JCIS open最新文献

筛选
英文 中文
Micromechanical properties of spray-dried core-shell silica aggregates along with drug release tests 喷雾干燥核壳二氧化硅聚集体的微力学性能及药物释放试验
JCIS open Pub Date : 2022-07-01 DOI: 10.1016/j.jciso.2022.100052
Matthäus Barasinski , Carsten Schilde , Sebastian Melzig , Merle Hübner , Georg Garnweitner , Sabrina Zellmer
{"title":"Micromechanical properties of spray-dried core-shell silica aggregates along with drug release tests","authors":"Matthäus Barasinski ,&nbsp;Carsten Schilde ,&nbsp;Sebastian Melzig ,&nbsp;Merle Hübner ,&nbsp;Georg Garnweitner ,&nbsp;Sabrina Zellmer","doi":"10.1016/j.jciso.2022.100052","DOIUrl":"10.1016/j.jciso.2022.100052","url":null,"abstract":"<div><p>In order to enhance the quality of spray-dried products or to adjust material properties for new applications, precise control of the aggregate structure is desirable. For the purpose of preparing hierarchically structured aggregates in the micrometer range, the formulation of the suspension can be specifically designed, utilizing defined nanoparticulate building blocks to achieve a highly uniform structure and porosity. Further adjustments can be made by combining two types of primary particles that differ in size. Thereby, a segregation effect is observed, where nanoparticles with larger particle sizes accumulate rather within the core of an aggregate and those with smaller particle sizes gather mainly near the outer surface, resulting in the formation of a shell. Furthermore, it is possible to produce tailor-made porosities using template particles (e.g. polystyrene) of different sizes as part of the coarse and fine fractions. The removal of these particles by a subsequent tempering process can lead to aggregates with defined porous structures and thus, to different mechanical aggregate properties that can be specifically set by adjusting the process and formulation parameters. As a result, a promising building kit for the hierarchically structure formation via spray drying processes were achieved.</p><p>For the detailed characterization structural and mechanical material properties were investigated, using e.g. mercury intrusion and SEM. The influence of the formulation parameters of the suspension (primary particle size and template content) on the micromechanical properties of the aggregate structures was systematically investigated by nanoindentation to elucidate structure-property relationships regarding, for example elastic and plastic deformation. As a result, a correlation could be established between the experimentally determined mechanical parameters and the aggregate porosities.</p><p>Such microstructures with defined properties can be used in a variety of applications, including catalysis or as drug carriers. For instance, these spray-dried aggregates were loaded with ibuprofen as an exemplary active pharmaceutical ingredient and investigated with regard to their drug release behavior.</p></div>","PeriodicalId":73541,"journal":{"name":"JCIS open","volume":"6 ","pages":"Article 100052"},"PeriodicalIF":0.0,"publicationDate":"2022-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666934X22000101/pdfft?md5=08cbe6160eba2117836b718916e5947a&pid=1-s2.0-S2666934X22000101-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44110984","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Influence of molecular weight and concentration of carboxymethyl cellulose on rheological properties of concentrated anode slurries for lithium-ion batteries 羧甲基纤维素分子量和浓度对锂离子电池正极浓浆流变性能的影响
JCIS open Pub Date : 2022-07-01 DOI: 10.1016/j.jciso.2022.100048
Masahiko Ishii, Hiroshi Nakamura
{"title":"Influence of molecular weight and concentration of carboxymethyl cellulose on rheological properties of concentrated anode slurries for lithium-ion batteries","authors":"Masahiko Ishii,&nbsp;Hiroshi Nakamura","doi":"10.1016/j.jciso.2022.100048","DOIUrl":"10.1016/j.jciso.2022.100048","url":null,"abstract":"<div><p>The detailed behavior of carboxymethyl cellulose (CMC) as a dispersant in model anode slurries for lithium-ion batteries was investigated. Slurries with different graphite and CMC concentrations using three types of CMCs having different molecular weights were prepared, and changes in viscosity in the low shear rate range together with shear thickening