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Statistical and probabilistic modeling of groundwater contamination: A data-driven uncertainty and risk assessment in Barind Tract, Rajshahi, Bangladesh
Journal of trace elements and minerals Pub Date : 2025-03-04 DOI: 10.1016/j.jtemin.2025.100223
Mir Md Tasnim Alam , Md Opu Sarker , Mahfuzur Rahman , Nazmus Sakib , Mahir Tajwar , Md Yousuf Gazi , Shamiha Shafinaz Shreya , Saika Islam Meim , Anwar Zahid
{"title":"Statistical and probabilistic modeling of groundwater contamination: A data-driven uncertainty and risk assessment in Barind Tract, Rajshahi, Bangladesh","authors":"Mir Md Tasnim Alam ,&nbsp;Md Opu Sarker ,&nbsp;Mahfuzur Rahman ,&nbsp;Nazmus Sakib ,&nbsp;Mahir Tajwar ,&nbsp;Md Yousuf Gazi ,&nbsp;Shamiha Shafinaz Shreya ,&nbsp;Saika Islam Meim ,&nbsp;Anwar Zahid","doi":"10.1016/j.jtemin.2025.100223","DOIUrl":"10.1016/j.jtemin.2025.100223","url":null,"abstract":"<div><h3>Introduction</h3><div>Groundwater contamination by potentially toxic elements (PTEs) poses serious health risks in Bangladesh, yet limited studies have addressed their seasonal and spatial variability. In the Barind Tract, Rajshahi, groundwater is a critical resource for drinking and irrigation, emphasizing the need for a comprehensive evaluation of contamination patterns and health implications.</div></div><div><h3>Methods</h3><div>A total of 244 groundwater samples (122 per season) were analyzed for As, Al, Cu, Mn, Cr, and B using Atomic Absorption Spectrophotometry and VIS Spectrophotometry. Contamination was assessed using Metal Evaluation Index (MEI), Nemerow Pollution Index (NPI), Contamination Degree (CD), and Poseidon Index (PoS). Statistical analyses included ANOVA, effect size (η², f²), PCA, and HCA. Monte Carlo simulation (10,000 iterations, 95% CI) estimated probabilistic health risks for adults and children.</div></div><div><h3>Results</h3><div>Boron (1.034 mg L⁻¹) and manganese (0.824 mg L⁻¹) dominated during the wet season, while manganese (0.735 mg L⁻¹) and aluminum (0.605 mg L⁻¹) were highest in the dry season. MEI, NPI, and CD indices indicated significant contamination in Sirajganj, Chapai Nawabganj, and Natore, with Chapai Nawabganj (PoS 9.01) and Natore (PoS 8.223) showing extensive groundwater degradation. Statistical analyses confirmed significant seasonal variations, with aluminum, copper, chromium, and boron showing the most fluctuation due to hydrological and geochemical changes. Health risk assessments identified 64 samples unsafe for children and 32 for adults, with Monte Carlo simulations indicating hazard indices reaching up to 4.68 for children in certain hotspots.</div></div><div><h3>Conclusions</h3><div>Pronounced seasonal variations in groundwater contamination underscore the necessity of targeted, season-specific monitoring and mitigation measures. Tailored interventions are essential to safeguard public health, especially for children who face higher exposure risks. The findings offer critical insights for policy-makers and stakeholders, promoting sustainable groundwater management in the Barind Tract.</div></div>","PeriodicalId":73997,"journal":{"name":"Journal of trace elements and minerals","volume":"12 ","pages":"Article 100223"},"PeriodicalIF":0.0,"publicationDate":"2025-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143637625","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The phosphate solubilizing and N fixing Pantoea agglomerans bacteria affecting yield and biochemical properties including nutrient uptake of different tomato genotypes
Journal of trace elements and minerals Pub Date : 2025-03-03 DOI: 10.1016/j.jtemin.2025.100225
Hamed Soltani , Akbar Hassani , Mohammad Baba Akbari Sari , Mehrdad Hanifei
