Advances in Materials Science最新文献

{"title":"Effect of Concrete Class, Maximum Aggregate Size and Specimen Size on the Compressive Strength of Cores and Cast Specimens","authors":"Salem Merabti","doi":"10.2478/adms-2022-0016","DOIUrl":"https://doi.org/10.2478/adms-2022-0016","url":null,"abstract":"Abstract Core sampling is the most accurate method of evaluating the compressive strength of concrete structures. However, it is preferable to take only small cores to avoid damaging the structures. It turns out that various elements influence the strength of compressed cores. This study examines the influence of specimen size, aggregate size, concrete class, and curing method on compressive strength. Three aggregates measuring 3/8, 8/15, and 15/25 mm are used to make six sets of concrete compositions with strengths of 25 MPa and 30 MPa. Nine specimens are made, one for each variety of aggregate and concrete. Cores of 100 mm, 75 mm, and 50 mm sizes are made. These cores are extracted from concrete blocks curing in the outside air to simulate the real concrete curing environment. Cast specimens cured in water and air with diameters of 50 mm, 100 mm, and 150 mm are also made. The objective is to compare the average compressive strength of all cast or extracted specimens with that of cylindrical standard specimens of diameter 150/300 mm and the cores and cast specimens. The obtained findings showed that the compressive strength is overestimated when we compare fp100 cores and standard air-cured specimens (fc), with a conversion factor varying from 0.69 to 0.96. However, a decrease is observed in comparison with water-cured specimens. The use of fp75 cores reduced the conversion factors, which are between 0.83 and 0.87 for B25 concrete. The highest fp/fc ratios are obtained for fc50 cores, which can reach 1.24. It turns out that the size of the core and the class of concrete have a much greater influence on the fp/fc ratios.","PeriodicalId":7327,"journal":{"name":"Advances in Materials Science","volume":"38 1","pages":"21 - 31"},"PeriodicalIF":1.3,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86907114","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Investigation on the Microstructure and Mechanical Properties of ASTM A131 Steel Manufactured by Different Welding Methods","authors":"Fatih Ata, A. Çalık, N. Uçar","doi":"10.2478/adms-2022-0017","DOIUrl":"https://doi.org/10.2478/adms-2022-0017","url":null,"abstract":"Abstract Welding is an indispensable manufacturing process in the shipbuilding industry. The fierce competition involved often necessitates a cost-effective and reliable welding method. In this study, the weldabilities, microstructures and some mechanical properties of ASTM A131 (Grade A) steel joints fabrication by submerged arc welding (SAW), metal active gas (MAG) welding and plasma arc welding (PAW) have been investigated. The microstructures of the welds were examined by optical microscopy. The mechanical properties of the joints were determined by microhardness measurements, tensile and impact tests. The results showed that tensile strength of the joints reached a tensile strength of up to 462 MPa. The locations of the fractures were always adjacent to the base metal. The Charpy impact energy of the weld metal reached a value of 72.5 J, which was 25 % higher than that of the base metal at 57.7 J. A relatively high hardness of 221 HV was obtained in the PAW method compared to 179 HV in the base metal.","PeriodicalId":7327,"journal":{"name":"Advances in Materials Science","volume":"47 1","pages":"32 - 40"},"PeriodicalIF":1.3,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75738170","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Microstructure and Mechanical Properties of Sc-Modified AA2519-T62 Laser Beam Welded Butt Joints","authors":"R. Kosturek, K. Grzelak, J. Torzewski, M. Wachowski, L. Śnieżek","doi":"10.2478/adms-2022-0019","DOIUrl":"https://doi.org/10.2478/adms-2022-0019","url":null,"abstract":"Abstract The fundamental aim of the research is to investigate the microstructure and mechanical properties of the AA2519-T62 laser beam welded joints obtained with various values of welding velocity. For the constant value of laser power (3.2 kW) three joints have been produced with various values of welding velocity: 0.8, 1.1, and 1.4 m/min. The joints have been subjected to