Nature synthesis最新文献

Durable, highly loaded atomically dispersed catalysts via a reticular coordination strategy 通过网状配位策略，持久、高负载的原子分散催化剂

Nature synthesis Pub Date : 2026-10-22 DOI: 10.1038/s44160-026-01204-3

Yoon Jung, Jaeho Moon, Jaehyuk Shim, Sein Hwang, Seong-Uk Bang, Sungeun Heo, Hyunsoo Ahn, Seungwoo Yoo, Dongho Shin, Sung Eun Chun, Megalamane S. Bootharaju, Jaeyune Ryu, Do Heui Kim, Sung-Pyo Cho, Yung-Eun Sung, Minho Kim, Taeghwan Hyeon, Byoung-Hoon Lee

{"title":"Durable, highly loaded atomically dispersed catalysts via a reticular coordination strategy","authors":"Yoon Jung, Jaeho Moon, Jaehyuk Shim, Sein Hwang, Seong-Uk Bang, Sungeun Heo, Hyunsoo Ahn, Seungwoo Yoo, Dongho Shin, Sung Eun Chun, Megalamane S. Bootharaju, Jaeyune Ryu, Do Heui Kim, Sung-Pyo Cho, Yung-Eun Sung, Minho Kim, Taeghwan Hyeon, Byoung-Hoon Lee","doi":"10.1038/s44160-026-01204-3","DOIUrl":"https://doi.org/10.1038/s44160-026-01204-3","url":null,"abstract":"Developing catalysts that can support high metal loadings (>10 wt%) that are resistant to sintering under harsh reaction conditions remains a fundamental challenge. Here we present a reticular coordination strategy to maximize precious metal utilization where Pt atoms are anchored onto Ce-oxo clusters within metal–organic frameworks and then converted into PtRC/CeOx (where RC denotes reticular coordination) by calcination, yielding catalysts with high atomic dispersion (14.9 wt%). Upon high-temperature (>300 °C) treatment under H2, the isolated Pt species do not undergo uncontrolled sintering; instead, their migration is suppressed after limited restructuring into flat, strongly confined ultrasmall clusters. Using the treated material (0.15 mgPt cm‒2) in proton exchange membrane water electrolysers results in a degradation rate of 25 μV h‒1, which outperforms 40 wt% Pt/C (106 μV h‒1 at 0.40 mgPt cm‒2) and retains its structural integrity after 500 h at 1 A cm‒2.","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":"17 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-10-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149241767","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Stepwise and chemoselective installation of carbon substituents at silicon atoms via monobromination of hydrosilanes 通过氢硅烷的单溴化，碳取代基在硅原子上的逐步和化学选择性安装

Nature synthesis Pub Date : 2026-10-19 DOI: 10.1038/s44160-026-01178-2

Sanjay Singh, Tobias Randt, Hendrik F. T. Klare, Martin Oestreich

{"title":"Stepwise and chemoselective installation of carbon substituents at silicon atoms via monobromination of hydrosilanes","authors":"Sanjay Singh, Tobias Randt, Hendrik F. T. Klare, Martin Oestreich","doi":"10.1038/s44160-026-01178-2","DOIUrl":"https://doi.org/10.1038/s44160-026-01178-2","url":null,"abstract":"Although organosilicon compounds containing different carbon substituents are ubiquitous in synthetic chemistry, their preparation is challenging. Laboratory synthesis commonly relies on the sequential substitution of tetrachlorosilane or tetraalkoxysilanes, producing complex mixtures that require demanding purification. This arises from limited control over nucleophilic substitution in functionalized silanes containing three or four (identical) leaving groups. Here we introduce an experimentally straightforward and reliable procedure for the preparation of both hetero- and homoleptic silanes using an overlooked monobromination of primary and secondary hydrosilanes. An equimolar amount of elemental bromine converts a Si–H bond into an Si–Br bond without ‘overbromination’. This step also shows exceptional functional-group tolerance to existing substituents at the silicon atom. Unsaturated moieties as well as heteroatom and heteroaryl groups are compatible. When performed in an iterative fashion, multihydrosilanes can be selectively converted into secondary, tertiary and quaternary silanes with two, three or four different carbon substituents in high yields. These functionalized silicon building blocks are relevant to synthetic chemistry as well as applied chemistry materials.","PeriodicalId":74251,"journal":{"name":"Nature synthesis","volume":"4 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149218191","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hydrogel-confined environment for aqueous-compatible perovskite crystallization 水相容钙钛矿结晶的水凝胶限制环境

