{"title":"The Chemical Exposure Multiverse: A Call for Papers that Provide Accurate Toxicity and Exposure Data in the Laboratory and Beyond","authors":"Pamela Pollet*, and , Jeremy Breuzard, ","doi":"10.1021/acs.chas.4c0005510.1021/acs.chas.4c00055","DOIUrl":"https://doi.org/10.1021/acs.chas.4c00055https://doi.org/10.1021/acs.chas.4c00055","url":null,"abstract":"","PeriodicalId":73648,"journal":{"name":"Journal of chemical health & safety","volume":"31 4","pages":"268–269 268–269"},"PeriodicalIF":0.0,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141956105","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xue Han, Xiaoyan Wang*, Xinglong Jin* and Minghua Zhou,
{"title":"Examining the Mediating Role of Psychological Capital between Perceived Management Commitment and Safety Compliance/Participation of Graduate Students in Research Laboratories","authors":"Xue Han, Xiaoyan Wang*, Xinglong Jin* and Minghua Zhou, ","doi":"10.1021/acs.chas.4c0000210.1021/acs.chas.4c00002","DOIUrl":"https://doi.org/10.1021/acs.chas.4c00002https://doi.org/10.1021/acs.chas.4c00002","url":null,"abstract":"<p >This study conducted a questionnaire survey to examine the influence mechanism of perceived management commitment on the safety compliance and participation of graduate students and to verify the mediating role of psychological capital. The questionnaire was distributed to graduate students through the MyCOS network platform. SPSS was used to conduct reliability and validity tests,test, correlation analysis, and bootstrapping mediation effect test. The results demonstrated that the perceived management commitment has a positive effect on both safety compliance and safety participation, with psychological capital as the mediating role. This study explains how graduate students’ perceived management commitment from their supervisors influences their safety behaviors.</p>","PeriodicalId":73648,"journal":{"name":"Journal of chemical health & safety","volume":"31 4","pages":"300–305 300–305"},"PeriodicalIF":0.0,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141959068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Reflections in Chemical Safety and Research: The Odyssey of a Female Chemical Engineer from Iraq","authors":"Saba A. Gheni*, ","doi":"10.1021/acs.chas.4c00039","DOIUrl":"https://doi.org/10.1021/acs.chas.4c00039","url":null,"abstract":"","PeriodicalId":73648,"journal":{"name":"Journal of chemical health & safety","volume":"31 3","pages":"174–175"},"PeriodicalIF":0.0,"publicationDate":"2024-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141156551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Introducing “Reflections in Chemical Safety and Research” Series","authors":"Mary Beth Mulcahy*, ","doi":"10.1021/acs.chas.4c00038","DOIUrl":"https://doi.org/10.1021/acs.chas.4c00038","url":null,"abstract":"","PeriodicalId":73648,"journal":{"name":"Journal of chemical health & safety","volume":"31 3","pages":"172–173"},"PeriodicalIF":0.0,"publicationDate":"2024-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141156533","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yu Liu, Kai Wang, Mengmeng Luo, Jieqi Bai, Lin Wang and Fuchao Tian*,
{"title":"Study on the Explosion Characteristics of CH4 with the Addition of Coal Spontaneous Combustion Gases","authors":"Yu Liu, Kai Wang, Mengmeng Luo, Jieqi Bai, Lin Wang and Fuchao Tian*, ","doi":"10.1021/acs.chas.4c0001610.1021/acs.chas.4c00016","DOIUrl":"https://doi.org/10.1021/acs.chas.4c00016https://doi.org/10.1021/acs.chas.4c00016","url":null,"abstract":"<p >Combustible gases produced during the coal spontaneous combustion (CSC) process will cause hidden danger for mine safety. For studying the effect of the addition of CSC gas on CH<sub>4</sub> explosion characteristics, a 20 L explosive device was adopted to obtain the explosion characteristics of CH<sub>4</sub> (7%, 9.5%, and 11% in vol.) and CSC gas (0–2% in vol.) premixed fuel, and the effect of CSC gas on CH<sub>4</sub> explosion characteristics was analyzed. Results show that for 7% CH<sub>4</sub>, CSC gas promotes the CH<sub>4</sub> explosion. However, for 11% CH<sub>4</sub>, CSC gas inhibits the explosion of CH<sub>4</sub>. Based on the chemical reaction kinetics analysis, it indicates that adding CSC gas at different stages changes the sensitivity coefficients, which affects the concentration of active radicals. With the increase of CSC gas in CH<sub>4</sub>, the concentration of H increased, the concentration of O decreased, and the concentration of OH increased first and then decreased. The variations of O and OH are regarded to be the main reason for promoting the explosion of dilute CH<sub>4</sub> and inhibiting the explosion of concentrated CH<sub>4</sub>. The variations of H, O, and OH indicate that the addition of the self-heating oxidation stage of CSC gas has a more evident effect on the CH<sub>4</sub> explosion characteristics.