Advances in Physical Chemistry最新文献_第6页

Calculation of Thermal Pressure Coefficient of R11, R13, R14, R22, R23, R32, R41, and R113 Refrigerants by Data R11、R13、R14、R22、R23、R32、R41、R113制冷剂热压系数的数据计算

Advances in Physical Chemistry Pub Date : 2013-05-28 DOI: 10.1155/2013/327419

V. Moeini, Mahin Farzad

引用次数: 2

Self-Organization Schemes towards Thermodynamic Stable Bulk Heterojunction Morphologies: A Perspective on Future Fabrication Strategies of Polymer Photovoltaic Architectures 面向热力学稳定体异质结形态的自组织方案:聚合物光伏结构未来制造策略的展望

Advances in Physical Chemistry Pub Date : 2013-04-16 DOI: 10.1155/2013/948189

A. Benmouna, R. Benmouna, M. Bockstaller, I. F. Hakem

{"title":"Self-Organization Schemes towards Thermodynamic Stable Bulk Heterojunction Morphologies: A Perspective on Future Fabrication Strategies of Polymer Photovoltaic Architectures","authors":"A. Benmouna, R. Benmouna, M. Bockstaller, I. F. Hakem","doi":"10.1155/2013/948189","DOIUrl":"https://doi.org/10.1155/2013/948189","url":null,"abstract":"Research efforts to improve our understanding of electronic polymers are developing fast because of their promising advantages over silicon in photovoltaic solar cells. A major challenge in the development of polymer photovoltaic devices is the viable fabrication strategies of stable bulk heterojunction architecture that will retain functionality during the expected lifetime of the device. Block copolymer self-assembly strategies have attracted particular attention as a scalable means toward thermodynamically stable microstructures that combine the ideal geometrical characteristics of a bulk heterojunction with the fortuitous combination of properties of the constituent blocks. Two primary routes that have been proposed in the literature involve the coassembly of block copolymers in which one domain is a hole conductor with the electron-conducting filler (such as fullerene derivatives) or the self-assembly of block copolymers in which the respective blocks function as hole and electron conductor. Either way has proven difficult because of the combination of synthetic challenges as well as the missing understanding of the complex governing parameters that control structure formation in semiconducting block copolymer blends. This paper summarizes important findings relating to structure formation of block copolymer and block copolymer/nanoparticle blend assembly that should provide a foundation for the future design of block copolymer-based photovoltaic systems.","PeriodicalId":7371,"journal":{"name":"Advances in Physical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2013-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83330981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Theoretical Study on the Static (Hyper)Polarizabilities of α-t-Bu-ω-CN-Poly(methylphenyl)silane α-t-Bu-ω- cn -聚甲基苯基硅烷静态(超)极化的理论研究

Advances in Physical Chemistry Pub Date : 2013-03-31 DOI: 10.1155/2013/905910

Jing Li, Liang Peng, F. Gu

引用次数: 0

Quantum-Dynamical Theory of Electron Exchange Correlation 电子交换相关的量子动力学理论

Advances in Physical Chemistry Pub Date : 2013-03-20 DOI: 10.1155/2013/497267

B. Ritchie, C. Weatherford

{"title":"Quantum-Dynamical Theory of Electron Exchange Correlation","authors":"B. Ritchie, C. Weatherford","doi":"10.1155/2013/497267","DOIUrl":"https://doi.org/10.1155/2013/497267","url":null,"abstract":"The relationship between the spin of an individual electron and Fermi-Dirac statistics (FDS), which is obeyed by electrons in the aggregate, is elucidated. The relationship depends on the use of spin-dependent quantum trajectories (SDQT) to evaluate Coulomb’s law between any two electrons as an instantaneous interaction in space and time rather than as a quantum-mean interaction in the form of screening and exchange potentials. Hence FDS depends in an ab initio sense on the inference of SDQT from Dirac’s equation, which provides for relativistic Lorentz invariance and a permanent magnetic moment (or spin) in the electron’s equation of motion. Schroedinger’s time-dependent equation can be used to evaluate the SDQT in the nonrelativistic regime of electron velocity. Remarkably FDS is a relativistic property of an ensemble of electron, even though it is of order in the nonrelativistic limit, in agreement with experimental observation. Finally it is shown that covalent versus separated-atoms limits can be characterized by the SDQT. As an example of the use of SDQT in a canonical structure problem, the energies of the 1Σg and 3Σu states of H2 are calculated and compared with the accurate variational energies of Kolos and Wolniewitz.","PeriodicalId":7371,"journal":{"name":"Advances in Physical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2013-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88750010","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

Sorption of from Aqueous Solution unto Modified Rice Husk: Isotherms Studies 改性稻壳对水溶液的吸附:等温线研究

Advances in Physical Chemistry Pub Date : 2013-03-18 DOI: 10.1155/2013/842425

A. Dada, J. Ojediran, A. P. Olalekan

引用次数: 64

Polyethylene Glycols as Efficient Media for Decarboxylative Nitration of α,β-Unsaturated Aromatic Carboxylic Acids by Ceric Ammonium Nitrate in Acetonitrile Medium: A Kinetic and Mechanistic Study 聚乙二醇在乙腈介质中作为硝酸铈铵脱羧硝化α，β-不饱和芳香族羧酸的高效介质:动力学和机理研究

Advances in Physical Chemistry Pub Date : 2013-03-04 DOI: 10.1155/2013/146585

K. Ramesh, S. Shylaja, K. Rajanna, P. G. Reddy, P. Saiprakash

引用次数: 6

Synergistic Effect of [Ru(III) + Ir(III)] in N-Bromosuccinimide Reaction with Certain Aliphatic Ketones: A Kinetic Study [Ru(III) + Ir(III)]在n -溴代琥珀酰亚胺与某些脂肪族酮反应中的协同作用动力学研究

Advances in Physical Chemistry Pub Date : 2012-12-25 DOI: 10.1155/2012/292908

P. G. Reddy, K. Ramesh, S. Shylaja, K. Rajanna, S. Kandlikar