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Review—Metal Oxide Chemoresistive Gas Sensing Mechanism, Parameters, and Applications 回顾--氧化金属化阻气体传感机理、参数和应用
ECS sensors plus Pub Date : 2024-01-22 DOI: 10.1149/2754-2726/ad2152
A. Pathania, Neetu Dhanda, Ritesh Verma, A. C. Sun, P. Thakur, A. Thakur
{"title":"Review—Metal Oxide Chemoresistive Gas Sensing Mechanism, Parameters, and Applications","authors":"A. Pathania, Neetu Dhanda, Ritesh Verma, A. C. Sun, P. Thakur, A. Thakur","doi":"10.1149/2754-2726/ad2152","DOIUrl":"https://doi.org/10.1149/2754-2726/ad2152","url":null,"abstract":"\u0000 Economic growth depends upon Micro, Small and Medium Enterprises (MSMEs) as they play a vital role in GDP and employment. Transportation is considered the lifeline of any country. In the last 10 years, ferrite-based sensors have been used primarily to detect harmful gases, pollutants from vehicle exhaust, and for environmental pollution monitoring. These soft ferrites have excellent electrical and magnetic properties that can be tuned to increase sensitivity and selectivity. The tuning of ferrite sensors depends upon synthesis technique, optimizing preparation conditions, sintering temperatures, operating temperatures, dopant concentration, etc. This paper is based on a deep study of the gas sensing mechanisms, parameters, and application of chemo-resistive metal oxide gas sensors. The key parameters for the ferrite gas sensors are phase formation, crystallite size, grain size, surface area, selectivity, dopants, sensitivity, gas concentration, operating temperature, response/recovery time. This review paper also includes the study of different researchers to find the impact of high concentration of gases like hydrogen, carbon monoxide, carbon dioxide , oxygen (O2), ethylene glycol 〖〖(CH〗_2 OH)〗_(2 ), methane (CH4), ammonia (NH3) liquid petroleum gas (LPG), acetylene (C2H2), and nitrogen oxides (NOx) in the environment and the metal oxide materials selected sensor applications.","PeriodicalId":72870,"journal":{"name":"ECS sensors plus","volume":"29 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139607175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Editors' Choice—Review—The Future of Carbon-Based Neurochemical Sensing: A Critical Perspective 编辑推荐-评论-碳基神经化学传感的未来:批判性视角
ECS sensors plus Pub Date : 2023-12-14 DOI: 10.1149/2754-2726/ad15a2
Blaise J Ostertag, Ashley E Ross
{"title":"Editors' Choice—Review—The Future of Carbon-Based Neurochemical Sensing: A Critical Perspective","authors":"Blaise J Ostertag, Ashley E Ross","doi":"10.1149/2754-2726/ad15a2","DOIUrl":"https://doi.org/10.1149/2754-2726/ad15a2","url":null,"abstract":"\u0000 Carbon-based sensors have remained critical materials for electrochemical detection of neurochemicals rooted in their inherent biocompatibility and broad potential window. Real-time monitoring, using fast-scan cyclic voltammetry, has resulted in the rise of minimally invasive carbon -fiber microelectrodes as the material of choice for making measurements in tissue, but challenges with carbon fiber’s innate properties have limited its applicability to understudied neurochemicals. Here, we provide a critical review of the state of carbon-based real-time neurochemical detection and offer insight into ways we envision addressing these limitations in the future. We focus on three main hinderances of traditional carbon-fiber based materials: diminished temporal resolution due to geometric properties and adsorption/desorption properties of the material, poor selectivity/specificity to most neurochemicals, and the inability to tune amorphous carbon surfaces for specific interfacial interactions. Routes to addressing these challenges could lie in methods like computational modeling of single-molecule interfacial interactions, expansion to tunable carbon-based materials, and novel approaches to synthesizing these materials. We hope this critical piece does justice to describing the novel carbon-based materials that have preceded this work, and we hope this review provides useful solutions to innovate carbon-based material development in the future for individualized neurochemical structures.","PeriodicalId":72870,"journal":{"name":"ECS sensors plus","volume":"279 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139002124","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Operando Color-Coding of Reversible Lithiation and Cycle Life in Batteries Using Photonic Crystal Materials 使用光子晶体材料对电池中的可逆锂化和循环寿命进行 Operando 颜色编码
ECS sensors plus Pub Date : 2023-12-14 DOI: 10.1149/2754-2726/ad15a0
Alex Lonergan, U. Gulzar, Yan Zhang, C. O’Dwyer
