Environmental Science: Nano最新文献_第2页

Efficient simultaneously quantitative and qualitative detection of multiple phenols using highly water-stable Co2+‐doped Cu-BTC as electrocatalyst

IF 8.131 2区环境科学与生态学

Environmental Science: Nano Pub Date : 2024-12-11 DOI: 10.1039/d4en00912f

Yuanfang Li, Xiaoshu Lv, Yan Liu, Jie Yin, Ruimei Fang, Guangming Jiang, Zhehan Yang

{"title":"Efficient simultaneously quantitative and qualitative detection of multiple phenols using highly water-stable Co2+‐doped Cu-BTC as electrocatalyst","authors":"Yuanfang Li, Xiaoshu Lv, Yan Liu, Jie Yin, Ruimei Fang, Guangming Jiang, Zhehan Yang","doi":"10.1039/d4en00912f","DOIUrl":"https://doi.org/10.1039/d4en00912f","url":null,"abstract":"Abstract: A rational design of water-stable and high-efficiency MOFs-based electrocatalysts thus achieving durable sensitive electrochemical sensors remains a great challenge. Herein, water-stable Co2+ doped-Cu2+ and 1,3,5-benzene tricarboxylic coordination polymers (Cu-BTC@Co) were designed to construct a sensitive and durable electrochemical sensor for simultaneously detecting multiple hazardous phenols. Combining the Mulliken charges of H2O and BTC, the mechanism of the water-stability of Cu-BTC@Co was discussed, which is owing to the intermolecular force (Cu-BTC and Cu-OH2) and the intramolecular force (π-π bond, COO-H2O hydrogen bond), making Cu2+ coordination to BTC being much stronger than water, thereby the Cu-BTC@Co with strong stability in the water environment was achieved. Moreover, doping Co2+ into Cu-BTC not only improves the electron transfer efficiency of Cu-BTC but also enhances the catalytical efficiency of Cu-BTC. Combining the high-efficiency selective catalysis of Cu-BTC@Co and oxidation potential difference among multiple phenols, the Cu-BTC@Co sensor can simultaneously quantitative and qualitative detection of multiple phenols with good multicycle sensing performance. This article clarifies the mechanism of synthesizing water-stable MOFs and promotes the application of MOFs-based sensors in the quantitative analysis of water pollutants.","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":"21 1","pages":""},"PeriodicalIF":8.131,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142805218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Investigating gold nanorod-mediated hydrolysis of acetylthiocholine: A way for electrochemical detection of organophosphate pesticides

IF 8.131 2区环境科学与生态学

Environmental Science: Nano Pub Date : 2024-12-11 DOI: 10.1039/d4en00913d

Chumki Praharaj, Smriti Singh, Pranav Tripathi, Seema Nara

{"title":"Investigating gold nanorod-mediated hydrolysis of acetylthiocholine: A way for electrochemical detection of organophosphate pesticides","authors":"Chumki Praharaj, Smriti Singh, Pranav Tripathi, Seema Nara","doi":"10.1039/d4en00913d","DOIUrl":"https://doi.org/10.1039/d4en00913d","url":null,"abstract":"Pesticides and their metabolites threaten the environment and human health even at low concentrations. Therefore, the development of sensors to track such substances is crucial. Nanoparticle-based sensors have been widely used recently as a possible substitute analytical tool to traditional pesticide detection techniques. Artificial enzymes, also known as enzyme mimics or nanozymes, are gaining attention due to their innate ability to overcome the limitations of natural enzymes and their efficacy to be sufficient for upcoming advancements in treatments and diagnostics. Nanozyme-based assays may enable organophosphate pesticide detection without relying on the natural cholinesterase enzymes while retaining similar or higher sensitivity at a lower cost. Therefore, the present work investigates the acetylthiocholine (ATCH) hydrolyzing ability of gold nanorods (GNRs) through colorimetric, computational, and electrochemical methods. The GNRs were observed to intrinsically exhibit ATCH hydrolyzing ability, like acetylcholine esterase (AChE). Further, the effect of different organophosphates (OPs) (malathion, methyl parathion, chlorpyrifos, parathion, and dichlorvos) on the ATCH hydrolyzing ability of nanostructures was studied using an electrochemical approach. Their activity was significantly quenched in the presence of malathion and methyl parathion as compared to other OPs. The increasing order of OP's inhibitory effect was malathion>methyl parathion>dichlorvos>chlorpyrifos>parathion. It was observed that inhibition was proportional to the increasing concentration of OPs, and the linear range of detection was 0.0005-200.0 µg mL-1, with a limit of detection (LOD) of 8.1 pg mL-1 and 30.2 pg mL-1 respectively, for malathion and methyl parathion. Validation of river water samples spiked with different concentrations of malathion shows good recovery in the range of 100–110 %. Keywords: Acetylthiocholine; Cyclic Voltammetry; Electrochemical; Nanozyme; Organophosphate; Gold nanorod","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":"95 1","pages":""},"PeriodicalIF":8.131,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142804694","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Quartz sand surface-bound rice root exudates decreased the transport of microplastics in porous media

