Advanced Engineering Materials最新文献

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Tailoring the Properties of 2D Nanomaterial-Polymer Composites for Electromagnetic Interference Shielding and Energy Storage by 3D Printing—A Review 利用3D打印技术定制用于电磁干扰屏蔽和储能的二维纳米材料-聚合物复合材料的性能-综述
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-04-08 DOI: 10.1002/adem.202570019
Amanuel Gebrekrstos, Tanyaradzwa S. Muzata, Anastasia Elias, Suprakas Sinha Ray
{"title":"Tailoring the Properties of 2D Nanomaterial-Polymer Composites for Electromagnetic Interference Shielding and Energy Storage by 3D Printing—A Review","authors":"Amanuel Gebrekrstos,&nbsp;Tanyaradzwa S. Muzata,&nbsp;Anastasia Elias,&nbsp;Suprakas Sinha Ray","doi":"10.1002/adem.202570019","DOIUrl":"https://doi.org/10.1002/adem.202570019","url":null,"abstract":"<p><b>Polymer Composites</b>\u0000 </p><p>In article number 2402179, Suprakas Sinha Ray and co-workers review the development of conductive inks derived from 2D nanomaterials. The work specifically explores how the addition of 2D nanomaterials, such as graphene and transition metal dichalcogenides, alters the rheology of different polymers for 3D printing. S. S. Ray designed the cover art in collaboration with the team at INMYWORK Studio.\u0000\u0000 <figure>\u0000 <div><picture>\u0000 <source></source></picture><p></p>\u0000 </div>\u0000 </figure></p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 7","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adem.202570019","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143801296","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Homogenization and Zn/Mg Ratio on the Mechanical Properties, Stress Corrosion Cracking Resistance, and Quench Sensitivity of Al–Zn–Mg–2.5Cu (AA7095) Alloys 均匀化和Zn/Mg比对Al-Zn-Mg-2.5Cu (AA7095)合金力学性能、抗应力腐蚀开裂性能和淬火敏感性的影响
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-04-07 DOI: 10.1002/adem.202402281
Jhen-Hau Jan, Shao-Cheng Lee, Mian-Chung Chen, Sheng-Long Lee, Chun-Nan Lin, Yu-Chih Tzeng
{"title":"Effect of Homogenization and Zn/Mg Ratio on the Mechanical Properties, Stress Corrosion Cracking Resistance, and Quench Sensitivity of Al–Zn–Mg–2.5Cu (AA7095) Alloys","authors":"Jhen-Hau Jan,&nbsp;Shao-Cheng Lee,&nbsp;Mian-Chung Chen,&nbsp;Sheng-Long Lee,&nbsp;Chun-Nan Lin,&nbsp;Yu-Chih Tzeng","doi":"10.1002/adem.202402281","DOIUrl":"https://doi.org/10.1002/adem.202402281","url":null,"abstract":"<p>This study examines the effect of homogenization and Zn/Mg ratio on the mechanical properties, stress corrosion cracking resistance, and quench sensitivity of Al–Zn–Mg–2.5Cu (AA7095) alloys. The alloys are processed using one-stage and two-stage homogenization followed by high-temperature solution treatment and T6 aging. Mechanical properties, including hardness, tensile strength, and ductility, are evaluated. Quench sensitivity is assessed by measuring the loss of hardness at varying distances from the water-quenched end. The results indicate that alloy B (5.4) exhibits the highest quench sensitivity due to higher precipitation kinetics. Additionally, the study reveals that the alloy with a higher Zn/Mg ratio (5.4) displays better precipitation strengthening but shows a more significant loss in hardness during quenching. SCC resistance is evaluated in both air and NaCl solution environments, showing that the alloy with a lower Zn/Mg ratio demonstrated better SCC resistance. These findings provide insights into optimizing the mechanical properties and resistance to SCC of AA7095 alloys through homogenization and Zn/Mg ratio control.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 9","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143909130","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental and Numerical Analysis of Novel Polycontinuous Triply Periodic Minimal Surface Architectures 新型多连续三周期最小曲面结构的实验与数值分析
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-04-06 DOI: 10.1002/adem.202402679
Hossein Doostmohammadi, Saeed Khaleghi, Mostafa Baghani, Morad Karimpour, Sara Bagherifard, Majid Baniassadi