in the high shear rate range were assessed. At a constant CMC concentration, the viscosities at low shear rates decreased as the graphite concentration was increased. Shear thickening was also more evident at low CMC concentrations and when using CMCs with lower molecular weights as well as at high graphite concentrations. These results suggest that, within the CMC concentration range investigated in the present work, the majority of the CMC was adsorbed on the graphite particles and this adsorbed CMC affected the rheological properties of the slurry. Increases in graphite concentration decreased the amount of adsorbed CMC per graphite particle, which in turn lowered the viscosity in the low shear rate range and enhanced shear thickening in the high shear rate range. The adsorbed CMC affected the slurry viscosity via electrostatic and steric interactions at low shear rates and acted as a buffer to inhibit shear thickening at high shear rates, primarily as a result of steric effects.</p></div>","PeriodicalId":73541,"journal":{"name":"JCIS open","volume":"6 ","pages":"Article 100048"},"PeriodicalIF":0.0,"publicationDate":"2022-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666934X2200006X/pdfft?md5=5e297f19ed935f6aa4a5d884f73fb70c&pid=1-s2.0-S2666934X2200006X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46963057","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Recognition of spatiotemporal patterns of the periodically precipitating 2D reaction-diffusion system by determination of precise band location: Implications on the Matalon-Packter law 通过确定精确的能带位置识别周期沉淀二维反应扩散系统的时空模式:对Matalon-Packter定律的启示
JCIS open Pub Date : 2022-07-01 DOI: 10.1016/j.jciso.2022.100053
Sunil D. Kulkarni , Smita D. Takawane , Prasad C. Walimbe , Kiran D. Takale , Preeti S. Kulkarni
{"title":"Recognition of spatiotemporal patterns of the periodically precipitating 2D reaction-diffusion system by determination of precise band location: Implications on the Matalon-Packter law","authors":"Sunil D. Kulkarni ,&nbsp;Smita D. Takawane ,&nbsp;Prasad C. Walimbe ,&nbsp;Kiran D. Takale ,&nbsp;Preeti S. Kulkarni","doi":"10.1016/j.jciso.2022.100053","DOIUrl":"10.1016/j.jciso.2022.100053","url":null,"abstract":"<div><p>Recently focus of studies on the periodic precipitation in gels is shifting from evaluation of its spatio-temporal characteristics of the self-organized patterns to that of as a novel and viable method of synthesis of hierarchical monodispersed micro and nanomaterials in a single reactor. One of the parameters that profoundly affect the morphology, shape, size, and self-organization in the chemical systems is the supersaturation of the participating species. The Matalon-Packter (MP) law correlates the effect of the concentration of invading electrolytes to the spatial patterning in the Liesegang system. Although concentration and supersaturation have quantitative relations, the implications of supersaturation on the spatial arrangement of the band are not entirely understood. The present paper deals with studies on the periodically precipitating Co(OH)<sub>2</sub> in agar gel with respect to supersaturation of the participating reactants during the pattern formation. Varying inner and outer electrolytes concentrations were employed to determine spatial trends. Pattern image analysis was used to determine the precise location of the Liesegang bands. The supersaturation values showed a decreasing trend as the diffusion progressed outward. The present study led to the correlation between the supersaturation and the spacing coefficient.</p></div>","PeriodicalId":73541,"journal":{"name":"JCIS open","volume":"6 ","pages":"Article 100053"},"PeriodicalIF":0.0,"publicationDate":"2022-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666934X22000113/pdfft?md5=c49b55f71601b29f53afdbf4e6aba066&pid=1-s2.0-S2666934X22000113-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48212451","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Target polishing of KDP crystals by organic acid-ionic liquid-in-oil microemulsions 油中有机酸离子液体微乳液对KDP晶体的靶向抛光
JCIS open Pub Date : 2022-07-01 DOI: 10.1016/j.jciso.2022.100049
Hui Dong, Jinlong Pan, Shuke Huang, Pengfei Sun, Wei Gao