IF 8.131 2区环境科学与生态学

Environmental Science: Nano Pub Date : 2024-12-11 DOI: 10.1039/d4en00984c

Genyao Gu, Dan Wu, Yanan Liu, Junfu Wang, Yunfei Zhang, Xiaopeng Min, Li Cai

{"title":"Quartz sand surface-bound rice root exudates decreased the transport of microplastics in porous media","authors":"Genyao Gu, Dan Wu, Yanan Liu, Junfu Wang, Yunfei Zhang, Xiaopeng Min, Li Cai","doi":"10.1039/d4en00984c","DOIUrl":"https://doi.org/10.1039/d4en00984c","url":null,"abstract":"Plants are widely present in soil ecosystems, and plant root exudates are therefore considered as an important factor that could affect the fate and transport of microplastics (MPs). The effect of quartz sand surface-bound root exudates of rice (long-grained rice) was used to explore its influence on both PS and PET MPs in porous media. 0.51 μm, PS MPs and 1.1 μm PS MPs, and 1 μm PET MPs were investigated under 0.1-10 mM NaCl and 0.1-1 mM CaCl2 solutions. The sand surface-bound root exudates were found to decrease the transport of both PS and PET MPs, with the most obvious difference in the intermediate ionic strengths in both NaCl and CaCl2 solutions. By performing the column experiment after the removal of sand surface-bound root exudates, it was verified that the role of physical space occupation by the root was not the factor driving the inhibited transport of PS and PET MPs. Further investigations revealed that the surface properties of quartz sand altered by the presence of root exudates was the main factor responsible for the decreased transport of PS and PET MPs. The zeta potentials, excitation−emission−matrix (EEM) spectra, and the components of the root exudates were determined. It was obtained that microbial by-product like, fluvic acid-like substances and aromatic protein were the major components of the root exudates. The results indicated that the electrostatic repulsive forces between MPs and quartz sand were expected to be lower in the presence of sand surface bound-root exudates as predicted by the DLVO theory. The findings of this study are essential to shine light on the knowledge of the fate and transport of plastic particles in soil systems with ubiquitous plants.","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":"117 1","pages":""},"PeriodicalIF":8.131,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142804591","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Micro- and nanoplastics-mediated phototransformation and bioaccessibility of fluorinated liquid crystal monomer in aquatic environments

IF 8.131 2区环境科学与生态学

Environmental Science: Nano Pub Date : 2024-12-10 DOI: 10.1039/d4en00723a

Yiping Feng, Jingyi Wu, Wenhao Lao, Weibiao Ye, Danni Guo, Zhu Wang, Xaiowei Wu, Racliffe W.S. Lai