{"title":"The phosphate solubilizing and N fixing Pantoea agglomerans bacteria affecting yield and biochemical properties including nutrient uptake of different tomato genotypes","authors":"Hamed Soltani ,&nbsp;Akbar Hassani ,&nbsp;Mohammad Baba Akbari Sari ,&nbsp;Mehrdad Hanifei","doi":"10.1016/j.jtemin.2025.100225","DOIUrl":"10.1016/j.jtemin.2025.100225","url":null,"abstract":"<div><h3>Background</h3><div>Suggesting and testing innovative methods, which may enhance the growth and quality of crop plants in the field is of economic and health significance.</div></div><div><h3>Objectives and methods</h3><div>There is not much data, to our knowledge, on the use of the endophytic bacteria, <em>Pantoea agglomerans</em>, affecting growth, yield and biochemical properties of different tomato (<em>Solanum lycopersicum</em>) genotypes (Rusha, Maranku, Hiro, and Vitara, supplied by the Zola Company, Holland) in the field conditions, as the objective of the present research. Different tomato growth and quality parameters including leaf greenness, number of flower, yield, fruit dissolved solids and dry biomass, pH, vitamin C, and nutrient uptake (N, P, K) were determined.</div></div><div><h3>Results</h3><div>Genotype 3 followed by Genotype 4 indicated to be the most efficient ones with significantly higher tomato yield and nutrient uptake. The bacterial inoculation significantly increased tomato yield from a minimum of 7.58 kg plot<sup>−1</sup> (control) to a maximum of 11.08 kg plot<sup>−1</sup> (bacteria and Genotype 3). Interestingly, the highest vitamin C was resulted by the combination of the bacteria and Genotype 2 (15.53 mg 100g<sup>−1</sup>) and the least by the control treatment (12.18 mg 100g<sup>−1</sup>). The bacteria and Genotype 3 resulted in the highest N (3.76 and 4.46%) and P (0.38 and 0.52%) concentrations, and for K (2.67 and 3.83%) it was resulted by Genotype 1 and the bacteria. Fruit pH was negatively and significantly correlated with all the measured parameters.</div></div><div><h3>Conclusions</h3><div>Although genotype was a determining factor significantly affecting tomato growth, yield and biochemical properties including nutrient uptake (N, P and K), its combination with <em>P. agglomerans</em>, intensified such enhancing effects. The tested bacterial strain, as a suitable biofertilization method, with respect to the compatibility of tomato genotype, is able to enhance tomato growth, yield and quality by affecting plant biochemical properties. The future research may look for the single and combined effects of <em>P. agglomerans</em> with the other PGPR strains on tomato quality and yield in different conditions including stress, which is of economic and health significance.</div></div>","PeriodicalId":73997,"journal":{"name":"Journal of trace elements and minerals","volume":"12 ","pages":"Article 100225"},"PeriodicalIF":0.0,"publicationDate":"2025-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143591756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Health risks of geogenic contaminants in gold mining areas in Geita, Tanzania
Journal of trace elements and minerals Pub Date : 2025-03-03 DOI: 10.1016/j.jtemin.2025.100222
Noel Isack Kaaya , Maheswara Rao Vegi , Athanas Simon Macheyeki
{"title":"Health risks of geogenic contaminants in gold mining areas in Geita, Tanzania","authors":"Noel Isack Kaaya ,&nbsp;Maheswara Rao Vegi ,&nbsp;Athanas Simon Macheyeki","doi":"10.1016/j.jtemin.2025.100222","DOIUrl":"10.1016/j.jtemin.2025.100222","url":null,"abstract":"<div><h3>Background</h3><div>Mining in Tanzania's Lake Zone, especially Geita, may release toxic elements linked to health risks like cancer, but the most hazardous PTEs and vulnerable groups are uncertain.