{"title":"Experimental and Numerical Analysis of Novel Polycontinuous Triply Periodic Minimal Surface Architectures","authors":"Hossein Doostmohammadi,&nbsp;Saeed Khaleghi,&nbsp;Mostafa Baghani,&nbsp;Morad Karimpour,&nbsp;Sara Bagherifard,&nbsp;Majid Baniassadi","doi":"10.1002/adem.202402679","DOIUrl":"https://doi.org/10.1002/adem.202402679","url":null,"abstract":"<p>Triply periodic minimal surface (TPMS) structures are architectures that possess unique geometrical features, like a smooth surface and zero-mean curvature. This article proposes two novel multivoid TPMS shell network structures, namely, IP and iBP based on I-WP, Primitive, and iBase architectures. A voxel-based approach is employed as a numerical homogenization method to calculate the mechanical and thermal properties of the structures. LCD 3D printing is employed for experimental validation which demonstrates close agreement with finite element analysis with ≈5% deviation in predicted elastic modulus. The proposed IP and iBP architectures exhibit up to 15% higher thermal conductivity compared to their base TPMS structures, while maintaining almost similar elastic modulus, with only a 4% deviation. Also, the directional elastic properties of the modified TPMS architectures have been examined by the Zener anisotropy index. Compared to the base structures, both architectures exhibit high anisotropy at volume fraction of 40%, but the anisotropy decreases drastically as volume fraction increases to 60%. Additionally, detailed geometrical analysis of these architectures indicates that they exhibit three void phases at specific TPMS parameters. The results demonstrate that the developed architectures have high potential to be employed in heat and mass transfer systems, including multifluid heat exchangers.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 9","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-04-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143909339","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Improved Mechanical Performance of Epoxy Systems with Low Loadings of Milled Carbon Fiber via Chemical Surface Modification 通过化学表面改性提高低负荷碳纤维环氧树脂体系的机械性能
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-04-04 DOI: 10.1002/adem.202402306
Ben Newman, Filip Stojcevski, Karyn L. Jarvis, Piers Coia, Luke C. Henderson
{"title":"Improved Mechanical Performance of Epoxy Systems with Low Loadings of Milled Carbon Fiber via Chemical Surface Modification","authors":"Ben Newman,&nbsp;Filip Stojcevski,&nbsp;Karyn L. Jarvis,&nbsp;Piers Coia,&nbsp;Luke C. Henderson","doi":"10.1002/adem.202402306","DOIUrl":"https://doi.org/10.1002/adem.202402306","url":null,"abstract":"<p>The chemical surface modification of carbon fibers has been a prolific area of literature in recent years, but little has been done to translate these advances to short discontinuous carbon fibers. Routinely used as fillers in composite materials, the prospect of using chemical surface modification to improve the performance of milled carbon fibers carries appeal. This work describes the adaptation of conventional electrochemical reduction of aryl diazonium salts to recycled milled carbon fibers and explores the improvements in mechanical performance achieved therein in a simple epoxy resin system. Increasing fiber mass loadings are examined using conventional unmodified milled carbon fiber, and two species of chemically modified fibers, one featuring benzyl alcohol and the other nitrophenyl groups. At low loadings, milled carbon fibers with a surface featuring aryl alcohol functionality significantly improve the mechanical properties of epoxy specimens, increasing flexural strength by an average of 35% and tensile strength by 31.5%. Significant improvements are also seen at low loadings (&lt;1% w/w) using aryl nitro-modified fibers. It is proposed that fibers modified with these functionalities promote hydrogen-bonding at the fiber–polymer interface and result in greater mechanical performance, and that this improvement is pronounced at ≤1 wt%.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 9","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adem.202402306","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143908900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Monitoring and Maintaining Laser Surface Texture Quality Based on Acoustic and Optical Process Emissions during Direct Laser Interference Patterning 基于直接激光干涉图样声光过程发射的激光表面纹理质量监测与维护
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-04-04 DOI: 10.1002/adem.202402505
Tobias Steege, Frederic Schell, Adrian Belkin, Christoph Zwahr, Andrés F. Lasagni
{"title":"Monitoring and Maintaining Laser Surface Texture Quality Based on Acoustic and Optical Process Emissions during Direct Laser Interference Patterning","authors":"Tobias Steege,&nbsp;Frederic Schell,&nbsp;Adrian Belkin,&nbsp;Christoph Zwahr,&nbsp;Andrés F. Lasagni","doi":"10.1002/adem.202402505","DOIUrl":"https://doi.org/10.1002/adem.202402505","url":null,"abstract":"<p>Direct laser interference patterning (DLIP) is a promising technique for fabricating periodic surface structures on large areas, but controlling process quality can be challenging due to laser power fluctuations. This study presents a novel monitoring approach using acoustic and optical emissions to diagnose and correct these fluctuations during DLIP structure fabrication. Experiments are conducted using a nanosecond-pulsed