Mohammad Reza Alizadeh Kiapi, Christos Tampaxis, Jiarui Fan, Hamish W. MacLeod, Yan Zheng, Benjamin J. Moore, Pascal Manuel, Fabio Orlandi, Luke L. Keenan, Enci Zhang, Mehrdad Asgari, Dhruv Menon, Georgia Charalambopoulou, Tom Willhammar, Sihai Yang, William Shepard, Yong Cui, Theodore Steriotis, David Fairen-Jimenez","doi":"10.1038/s44160-026-01163-9","DOIUrl":"https://doi.org/10.1038/s44160-026-01163-9","url":null,"abstract":"The construction of highly porous metal–organic frameworks with complex topologies requires precise matching between linker conformation and node connectivity. Here we report the reticular design and synthesis of CU-6-M (M = Fe or Cr), assembled from conformationally adaptive diphenylethynyl linkers and six-connected trinuclear oxo-centred clusters. The ability of the linker to adopt multiple out-of-plane conformations satisfies the geometric requirements of a red topology, resulting in a highly interconnected hierarchical pore architecture. CU-6-Fe and CU-6-Cr exhibit an interconnected hierarchical pore system with Brunauer–Emmett–Teller surface areas up to 7,145 m2 g−1. This architecture enables total H2 uptakes of up to 17.5 wt% and 45.4 g l−1 at 100 bar and 77 K. Under temperature–pressure swing conditions, CU-6-Fe and CU-6-Cr deliver up to 16.9 wt% and 44.1 g l−1 and also show record gravimetric CH4 storage at ambient temperature. These results establish linker flexibility as a key design parameter for the realization of complex, highly porous topologies for high-capacity storage of clean-energy fuel gases.","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149087670","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrosynthesis of arylglycines from carbon dioxide, nitrite and aldehydes 用二氧化碳、亚硝酸盐和醛电合成芳基甘氨酸
Nature synthesis Pub Date : 2026-09-24 DOI: 10.1038/s44160-026-01161-x
Qi Sun,Nia J. Harmon,Zhaoyu ‘Charlie’ Cheng,Yuanzuo Gao,Hailiang Wang
{"title":"Electrosynthesis of arylglycines from carbon dioxide, nitrite and aldehydes","authors":"Qi Sun,Nia J. Harmon,Zhaoyu ‘Charlie’ Cheng,Yuanzuo Gao,Hailiang Wang","doi":"10.1038/s44160-026-01161-x","DOIUrl":"https://doi.org/10.1038/s44160-026-01161-x","url":null,"abstract":"","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":"5 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149050301","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electroreductive oxime carboxylation with CO2 produces arylglycines 与CO2电还原肟羧化反应产生芳基甘氨酸
Nature synthesis Pub Date : 2026-09-24 DOI: 10.1038/s44160-026-01160-y
Zhirong Zhang,Shaofeng Li,Jie Zeng
{"title":"Electroreductive oxime carboxylation with CO2 produces arylglycines","authors":"Zhirong Zhang,Shaofeng Li,Jie Zeng","doi":"10.1038/s44160-026-01160-y","DOIUrl":"https://doi.org/10.1038/s44160-026-01160-y","url":null,"abstract":"","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":"168 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149050302","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Crystallization control for narrow-linewidth perovskite LEDs 窄线宽钙钛矿led的结晶控制
Nature synthesis Pub Date : 2026-09-23 DOI: 10.1038/s44160-026-01157-7
Natalia Murrietta,Daniel N. Congreve
{"title":"Crystallization control for narrow-linewidth perovskite LEDs","authors":"Natalia Murrietta,Daniel N. Congreve","doi":"10.1038/s44160-026-01157-7","DOIUrl":"https://doi.org/10.1038/s44160-026-01157-7","url":null,"abstract":"","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":"15 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149022369","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enantio- and diastereoselective synthesis of multi-helical nanographenes 多螺旋纳米石墨烯的对映和非对映选择性合成
Nature synthesis Pub Date : 2026-09-22 DOI: 10.1038/s44160-026-01155-9
Ryota Shimizu,Juntaro Nogami,Yuko Kishida,Futo Morita,Chihiro Maeda,Hidehiro Uekusa,Ken Tanaka
{"title":"Enantio- and diastereoselective synthesis of multi-helical nanographenes","authors":"Ryota Shimizu,Juntaro Nogami,Yuko Kishida,Futo Morita,Chihiro Maeda,Hidehiro Uekusa,Ken Tanaka","doi":"10.1038/s44160-026-01155-9","DOIUrl":"https://doi.org/10.1038/s44160-026-01155-9","url":null,"abstract":"","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":"38 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149022368","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Through-space conductive pathways for polyoxometalate electronics 多金属氧酸盐电子器件的空间导电通路
Nature synthesis Pub Date : 2026-09-18 DOI: 10.1038/s44160-026-01159-5
Lin-Mei Zhang,Tao Wu
{"title":"Through-space conductive pathways for polyoxometalate electronics","authors":"Lin-Mei Zhang,Tao Wu","doi":"10.1038/s44160-026-01159-5","DOIUrl":"https://doi.org/10.1038/s44160-026-01159-5","url":null,"abstract":"","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":"10 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-09-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149022370","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
首页 上一页 下一页 尾页
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整，为了账户安全，请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们：info@booksci.cn Book学术提供免费学术资源搜索服务，方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号：604180095
Book学术官方微信
小红书