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Adhesion on Nanoorganized Multilayers 纳米组织多层膜的粘附性
Advances in Physical Chemistry Pub Date : 2011-11-13 DOI: 10.1155/2011/850243
Yolla Kazzi, Houssein Awada
{"title":"Adhesion on Nanoorganized Multilayers","authors":"Yolla Kazzi, Houssein Awada","doi":"10.1155/2011/850243","DOIUrl":"https://doi.org/10.1155/2011/850243","url":null,"abstract":"Nanostructured multilayers composed of alternate organic (alkyldithiol) and metallic (gold) layers are grafted onto glass plates and prepared in order to modify the mechanical and local dissipative properties of a thin surface layer of the substrate. The adhesion phenomenon between a polyisoprene elastomer and these layers is presented and verified by two theories, namely, Johnson, Kendall, Roberts (JKR) and linear elastic fracture mechanics. The increase in adhesion with contact time following a power law has been clearly noted.","PeriodicalId":7371,"journal":{"name":"Advances in Physical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2011-11-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88470768","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent Developments of Nanostructured Electrodes for Bioelectrocatalysis of Dioxygen Reduction 二氧还原生物电催化纳米电极研究进展
Advances in Physical Chemistry Pub Date : 2011-10-03 DOI: 10.1155/2011/947637
M. Opallo, R. Bilewicz
{"title":"Recent Developments of Nanostructured Electrodes for Bioelectrocatalysis of Dioxygen Reduction","authors":"M. Opallo, R. Bilewicz","doi":"10.1155/2011/947637","DOIUrl":"https://doi.org/10.1155/2011/947637","url":null,"abstract":"The recent development of nanostructured electrodes for bioelectrocatalytic dioxygen reduction catalysed by two copper oxidoreductases, laccase and bilirubin oxidase, is reviewed. Carbon-based nanomaterials as carbon nanotubes or carbon nanoparticles are frequently used for electrode modification, whereas there are only few examples of biocathodes modified with metal or metal oxide nanoparticles. These nanomaterials are adsorbed on the electrode surface or embedded in multicomponent film. The nano-objects deposited act as electron shuttles between the enzyme and the electrode substrate providing favourable conditions for mediatorless bioelectrocatalysis.","PeriodicalId":7371,"journal":{"name":"Advances in Physical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2011-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86345499","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 27
FeCrO Nanoparticles as Anode Catalyst for Ethane Proton Conducting Fuel Cell Reactors to Coproduce Ethylene and Electricity FeCrO纳米颗粒作为乙烷质子传导燃料电池反应器的阳极催化剂共产乙烯和电
Advances in Physical Chemistry Pub Date : 2011-09-21 DOI: 10.1155/2011/407480
Jian-Hui Li, Xianzhu Fu, Guihua Zhou, Jingli Luo, K. Chuang, A. R. Sanger
{"title":"FeCrO Nanoparticles as Anode Catalyst for Ethane Proton Conducting Fuel Cell Reactors to Coproduce Ethylene and Electricity","authors":"Jian-Hui Li, Xianzhu Fu, Guihua Zhou, Jingli Luo, K. Chuang, A. R. Sanger","doi":"10.1155/2011/407480","DOIUrl":"https://doi.org/10.1155/2011/407480","url":null,"abstract":"Ethylene and electrical power are cogenerated in fuel cell reactors with FeCr2O4 nanoparticles as anode catalyst, La0.7Sr0.3FeO3-𝛿 (LSF) as cathode material, and BaCe0.7Zr0.1Y0.2O3-𝛿 (BCZY) perovskite oxide as proton-conducting ceramic electrolyte. FeCr2O4, BCZY and LSF are synthesized by a sol-gel combustion method. The power density increases from 70 to 240 mW cm−2, and the ethylene yield increases from about 14.1% to 39.7% when the operating temperature of the proton-conducting fuel cell reactor increases from 650∘C to 750∘C. The FeCr2O4 anode catalyst exhibits better catalytic performance than nanosized Cr2O3 anode catalyst.","PeriodicalId":7371,"journal":{"name":"Advances in Physical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2011-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78067341","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 9
Transport of Carbon Dioxide through a Biomimetic Membrane 二氧化碳通过仿生膜的运输
Advances in Physical Chemistry Pub Date : 2011-09-05 DOI: 10.1155/2011/210802
Efstathios Matsaridis, V. Savov, Alexandre Gritzkov, N. Zheleva, S. Gutzov