</p>","PeriodicalId":73648,"journal":{"name":"Journal of chemical health & safety","volume":"31 4","pages":"313–323 313–323"},"PeriodicalIF":0.0,"publicationDate":"2024-05-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141959332","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The Gist of the List","authors":"Lauren Goulding, ","doi":"10.1021/acs.chas.4c00034","DOIUrl":"10.1021/acs.chas.4c00034","url":null,"abstract":"","PeriodicalId":73648,"journal":{"name":"Journal of chemical health & safety","volume":"31 3","pages":"176–178"},"PeriodicalIF":0.0,"publicationDate":"2024-05-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140935898","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Claudia Cirillo, Mariagrazia Iuliano, Davide Scarpa*, Luca Gallucci, Claudia Florio, Gaetano Maffei, Andrea Loi and Maria Sarno,
{"title":"Nanoparticle Usage in Leather Processing: Worker Safety and Health","authors":"Claudia Cirillo, Mariagrazia Iuliano, Davide Scarpa*, Luca Gallucci, Claudia Florio, Gaetano Maffei, Andrea Loi and Maria Sarno, ","doi":"10.1021/acs.chas.4c0000610.1021/acs.chas.4c00006","DOIUrl":"https://doi.org/10.1021/acs.chas.4c00006https://doi.org/10.1021/acs.chas.4c00006","url":null,"abstract":"<p >The focus on the leather market has recently been on the rise due to the global increase in demand for leather products, driven by rising disposable income levels and improving standards of living among the expanding middle-class population. To enhance the performance of the final leather product, we have employed nanoparticles (NPs) across various stages of leather manufacturing. Specifically, in the finishing process─the ultimate stage of leather production─numerous studies have underscored the significance of Ag, TiO<sub>2</sub>, and SiO<sub>2</sub> NPs in significantly enhancing various characteristics of leather. On the other hand, the rapid growth in the application of NPs to leather finishing, and more in general in the leather industry, has occurred concomitantly with increased attention toward potential risks associated with their usage in biological systems and ecosystems. Given these considerations, the objective of this critical review is to provide a detailed and thorough analysis of the factors influencing the toxicity and cytotoxicity of nanoparticles commonly adopted in the leather finishing stage, with particular emphasis on Ag, TiO<sub>2,</sub> and SiO<sub>2</sub> NPs, along with their effects on the safety and health of workers. Moreover, the following study aims to identify necessary precautions and safety measures that the leather industry should implement when handling nanoparticles during the finishing stage.</p>","PeriodicalId":73648,"journal":{"name":"Journal of chemical health & safety","volume":"31 4","pages":"276–290 276–290"},"PeriodicalIF":0.0,"publicationDate":"2024-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141957244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Caroline M. Donaghy*, Adelina Oronova, Aishanee Sur, Daniel D. Hu, Emily E. A. Robinson, E. Rachel Wiley, Noah J. Gibson, Sarah Mutchek, Brady L. Bresnahan, Hossain Shadman, Abbigayle E. Cuomo, Christy Lynn Dyer, Mariya Aleksich and Monica Nyansa,
{"title":"Empowering Student Laboratory Safety Officer Programs to Strengthen Academic Safety Culture","authors":"Caroline M. Donaghy*, Adelina Oronova, Aishanee Sur, Daniel D. Hu, Emily E. A. Robinson, E. Rachel Wiley, Noah J. Gibson, Sarah Mutchek, Brady L. Bresnahan, Hossain Shadman, Abbigayle E. Cuomo, Christy Lynn Dyer, Mariya Aleksich and Monica Nyansa, ","doi":"10.1021/acs.chas.3c0010310.1021/acs.chas.3c00103","DOIUrl":"https://doi.org/10.1021/acs.chas.3c00103https://doi.org/10.1021/acs.chas.3c00103","url":null,"abstract":"<p >A student Laboratory Safety Officer (LSO) program formalizes a position often found within academic institutions. Through clearly defined responsibilities and effective communication between an LSO and their principal investigators, environmental health and safety office, and department administrators, this program can be effectively used to establish a baseline for safety standards. This article outlines pathways for an institution to establish