{"title":"Operando Color-Coding of Reversible Lithiation and Cycle Life in Batteries Using Photonic Crystal Materials","authors":"Alex Lonergan, U. Gulzar, Yan Zhang, C. O’Dwyer","doi":"10.1149/2754-2726/ad15a0","DOIUrl":"https://doi.org/10.1149/2754-2726/ad15a0","url":null,"abstract":"\u0000 Innovative new materials are consistently emerging as electrode candidates from lithium-ion battery research, promising high energy densities and high-rate capabilities. Understanding potential structural changes, morphology evolution, degradation mechanisms, and side reactions during lithiation is important for designing, optimizing, and assessing aspiring electrode materials. In-situ and operando analysis techniques provide a means to investigate these material properties under realistic operating conditions. Here, we demonstrate operando spectroscopic sensing using photonic crystal-structured electrodes that uses the optical transmission spectrum to monitor changes to the state of charge or discharge during lithiation, and the change to electrode structure, in real-time. Photonic crystals possess a signature optical response, with a photonic bandgap (or stopband) presenting as a structural color reflection from the material. We leverage the presence of this photonic stopband, alongside its intricate relationship to the electrode structure and material phase, to correlate electrode lithiation with changes to the optical spectrum during operation. We explore the optical and electrochemical behavior of a TiO2 anode in a lithium-ion battery, structured as a photonic crystal. The operando optical sensing demonstrated here is versatile and applicable to a wide range of electrochemical electrode material candidates when structured with ordered porosity akin to a photonic crystal structure.","PeriodicalId":72870,"journal":{"name":"ECS sensors plus","volume":"15 12","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138971919","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Assessing Electrochemical, Aptamer-Based Sensors for Dynamic Monitoring of Cellular Signaling 评估用于动态监测细胞信号的电化学色素传感器
ECS sensors plus Pub Date : 2023-12-14 DOI: 10.1149/2754-2726/ad15a1
Celeste R. Rousseau, Hope Kumakli, Ryan J. White
{"title":"Assessing Electrochemical, Aptamer-Based Sensors for Dynamic Monitoring of Cellular Signaling","authors":"Celeste R. Rousseau, Hope Kumakli, Ryan J. White","doi":"10.1149/2754-2726/ad15a1","DOIUrl":"https://doi.org/10.1149/2754-2726/ad15a1","url":null,"abstract":"\u0000 Electrochemical, aptamer-based (E-AB) sensors provide a generalizable strategy to quantitatively detect a variety of targets including small molecules and proteins. The key signaling attributes of E-AB sensors (sensitivity, selectivity, specificity, and reagentless and dynamic sensing ability) make them well suited to monitor dynamic processes in complex environments. A key bioanalytical challenge that could benefit from the detection capabilities of E-AB sensors is that of cell signaling, which involves the release of molecular messengers into the extracellular space. Here, we provide a perspective on why E-AB sensors are suited for this measurement, sensor requirements, and pioneering examples of cellular signaling measurements.","PeriodicalId":72870,"journal":{"name":"ECS sensors plus","volume":"184 1‐2","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139002335","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Simultaneous Detection of CO and NO2 Gases using Interaction Analysis of SnS2 Sensor Array Response 利用 SnS2 传感器阵列响应的交互分析同时检测 CO 和 NO2 气体
ECS sensors plus Pub Date : 2023-11-16 DOI: 10.1149/2754-2726/ad0cd6
Srinivasulu Kanaparthi, S. Singh
{"title":"Simultaneous Detection of CO and NO2 Gases using Interaction Analysis of SnS2 Sensor Array Response","authors":"Srinivasulu Kanaparthi, S. Singh","doi":"10.1149/2754-2726/ad0cd6","DOIUrl":"https://doi.org/10.1149/2754-2726/ad0cd6","url":null,"abstract":"Developing a multi-analyte gas sensing system that simultaneously detects trace levels of CO and NO2 at low temperatures is necessary for the Internet of Things (IoT) based air quality monitoring applications. Nevertheless, gas sensors operating at low temperatures are nonspecific and rarely detect target gases at lower ppb levels in the air. Herein, an array of two SnS2 sensors with different bias voltages has been developed and characterized upon exposure to individual and binary mixtures of CO and NO2 gases at different concentrations. The developed gas sensors array achieved the lower detection limit of 45 ppb for NO2 and 150 ppb for CO. Further, co-adsorption-induced interaction analysis