{"title":"Transport of Carbon Dioxide through a Biomimetic Membrane","authors":"Efstathios Matsaridis, V. Savov, Alexandre Gritzkov, N. Zheleva, S. Gutzov","doi":"10.1155/2011/210802","DOIUrl":"https://doi.org/10.1155/2011/210802","url":null,"abstract":"Biomimetic membranes (BMM) based on polymer filters impregnated with lipids or their analogues are widely applied in numerous areas of physics, biology, and medicine. In this paper we report the design and testing of an electrochemical system, which allows the investigation of CO2 transport through natural membranes such as alveoli barrier membrane system and also can be applied for solid-state measurements. The experimental setup comprises a specially designed two-compartment cell with BMM connected with an electrochemical workstation placed in a Faraday cage, two PH meters, and a nondispersive infrared gas analyzer. We prove, experimentally, that the CO2 transport through the natural membranes under different conditions depends on pH and displays a similar behavior as natural membranes. The influence of different drugs on the CO2 transport process through such membranes is discussed.","PeriodicalId":7371,"journal":{"name":"Advances in Physical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2011-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78444064","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nanoporous PdCo catalyst for microfuel cells: Electrodeposition and dealloying 微燃料电池用纳米多孔PdCo催化剂:电沉积和合金化
Advances in Physical Chemistry Pub Date : 2011-08-18 DOI: 10.1155/2011/821916
Satoshi Tominaka, T. Osaka
{"title":"Nanoporous PdCo catalyst for microfuel cells: Electrodeposition and dealloying","authors":"Satoshi Tominaka, T. Osaka","doi":"10.1155/2011/821916","DOIUrl":"https://doi.org/10.1155/2011/821916","url":null,"abstract":"PdCo alloy is a promising catalyst for oxygen reduction reaction of direct methanol fuel cells because of its high activity and the tolerance to methanol. We have applied this catalyst in order to realize on-chip fuel cell which is a membraneless design. The novel design made the fuel cells to be flexible and integratable with other microdevices. Here, we summarize our recent research on the synthesis of nanostructured PdCo catalyst by electrochemical methods, which enable us to deposit the alloy onto microelectrodes of the on-chip fuel cells. First, the electrodeposition of PdCo is discussed in detail, and then, dealloying for introducing nanopores into the electrodeposits is described. Finally, electrochemical response and activities are fully discussed.","PeriodicalId":7371,"journal":{"name":"Advances in Physical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2011-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73283729","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 16
Suppression of Intramolecular Vibrational Energy Redistribution by Intense CW-Laser Fields 强激光场对分子内振动能量再分配的抑制
Advances in Physical Chemistry Pub Date : 2011-07-24 DOI: 10.1155/2011/584082
M. Sugawara
{"title":"Suppression of Intramolecular Vibrational Energy Redistribution by Intense CW-Laser Fields","authors":"M. Sugawara","doi":"10.1155/2011/584082","DOIUrl":"https://doi.org/10.1155/2011/584082","url":null,"abstract":"We present a quantum control scheme which realizes suppression of the intramolecular vibrational energy redistribution (IVR). In this scheme, we utilize effective decomposition brought by intense CW-laser fields, which enables to exclude\u0000the doorway state coupled to background manifolds. In doing so, we introduce a helper state and make it optically coupled with the doorway state through the intense CW-laser field. We have applied the present scheme to both the Bixon-Jortner model and the\u0000SCCl2 model system.","PeriodicalId":7371,"journal":{"name":"Advances in Physical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2011-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88215624","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Hydrogen Adsorption on Palladium and Platinum Overlayers: DFT Study 钯和铂覆盖层对氢的吸附:DFT研究
Advances in Physical Chemistry Pub Date : 2011-07-10 DOI: 10.1155/2011/305634
I. Pašti, N. Gavrilov, S. Mentus
{"title":"Hydrogen Adsorption on Palladium and Platinum Overlayers: DFT Study","authors":"I. Pašti, N. Gavrilov, S. Mentus","doi":"10.1155/2011/305634","DOIUrl":"https://doi.org/10.1155/2011/305634","url":null,"abstract":"Hydrogen adsorption on twenty different palladium and platinum overlayer surfaces with (111) crystallographic orientation was studied by means of periodic DFT calculations on the GGA-PBE level. Palladium and platinum overlayers here denote either the Pd and Pt mono- and bilayers deposited over (111) crystallographic plane of Pd, Pt, Cu, and Au monocrystals or the (111) crystallographic plane of Pd and Pt monocrystals with inserted one-atom-thick surface underlayer of Pd, Pt, Cu, and Au. The attention was focused on the bond lengths, hydrogen adsorption energetics, mobility of adsorbed hydrogen, and surface reactivity toward hydrogen electrode reactions. Both the ligand and strain effects were considered, found to lead to a significant modification of the electronic structure of Pd and Pt overlayers, described through the position of the d-band center, and tuning of the hydrogen adsorption energy in the range that covers approximately 120 kJmol−1. Mobility of hydrogen adsorbed on studied overlayers was found to be determined by hydrogen-metal binding energy. Obtained results regarding Pd layers on Pt(111) and Au(111) surfaces, in conjunction with some of the recent experimental data, were used to explain its electrocatalytic activity towards hydrogen evolution reaction.","PeriodicalId":7371,"journal":{"name":"Advances in Physical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2011-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79178650","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 51