{"title":"Micro- and nanoplastics-mediated phototransformation and bioaccessibility of fluorinated liquid crystal monomer in aquatic environments","authors":"Yiping Feng, Jingyi Wu, Wenhao Lao, Weibiao Ye, Danni Guo, Zhu Wang, Xaiowei Wu, Racliffe W.S. Lai","doi":"10.1039/d4en00723a","DOIUrl":"https://doi.org/10.1039/d4en00723a","url":null,"abstract":"Micro- and nanoplastics are emerging pollutants that have attracted significant attention due to their potential to concentrate and transport coexisting organic pollutants in aquatic environments. Fluorinated liquid-crystal monomers (FLCMs) have also emerged as contaminants of concern, given their frequent occurrence, potential toxic effects, and propensity to co-occur with plastics in the environment. However, the influence of plastics on the environmental fate of FLCMs remains unclear yet. To address this knowledge gap, we investigated the accumulation of a key FLCM, 4-cyano-3-fluorophenyl 4-ethylbenzoate (CEB-F), on three common plastics, and examined the effects of nanoplastics on the phototransformation of CEB-F and its acute toxicity to Daphnia magna (D. magna). Our findings revealed that the adsorption capacity of CEB-F on different plastic materials followed the order: polystyrene (PS) < mixed cellulose ester (MCE) < polyamide (PA). The adsorption processes of CEB-F on the three plastics aligned more closely with the pseudo-first-order kinetic model and the Langmuir isotherm model, suggesting that the adsorption is primarily governed by physical diffusion. Theoretical calculations indicated that the adsorption of CEB-F on PS plastics is mainly driven by hydrophobic interactions. Additionally, PS nanoplastics (PSNPs) significantly enhanced the UV degradation of CEB-F, although the types of degradation intermediates did not change substantially, suggesting a limited impact on the degradation process and mechanism. Acute toxicity tests showed that PSNPs increased the toxicity of CEB-F to D. magna at lower concentrations, while the toxicity was reduced at higher concentrations. The obtained findings are of great significance to unraveling the plastic-mediated environmental fate and aquatic toxicity of FLCMs in natural waters.","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":"10 1","pages":""},"PeriodicalIF":8.131,"publicationDate":"2024-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142797148","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Biomass-based water purification: A simple and novel one-pot process for converting date palm mesh fibers into a valuable nanomagnetic composite for water treatment

IF 8.131 2区环境科学与生态学

Environmental Science: Nano Pub Date : 2024-12-09 DOI: 10.1039/d4en00378k

Batool Vahedi Sarrygani, Fayezeh Samari, Fatemeh Sedaghati

{"title":"Biomass-based water purification: A simple and novel one-pot process for converting date palm mesh fibers into a valuable nanomagnetic composite for water treatment","authors":"Batool Vahedi Sarrygani, Fayezeh Samari, Fatemeh Sedaghati","doi":"10.1039/d4en00378k","DOIUrl":"https://doi.org/10.1039/d4en00378k","url":null,"abstract":"A novel magnetic nanocomposite was successfully synthesized using date palm mesh fiber waste as a sustainable substrate. This green and cost-effective approach produced a nanocomposite characterized by various techniques. The BET-specific surface area and total pore volume of the magnetic nanocomposite were 19.46 m2/g and 0.099 m3/g, respectively. These values were much higher than the raw substrate. The synthesized magnetic nanocomposite was tested as an adsorbent for removing methylene blue (MB-organic pollutant) and potassium permanganate (MnO4-inorganic pollutant) from water. Optimal conditions (adsorbent dosage, pH, temperature, equilibrium time) for removing MB and MnO4- from water using the magnetic nanocomposite were determined. Under these conditions, the nanocomposite exhibited excellent removal efficiency for MB and MnO4- with ~ 95% and 99%, respectively The experimental data were best fitted by the Langmuir model and the pseudo-second-order kinetic model for MB and MnO4- with highest sorption capability of 10.77 and 58.48 mg/g, respectively The applicability of the nanocomposite was examined in various real-water samples and satisfactory results were obtained. The magnetic biosorbent showed good reusability, maintaining 81.3% removal efficiency for MB after eleven consecutive adsorption-desorption cycles using ethanol. It is expected that this high-capacity, recyclable magnetic adsorbent can potentially offer a promising, facile, cost-efficient, and eco-friendly route to pollutant water treatment.","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":"90 1","pages":""},"PeriodicalIF":8.131,"publicationDate":"2024-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142793236","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Recent Advances in Applications of MXenes for Desalination, Water Purification and as an Antibacterial: A Review