</div></div><div><h3>Objectives</h3><div>This study aims to assess the health risks posed by metal(loid)s in &lt;75 µm particles of gold mine tailings for workers, children, and adults at four artisanal and small-scale gold mining (ASGM) sites in Geita: Bululu, Ifugandi, Nyarugusu, and Lwamgasa.</div></div><div><h3>Methods</h3><div>Concentrations of metal(loid)s in tailings were measured using ICP-OES. Carcinogenic and non-carcinogenic risks were assessed for children, gold mine workers, and adult residents using the USEPA risk assessment approach. Multivariate analysis using Minitab 18 software was used for the identification of metal(loid)s source.</div></div><div><h3>Results</h3><div>Tailings from ASGM sites contain 49 % to 54 % of particles &lt;75 µm, which can be ingested or transported by wind, presenting significant health risks. The most carcinogenic PTEs are As (86 %), Ni (9 %), and Cr (5 %), while Cd and Pb pose negligible risks. As causes the highest risk in Bululu and Ifugandi, while Cr and Ni are most concerning in Nyarugusu and Lwamgasa. The Health Hazard Index (HI) exceeds the safe limit (1.00) in Bululu for As, while in Nyarugusu, Cr and Mn also surpass the limit.</div></div><div><h3>Conclusions</h3><div>Geogenic contaminants from mining may cause cancer. Therefore, there is a need to mitigate pollution by using methods such as tailing stabilization, phytoremediation, better tailings management, awareness programs, health screenings, and safety regulation enforcement.</div></div>","PeriodicalId":73997,"journal":{"name":"Journal of trace elements and minerals","volume":"12 ","pages":"Article 100222"},"PeriodicalIF":0.0,"publicationDate":"2025-03-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143580551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Amaranthus: A nutritious solution to malnutrition for underprivileged populations in Pakistan
Journal of trace elements and minerals Pub Date : 2025-03-02 DOI: 10.1016/j.jtemin.2025.100221
Tanveer Ahmad , Mirza Abrar , Syeda Anum Masood Bokhari , Shahid Iqbal , Abid Mahmood Alvi , Qumer Iqbal , Muhammad Awais Ghani , Muhammad Umar , Raja Tahir Iqbal
{"title":"Amaranthus: A nutritious solution to malnutrition for underprivileged populations in Pakistan","authors":"Tanveer Ahmad ,&nbsp;Mirza Abrar ,&nbsp;Syeda Anum Masood Bokhari ,&nbsp;Shahid Iqbal ,&nbsp;Abid Mahmood Alvi ,&nbsp;Qumer Iqbal ,&nbsp;Muhammad Awais Ghani ,&nbsp;Muhammad Umar ,&nbsp;Raja Tahir Iqbal","doi":"10.1016/j.jtemin.2025.100221","DOIUrl":"10.1016/j.jtemin.2025.100221","url":null,"abstract":"<div><div>Malnutrition in Pakistan is cause of concern which is affecting everyone regardless of age and gender. The situation for women and children is even more alarming and prevalence of malnutrition in Pakistan exceeds against other developing countries. The poor and underprivileged populations in Sindh, Balochistan, KPK and South Punjab are severely affected by undernutrition of macro and micronutrients. Despite continuous efforts, malnutrition in certain areas of Pakistan is on surge due to many factors. Poverty, lack of sufficient nutritious food coupled with lack of food diversity are main factors of undernutrition in Pakistan. Amaranth is a climate resilient; drought tolerant plant and it can be produced with minimal number of resources even in poor soils. The adaptability and nutritional value of 25 exotic vegetable amaranth genotypes were investigated using standard analytical approaches in order to evaluate the several possibilities of the plant leaves in underprivileged population of Pakistan. The study discovered that exotic amaranth genotypes produce abundant green matter with optimum moisture contents and number of leaves per plant with good height. The investigation for nutrients disclosed the maximum ash content, crude protein, crude fat, crude fiber and carbohydrate from the leaves as (4.32 g 100<em>g</em><sup>−1</sup> FW), (6.76 g 