V. S. Patrusheva, S. V. Gavrilov, T. I. Yanson, O. V. Kulikova
{"title":"Protective Technological Thermal Insulation Coating for Heat-Resistant Nickel Alloys","authors":"V. S. Patrusheva, S. V. Gavrilov, T. I. Yanson, O. V. Kulikova","doi":"10.1134/S1995421226700395","DOIUrl":"10.1134/S1995421226700395","url":null,"abstract":"<p>Protective technological coatings based on refractory glass in the BaO–CaO–SiO<sub>2</sub> system, a refractory modification filler, and a blowing additive are studied. It was found that the introduction of zirconium oxide as a modifier in an amount of no more than 10 wt % has a positive influence on the protective properties of the coating. There is no interaction between the alloy and the coating after heat treatment of the EP742 alloy coated at 1150°C for 2 h, and there is no oxidation of the alloy. Additional incorporation of graphite and silicon carbide into the coating composition decreases significantly the cooling rate of the samples. A heterogeneous large-porous structure increases the thermal insulation properties of the coating compositions. The study of lubrication properties of the coatings showed that the friction coefficient depends on not only the temperature and the degree of deformation, but also the coating composition to a significant extent. A friction coefficient decreases by 8–10 times with the use of protective coatings compared to those of uncoated EP742 alloy samples. Moreover, both silicon carbide and graphite additions are equally effective.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 1","pages":"157 - 162"},"PeriodicalIF":0.58,"publicationDate":"2026-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148299969","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
K. B. Vernigorov, V. V. Bushkov, V. I. Mashukov, S. A. Efremov, S. N. Rusanova, N. E. Temnikova, R. M. Ziyatdinova, Yu. G. Galyametdinov, Yu. M. Kazakov, O. V. Stoyanov
{"title":"Experimental Substantiation of the Antioxidant Effect of Carbon-Mineral Filler for Polymer Materials","authors":"K. B. Vernigorov, V. V. Bushkov, V. I. Mashukov, S. A. Efremov, S. N. Rusanova, N. E. Temnikova, R. M. Ziyatdinova, Yu. G. Galyametdinov, Yu. M. Kazakov, O. V. Stoyanov","doi":"10.1134/S1995421226700346","DOIUrl":"10.1134/S1995421226700346","url":null,"abstract":"<p>In modern polymer materials science, special attention is paid to the rational use of industrial waste as additional sources of raw materials. A new natural complex carbon–mineral filler (CMF) is a byproduct of coal shale mining—a layered rock with a significant content of carbonized plant particles. It was previously established that its introduction into polyethylene significantly inhibits the processes of polymer thermo-oxidative aging. To identify the causes of the observed effect, the chemical compositionof CMF was studied.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 1","pages":"125 - 129"},"PeriodicalIF":0.58,"publicationDate":"2026-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148299910","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
N. V. Kostromina, Yu. V. Olikhova, N. I. Lukashov, I. Yu. Gorbunova, D. V. Kramarev, N. D. Shesterin, A. N. Kochergin, V. Yu. Pivsaev, D. S. Kalinovsky
{"title":"The Influence of Carbonyl Nickel on Rheological Properties of Chlorosulfonated Polyethylene Materials","authors":"N. V. Kostromina, Yu. V. Olikhova, N. I. Lukashov, I. Yu. Gorbunova, D. V. Kramarev, N. D. Shesterin, A. N. Kochergin, V. Yu. Pivsaev, D. S. Kalinovsky","doi":"10.1134/S1995421226700358","DOIUrl":"10.1134/S1995421226700358","url":null,"abstract":"<p>The rheological properties of the materials based on toluene solution of chlorosulfonated polyethylene and filled with carbonyl nickel were studied. It was found that the filled materials are the systems with clear thixotropic properties. A decrease in solvent amount leads to an increase in sedimentation stability of the compounds. The filled wear-resistant composites with enhanced salt and water resistance were obtained.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 1","pages":"130 - 135"},"PeriodicalIF":0.58,"publicationDate":"2026-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148299911","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The Synthesis of Aromatic Mannich Polyol and a Polyurethane Coating Based on It","authors":"S. A. Baltacheva, I. N. Bakirova","doi":"10.1134/S199542122670019X","DOIUrl":"10.1134/S199542122670019X","url":null,"abstract":"<p>Aromatic polyol 2,6-bis[[bis(2-hydroxyethyl)amino]methyl]-4-nonylphenol is synthesized by the Mannich reaction via condensation of nonylphenol with formaldehyde and diethanolamine at their molar ratio of 1 : 2 : 2, respectively. Orthophosphoric acid is used as a catalyst. The structure of the obtained polyol is identified by IR spectroscopy and chemical analysis. A two-component polyurethane varnish is developed, the hydroxyl-containing component of which includes the synthesized Mannich polyol, acrylic polyol in xylene, and a solvent, and the isocyanate component, a solution of 1,3,5-tris(6-isocyanatohexyl)biuret in a mixture of methoxypropyl acetate and xylene. The polyurethane coating is distinguished by high adhesion, hardness in combination with impact strength, and a fast time of drying.