IF 8.131 2区环境科学与生态学

Environmental Science: Nano Pub Date : 2024-12-05 DOI: 10.1039/d4en00427b

Hicham Meskher, Amrit Thakur, Soumya Kanti Hazra, Md Shamim Ahamed, Ahmed Mortuza Saleque, Qusay F. Alsalhy, Muhammad Shahzad, Md. Nahian Al Subri Ivan, Shuvra Saha, Iseult Lynch

{"title":"Recent Advances in Applications of MXenes for Desalination, Water Purification and as an Antibacterial: A Review","authors":"Hicham Meskher, Amrit Thakur, Soumya Kanti Hazra, Md Shamim Ahamed, Ahmed Mortuza Saleque, Qusay F. Alsalhy, Muhammad Shahzad, Md. Nahian Al Subri Ivan, Shuvra Saha, Iseult Lynch","doi":"10.1039/d4en00427b","DOIUrl":"https://doi.org/10.1039/d4en00427b","url":null,"abstract":"Membranes have become a basis for tackling the global challenge of freshwater scarcity, notably in the fields of desalination and water purification. MXenes, distinguished by their notable high aspect ratio, extensive surface area, robust mechanical strength, and enduring chemical resilience, have emerged as highly promising materials for membrane development. Recent progress in the research and application of MXene membranes, especially in the areas of water desalination and treatment, marks a significant leap forward in this domain. This study conducts an exhaustive analysis of the state-of-the-art developments in the creation and enhancement of MXene-based membranes. It delves into their application in various desalination processes, including membrane-based desalination and solar-driven interfacial steam generation, alongside their use in water purification. This analysis sheds light on their efficacy in the desalination processes, in addition to evaluating their antimicrobial properties and salt rejection efficiency. Moreover, the review provides an in-depth examination of the mechanics behind MXene membrane functionality and assesses their overall impact, pinpointing both the current opportunities they present and the challenges they face. The primary goal of this discussion is to enrich the collective understanding of MXene membrane technology and to spur ongoing refinement and innovation in this area. By doing so, the review aims to contribute to the advancement of sustainable solutions to water scarcity through the development of more efficient and effective membrane technologies.","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":"3 1","pages":""},"PeriodicalIF":8.131,"publicationDate":"2024-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142777232","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Characterizing airborne nanoparticles in six Chinese cities based on their interactions with natural air ions

IF 8.131 2区环境科学与生态学

Environmental Science: Nano Pub Date : 2024-12-04 DOI: 10.1039/d4en00796d

Jin Wu, Hao Wu, Yiran Li, Tingyu Liu, Mei Zheng, Cheng Huang, Fang Zhang, Jun Zhao, Jianwu Shi, Xiaoxiao Li, Yongchun Liu, Rujing Yin, Xiaotong Chen, Qiang Zhang, Jiming Hao, Jingkun Jiang

{"title":"Characterizing airborne nanoparticles in six Chinese cities based on their interactions with natural air ions","authors":"Jin Wu, Hao Wu, Yiran Li, Tingyu Liu, Mei Zheng, Cheng Huang, Fang Zhang, Jun Zhao, Jianwu Shi, Xiaoxiao Li, Yongchun Liu, Rujing Yin, Xiaotong Chen, Qiang Zhang, Jiming Hao, Jingkun Jiang","doi":"10.1039/d4en00796d","DOIUrl":"https://doi.org/10.1039/d4en00796d","url":null,"abstract":"Airborne nanoparticles (NPs) are particles with diameter smaller than 100 nm, which can significantly influence global climate, regional air quality, and human health. The interactions between airborne nanoparticles and atmospheric ions are ubiquitous, which also condition the charge state of nanoparticles. To deepen our understanding of nanoparticles in different regions of China and explore their interactions with air ions, we conducted a one-year measurement of airborne nanoparticle number size distributions in six Chinese cities. Six homemade bipolar scanning mobility particle sizers were applied to scan both positively and negatively charged nanoparticles. The annual average number concentration of nanoparticles (NNPs) are 5880±3140 #·cm-3 (Beijing), 6280±2910 #·cm-3 (Shanghai), 5440±3370 #·cm-3 (Wuhan) in three urban sites, and 5320±3440 #·cm-3 (Shenzhen), 3440±2370 #·cm-3 (Zhuhai) and 2440±1870 #·cm-3 (Kunming) in three suburban sites. NNPs account for 65.6%–80.4% of total particle number concentration in six cities. Besides, NNPs contributed by new particle formation in suburban areas are comparable to or even higher than those in urban areas. In Beijing and Shanghai, NNPs decreased by 55.2% and 66.4% from 2013 to 2023, respectively. Ion mobility, composition, and concentration are the parameters governing charge state of nanoparticles. In Beijing, we found that the ion mobility distribution and nanoparticle charge state vary at the same time, and the composition of negative cluster ions are mainly composed by inorganic nitrogen-containing ions, inorganic sulfur-containing ions, and organic ions.","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":"20 1","pages":""},"PeriodicalIF":8.131,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142763152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Mn3O4 nanoparticles maintain ROS homeostasis to modulate stomatal aperture to improve cotton drought tolerance