100<em>g</em><sup>−1</sup> FW), (0.66 g 100<em>g</em><sup>−1</sup> FW), (4.29 g 100<em>g</em><sup>−1</sup> FW) and (18.19 g 100<em>g</em><sup>−1</sup> FW) respectively in different genotypes. The maximum energy yielded in calories was 407.41 (kJ 100<em>g</em><sup>−1</sup> FW). Elemental breakdown was performed in (mg g<sup>−1</sup> DW) and it indicated that the leaves contained maximum potassium (15.52 mg g<sup>−1</sup> DW), calcium (11.11 mg g<sup>−1</sup> DW), Magnesium (9.67 mg g<sup>−1</sup> DW), Iron (0.24 mg g<sup>−1</sup> DW), Zinc (0.18 mg g<sup>−1</sup> DW) and phosphorus (5.85 mg g<sup>−1</sup> DW) in different genotypes under investigation. Comparing the nutrients in exotic vegetable amaranth genotypes with recommended dietary allowance (RDA) values, the outcomes expose that the leaves of amaranth contain substantial amount of important nutrients that are crucial in combating malnutrition in underprivileged populations in Pakistan.</div></div>","PeriodicalId":73997,"journal":{"name":"Journal of trace elements and minerals","volume":"12 ","pages":"Article 100221"},"PeriodicalIF":0.0,"publicationDate":"2025-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143580640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Are industrial footprints driving potentially toxic element contamination in the Karnaphuli River Estuary?
Journal of trace elements and minerals Pub Date : 2025-02-25 DOI: 10.1016/j.jtemin.2025.100220
Istiak Ahmed , Md. Mostafa Monwar , Md Iqram Uddin Al Amran , Md Mehedi Iqbal , Israt Sultana Isha , Md Masum Billah , Mohammad Rafiqul Islam , Abdullah Al Mamun , Md Khurshid Alam Bhuiyan
{"title":"Are industrial footprints driving potentially toxic element contamination in the Karnaphuli River Estuary?","authors":"Istiak Ahmed ,&nbsp;Md. Mostafa Monwar ,&nbsp;Md Iqram Uddin Al Amran ,&nbsp;Md Mehedi Iqbal ,&nbsp;Israt Sultana Isha ,&nbsp;Md Masum Billah ,&nbsp;Mohammad Rafiqul Islam ,&nbsp;Abdullah Al Mamun ,&nbsp;Md Khurshid Alam Bhuiyan","doi":"10.1016/j.jtemin.2025.100220","DOIUrl":"10.1016/j.jtemin.2025.100220","url":null,"abstract":"<div><h3>Background</h3><div>The contamination of estuarine sediments with potentially toxic elements (PTEs) is a growing concern in industrialized regions. The Karnaphuli River estuary, a critical ecosystem in Bangladesh, is exposed to untreated industrial, agricultural, and urban effluents, posing ecological and health risks.</div></div><div><h3>Objective</h3><div>This study aimed to assess the levels and spatial distribution of chromium (Cr), cadmium (Cd), lead (Pb), copper (Cu), zinc (Zn), and nickel (Ni) in sediments of the estuary, along with potential contamination sources and the associated ecological risks.</div></div><div><h3>Methods</h3><div>Sediment samples were collected from six key discharge points and analyzed using atomic absorption spectrophotometry. The data were examined to identify contamination patterns using geostatistical techniques, element correlations, and possible pollution sources. Results were compared with international sediment quality guidelines and findings from global estuarine systems to assess ecological risks.</div></div><div><h3>Results</h3><div>The concentrations of Cr (77.13–165.29 mg kg<sup>-1</sup>), Zn (67.86–83.29 mg kg<sup>-1</sup>), and Cu (53.28–73.66 mg kg<sup>-1</sup>) were highest near industrial zones. Strong correlations were observed among Cr, Zn, and Pb, indicating overlapping anthropogenic sources such as industrial discharges and urban runoff. When compared to global estuarine systems, the contamination levels of PTEs in the Karnaphuli estuary were found to be moderate to high, reflecting similar patterns observed in other industrialized regions. Several PTEs exceeded permissible limits, raising significant ecological concerns.