IR laser to create 6 μm periodic microstructures on stainless steel. Significant laser power fluctuations are observed over time, resulting in noticeable surface texture inhomogeneity across larger areas. Acoustic and optical emissions, recorded via microphone and photodiodes respectively, are found to correlate well with local structure depth, surface roughness, and macroscopic appearance of the textured surface. A strategy for in-process correction is demonstrated using a PI controller to adjust laser power based on acoustic emission feedback in the 18–22 kHz range during processing. Implementing this closed-loop control system achieves a homogeneous texture with a consistent 2 μm structure depth, compared to significant variations between 0.8 and 2.4 μm without the controller. This monitoring and control approach offers a simple, cost-effective solution for ensuring quality and consistency in large-area DLIP fabrication processes, potentially improving the reliability and efficiency of surface texturing applications.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 9","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adem.202402505","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143908901","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring the Effect of Polymer Addition to the Room Temperature Synthesis of Colloidal Lead Halide Perovskite for Better Stability, Higher Passivation, and More Uniform Particle Size 探索添加聚合物对室温合成胶体卤化铅钙钛矿的影响,以获得更好的稳定性,更高的钝化度和更均匀的粒度
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-04-04 DOI: 10.1002/adem.202402713
Elshaimaa Darwish, Jack Elia, Miroslaw Batentschuk, Andres Osvet, Christoph J. Brabec
{"title":"Exploring the Effect of Polymer Addition to the Room Temperature Synthesis of Colloidal Lead Halide Perovskite for Better Stability, Higher Passivation, and More Uniform Particle Size","authors":"Elshaimaa Darwish,&nbsp;Jack Elia,&nbsp;Miroslaw Batentschuk,&nbsp;Andres Osvet,&nbsp;Christoph J. Brabec","doi":"10.1002/adem.202402713","DOIUrl":"https://doi.org/10.1002/adem.202402713","url":null,"abstract":"<p>In recent years, metal halide perovskites have emerged as a promising alternative to existing semiconductor materials in many applications due to its appealing properties. Despite perovskite huge potentials in many applications, they are still suffering from different kinds of stability issues that are hindering their marketability. Several attempts to stabilize perovskites including polymer encapsulations and inclusions of perovskite materials into polymer matrices due to the stability against moisture that the polymer can offer. Nevertheless, the polymer is acting as an unreactive component without any role into enhancing the optical properties of the studies metal halide perovskite. This study examines the incorporation of the polymer BUTVAR (polyvinyl butyral [PVB]) in the production of various perovskite structures at room temperature: CsPbBr<sub>3</sub>, Cs<sub>2</sub>PbBr<sub>5</sub>, FAPbBr<sub>3</sub>, and MAPbBr<sub>3</sub>. The study demonstrates that the incorporation of the polymer solution enhances the optical characteristics and improves the shape uniformity of the resultant perovskite material without altering the inherent structure of the original perovskite material. Furthermore, it improves the durability of the acquired particles against UV irradiation.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 9","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adem.202402713","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143908899","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advances in the Corrosion Behavior of High-Entropy Alloys in Lead-Bismuth Eutectic System 高熵合金在铅铋共晶体系中的腐蚀行为研究进展
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-04-04 DOI: 10.1002/adem.202402774
Wenmin Wu, Xiaogang Hu, Xiangyang Peng, Longshi Qiu, PeiPei Cao, Huan He, Zhiwen Gao, Xiaolong Pan, Yusheng Zhang
{"title":"Advances in the Corrosion Behavior of High-Entropy Alloys in Lead-Bismuth Eutectic System","authors":"Wenmin Wu,&nbsp;Xiaogang Hu,&nbsp;Xiangyang Peng,&nbsp;Longshi Qiu,&nbsp;PeiPei Cao,&nbsp;Huan He,&nbsp;Zhiwen Gao,&nbsp;Xiaolong Pan,&nbsp;Yusheng Zhang","doi":"10.1002/adem.202402774","DOIUrl":"https://doi.org/10.1002/adem.202402774","url":null,"abstract":"<p>The service life and safety of advanced nuclear reactors are heavily dependent on the stability of core materials. In lead-cooled fast reactors (LFRs), lead-bismuth eutectic (LBE) serves as the coolant due to its superior thermal conductivity, low melting point, high boiling point, excellent fluidity, and radiation resistance. During the operation of LFRs, the core materials are in direct contact with LBE, making the compatibility