was carried out to predict the target gas concentration in the binary mixture using the mixed gas response. The mean absolute percentage error of 7.86% is observed in predicting the target gas concentrations in the binary mixture, which indicates the high prediction accuracy of proposed method. As a minimal resource intensive approach, the proposed method can be used in air quality monitoring applications that require low-power and low-cost sensors.","PeriodicalId":72870,"journal":{"name":"ECS sensors plus","volume":"160 12","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139267108","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Perspective—Five Sensor-Centric Grand Challenges in Soft Robotics 软机器人中以传感器为中心的五大挑战
ECS sensors plus Pub Date : 2023-11-10 DOI: 10.1149/2754-2726/ad08d6
Kunal Singh, Ajit Khosla, Shilpa Gupta
{"title":"Perspective—Five Sensor-Centric Grand Challenges in Soft Robotics","authors":"Kunal Singh, Ajit Khosla, Shilpa Gupta","doi":"10.1149/2754-2726/ad08d6","DOIUrl":"https://doi.org/10.1149/2754-2726/ad08d6","url":null,"abstract":"Soft robotics, offering precise actions in complex environments, stands at the brink of transformative advancements across diverse fields. To realize this potential, the field must address five key challenges: creation of soft power and control mechanisms, emphasis on sustainability, cultivation of advanced intelligence, and the imperative for standardization. This perspective argues for solutions grounded in sensory feedback systems, aiming to fortify the foundation of soft robotics, ensure its sustainability, enhance adaptability in robot intelligence, and set the stage for scalable robot production. Addressing these challenges, we aim to pave the way for a more inclusive era of soft robotic technology.","PeriodicalId":72870,"journal":{"name":"ECS sensors plus","volume":"64 23","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135091303","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Refractive Index-Modulated LSPR Sensing in 20-120 nm Gold and Silver Nanoparticles: A Simulation Study 20-120纳米金、银纳米粒子的折射率调制LSPR传感:模拟研究
ECS sensors plus Pub Date : 2023-11-02 DOI: 10.1149/2754-2726/ad08d8
Zoe Bradley, David Cunningham, Nikhil Bhalla
{"title":"Refractive Index-Modulated LSPR Sensing in 20-120 nm Gold and Silver Nanoparticles: A Simulation Study","authors":"Zoe Bradley, David Cunningham, Nikhil Bhalla","doi":"10.1149/2754-2726/ad08d8","DOIUrl":"https://doi.org/10.1149/2754-2726/ad08d8","url":null,"abstract":"Abstract Localized surface plasmon resonance (LSPR) based sensing has been a simple and cost-effective way to measure local refractive index changes. LSPR materials exhibit fascinating properties that have significant implications for various bio/chemical sensing applications. In many of these applications, the focus has traditionally been on analyzing the intensity of the reflected or transmitted signals in terms of the refractive index of the surrounding medium. However, limited simulation work is conducted on investigating the refractive index sensitivity of LSPR materials. Within this context, here we simulate the refractive index sensing properties of spherical gold (Au) and silver (Ag) nanoparticles ranging from 20-120 nm diameter within 1.0 to 1.50 refractive index units (RIU). After analyzing the peak optical efficiency and peak wavelength, we report the sensing performance of these materials in terms of sensitivity, linearity and figure of merit (FOM). Overall, our observations have revealed greatest FOM values for the smallest sized nanoparticles, a FOM of 6.6 for 20 nm AuNPs and 11.9 for 20 nm AgNPs with refractive index of 1.","PeriodicalId":72870,"journal":{"name":"ECS sensors plus","volume":"11 S1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135875390","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Anticipating Challenges in Optical Nanobiosensors for Global Detection of Respiratory Viruses and Emerging Threats 预测光学纳米生物传感器在全球检测呼吸道病毒和新出现的威胁方面的挑战
ECS sensors plus Pub Date : 2023-11-02 DOI: 10.1149/2754-2726/ad08d5
Shirlley E. Martínez Tolibia, Andrés Galdámez-Martínez, Rafael A. Salinas, Ateet Dutt
