S. A. Mamadzhanova, O. I. Odintsova, I. N. Tyurin, S. Sh. Tashpulatov
{"title":"Chemical Functionalization of Textiles for the Synthesis of Conductive and Multifunctional Fabrics (A Review)","authors":"S. A. Mamadzhanova, O. I. Odintsova, I. N. Tyurin, S. Sh. Tashpulatov","doi":"10.1134/S1995421226701352","DOIUrl":"10.1134/S1995421226701352","url":null,"abstract":"<p>Chemical functionalization of textiles has recently become a key area in the creation of conductive and multifunctional materials for wearable electronics, protective clothing, and sensor systems. This review systematizes the main approaches to the formation of stable conductivity and additional functional properties in textiles, including plasma surface activation, chemical grafting, sol–gel processing, and the deposition of silver-based conductive phases, carbon nanostructures, and conductive polymers. It is shown that the durability of such materials is determined not only by the nature of the conductive component, but also by interfacial adhesion, the stability of the percolation structure during bending and washing, and the effectiveness of crosslinking agents and primers that prevent coating delamination. Particular attention is focused on hybrid systems that combine electrical conductivity, electromagnetic radiation shielding, antibacterial properties, and UV protection. Key performance parameters relevant for industrial applications are summarized, including resistance to household washing, abrasion, vapor permeability, and shielding effectiveness. It is concluded that the development of interfacial chemistry, eco-friendly dispersion systems, and scalable encapsulation methods is crucial condition for the transition from laboratory development to industrially applicable electronic textiles.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 3","pages":"744 - 750"},"PeriodicalIF":0.58,"publicationDate":"2026-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149309713","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
I. N. Kravchenko, N. V. Danyakin, S. V. Zanozin, A. A. Baranov, A. K. Anoprienko
{"title":"Development of a Chemical Method for Modifying the Polyurethane Surface to Improve Adhesion Properties during Gluing","authors":"I. N. Kravchenko, N. V. Danyakin, S. V. Zanozin, A. A. Baranov, A. K. Anoprienko","doi":"10.1134/S1995421226701212","DOIUrl":"10.1134/S1995421226701212","url":null,"abstract":"<p>The article proposes a new method for modifying the surface of polymers, in particular, a method for increasing the roughness of polyurethane-based materials through their chemical treatment without preliminary and subsequent operations of other types of treatment, ensuring increased adhesion between the modified polyurethane surface and the applied adhesive.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 3","pages":"668 - 671"},"PeriodicalIF":0.58,"publicationDate":"2026-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149309727","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
O. V. Startsev, I. G. Lukachevskaya, D. R. Nizin, M. P. Lebedev, A. L. Tereshkin
{"title":"Influence of Curing Agents on the Initial Stage of Ageing of the Etal‑247 Epoxy Polymer in Cold Climate Conditions","authors":"O. V. Startsev, I. G. Lukachevskaya, D. R. Nizin, M. P. Lebedev, A. L. Tereshkin","doi":"10.1134/S1995421226701224","DOIUrl":"10.1134/S1995421226701224","url":null,"abstract":"<p>Initial stage of aging of the epoxy polymer Etal-247 in the cold climates of Tiksi and Yakutsk was studied. Deformation, strength, and dynamic mechanical properties of Etal-247 vary widely when using the hardeners Etal-1472, Etal-45TZ<sub>2</sub>, Etal-45M, and Etal-M7. After exposure for three winter months, a significant deterioration in mechanical properties was observed, caused by the sorbed moisture’ plasticizing effect. Depending on the hardener used, the glass transition temperature of polymer decreases by 8–22°C upon moisture sorption. Effect of moisture was reversible. After removal of moisture, the deformation, strength, and dynamic mechanical properties returned to their original values. As a result of climatic influence, the degree of crosslinking increases, which is caused by the additional curing of Etal-247, which is most noticeable when using the Etal-1472 hardener.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 3","pages":"672 - 680"},"PeriodicalIF":0.58,"publicationDate":"2026-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149309728","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. G. Tsverava, S. V. Kuznetsov, M. Yu. Rusin, D. V. Alekseev, A. V. Terekhin
{"title":"Some Features of the Fracture Dynamics of Glass-Ceramic Samples under Three-Point Bending","authors":"V. G. Tsverava, S. V. Kuznetsov, M. Yu. Rusin, D. V. Alekseev, A. V. Terekhin","doi":"10.1134/S1995421226701431","DOIUrl":"10.1134/S1995421226701431","url":null,"abstract":"<p>Research has been conducted into the relationship between the dynamics of destruction process of glass-ceramic samples with the macrorelief’ features of their destruction surfaces.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 3","pages":"791 - 793"},"PeriodicalIF":0.58,"publicationDate":"2026-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149309764","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. A. Abduvakhidova, S. V. Polunin, I. Yu. Gorbunova, D. A. Konstantinova, V. V. Shutov, D. A. Trofimov, E. V. Belyaeva, T. I. Andreeva
{"title":"Curing Kinetics of an Epoxy Binder Modified with Cardo Polysulfone","authors":"A. A. Abduvakhidova, S. V. Polunin, I. Yu. Gorbunova, D. A. Konstantinova, V. V. Shutov, D. A. Trofimov, E. V. Belyaeva, T. I. Andreeva","doi":"10.1134/S1995421226701157","DOIUrl":"10.1134/S1995421226701157","url":null,"abstract":"<p>This paper is devoted to studying the curing kinetics of an epoxy–amine binder modified with a polysulfone cardo copolymer. Using differential scanning calorimetry, it was shown that, at the initial stage, the curing process is satisfactorily described by a second-order kinetic equation. It was found that the adding of polysulfone decreases the reaction activation energy by an average of 8–17 kJ/mol. It was shown that at the extent of conversion above 0.7, the curing process is described by a kinetic equation taking into account self-inhibition and the activation energy at this stage takes the value of 9–12 kJ/mol. The dependence of the activation energy on the extent of conversion for epoxy-polysulfone binders was calculated using the Vyazovkin method. It was demonstrated that an increase in the thermoplastic content shortens the region of the rubbery state of the reactive system.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 3","pages":"634 - 639"},"PeriodicalIF":0.58,"publicationDate":"2026-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149309769","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