Vibrational Study and Force Field of the Citric Acid Dimer Based on the SQM Methodology 基于SQM方法的柠檬酸二聚体的振动和力场研究
Advances in Physical Chemistry Pub Date : 2011-06-20 DOI: 10.1155/2011/347072
L. C. Bichara, H. E. Lanús, E. Ferrer, M. B. Gramajo, S. Brandán
{"title":"Vibrational Study and Force Field of the Citric Acid Dimer Based on the SQM Methodology","authors":"L. C. Bichara, H. E. Lanús, E. Ferrer, M. B. Gramajo, S. Brandán","doi":"10.1155/2011/347072","DOIUrl":"https://doi.org/10.1155/2011/347072","url":null,"abstract":"We have carried out a structural and vibrational theoretical study for the citric acid dimer. The Density Functional Theory (DFT) method with the B3LYP/6-31G∗ and B3LYP/6-311","PeriodicalId":7371,"journal":{"name":"Advances in Physical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2011-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89468334","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 72
Synthesis, Characterization, and Electrochemical Study of Tetradentate Ruthenium-Schiff Base Complexes: Dioxygen Activation with a Cytochrome P450 Model Using 1- or 2-Methylimidazole as Axial Bases 四齿钌-席夫碱配合物的合成、表征和电化学研究:以1-或2-甲基咪唑为轴碱的细胞色素P450模型的二氧活化
Advances in Physical Chemistry Pub Date : 2011-06-14 DOI: 10.1155/2011/157484
A. Ourari, M. Khelafi, D. Aggoun, G. Bouet, M. Khan
{"title":"Synthesis, Characterization, and Electrochemical Study of Tetradentate Ruthenium-Schiff Base Complexes: Dioxygen Activation with a Cytochrome P450 Model Using 1- or 2-Methylimidazole as Axial Bases","authors":"A. Ourari, M. Khelafi, D. Aggoun, G. Bouet, M. Khan","doi":"10.1155/2011/157484","DOIUrl":"https://doi.org/10.1155/2011/157484","url":null,"abstract":"Salicylaldehyde, 2-hydroxyacetophenone, and 3,5-dichlorosalicylaldehyde react with 1,2-diaminoethane to give three symmetrical Schiff bases H2L1, H2L2, and H2L3, respectively. With Ru(III) ions, these ligands lead to three complexes: Ru(III)ClL1 (𝟏), Ru(III)ClL2 (𝟐), and Ru(III)ClL3 (𝟑). The purity of these compounds was estimated by TLC technique and microanalysis while their structures were supported by the usual spectroscopic methods such as NMR, infrared, and electronic spectra. The cyclic voltammetry in acetonitrile showed irreversible waves for all three ligands. Under the same experimental conditions, it was proved that the ruthenium is coordinated in the three complexes 𝟏, 𝟐, and 𝟑 showing quasireversible redox systems. The behavior of these complexes and their comparison with cytochrome P450 are investigated using them as catalysts in the presence of molecular oxygen with an apical nitrogen base: 1- or 2-methylimidazole.","PeriodicalId":7371,"journal":{"name":"Advances in Physical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2011-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90885688","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
Recent Progress in Hydrogen Electrocatalysis 氢电催化研究进展
Advances in Physical Chemistry Pub Date : 2011-06-04 DOI: 10.1155/2011/851640
P. Quaino, E. Santos, G. Soldano, W. Schmickler
{"title":"Recent Progress in Hydrogen Electrocatalysis","authors":"P. Quaino, E. Santos, G. Soldano, W. Schmickler","doi":"10.1155/2011/851640","DOIUrl":"https://doi.org/10.1155/2011/851640","url":null,"abstract":"Recently, we have proposed a unified model for electrochemical electron transferreactions which explicitly accounts for the electronic structure of the electrode.It provides a framework describing the whole course of bond-breaking electrontransfer, which explains catalytic effects caused by the presence of surface d bands.In application on real systems, the parameters of this model—interaction strengths,densities of states, and energies of reorganization—are obtained from densityfunctional theory (DFT). In this opportunity, we review our main achievements in applying the theory ofelectrocatalysis. Particularly, we have focused on the electrochemical adsorptionof a proton from the solution—the Volmer reaction—on a variety of systems oftechnological interest, such as bare single crystals and nanostructured surfaces. Wediscuss in detail the interaction of the surface metal d band with the valence orbitalof the reactant and its effect on the catalytic activity as well as other aspects thatinfluence the surface-electrode reactivity such as strain and chemical factors.","PeriodicalId":7371,"journal":{"name":"Advances in Physical Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2011-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81308999","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 25
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