{"title":"Target polishing of KDP crystals by organic acid-ionic liquid-in-oil microemulsions","authors":"Hui Dong,&nbsp;Jinlong Pan,&nbsp;Shuke Huang,&nbsp;Pengfei Sun,&nbsp;Wei Gao","doi":"10.1016/j.jciso.2022.100049","DOIUrl":"10.1016/j.jciso.2022.100049","url":null,"abstract":"<div><p>Chemical polishing is an effective method to remove a subsurface damage layer with the advantages of no mechanical stress and no new subsurface damage. In this paper, we report a target polishing method that employs an anhydrous organic acid-ionic liquid-in-oil (OA-IL/O) microemulsion as the etching solution for chemical polishing of KDP crystals. OA-IL/O microemulsions were prepared with 1-butyl-3-methyl imidazolium bis [(trifluoromethyl) sulfonyl] imide ([Bmim]TF<sub>2</sub>N) and bis (trifluoromethane sulfonimide) (TF<sub>2</sub>NH) as the internal phase, castor oil as the external phase, TX-100 as the surfactant, and n-butanol as the co-surfactant. TF<sub>2</sub>NH irreversibly reacts with KDP when microemulsion micelles driven by Brownian motion collide with the KDP surface. The organic salt products are removed by the ionic liquid in the microemulsion, resulting in the effective elimination of KDP. Moreover, the organic acid-ionic liquid solution will preferentially diffuse to the high points of the KDP surface and react with the KDP to achieve the target polishing. As a new type of water-free surface polishing technology, OA-IL/O microemulsion not only has the advantages of traditional CMP, but also avoids the recrystallization that can occur with water-in-oil microemulsions and achieves target polishing of the KDP crystal.</p></div>","PeriodicalId":73541,"journal":{"name":"JCIS open","volume":"6 ","pages":"Article 100049"},"PeriodicalIF":0.0,"publicationDate":"2022-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666934X22000071/pdfft?md5=e3d2cd408347b268ef7c72ce0945bb95&pid=1-s2.0-S2666934X22000071-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45187317","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Pattern selection in radial displacements of a confined aging viscoelastic fluid 有限时效粘弹性流体径向位移的模式选择
JCIS open Pub Date : 2022-07-01 DOI: 10.1016/j.jciso.2022.100047
Palak, Vaibhav Raj Singh Parmar, Debasish Saha, Ranjini Bandyopadhyay
{"title":"Pattern selection in radial displacements of a confined aging viscoelastic fluid","authors":"Palak,&nbsp;Vaibhav Raj Singh Parmar,&nbsp;Debasish Saha,&nbsp;Ranjini Bandyopadhyay","doi":"10.1016/j.jciso.2022.100047","DOIUrl":"10.1016/j.jciso.2022.100047","url":null,"abstract":"<div><p>Intricate fluid displacement patterns, arising from the unstable growth of interfacial perturbations, can be driven by fluid viscoelasticity and surface tension. A soft glassy suspension ages, <em>i.e.</em> its mechanical moduli evolve with time, due to the spontaneous formation of suspension microstructures. The shear and time-dependent rheology of an aging suspension can be exploited to generate a wide variety of interfacial patterns during its displacement by a Newtonian fluid. Using video imaging, we report a rich array of interfacial pattern morphologies: dense viscous, dendritic, viscoelastic fracture, flower-shaped, jagged and stable, during the miscible and immiscible displacements of an aging colloidal clay suspension by Newtonian fluids injected into a radial quasi-two-dimensional geometry at different flow rates. We propose a new parameter, the areal ratio, which we define as the fully developed pattern area normalized by the area of the smallest circle enclosing it. We show that the natural logarithms of the areal ratios uniquely identify the distinct pattern morphologies, such that each pattern can be segregated in a three-dimensional phase diagram spanned by the suspension aging time, the displacing fluid flow rate, and interfacial tension. Besides being of fundamental interest, our results are useful in predicting and controlling the growth of interfaces during fluid displacements.</p></div>","PeriodicalId":73541,"journal":{"name":"JCIS open","volume":"6 ","pages":"Article 100047"},"PeriodicalIF":0.0,"publicationDate":"2022-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666934X22000058/pdfft?md5=f09f6a66254fc891120be1763261a151&pid=1-s2.0-S2666934X22000058-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43689617","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