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 1","pages":"14 - 19"},"PeriodicalIF":0.58,"publicationDate":"2026-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148299939","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Silicone Materials Intended for the Protection and Sealing of Microelectronics and Electronic Equipment","authors":"O. V. Neelova","doi":"10.1134/S1995421226700218","DOIUrl":"10.1134/S1995421226700218","url":null,"abstract":"<p>This article presents a review of research results on the physicochemical properties and applications of foreign and domestic organosilicon polymer materials designed to protect and seal micro- and nanoelectronics and electronic products.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 1","pages":"26 - 39"},"PeriodicalIF":0.58,"publicationDate":"2026-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148299987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. V. Artyomov, A. E. Shkuro, V. G. Buryndin, V. E. Tsvetkov
{"title":"Obtaining and Investigating the Physical and Mechanical Properties of Binder‑Free Plastics Produced by the “Blow‑Off” Method","authors":"A. V. Artyomov, A. E. Shkuro, V. G. Buryndin, V. E. Tsvetkov","doi":"10.1134/S199542122670022X","DOIUrl":"10.1134/S199542122670022X","url":null,"abstract":"<p>An analysis of literature shows that domestic and international scientists are focusing on the removal of excess steam during the production of wood-based materials and their derivatives by hot compression molding. Under piezothermic conditions (application of high pressure and temperature to wet molding raw materials), the necessary chemical reactions, resulting in the formation of new lignin-carbohydrate compounds, are facilitated during the production of binder-free plastic (BFP) in a closed mold. Under these conditions, the high-pressure steam is generated, which impedes the molding material compaction and generates internal stresses caused by elastic deformations and compressed vapors and gases remaining in the material. Consequently, this leads to a decrease in the physical and mechanical properties of resulting material. This study examines the feasibility of using the “blow‑off” method to produce binder-free plastic by closed-mold pressing. A mathematical design of the experiment was used to conduct this study. As a result of the adopted experimental model, the BFP samples were obtained and the influence of filler moisture content and pressing conditions on their physical and mechanical properties was determined. Based on the resulting regression equation describing the process, the optimal BFP pressing conditions were determined using the “blow‑off” method. Samples based on pine and birch sawdust and sunflower husks were obtained and tested using the optimal factors. Results of study demonstrated a positive effect of the “blow‑off” method when pressing various plant materials on the physical and mechanical properties of binder-free plastics.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 1","pages":"40 - 49"},"PeriodicalIF":0.58,"publicationDate":"2026-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148299914","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Compatibilization of Immiscible Polymer Blends with Solid Nanoparticles: Part 1. Morphology (A Review)","authors":"A. E. Zaikin","doi":"10.1134/S1995421226700188","DOIUrl":"10.1134/S1995421226700188","url":null,"abstract":"<p>This review summarizes current knowledge on the compatibilization of immiscible polymer blends using solid nanoparticles. The first section examines the patterns and analyzes the mechanisms of polymer phase size reduction and morphological stabilization in polymer blends under the influence of nanoparticles. It is emphasized that these changes do not always indicate compatibilization.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 1","pages":"1 - 13"},"PeriodicalIF":0.58,"publicationDate":"2026-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148299937","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
D. S. Kralechkin, M. I. Gubanova, I. A. Kirsh, O. A. Bannikova