{"title":"Anticipating Challenges in Optical Nanobiosensors for Global Detection of Respiratory Viruses and Emerging Threats","authors":"Shirlley E. Martínez Tolibia, Andrés Galdámez-Martínez, Rafael A. Salinas, Ateet Dutt","doi":"10.1149/2754-2726/ad08d5","DOIUrl":"https://doi.org/10.1149/2754-2726/ad08d5","url":null,"abstract":"Abstract The unprecedented SARS-CoV-2 pandemic has opened huge opportunities for nanostructure-based biosensors focused on timely detection of emerging respiratory viruses, where challenges must address actions for fast response and massive application. Accordingly, we present a comprehensive perspective covering critical aspects of nanomaterials, biofunctionalization strategies, and bioreceptors engineering to increase accuracy, emphasizing optical nanobiosensors. The first biosensing prototype performance reveals the need to consider crucial factors for improvement, such as handling detection in complex matrices, standardization for commercial purposes, portability, integration with artificial intelligence, sustainability, and economic feasibility. By achieving these goals, biosensors would foster a prepared global healthcare landscape.","PeriodicalId":72870,"journal":{"name":"ECS sensors plus","volume":"11 2","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135875392","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Direct Laser-Functionalized Au-LIG Sensors for Real-time Electrochemical Monitoring of Response of Pseudomonas aeruginosa Biofilms to Antibiotics 直接激光功能化Au-LIG传感器用于铜绿假单胞菌生物膜对抗生素反应的实时电化学监测
ECS sensors plus Pub Date : 2023-11-02 DOI: 10.1149/2754-2726/ad08d4
Keren Zhou, Vinay Kammarchedu, Aida Ebrahimi
{"title":"Direct Laser-Functionalized Au-LIG Sensors for Real-time Electrochemical Monitoring of Response of Pseudomonas aeruginosa Biofilms to Antibiotics","authors":"Keren Zhou, Vinay Kammarchedu, Aida Ebrahimi","doi":"10.1149/2754-2726/ad08d4","DOIUrl":"https://doi.org/10.1149/2754-2726/ad08d4","url":null,"abstract":"Abstract Pseudomonas aeruginosa (P. aeruginosa) is a phenazine-producing pathogen recognized for its biofilm-mediated antibiotic resistance, showing up to 1000 times higher resistance than planktonic cells. In particular, it is shown that a phenazine called pyocyanin promotes antibiotic tolerance in P. aeruginosa cultures by upregulating efflux pumps and inducing biofilm formation. Therefore, real-time study of phenazine production in response to antibiotics could offer new insights for early detection and management of infection. Toward this goal, this work demonstrates real-time monitoring of P. aeruginosa colony biofilms challenged by antibiotics using electrochemical sensors based on direct laser functionalization of laser induced graphene (LIG) with gold (Au) nanostructures. Specifically, two routes for functionalization of LIG electrodes with Au-containing solutions are studied: electroless deposition and direct laser functionalization (E-Au/LIG and L-Au/LIG). While both methods show comparable sensitivity (1.276 vs 1.205 µA/µM), E-Au/LIG has bactericidal effects which makes it unsuitable as a sensor material. The effect of antibiotics (gentamicin as a model drug) on the production rate of phenazines before (i.e., in planktonic phase) or after biofilm formation is studied. The sensor data confirms that the P. aeruginosa biofilms are at least 100 times more tolerant to the antibiotic than planktonic cells.","PeriodicalId":72870,"journal":{"name":"ECS sensors plus","volume":"12 2","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135875582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Review—Prospects in Cancer Diagnosis: Exosome-Chip for Liquid Biopsy 肿瘤诊断:外泌体芯片液体活检技术的研究进展
ECS sensors plus Pub Date : 2023-11-02 DOI: 10.1149/2754-2726/ad08d7
Kamil Reza Khondakar, Matin Ataei Kachouei, Frank Efe Efe Erukainure, Md. Azahar Ali
{"title":"Review—Prospects in Cancer Diagnosis: Exosome-Chip for Liquid Biopsy","authors":"Kamil Reza Khondakar, Matin Ataei Kachouei, Frank Efe Efe Erukainure, Md. Azahar Ali","doi":"10.1149/2754-2726/ad08d7","DOIUrl":"https://doi.org/10.1149/2754-2726/ad08d7","url":null,"abstract":"Abstract A liquid biopsy combined with an exosome chip is an important detection tool for early cancer diagnosis. Exosomes have a crucial function in the exchange of information between cells and are present in biological fluids. Exosome chips are microfluidic devices designed to isolate, capture, and analyze exosomes for analysis of patient samples. These offer on-chip detection, high-throughput analysis, and multiplex measurements. Such chips can integrate with electrochemical and optical detectors, and mass spectrometry enabling comprehensive studies of diseases. This perspective will cover the outlook on chip-based diagnostics for liquid biopsy, detection, and isolation of exosomes to support cancer diagnostics.","PeriodicalId":72870,"journal":{"name":"ECS sensors plus","volume":"12 6","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135875578","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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