microstructure analysis (including both light and scanning electron microscope), microhardness measurements, tensile tests, and fractography of tensile samples. The established values of joint efficiency contain within the range of 55-66% with the highest value (66%) reported for the joint obtained with 1.1 m/min welding velocity. The produced welds have noticeable participation of pores, which tends to increase together with the value of welding velocity. In all cases, the failure has occurred in the fusion zone by ductile fracture.","PeriodicalId":7327,"journal":{"name":"Advances in Materials Science","volume":"36 1","pages":"57 - 69"},"PeriodicalIF":1.3,"publicationDate":"2022-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91166595","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effect of Chemical Composition of Boriding Agent on the Optimization of Surface Hardness and Layer Thickness on AISI 8620 Steel by Solid and Liquid Boriding Processes","authors":"M. Kul, Y. Yilmaz, K. O. Oskay, L. C. Kumruoglu","doi":"10.2478/adms-2022-0010","DOIUrl":"https://doi.org/10.2478/adms-2022-0010","url":null,"abstract":"Abstract Surfaces of cam shafts made of AISI 8620 steels were hardened by boriding processes in both solid and liquid mediums. Various chemical agents were used to achieve boride layers on the surfaces of the cam shafts in these processes. It was aimed to examine effects of the chemical agents on microhardness and thickness of the boride layers obtained. It was concluded that a bath composition of 5% B4C-90% SiC-5% KBF4 was appropriate for the hardest and thickest boride layer achieved in the solid medium, and a composition of 70% Na2B4O7-30% B4C in the liquid medium.","PeriodicalId":7327,"journal":{"name":"Advances in Materials Science","volume":"41 1","pages":"14 - 22"},"PeriodicalIF":1.3,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82250697","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Prediction of Filler Added Friction Stir Welding Parameters for Improving Corrosion Resistance of Dissimilar Aluminium Alloys 5052 and 6082 Joints","authors":"A. Sasikumar, S. Gopi, D. Mohan","doi":"10.2478/adms-2022-0014","DOIUrl":"https://doi.org/10.2478/adms-2022-0014","url":null,"abstract":"Abstract The aluminium alloys 5052 and 6082 are extensively used in manufacturing lighter structural members, having improved strength and resistance to corrosion. Magnesium (Mg) and Chromium (Cr) powder were the filler materials selected for enhanced corrosion protection properties in this investigation. Friction stir welding (FSW) process parameters viz., spindle speed, welding speed, shoulder penetration, the centre distance between the holes and filler ratio are used to forecast the minimum corrosion rate from different weld regions of AA5052-AA6082 dissimilar joints. Response surface methodology based on a central composite design was used to evolve the mathematical models and estimate dissimilar FSW joints’ corrosion rates. Response optimization shows that the minimum corrosion rate was achieved by the welding parameters of spindle speed 1000 rev/min, welding speed 125 mm/min, holes spacing of 2 mm and filler ratio 95% of Mg and 5% of Cr.","PeriodicalId":7327,"journal":{"name":"Advances in Materials Science","volume":"32 1","pages":"79 - 95"},"PeriodicalIF":1.3,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81960094","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The Effect of Resistance Spot Welding Parameters on Microstructure and Strength of DP800 Steel Joints Using Response Surface Methodology","authors":"Chakkravarthi Rajarajan, Tushar Sonar, P. Sivaraj, S. Raja, N. Mathiazhagan","doi":"10.2478/adms-2022-0013","DOIUrl":"https://doi.org/10.2478/adms-2022-0013","url":null,"abstract":"Abstract The main objective of this paper is to analyze the direct and interaction effect of resistance spot welding (RSW) parameters on microstructure and strength of DP800 steel joints using response surface methodology (RSM). The DP800 steel sheets were spot welded in straight lap and cross lap joint configuration using RSW. The relationship between the RSW parameters, tensile shear fracture load (TSFL) and nugget zone hardness (NZH) was established employing statistical regression analysis and validated using Analysis of Variance (ANOVA). The DP800 steel joints made using welding current of 5.0 