The preparation of NiCo2O4 nanoboulders and their application in the electrochemical detection of ofloxacin drug NiCo2O4纳米巨砾的制备及其在氧氟沙星药物电化学检测中的应用
JCIS open Pub Date : 2022-07-01 DOI: 10.1016/j.jciso.2022.100054
Nizamuddin Solangi , Jai Kumar , Gul Naz , Razium Ali Soomro
{"title":"The preparation of NiCo2O4 nanoboulders and their application in the electrochemical detection of ofloxacin drug","authors":"Nizamuddin Solangi ,&nbsp;Jai Kumar ,&nbsp;Gul Naz ,&nbsp;Razium Ali Soomro","doi":"10.1016/j.jciso.2022.100054","DOIUrl":"10.1016/j.jciso.2022.100054","url":null,"abstract":"<div><p>A sensitive electroactive platform relies directly upon the efficient and conductive interface. This work offers a simple and effective method for synthesizing NiCo<sub>2</sub>O<sub>4</sub> using CTAB surfactant, suited for trace-level antibiotic detection. The route realized the controlled growth of tiny NiCo<sub>2</sub>O<sub>4</sub> nanoboulders with an exposed interface. A comparative evaluation of the bimetallic nanostructures with their pristine compositional counterparts, i.e., NiO and Co<sub>3</sub>O<sub>4</sub>, supports its superior electrochemical characteristics based on the synergism of strong redox activity and conductivity from the bimetallic components. The NiCo<sub>2</sub>O<sub>4</sub> nanoboulders exhibited strong electrochemical activity when configured as electrode material for detecting ofloxacin (OFL), a common antibiotic. The sensor exhibited excellent working linearity in a low-concentration range of 0.01–5 ​μM with a detection limit of 1 ​× ​10<sup>−3</sup> ​μM for OFL. The kinetics of the NiCo<sub>2</sub>O<sub>4</sub> further supported the electrocatalytic oxidation of OFL to be diffusion controlled with an estimated diffusion coefficient of 2.03310<sup>−6</sup> ​cm<sup>2</sup> ​s<sup>−1</sup>. Moreover, the constructed sensor is applicable for detecting OFL from environmental samples, reflecting its workability in complex real-environment.</p></div>","PeriodicalId":73541,"journal":{"name":"JCIS open","volume":"6 ","pages":"Article 100054"},"PeriodicalIF":0.0,"publicationDate":"2022-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666934X22000125/pdfft?md5=a91a742cfcf998d05e89d5e66f6ed042&pid=1-s2.0-S2666934X22000125-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45600770","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Inducing the formation of a colloidal albumin carrier of curcumin 姜黄素胶体白蛋白载体的诱导形成
JCIS open Pub Date : 2022-07-01 DOI: 10.1016/j.jciso.2022.100051
Konstantina Matskou , Berke Kisaoglan , Barbara Mavroidi , Maria Pelecanou , Maria Zoumpanioti , Ilias Matis , Aristotelis Xenakis
{"title":"Inducing the formation of a colloidal albumin carrier of curcumin","authors":"Konstantina Matskou ,&nbsp;Berke Kisaoglan ,&nbsp;Barbara Mavroidi ,&nbsp;Maria Pelecanou ,&nbsp;Maria Zoumpanioti ,&nbsp;Ilias Matis ,&nbsp;Aristotelis Xenakis","doi":"10.1016/j.jciso.2022.100051","DOIUrl":"10.1016/j.jciso.2022.100051","url":null,"abstract":"<div><p>The administration and delivery of pharmaceuticals faces a variety of well-known obstacles that result in limited biocompatibility and bioavailability. Efforts to improve these properties have often employed serum albumin, primarily due to its inherent biocompatibility and its ability to enhance the circulation times of pharmaceuticals. In this work, we have adapted a nanoparticle-formulation protocol, to produce a protein carrier of curcumin with bovine serum albumin. This was achieved by using a near-equimolar protein:curcumin ratio instead of the abundance of curcumin that would be normally used in a nanoparticle formulation. Photometric and quantitative analysis of this carrier showed an increased curcumin content in the produced aqueous solutions following the homogenization of bovine serum albumin (water) and curcumin (dichloromethane) phases. Albumin fluorescence studies indicated curcumin association near a tryptophan residue, without excluding the possibility of additional sites. Circular dichroism provided strong evidence of this association through the induced circular dichroism effect and showed that the secondary structure of bovine serum albumin was effectively maintained. Overall, this work presented a new means of facilitating the association of increased levels of curcumin with bovine serum albumin, which could potentially be used to generate additional non-covalent albumin carriers for pharmaceutical compounds.