</div></div><div><h3>Conclusions</h3><div>The findings underscore the need for stricter wastewater management, advanced remediation technologies, and robust monitoring frameworks to mitigate contamination risks. The study provides a baseline for policymaking to protect estuarine ecosystems in rapidly industrializing regions.</div></div>","PeriodicalId":73997,"journal":{"name":"Journal of trace elements and minerals","volume":"12 ","pages":"Article 100220"},"PeriodicalIF":0.0,"publicationDate":"2025-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143547802","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Determination of potentially toxic heavy metals in milk powder marketed in Kurdistan of Iraq
Journal of trace elements and minerals Pub Date : 2025-02-12 DOI: 10.1016/j.jtemin.2025.100219
Hiwa Mohammad Qadr, Midya Hussen Ibrahim, Hanifa Younis Hassan
{"title":"Determination of potentially toxic heavy metals in milk powder marketed in Kurdistan of Iraq","authors":"Hiwa Mohammad Qadr,&nbsp;Midya Hussen Ibrahim,&nbsp;Hanifa Younis Hassan","doi":"10.1016/j.jtemin.2025.100219","DOIUrl":"10.1016/j.jtemin.2025.100219","url":null,"abstract":"<div><h3>Background</h3><div>Milk products have become a popular human nutrient in recent years because of their vitamins and minerals that are essential for the development and function of various organs and tissues. Additionally, excessive consumption of these vitamins and minerals may adversely affect our health.</div></div><div><h3>Objective</h3><div>This study aimed to determine the concentration of five potentially toxic heavy metals, namely cadmium (Cd), lead (Pb), nickel (Ni), copper (Cu), and zinc (Zn) in 14 samples of powdered milk collected from the Iraqi Kurdistan Region markets. Furthermore, the experimental data were then used to determine the potential health risk for an adult age through the metal pollution index (MPI), estimated daily intake of metals (EDIM), human health risk index (HHRI) and hazard index (HI)</div></div><div><h3>Methodology</h3><div>In this study, the concentrations were determined using energy dispersive X-ray fluorescence (EDXRF).</div></div><div><h3>Results</h3><div>The findings demonstrate that the mean concentrations of Cd, Pb, Ni, Cu, and Zn in powdered milk samples were 0.079, 0.042, 0.077, 0.056 and 0.847 mg kg<sup>−1</sup>, respectively. Human health was found to be very lowly affected by these metals based on the results of the estimated daily intake of metals (EDIM). Hazard index (HI) values in 36 % were less than 1 and 64 % were higher than 1.</div></div><div><h3>Conclusion</h3><div>The consumption of powdered milk by adults may pose potential health risks, and other protein sources should be monitored for metals.</div></div>","PeriodicalId":73997,"journal":{"name":"Journal of trace elements and minerals","volume":"12 ","pages":"Article 100219"},"PeriodicalIF":0.0,"publicationDate":"2025-02-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143422028","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Source apportionment, ecological and toxicological risk assessment of trace metals in agricultural soils of Wabane, South West Region, Cameroon
Journal of trace elements and minerals Pub Date : 2025-02-09 DOI: 10.1016/j.jtemin.2025.100218
Guedjeo Christian Suh , Ngambu Aloysius Afahnwie , Anicet Feudjio Tiabou , Kouankap Nono Gus Djibril , Adze Rene Meniemoh , Lemnyuy Prosper Yiika
