MOF-on-MOF Derived Magnetic CoFe2O4@Fe0 Nanocomposites for Ultra-Rapid Peroxymonosulfate Activation: Mechanistic Insights and Eco-Toxicological Validation

IF 5.1 2区环境科学与生态学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Environmental Science: Nano Pub Date : 2025-09-17 DOI:10.1039/d5en00688k

Zi-Chen Zhang, Ruo-Xuan Mei, Chong-Chen Wang, Fu-Xue Wang, Yuliang Dong, Jian-Feng Wang

引用次数: 0

Abstract

CoFe2O4@Fe0 nanocatalysts derived from epitaxially grown S-BUC-21(Fe)@FeCo-PBA MOF-on-MOF precursors achieved complete atrazine degradation within 5 minutes via peroxymonosulfate activation. Mechanistic studies revealed synergistic radical/non-radical pathways, while phytotoxicity tests with Setaria viridis and Eleusine indica seedlings confirmed the environmental safety of degradation products. This work presents an efficient, eco-friendly solution for water purification.

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MOF-on-MOF衍生的磁性CoFe2O4@Fe0纳米复合材料用于超快速过氧单硫酸盐活化：机理见解和生态毒理学验证

CoFe2O4@Fe0纳米催化剂来源于外延生长的S-BUC-21(Fe)@ feo - pba MOF-on-MOF前体，通过过氧单硫酸盐活化，在5分钟内完全降解了阿特拉津。机制研究揭示了自由基/非自由基的协同作用途径，而对狗尾草和印度莲子幼苗的植物毒性试验证实了降解产物的环境安全性。这项工作提出了一种高效、环保的水净化解决方案。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Environmental Science: Nano CHEMISTRY, MULTIDISCIPLINARY-ENVIRONMENTAL SCIENCES

CiteScore

12.20

自引率

5.50%

发文量

290

审稿时长

2.1 months

期刊介绍： Environmental Science: Nano serves as a comprehensive and high-impact peer-reviewed source of information on the design and demonstration of engineered nanomaterials for environment-based applications. It also covers the interactions between engineered, natural, and incidental nanomaterials with biological and environmental systems. This scope includes, but is not limited to, the following topic areas: Novel nanomaterial-based applications for water, air, soil, food, and energy sustainability Nanomaterial interactions with biological systems and nanotoxicology Environmental fate, reactivity, and transformations of nanoscale materials Nanoscale processes in the environment Sustainable nanotechnology including rational nanomaterial design, life cycle assessment, risk/benefit analysis