or strengthen a student LSO program. The strength within this program goes beyond defined responsibilities, where the program’s initiatives can deepen a department-wide community while improving access to resources and advancing leadership skills. The common hurdles faced by these programs are discussed at length for new and existing programs to gain insights into how to address those obstacles while also elucidating the pathways to empower the program. Faculty and student buy-in is fundamental for the success of this program, which often is best addressed by giving visibility to the program itself and its outstanding participants. This article gives an overview of laboratory safety teams (LSTs), a separate graduate student-led laboratory safety initiative, and how an LST can be used to support and even serve as an LSO program. The implementation of a student LSO program has the potential to foster a greater sense of community and safety culture within a department, while giving students the opportunity to enhance their leadership and laboratory skills.</p>","PeriodicalId":73648,"journal":{"name":"Journal of chemical health & safety","volume":"31 4","pages":"291–299 291–299"},"PeriodicalIF":0.0,"publicationDate":"2024-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141956677","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xinyi Niu, Peyton Hall, Jun Wang* and Steven Lange,
{"title":"Airborne Hexavalent Chromium and Particulate Matter Emissions during the Laser Cutting of Leathers","authors":"Xinyi Niu, Peyton Hall, Jun Wang* and Steven Lange, ","doi":"10.1021/acs.chas.4c0001010.1021/acs.chas.4c00010","DOIUrl":"https://doi.org/10.1021/acs.chas.4c00010https://doi.org/10.1021/acs.chas.4c00010","url":null,"abstract":"<p >Workers may be at risk of exposure to airborne contaminants, including hexavalent chromium (Cr(VI)) and particles of diverse shapes and sizes during the laser cutting of leathers because of the extensive chemicals employed in leather tanning processes. Desktop carbon dioxide (CO<sub>2</sub>) laser engraving machines have gained popularity in various industries; however, airborne contaminant exposure in the laser cutting process of leathers remains unclear. This study investigated Cr(VI) and particle emissions during laser cutting/engraving of leather treated with various tanning methods. Six tanning methods (chrome 1-, chrome 2-, vegetable 1-, vegetable 2-, oil-, and alum-tanned) were studied at three laser power settings (15, 45, and 75%). A personal air sampler coupled with a sampling cassette and ISO 17075–2 evaluation were used to sample and analyze airborne Cr(VI) concentrations, respectively. Two real-time aerosol monitors were utilized to assess particulate concentrations and size distributions from 10 nm to 10 μm. High concentrations of Cr(VI) were detected in chrome-tanned leathers when the ventilation system was off, indicating the critical role of ventilation. The particle number concentrations were statistically significantly affected by various leather tanning methods and laser powers. Chrome 1-tanned leather exhibited the highest concentration of nanoparticles (<420 nm) at low (14,733 #/cm<sup>3</sup>) and medium (20,725 #/cm<sup>3</sup>) laser powers, while veg 2-tanned leather produced the highest micrometer-sized particle (>0.3 μm) concentration, over 1,600 #/cm<sup>3</sup> at all laser powers. The medium laser power exhibited higher nanoparticles than other powers when laser cutting most tanned leathers. The higher power resulted in the generation of smaller-sized particles for chrome-, oil-, and alum-tanned leathers. These findings underscore the importance of adequate ventilation and controlled laser power settings in minimizing health risks during the leather laser cutting processes.</p>","PeriodicalId":73648,"journal":{"name":"Journal of chemical health & safety","volume":"31 4","pages":"306–312 306–312"},"PeriodicalIF":0.0,"publicationDate":"2024-04-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141955357","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Spotlights: Peroxide Formation in 2-Propanol and Learning from Incidents and Near Misses","authors":"Lauren Goulding*, ","doi":"10.1021/acs.chas.4c00033","DOIUrl":"10.1021/acs.chas.4c00033","url":null,"abstract":"","PeriodicalId":73648,"journal":{"name":"Journal of chemical health & safety","volume":"31 3","pages":"179"},"PeriodicalIF":0.0,"publicationDate":"2024-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140657124","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}