N. A. Keibal, V. F. Kablov, O. M. Novopol’tseva, V. G. Kochetkov, D. A. Kryukova, D. A. Urzhumov, K. E. Yakimenko
{"title":"Development of Fire–Heat Resistant Coatings Based on Chlorosulfonated Polyethylene for Elastomer Materials Based on EPDM-40","authors":"N. A. Keibal, V. F. Kablov, O. M. Novopol’tseva, V. G. Kochetkov, D. A. Kryukova, D. A. Urzhumov, K. E. Yakimenko","doi":"10.1134/S1995421226701066","DOIUrl":"10.1134/S1995421226701066","url":null,"abstract":"<p>The properties of a composition based on chlorosulfonated polyethylene modified with a ternary product that is a mixture of carbon microfibers, aluminosilicate microspheres, and hexakis(2-(2-(boroxy)ethoxy)ethyl) nitrilotris(methylene)trisphosphonate that is a product of interaction of aminotrimethylene phosphonic acid, diethylene glycol, and boric acid and its use as protective coatings for rubber materials based on EPDM-40 with increased fire–heat-resisting properties are studied.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 3","pages":"575 - 579"},"PeriodicalIF":0.58,"publicationDate":"2026-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149309773","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Study of Illusory Effects of Textiles with Nanocoatings","authors":"M. A. Guseva, V. V. Getmantseva, E. V. Egupova","doi":"10.1134/S1995421226701297","DOIUrl":"10.1134/S1995421226701297","url":null,"abstract":"<p>The results of a comprehensive study of reflective textile materials as a promising class of polymer-composite systems are presented. The composition and structure of functional polymer-based coatings containing retroreflective elements (microspheres, microprisms) that determine their performance characteristics are analyzed. Particular attention is paid to the analysis of the optical-dynamic properties of the materials and their evolution from highly specialized personal protective equipment to modern applications in the design of sports and casual clothing. Modern computer visualization methods that allow for the simulation of complex optical effects (light reflection, color rendering) of virtual analogues of reflective textiles with a high degree of accuracy were developed and presented. The proposed approaches are based on computer graphics and physically based rendering, which enables accurate prediction of the visual characteristics of materials at the design stage.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 3","pages":"715 - 718"},"PeriodicalIF":0.58,"publicationDate":"2026-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149309777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. E. Zaikin, N. E. Temnikova, S. V. Tutov, K. B. Vernigorov, V. I. Mashukov, Yu. M. Kazakov, O. V. Stoyanov
{"title":"Grafting Maleic Anhydride onto Ethylene–Vinyl Acetate Copolymer","authors":"A. E. Zaikin, N. E. Temnikova, S. V. Tutov, K. B. Vernigorov, V. I. Mashukov, Yu. M. Kazakov, O. V. Stoyanov","doi":"10.1134/S1995421226701327","DOIUrl":"10.1134/S1995421226701327","url":null,"abstract":"<p>The synthesis of a graft copolymer of maleic anhydride and a random ethylene–vinyl acetate copolymer containing 28 wt % of vinyl acetate units via a radical-chain mechanism was studied. It was shown that peroxide 2,5-dimethyl-2,5-di(<i>tert</i>-butylperoxy)hexane used as an initiator exhibits higher efficiency than benzoyl peroxide both in terms of the degree of grafting and the conversion of maleic anhydride and in the activation of side reactions.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 3","pages":"728 - 733"},"PeriodicalIF":0.58,"publicationDate":"2026-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149309837","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. M. Bessarabov, V. E. Trokhin, E. V. Tatarnitseva, O. V. Stoyanov
{"title":"Determination of the Reaction Mechanism and Impurity Form at the Chemical Processing Stage in the Technology of High-Purity Materials","authors":"A. M. Bessarabov, V. E. Trokhin, E. V. Tatarnitseva, O. V. Stoyanov","doi":"10.1134/S1995421226701303","DOIUrl":"10.1134/S1995421226701303","url":null,"abstract":"<p>A method for chemical processing of high-purity materials (aluminum sec-butoxide, tetraethoxysilane, ethyl and sec-butyl alcohols) is considered. Models and methods for analyzing kinetic and equilibrium data are developed. It is shown that accurately determining the reaction mechanism and the trace impurity form improves the adequacy of the mathematical description of the process. Approaches proposed reduce the scope of experimental studies.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 3","pages":"719 - 723"},"PeriodicalIF":0.58,"publicationDate":"2026-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149309836","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"High-Strength Polymer Composite Material Made of Epoxy Resin","authors":"O. Yu. Erenkov, S. P. Isaev, B. I. Potapenko","doi":"10.1134/S1995421226701170","DOIUrl":"10.1134/S1995421226701170","url":null,"abstract":"<p>A new method for molding a composite material from epoxy resin is presented. The developed invention’ technical objective is to improve the strength properties of a composite material based on an epoxy resin. This objective is achieved through the use of combined electromagnetic treatment of the epoxy resin at different stages of the composite material molding process.</p>","PeriodicalId":741,"journal":{"name":"Polymer Science, Series D","volume":"19 3","pages":"645 - 649"},"PeriodicalIF":0.58,"publicationDate":"2026-11-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149309726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}