{"title":"Current Trends and Scientific Achievements in the Global Market of Structural Adhesives","authors":"D. S. Kralechkin, M. I. Gubanova, I. A. Kirsh, O. A. Bannikova","doi":"10.1134/S1995421226700371","DOIUrl":"10.1134/S1995421226700371","url":null,"abstract":"<p>The paper provides an analytical review of the main trends in the global market of structural adhesives, as well as recent scientific research and developments in this field. It shows that adhesive bonding technologies are becoming increasingly in demand and are being used in various industries—aircraft manufacturing, automotive, packaging, and construction. It is demonstrated that the annual growth of the global market of structural adhesives and sealants is driven by their high strength properties combined with factors such as product weight reduction, shorter production cycle times, environmental friendliness, and production sustainability. Key trends include the development of engineering adhesives used in additive manufacturing, innovations aimed at reducing toxicity and developing eco-friendly bio-based adhesives, as well as the application of artificial intelligence systems in theoretical and applied research. Based on the findings, the market of structural adhesives can be objectively regarded as one of the dynamically developing sectors of the global market.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 1","pages":"142 - 151"},"PeriodicalIF":0.58,"publicationDate":"2026-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148299967","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of the Size of Polymer—Fiber Joints on the Change in Adhesive Strength under Various External Influences: Part 1. Scale Dependence of the Adhesive Strength of Fiber—Thermosetting Binder Joints under Normal Conditions","authors":"Yu. A. Gorbatkina, V. G. Ivanova-Mumzhieva","doi":"10.1134/S1995421226700206","DOIUrl":"10.1134/S1995421226700206","url":null,"abstract":"<p>An analysis of scale dependences of the force <i>F</i> required to shear the fiber relative to the polymer layer and the adhesive strength τ of fiber—thermosetting binder joints shows that a wide variation in the bond area <i>S</i> is possible only using fibers with a diameter <i>d</i> ≥ 100 μm; if <i>d</i> ≤ 10–15 μm, the <i>F</i>–<i>S</i> and τ–<i>S</i> dependences can currently only be measured for large bonding areas. Below the glass transition temperature of the adhesive pair components, with an increase in area <i>S</i> (in any system), the <i>F</i>–<i>S</i> dependence is described by a monotonically increasing curve tending to saturation, while the τ–<i>S</i> dependence is described by a monotonically nonlinearly decreasing curve. An analysis of τ–<i>S</i> curves allows us to introduce the concept of local adhesive strength as a characteristic of adhesive pair and to formulate the conditions for the failure of joints, as well as the conditions for constructing the composite strength—adhesive strength and binder strength—adhesive strength correlation curves.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 1","pages":"20 - 25"},"PeriodicalIF":0.58,"publicationDate":"2026-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148299986","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. V. Lobanov, A. A. Alekseev, E. A. Korobko, V. S. Osipchik, T. P. Kravchenko, N. G. David’yants, A. A. Alekseev Jr.
{"title":"Effect of Repeated Injection Molding Recycling of Polypropylene on Its Properties","authors":"A. V. Lobanov, A. A. Alekseev, E. A. Korobko, V. S. Osipchik, T. P. Kravchenko, N. G. David’yants, A. A. Alekseev Jr.","doi":"10.1134/S1995421226700450","DOIUrl":"10.1134/S1995421226700450","url":null,"abstract":"<p>The effect of five-fold injection molding on the properties of polypropylene grades PP H030 GP (230°C) and PPG 1350-21 (190°C) has been studied. For PP H030 GP, an increase in the melt flow index by 33% has been established, along with stability of strength indicators under tension, bending, and shrinkage; elongation increases, but decreases after the 5th recycling cycle. The Charpy unnotched impact strength at ‒20°C monotonically decreases by 28%. The properties of PPG 1350-21 are stable under five-fold recycling conditions. Heat treatment of all samples at 120°C for 1 h has a significant effect on their properties: the “neck” disappears, strength increases and elongation at break decreases, leveling both the effect of the polypropylene grade and the number of recycling cycles.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 1","pages":"202 - 206"},"PeriodicalIF":0.58,"publicationDate":"2026-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148299989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}