IF 8.131 2区环境科学与生态学

Environmental Science: Nano Pub Date : 2024-12-04 DOI: 10.1039/d4en00963k

Yanhui Li, Yunpeng Tao, Wenying Xu, Han Wu, Guangjing Li, Lin Yue, Jiangjiang Gu, Fangjun Li, Honghong Wu, Juan Pablo Giraldo, Zhaohu Li

{"title":"Mn3O4 nanoparticles maintain ROS homeostasis to modulate stomatal aperture to improve cotton drought tolerance","authors":"Yanhui Li, Yunpeng Tao, Wenying Xu, Han Wu, Guangjing Li, Lin Yue, Jiangjiang Gu, Fangjun Li, Honghong Wu, Juan Pablo Giraldo, Zhaohu Li","doi":"10.1039/d4en00963k","DOIUrl":"https://doi.org/10.1039/d4en00963k","url":null,"abstract":"Drought is a global issue causing severe reductions in crop yields. Use of nanobiotechnology to increase plant resistance to drought is widely reported. However, the mechanisms underlying nanomaterial improvement of crop drought tolerance are not well understood. Herein, we reported poly acrylic acid coated manganese oxide (Mn3O4) nanoparticles (PMO, 5.43 nm, -31.6 mV) increase cotton fresh weight (74.9%) under drought stress relative to controls by catalytically scavenging ROS and modulating stomatal aperture. PMO treated cotton leaves showed significantly lower ROS levels (60-70%) determined by confocal microscopy, biochemical and histochemical staining analysis. Also, plants exposed to PMO experienced less oxidative damage than controls under drought, as indicated by their lower malondialdehyde (MDA) content (2.02 ± 0.15 μmol/L vs 3.25 ± 0.27 μmol/L) and electrolyte leakage rate (31.13% ± 5.51 vs 64.83% ± 4.29). PMO treated cotton plants also maintained stomatal aperture and had higher photosynthetic performance (160%) under drought stress. Furthermore, we set up a portable monitoring system with low cost which can allow the real-time imaging of stomatal aperture and chlorophyll fluorescence in plants treated with nanomaterials. Overall, our results suggested that PMO could be a biocompatible and scalable tool for improving crop drought tolerance.","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":"16 1","pages":""},"PeriodicalIF":8.131,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142777233","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Silica nanoparticles enhance plant disease resistance by modulating the endophyte community structure in tomato (Solanum lycopersicum L.) roots

IF 8.131 2区环境科学与生态学

Environmental Science: Nano Pub Date : 2024-12-02 DOI: 10.1039/d4en00511b

Lei Wang, Taowen Pan, Sicong Li, Yi Wang, Jason C. White, Baoshan Xing, Kunzheng Cai