{"title":"Source apportionment, ecological and toxicological risk assessment of trace metals in agricultural soils of Wabane, South West Region, Cameroon","authors":"Guedjeo Christian Suh ,&nbsp;Ngambu Aloysius Afahnwie ,&nbsp;Anicet Feudjio Tiabou ,&nbsp;Kouankap Nono Gus Djibril ,&nbsp;Adze Rene Meniemoh ,&nbsp;Lemnyuy Prosper Yiika","doi":"10.1016/j.jtemin.2025.100218","DOIUrl":"10.1016/j.jtemin.2025.100218","url":null,"abstract":"<div><h3>Background</h3><div>This study seeks to evaluate the origins, ecological implications, and ecotoxicological risks of trace metals using single and cumulative pollution indicators as well as mitigation strategies in the agricultural soils of Wabane, Cameroon.</div></div><div><h3>Methods</h3><div>The soil samples were analyzed by ICP-OES (Inductively Coupled Plasma-Optical Emission Spectrometry).</div></div><div><h3>Results and Discussion</h3><div>The agricultural soil samples exhibit high levels of Al<sub>2</sub>O<sub>3</sub> and Fe<sub>2</sub>O<sub>3</sub>, which have high adsorption capacity for trace metals and are important carriers of trace metal migration and enrichment. The results highlight significant concentrations of Co, Cu, Cr, Ni, Hg, Mn, La, Sn and Zn above the geochemical threshold values, sourced from mixed provenance. Contamination assessment indicators: contamination factor (CF: 1–6), pollution load index (PLI: 0.02–1.23), and enrichment factor (EF: 0.21–604.80) suggest soil contamination and metallic pollution. The potential ecological risk indicators show minimal ecological effect of trace metals on the soil ecosystem. Toxic risk index (TRI: 0.36–7.60) and toxicity unit analysis (TUs: 0.004 to 0.96) indicates low toxicity, suggesting low toxicological effects of trace metals on the soil ecosystem. According to Pearson correlation matrix and principal component analysis, while Co, Cr, Cu, Ni, Zn and V were obtained from geogenic provenance, As, Cd, Pb, Hg and Mn originate from geogenic as well as anthropogenic input sources.</div></div><div><h3>Conclusion</h3><div>Lithogenic processes and anthropogenic practices contribute to contamination and metallic pollution of the soil ecosystem.</div></div><div><h3>Recommendations</h3><div>Concrete monitoring and mitigation measures (low metal cultivars, biochar, etc.) must be taken to reduce trace metal accumulation from point and non-point sources entering agricultural soils. This research acts as a baseline study to potential soil contamination and metal toxicity in soils within the vicinity of Mount Bamboutos.</div></div>","PeriodicalId":73997,"journal":{"name":"Journal of trace elements and minerals","volume":"12 ","pages":"Article 100218"},"PeriodicalIF":0.0,"publicationDate":"2025-02-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143422075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Trace element and mercury speciation analysis in yerba mate (Ilex paraguariensis)
Journal of trace elements and minerals Pub Date : 2025-02-03 DOI: 10.1016/j.jtemin.2025.100217
María Victoria Panzl , Jarol R. Miranda-Andrades , Wendy J. Sandoval Rojano , Joseane A. Mendes , Tatiana D. Saint'Pierre , Alejandra Rodríguez-Haralambides , Ricardo Q. Aucelio
{"title":"Trace element and mercury speciation analysis in yerba mate (Ilex paraguariensis)","authors":"María Victoria Panzl ,&nbsp;Jarol R. Miranda-Andrades ,&nbsp;Wendy J. Sandoval Rojano ,&nbsp;Joseane A. Mendes ,&nbsp;Tatiana D. Saint'Pierre ,&nbsp;Alejandra Rodríguez-Haralambides ,&nbsp;Ricardo Q. Aucelio","doi":"10.1016/j.jtemin.2025.100217","DOIUrl":"10.1016/j.jtemin.2025.100217","url":null,"abstract":"<div><h3>Background</h3><div>Yerba mate, a popular beverage in South America, is rich in bioactive compounds and minerals. However, yerba mate leaves may contain toxic metals and environmental contaminants. This study performed multi-element analyses using ICP-MS and ICP OES and mercury speciation by GC-CV-AFS and CV–AAS to profile infusions of ten yerba mate samples consumed in Brazil and Uruguay.</div></div><div><h3>Materials and methods</h3><div>For ICP OES and ICP-MS analyses, 500 mg infusions of samples were prepared and diluted with 10 % v/v HNO<sub>3</sub>. Ultrasonic-assisted extractions of mercurial species were made followed by distillation and dilution with water for CV-AAS. For GC-CV-AFS speciation, samples were extracted and distilled, using 200 μL aliquots for analysis.