kA, electrode pressure of 4.0 MPa, and welding time of 1.50 s displayed maximum STRAIGHT-TSFL of 21.7 kN, CROSS-TSFL of 17.65 kN, and NZH of 589 HV0.5 respectively.","PeriodicalId":7327,"journal":{"name":"Advances in Materials Science","volume":"2 1","pages":"53 - 78"},"PeriodicalIF":1.3,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88844829","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"g-C3N4/ Bio–Synthesized Silver Nanoparticle for Fluorometric Bio-Sensing of Acetylcholinesterase and Malathion","authors":"A. Ali","doi":"10.2478/adms-2022-0011","DOIUrl":"https://doi.org/10.2478/adms-2022-0011","url":null,"abstract":"Abstract Malathion is widely used in agriculture due to their high efficiency as insecticides. They are very toxic hazardous chemicals to both human health and environment even at low concentration. The detection of pesticides (malathion) at the low levels developed by the environmental protection agency (EPA) still remains a challenge. A highly efficient fluorescent biosensor based on g-C3N4/AgNPs for AChE and malathion detection is successfully developed by impregnation method. The structural and morphological properties of the nanocomposites were characterized by using powder X-ray diffraction (XRD), fourier- transform infrared spectroscopy (FT-IR) and scanning electron microscopy (SEM). The analysis confirmed that there is a strong interfacial interaction between g-C3N4 and AgNPs. The fluorescent responses show an increase in intensity upon the additions of AChE which indicates that AChE as enzyme was hydrolyzing the substrate ACh, with the increase in oxidative electron as the preferred route of reaction. The developed OFF-ON sensor immobilizes by Actylcholestrase (AChE) and use as new probe for malathion detection. In the absence of malathion, AChE−g-C3N4/AgNCs exhibit high fluorescence intensity. However, the strong interaction of the basic sites to malathion, causes fluorescence quenching via static quenching and Ag form aggregation on the surface of g-C3N4. The experimental parameter such as pH of buffer (pH=6), concentration of acetylcholine (1 mM) and malathion (500 μM) were optimized. The sensor was also more sensitive with Stern-Volmer quenching constants (KSV) of 3.48x10 3 M −1. The practical use of this sensor for malathion determination in Khat was also demonstrated. The obtained amount of malathion in Khat is 168.8 μM.","PeriodicalId":7327,"journal":{"name":"Advances in Materials Science","volume":"21 1","pages":"23 - 40"},"PeriodicalIF":1.3,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77807233","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Pb-Doped CuO Thin Films Synthetized by Sol-Gel Method","authors":"D. Tabli, N. Touka, K. Baddari, Nourddine Selmi","doi":"10.2478/adms-2022-0009","DOIUrl":"https://doi.org/10.2478/adms-2022-0009","url":null,"abstract":"Abstract The physical properties of pure CuO and Pb doped CuO thin films, deposited on glass substrates by a sol-gel method, were investigated. Structural analysis revealed the polycrystalline nature of the pure CuO and Pb:CuO composite films with a monoclinic structure, the crystallite size decreased and ranged from 36.78 nm to around 21.5 nm. The SEM images of the CuO thin films showed that the Pb doping concentration affects the surface morphology of the Pb:CuO composites. The absorbance of the Pb:CuO composites is higher than that of the undoped CuO thin films. The optical band gap energies of undoped CuO and Pb doped CuO thin films were estimated to 1.9 (pure), 2.17(5%) and 2.74 (7%)eV, and found that the band gap energy (Eg) increases with the Pb concentration. This blue shift is due to the quantum confinement induced by the reduction in the size of the crystallites.","PeriodicalId":7327,"journal":{"name":"Advances in Materials Science","volume":"12 1","pages":"5 - 13"},"PeriodicalIF":1.3,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87917158","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Analytical Description of Concentration of Radiation Displacement Defects in Oxide Crystals as Function of Electrons or Neutrons Energy","authors":"P. Potera","doi":"10.2478/adms-2022-0012","DOIUrl":"https://doi.org/10.2478/adms-2022-0012","url":null,"abstract":"Abstract The main purpose of this work is the description of dependence of the concentration of radiation displacements defects (RDD) induced by electrons and neutrons in garnets, perovskites, silicates, germanates, and tungsted bronzes type crystals (Y3Al5O12, Gd3Ga5O12, YAlO3, LiNbO3, Bi4Si3O12, Bi4Ge3O12, Ca0.28Ba0.72Nb2O6) on the energy of particles by analytical function. The dependences were determined on the basis of calculations made using the Monte-Carlo method realized in the Atom Collision Cascade Simulation program. The results of calculations show that the concentrations of RDD reduced to one impinging particle increased initially with the particles energy and they saturates for the electron and neutron energy above 3–36 MeV, depending on crystal, sublattice and kind of irradiation particle. A wide range of energies for which the concentration of RDD is independent of the energy of particles (neutrons, electrons) makes them potential materials for the dosimetry of high-energy particles. The comparison of the concentrations of RDD calculated for different sublattices as well as for the cases of electrons and neutrons is made. In the case of irradiation with electrons, the relative concentration of RDD of the oxygen sublattice strongly depends on the energy of electrons and the crystal and varies in the range of 10–90%. In the case of neutrons, the relative concentration of RDD of the oxygen sublattice does not depend on the neutron energy and is in the range of 66–84% depending on the crystal.","PeriodicalId":7327,"journal":{"name":"Advances in Materials Science","volume":"266 1","pages":"41 - 52"},"PeriodicalIF":1.3,"publicationDate":"2022-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79765245","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhancement Photocatalytic Activity of Mn Doped Cds/Zno Nanocomposites for the Degradation of Methylene Blue Under Solar Light Irradiation","authors":"K. Sivaranjani, S. Sivakumar, J. Dharmaraja","doi":"10.2478/adms-2022-0006","DOIUrl":"https://doi.org/10.2478/adms-2022-0006","url":null,"abstract":"Abstract In this study, Mn doped CdS/ZnO nanocomposites synthesized by co-precipitation method and its photocatalytic activity was tested using methylene blue under solar light irradiation. The prepared hybrid nanocomposites are characterized by using different physicochemical techniques including XRD, FESEM, EDX, TEM, UV-vis DRS and PL analysis. From the XRD analysis, Mn doped ZnO/CdS nanocomposite diffraction peaks only reflect the binary crystalline structures of ZnO and CdS. However, there is no characteristic peak of Mn is found that may be because of low content of Mn doped on ZnO/CdS. But Mn (2.9 wt%) was detected in the Mn doped ZnO/CdS nanocomposite, which was measured by EDX analysis. The FESEM and TEM results exhibit the surface particle of Mn doped ZnO/CdS nanocomposite which have spherical nature and confirmed the formation of Mn doped ZnO/CdS nanocomposites. The photocatalytic degradation results have revealed that the Mn doped CdS/ZnO nanocomposites exhibit admirable activity toward the photocatalytic degradation of the MB. The reason for excellent photocatalytic activity of Mn doped CdS/ZnO nanocomposites indicates the absorbance band shifted to red region and reduction of recombination of photogenerated electron-hole, which is in good agreement with UV-visible DRS analysis and PL study results. The fitted kinetic plots showed a pseudo-first-order reaction model and the appropriate rate constants were found to be 0.0068 min−1, 0.00846 min−1, and 0.0188 min−1, for ZnO, 25 % CdS/ZnO, and 0.8 mol% Mn doped CdS/ZnO nanocomposites, respectively. The maximum photocatalytic activity was achieved by 0.8 mol% Mn doped CdS/ZnO nanocomposites with a 95% degradation efficiency of MB. Hydroxyl and superoxide radicals, having a vital role in the degradation of MB, confirmed scavenging experiments. In addition, the recycling tests displays that the Mn doped CdS/ZnO nanocomposites have shown good stability and long durability. The enhanced photodegradation activity of Mn doped CdS/ZnO nanocomposites indicates the potential of the nanocomposite for the treatment of organic pollutants from the textile wastewater.","PeriodicalId":7327,"journal":{"name":"Advances in Materials Science","volume":"49 1","pages":"28 - 48"},"PeriodicalIF":1.3,"publicationDate":"2022-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81346176","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}