Nature synthesis Pub Date : 2026-10-16 DOI: 10.1038/s44160-026-01182-6

Aiping Zhang,Huiyi Zong,Ruihan Yuan,Xiaojuan Lu,Zerui Wang,Congcong Wu,Jin Qian,Kai Wang,Xiaojia Zheng

引用次数: 0

Topotactic synthesis of gradient-encoded covalent organic framework membranes 梯度编码共价有机框架膜的拓扑合成

Nature synthesis Pub Date : 2026-10-16 DOI: 10.1038/s44160-026-01192-4

Yunqing Su,Zhuozhi Lai,Huixia Lv,Kunkun Ren,Haitao Su,Sai Wang,Jianke Chen,Zhirou Huang,Banglin Chen,Qi Sun

引用次数: 0

Synthesis of covalent organic frameworks through hydrogen-bonding catalysis 氢键催化合成共价有机骨架

Nature synthesis Pub Date : 2026-10-16 DOI: 10.1038/s44160-026-01180-8

Xingyao Ye,Shanshan Tao,Hongde Yu,Thomas Heine,Haipei Shao,Xinyu Mu,Yang Liu,Haoying Xu,Ming Lin,Donglin Jiang

引用次数: 0

The synthetic evolution of porous liquids 多孔液体的合成演化

Nature synthesis Pub Date : 2026-10-16 DOI: 10.1038/s44160-026-01186-2

Stuart L. James

引用次数: 0

Reversible zinc oxidation as a route to on-demand hydrogen delivery 可逆锌氧化作为按需输送氢的途径

Nature synthesis Pub Date : 2026-10-16 DOI: 10.1038/s44160-026-01190-6

Zhexuan Liu,Yifei Zhu,Wenxuan Yao,Yexin Song,Guangmin Zhou

引用次数: 0

Mechanoradical-chain C(sp3)–C(sp2) coupling with unactivated arenes 机械自由基链C(sp3) -C （sp2）偶联与非活化芳烃

Nature synthesis Pub Date : 2026-10-14 DOI: 10.1038/s44160-026-01171-9

Xiang Gu,Taoyong Wang,Fang-Zi Liu,Yicheng Huang,Ping Yu,Heather J. Kulik,KaKing Yan

引用次数: 0

Enantioselective synthesis of π-extended carbo[17]helicene via sequence-controlled quadruple [2+2+2] cycloadditions 序控四重[2+2+2]环加成法对映选择性合成π-延伸碳[17]螺旋烯

Nature synthesis Pub Date : 2026-10-14 DOI: 10.1038/s44160-026-01193-3

Futo Morita,Takeshi Ichimura,Juntaro Nogami,Yuko Kishida,Kanato Takahashi,Ryota Shimizu,Hidehiro Uekusa,Ken Tanaka

引用次数: 0

Atomically ordered dual atomic pairs in CuAuZn2 intermetallics for efficient urea electrosynthesis CuAuZn2金属间化合物中原子有序双原子对用于高效尿素电合成

Nature synthesis Pub Date : 2026-10-14 DOI: 10.1038/s44160-026-01187-1

Jiao Lan,Zhiwen Chen,Feng Xie,Zhen Wang,Jilong Li,Shanqiang Gao,Ming Peng,Yongwen Tan

引用次数: 0