{"title":"Silica nanoparticles enhance plant disease resistance by modulating the endophyte community structure in tomato (Solanum lycopersicum L.) roots","authors":"Lei Wang, Taowen Pan, Sicong Li, Yi Wang, Jason C. White, Baoshan Xing, Kunzheng Cai","doi":"10.1039/d4en00511b","DOIUrl":"https://doi.org/10.1039/d4en00511b","url":null,"abstract":"Nanoparticles have attracted widespread attention for their positive role in suppressing plant diseases. In the present work, the impact of silica nanoparticles (SNPs) on the bacterial community of tomato root endophytes under<em> Ralstonia solanacearum </em>(Rs) infection was investigated. Tomato infection by Rs led to a 17.78% reduction in shoot fresh weight and a 66.44% reduction in root fresh weight. Repeated three soil applications of 650 mg·L−1 SNPs significantly suppressed bacterial wilt, with a 40.27%-48.96% reduction in the disease index. SNPs also significantly increased the shoot fresh and dry weight by 17.43% and 17.13%, respectively. In the roots, SNPs altered the structure and increased the diversity of the endophytic bacteria community in infected plants. Notably, Mitsuaria, Sphingobium, Streptococcus, and Rhizobium were enriched with SNPs-Rs treatment; these are identified as beneficial bacteria that facilitate plant resistance to pathogens. Additionally, SNPs application significantly increased the root content of N (27.01%), K (8.34%), and Si (11.01%) under Rs infection. A correlation analysis indicated that the root nutritional element content was positively correlated with bacterial community diversity. These data show that SNPs can enhance plant resistance to disease by regulating the structure and diversity of root endophyte communities and that this may be mediated through improved plant nutrition. Our findings have important implications for the application of nanoparticles in sustainable nano-enabled agriculture.","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":"31 1","pages":""},"PeriodicalIF":8.131,"publicationDate":"2024-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142758224","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

High Selectivity of CO2 Capture with Single- and Double-Walled Carbon Nanotubes

IF 8.131 2区环境科学与生态学

Environmental Science: Nano Pub Date : 2024-11-29 DOI: 10.1039/d4en00496e

Winarto Winarto, Lilis Yuliati, Purnami Purnami, Paul E. Brumby, Kenji Yasuoka

{"title":"High Selectivity of CO2 Capture with Single- and Double-Walled Carbon Nanotubes","authors":"Winarto Winarto, Lilis Yuliati, Purnami Purnami, Paul E. Brumby, Kenji Yasuoka","doi":"10.1039/d4en00496e","DOIUrl":"https://doi.org/10.1039/d4en00496e","url":null,"abstract":"An excessive concentration of greenhouse gases, most significantly carbon dioxide (CO2), in the atmosphere has led to the serious environmental issue of global warming. Carbon capture is a suitable strategy to reduce the increase of CO2 in the atmosphere due to fossil fuel combustion. Innovative technologies for CO2 capture are urgently required and this is an area of intensive study in order to improve efficiency and reduce operational costs. In this work, we applied molecular dynamics simulations to demonstrate the ability of single–walled carbon nanotubes (SWCNT) and double–walled carbon nanotubes (DWCNT) to capture CO2 from flue gases. Both SWCNTs and DWCNTs prefer to adsorb CO2 rather than N2 and O2, resulting in a separation effect. CO2 molecules form a solid ice structure in the carbon nanotubes (CNT) while N2 and O2 remain gaseous. As a result, the potential energy of the CO2 structure inside the CNTs is lower than that of the N2 or O2 structures. This implies that CO2 is more stable in the CNTs. Therefore, the formation of these solid CO2 structures plays an important role in the process of capturing CO2 via CNTs. Moreover, the van der Waals interactions between CO2 molecules and the CNT walls make a significant contribution to the separation of CO2 as well. The potential energy of the CO2– CNT wall interactions is significantly lower than those of N2–CNT wall or O2–CNT wall interactions. In addition, the presence of a second wall in DWCNTs causes even stronger attractive CO2–CNT wall van der Waals interactions than those found in SWCNTs. As a result, the CO2 capturing effect of DWCNT is greater than that of SWCNT.","PeriodicalId":73,"journal":{"name":"Environmental Science: Nano","volume":"11 1","pages":""},"PeriodicalIF":8.131,"publicationDate":"2024-11-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142753010","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0