</div></div><div><h3>Results</h3><div>The most abundant elements in the digested solid samples were K, Ca, and Mg, whereas in infusions the ranges were up to 9.18 mg g<sup>−1</sup> for K, 0.68 mg g<sup>−1</sup> for Ca, and 2.74 mg g<sup>−1</sup> for Mg. Pb presented a mean concentration of 260 µg kg<sup>−1</sup> in leaves but it was not found in infusions. Hg<sup>2+</sup> was found from 0.67 to 0.96 μg kg<sup>−1</sup> in leaves with one sample presenting 0.67 μg kg<sup>−1</sup> of CH<sub>3</sub>Hg.</div></div><div><h3>Conclusion</h3><div>K, Ca, and Mg were the most abundant elements in the yerba mate samples. Four samples showed ultra-trace concentrations of Hg<sup>2+</sup> and one of CH<sub>3</sub>Hg.</div></div>","PeriodicalId":73997,"journal":{"name":"Journal of trace elements and minerals","volume":"12 ","pages":"Article 100217"},"PeriodicalIF":0.0,"publicationDate":"2025-02-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143369855","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Inorganic constituents in cassava derivatives: Total concentration, dietary intake and bioaccessibility
Journal of trace elements and minerals Pub Date : 2025-01-28 DOI: 10.1016/j.jtemin.2025.100216
Leilane R. Santos , Filipe B. Santana , Hilária F.A. Silveira , Wellington C. de Carvalho , Laís A. Souza , Rennan Geovanny O. Araujo , Maria Graças A. Korn , Daniele Cristina M.B. Santos
{"title":"Inorganic constituents in cassava derivatives: Total concentration, dietary intake and bioaccessibility","authors":"Leilane R. Santos ,&nbsp;Filipe B. Santana ,&nbsp;Hilária F.A. Silveira ,&nbsp;Wellington C. de Carvalho ,&nbsp;Laís A. Souza ,&nbsp;Rennan Geovanny O. Araujo ,&nbsp;Maria Graças A. Korn ,&nbsp;Daniele Cristina M.B. Santos","doi":"10.1016/j.jtemin.2025.100216","DOIUrl":"10.1016/j.jtemin.2025.100216","url":null,"abstract":"<div><h3>Introduction</h3><div>The objective of this study was to evaluate the concentration and in vitro bioaccessibility of inorganic constituents in cassava (Manihot esculenta Crantz) derivatives marketed in Brazil, aiming to uncover new data on the distribution and bioaccessibility of Mn and Mg. By identifying patterns in bioaccessibility, the study aims to provide crucial insights into the dietary impact of these chemical elements, with a focus on nutritional benefits and health risks.</div></div><div><h3>Methods</h3><div>The concentrations of As, Ba, Cd, Ca, Co, Cu, Fe, K, Mg, Mn, Na, Pb, Se, Sr, V, and Zn were determined in cassava samples using inductively coupled plasma optical emission spectrometry and inductively coupled plasma mass spectrometry after sample decomposition employed closed digester block and diluited nitric acid.</div></div><div><h3>Results and Discussion</h3><div>The concentration ranges (in μg g<sup>-1</sup>) were: Ba (&lt;0.32 - 0.60), Ca (&lt;11- 542), Fe (&lt;0.39 - 111), K (156 - 7362), Mg (9.8 - 533), Na (&lt;3.1 - 98), P (58 - 1774) and Sr (&lt;0.005 - 3.85). The concentration ranges (in ng g<sup>-1</sup>) obtained were: As (&lt;12 - 158), Cd (&lt;9 - 47), Co (&lt;17 - 295), Cu (&lt;90 - 1159), Mn (70 - 2523), Pb (&lt;14 - 521), Se (&lt;16 - 215), V (&lt;6 - 106) and Zn (&lt;3208 - 7277). The consumption of 100 g of starch contributes to the intake of Ca (1.0 - 2.8 %), Cu (3.8 - 2.9 %), Fe (1.2 - 12.4 %), Mg (0.2 – 11.0 %), Mn (0.6 - 8.0 %), P (1.6 - 18.0 %), Se (26.3 – 26.8 %) and Zn (4.0 – 6.0 %). No health risk was distributed for As and Cd. For Pb, the concentrations were three times higher than the legislated values in Brazil. The estimated bioaccessibility of Mg (up to 80 %) and Mn (up to 43 %) suggests that these chemical elements can be available for absorption and may contribute positively to dietary intake when consuming cassava derivatives.