</p></div>","PeriodicalId":73541,"journal":{"name":"JCIS open","volume":"6 ","pages":"Article 100051"},"PeriodicalIF":0.0,"publicationDate":"2022-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666934X22000095/pdfft?md5=41f79d90df8468b08f9974c45f546ef8&pid=1-s2.0-S2666934X22000095-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47352470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Supporting non-noble metal composite organosilica monolithic foam for efficiently catalytic degradation of aromatic compounds 支撑非贵金属复合有机硅单片泡沫高效催化降解芳香族化合物
JCIS open Pub Date : 2022-04-01 DOI: 10.1016/j.jciso.2021.100041
Jieli Lyu, Yuezhan Wan, Na Wang, Zetao Song, Zhongshan Liu, Junxia Peng
{"title":"Supporting non-noble metal composite organosilica monolithic foam for efficiently catalytic degradation of aromatic compounds","authors":"Jieli Lyu,&nbsp;Yuezhan Wan,&nbsp;Na Wang,&nbsp;Zetao Song,&nbsp;Zhongshan Liu,&nbsp;Junxia Peng","doi":"10.1016/j.jciso.2021.100041","DOIUrl":"10.1016/j.jciso.2021.100041","url":null,"abstract":"<div><p>The porous monolithic materials supporting non-noble metal nanoparticles that acted as catalysts have recently gained increasing attention due to their robust activity and regenerative ability, resulting in simple chemical progress. It is crucial for the catalytic performance that the monolithic supporters have a hierarchically porous structure while the non-noble metal nanoparticles show a good control of their dimensions and oxidation states. Herein this work reports the composite organosilica monolithic (OSM) foams containing non-noble metal like Cu-, Co-, or Ni-based nanoparticles. As-prepared the supporting non-noble metal nanoparticles organosilica monolithic foams could act as monolithic catalyst, showing the efficiently catalytic performance for the degradation of aromatic compounds. These monolithic catalysts were prepared via amino-functionalization of organosilica monolith with ethylenic groups, followed by supporting non-noble metal nanoparticles through a simple reduction process. The monolithic catalyst involved Cu-based nanoparticles (Cu/OSM) were obtained via reduction of Cu<sup>2+</sup> using a mixture of NaBH<sub>4</sub> with and without the aid of polyvinylpyrrolidone K 90 (PVP), as denoted by Cu/OSM-N and Cu/OSM-P, respectively. It was demonstrated that the addition of PVP into the system caused the higher Cu content, the better distribution of the smaller Cu-based nanoparticles and a richer Cu(0) nanoparticles. Furthermore Cu/OSM-P exhibited high stability and durable activity, with approximately 95% conversion within 14 successive cycles, for the catalytic reduction of 4-nitrophenol (4-NP) to 4-aminophenol (4-AP) with excess NaBH<sub>4</sub> in an aqueous solution. This catalyst also showed a remarkable catalytic performance for the degradation of other organic aromatic dyes like methylene blue (MB), methyl orange (MO), rhodamine B (RhB) and even their mixture. In addition, Co/OSM-P and Ni/OSM-P fabricated with the same method also showed high catalytic performance for reduction of 4-NP. We believe that the strategy developed in this work is very useful for the simple, low-cost, and environmentally friendly preparation of porous composite monolithic catalysts containing non-noble metal nanoparticles.</p></div>","PeriodicalId":73541,"journal":{"name":"JCIS open","volume":"5 ","pages":"Article 100041"},"PeriodicalIF":0.0,"publicationDate":"2022-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666934X21000404/pdfft?md5=607bd35c4c1d19d2319c2fe9f46f81e3&pid=1-s2.0-S2666934X21000404-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"54553299","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
3D printable self-propelling sensors for the assessment of water quality via surface tension 用于通过表面张力评估水质的3D打印自推进传感器
JCIS open Pub Date : 2022-04-01 DOI: 10.1016/j.jciso.2022.100044
Piyush Kumar , Abigail Legge , David A. Gregory , Andy Nichols , Henriette Jensen , Stephen J. Ebbens , Xiubo Zhao