</div></div><div><h3>Conclusion</h3><div>This study makes a significant contribution by proposing a simple and low-cost procedure for evaluating the mineral composition of cassava samples, as well as bioaccessibility estimation of Mn and Mg, providing new nutritional information of interest to public health.</div></div>","PeriodicalId":73997,"journal":{"name":"Journal of trace elements and minerals","volume":"12 ","pages":"Article 100216"},"PeriodicalIF":0.0,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143136069","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Wound healing potential of green synthesized silver nanoparticles of Glycyrrhiza glabra linn root extract: A preclinical study
Journal of trace elements and minerals Pub Date : 2025-01-14 DOI: 10.1016/j.jtemin.2025.100214
Laxman S. Vijapur , Mallappa Shalavadi , Anita R. Desai , Jayadev N. Hiremath , Avinash S. Gudigennavar , Somlingesh L. Shidramshettar , Shreyanka R. Hiremath , Malleswara Rao Peram , Bharatesh S. Kittur
{"title":"Wound healing potential of green synthesized silver nanoparticles of Glycyrrhiza glabra linn root extract: A preclinical study","authors":"Laxman S. Vijapur ,&nbsp;Mallappa Shalavadi ,&nbsp;Anita R. Desai ,&nbsp;Jayadev N. Hiremath ,&nbsp;Avinash S. Gudigennavar ,&nbsp;Somlingesh L. Shidramshettar ,&nbsp;Shreyanka R. Hiremath ,&nbsp;Malleswara Rao Peram ,&nbsp;Bharatesh S. Kittur","doi":"10.1016/j.jtemin.2025.100214","DOIUrl":"10.1016/j.jtemin.2025.100214","url":null,"abstract":"<div><h3>Background</h3><div>The research emphasizes the eco-friendly and sustainable approach of nanoparticle synthesis, leveraging the medicinal properties inherent in <em>Glycyrrhiza glabra</em> extract, which is known for its antimicrobial, anti-inflammatory, and antioxidant properties. By combining the therapeutic potential of the plant extract with the wound-healing capabilities of silver nanoparticles, the study seeks to develop an innovative, biocompatible, and effective treatment for enhanced wound healing process in excision and incision rat model.</div></div><div><h3>Methods</h3><div><em>Glycyrrhiza glabra</em> Linn root was extracted with alcohol and utilized in the green synthesis of silver nanoparticles. The green synthesized nanoparticles were characterized, formulated into gel, and evaluated for their potential to heal wound in rat wound model.</div></div><div><h3>Results</h3><div>The results of the study showed that the detection of ultra-violet visible spectroscopy peaks at 412 nm and 403 nm. The presence of tannins, saponins, flavonoids, and phenols in plant extract caused the capping and bio-reduction of silver, as demonstrated by FTIR. Silver nanoparticles that were biosynthesized were in between 69.7 and 419.1 nm in size. The study's formulation of synthesized silver nanoparticles demonstrated significant wound healing potential by promoting wound contraction and accelerating healing after 21 days of study, which was demonstrated by histopathological evaluation and complete epithelialization with regenerated hair follicles and higher collagen tissue.</div></div><div><h3>Conclusion</h3><div>The current study found that the biomolecules of <em>Glycyrrhiza glabra</em> Linn root alcoholic extract, which are responsible for augmenting the plant extract's capacity to heal wounds, were capped on silver nanoparticles.</div></div>","PeriodicalId":73997,"journal":{"name":"Journal of trace elements and minerals","volume":"11 ","pages":"Article 100214"},"PeriodicalIF":0.0,"publicationDate":"2025-01-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143153963","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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