{"title":"3D printable self-propelling sensors for the assessment of water quality via surface tension","authors":"Piyush Kumar ,&nbsp;Abigail Legge ,&nbsp;David A. Gregory ,&nbsp;Andy Nichols ,&nbsp;Henriette Jensen ,&nbsp;Stephen J. Ebbens ,&nbsp;Xiubo Zhao","doi":"10.1016/j.jciso.2022.100044","DOIUrl":"https://doi.org/10.1016/j.jciso.2022.100044","url":null,"abstract":"<div><h3>Hypothesis</h3><p>Water contamination is a serious global challenge and an on-site and out-of-lab method of assessment of contamination level is highly needed. In this study, we report the potential of using printable and biodegradable propelling sensors as indicators of water contamination in sewage wastewater.</p></div><div><h3>Experiments</h3><p>We used reactive 3D inkjet printing technology to fabricate self-propelling sensors which can quickly indicate the lowering of surface tension value caused by sewage contamination, and other surface tension lowering pollutants. The Z-shaped sensors were fabricated, with the dimensions of 2.0 ​mm at the longest side and 0.1 ​mm in thickness, from regenerated silk fibroin which is an environmentally friendly and biodegradable material. Inkjet printing has the advantage of high resolution and precise deposition of materials allowing the fabrication of small millimetre-sized sensors doped with a surface tension modifying polymer which acts as the ‘fuel’ to drive the sensors on the water surface via surface tension gradient.</p></div><div><h3>Findings</h3><p>Our results showed that the sensor's propulsion velocity decay rate is an excellent metric to indicate the presence and approximate level of sewage contamination.</p></div>","PeriodicalId":73541,"journal":{"name":"JCIS open","volume":"5 ","pages":"Article 100044"},"PeriodicalIF":0.0,"publicationDate":"2022-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666934X22000022/pdfft?md5=ac327cc36ba0c6e258a3ff02a781d47d&pid=1-s2.0-S2666934X22000022-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"92009300","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Rheological interpretation of the structural change of LiB cathode slurry during the preparation process 锂离子阴极浆料制备过程中结构变化的流变学解释
JCIS open Pub Date : 2022-04-01 DOI: 10.1016/j.jciso.2021.100038
Yoshiyuki Komoda , Kaoru Ishibashi , Kentaro Kuratani , Ruri Hidema , Hiroshi Suzuki , Hironori Kobayashi
{"title":"Rheological interpretation of the structural change of LiB cathode slurry during the preparation process","authors":"Yoshiyuki Komoda ,&nbsp;Kaoru Ishibashi ,&nbsp;Kentaro Kuratani ,&nbsp;Ruri Hidema ,&nbsp;Hiroshi Suzuki ,&nbsp;Hironori Kobayashi","doi":"10.1016/j.jciso.2021.100038","DOIUrl":"10.1016/j.jciso.2021.100038","url":null,"abstract":"<div><p>The dispersion behavior of lithium cobalt oxide (LCO) and acetylene black (AB) particles in the preparation process of the cathode slurry of LiB is investigated from the rheological viewpoint. The cathode slurry is considered as the dispersion of coarse LCO particles in the viscoelastic AB slurry. Viscosity as well as loss modulus of the cathode slurry are estimated from those of the AB slurry using and compared the measured results. After forming the AB network structure or When AB content is high enough, LCO particles can enter and destroy the AB network structure. As a result, LCO particles and fragmented AB network structures are homogeneously mixed, exhibiting better discharge performance. Once the cathode slurry is excessively diluted, the LCO particles are excluded from the AB network structure, resulting in low discharge capacity. Over fragmentation using a high-shear device causes the AB network structure into too small segments, which also lowers the battery performance. Viscosity is helpful to understand the entrance of LCO particles into the AB network, and the storage modulus detects the destruction of the AB network structure during the preparation process of cathode slurry.</p></div>","PeriodicalId":73541,"journal":{"name":"JCIS open","volume":"5 ","pages":"Article 100038"},"PeriodicalIF":0.0,"publicationDate":"2022-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666934X21000374/pdfft?md5=525ebca88233e7f85329425e3a680733&pid=1-s2.0-S2666934X21000374-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48860279","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
相关产品
×
本文献相关产品
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信