between LBE and these materials a critical concern. It has been established that LBE is highly corrosive to metallic materials, posing significant challenges to the long-term safety and operational reliability of LFRs. Consequently, researchers have focused on developing a range of corrosion-resistant materials, among which high-entropy alloys (HEAs) have gained considerable attention in recent years due to their exceptional resistance to high-temperature corrosion and radiation damage. This review summarizes the recent advance research on HEAs and their coatings on corrosion resistance in LBE environments. The article examines the effects of alloy composition, microstructure, oxygen concentration, corrosion exposure time, and temperature on the corrosion resistance of HEAs. The findings offer valuable insights into material selection and surface protection strategies for critical reactor components in advanced nuclear reactors.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 9","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143908903","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced Electrochemical Properties of Biobased Activated Carbon for Supercapacitors 生物基活性炭增强超级电容器电化学性能的研究
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-04-04 DOI: 10.1002/adem.202401964
Shengfei Zhou, Charles Tai-Chieh Wan, Nicolas Chanut, Fikile R. Brushett, Markus J. Buehler
{"title":"Enhanced Electrochemical Properties of Biobased Activated Carbon for Supercapacitors","authors":"Shengfei Zhou,&nbsp;Charles Tai-Chieh Wan,&nbsp;Nicolas Chanut,&nbsp;Fikile R. Brushett,&nbsp;Markus J. Buehler","doi":"10.1002/adem.202401964","DOIUrl":"https://doi.org/10.1002/adem.202401964","url":null,"abstract":"<p>Supercapacitors are great candidates for energy boosting, power, and memory backup. However, they suffer from low-energy density, relatively high cost, and carbon footprint problems due to their electrode materials, such as commonly used activated carbons (ACs). To prepare better renewable ACs, 11 biomass materials are pretreated with hydrothermal processing and then activated at high temperature with potassium hydroxide (KOH) in the present study. The prepared ACs are characterized for scanning electron microscopy images, atomic concentration, specific surface areas, electrical conductivity, cyclic voltammograms, and specific capacitance to determine their potential for supercapacitor application. The electrical conductivity reaches 0.47–1.23 S cm<sup>−1</sup>, and specific capacitance reaches 250–360 F g<sup>−1</sup> (at current density 20 A g<sup>−1</sup>), which are much higher than previously reported literature values (conductivity &lt;0.3 S cm<sup>−1</sup>, capacitance 40–160 F g<sup>−1</sup>) for biobased ACs, indicating great potential for supercapacitor application of our biobased ACs.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 9","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adem.202401964","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143908902","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correction to “Femtosecond Laser Carburization of WS2 Flakes to W2C for Enhanced Photothermal Conversion Efficiency” 对“飞秒激光碳化WS2薄片以提高W2C光热转换效率”的修正
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-04-03 DOI: 10.1002/adem.202500663
{"title":"Correction to “Femtosecond Laser Carburization of WS2 Flakes to W2C for Enhanced Photothermal Conversion Efficiency”","authors":"","doi":"10.1002/adem.202500663","DOIUrl":"https://doi.org/10.1002/adem.202500663","url":null,"abstract":"<p>Farman Ullah, Darren Chang, Fan Ye, Reza Karimi, Joseph Sanderson, Kevin Musselman. Femtosecond Laser Carburization of WS<sub>2</sub> Flakes to W<sub>2</sub>C for Enhanced Photothermal Conversion Efficiency. <i>Adv. Eng. Mater.</i> <b>2024</b>, <i>26</i>, 230222.</p><p>\u0000 https://advanced.onlinelibrary.wiley.com/doi/full/10.1002/adem.202302222\u0000 </p><p>The second author's surname name contained a typo in the final version of the article. This has been corrected to “Darren Chang”.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 9","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/adem.202500663","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143909392","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Janus Nanocomposite for Enhanced Bone Tissue Engineering: Polyurethane Nanofibers with Zoledronic Acid–Silk Fibroin and Silver-Infused Chitosan Hydrogel 用于增强骨组织工程的Janus纳米复合材料:聚氨酯纳米纤维与唑来膦酸-丝素蛋白和银注入壳聚糖水凝胶
IF 3.4 3区 材料科学
Advanced Engineering Materials Pub Date : 2025-04-01 DOI: 10.1002/adem.202402466
Rumysa Saleem Khan, Taha Umair Wani, Maida Lateef Tramboo, Anees Ellahi Khan, Anjum Hamid Rather, Hasham Shafi, Muheeb Rafiq, Sami-ullah Rather, Faheem A. Sheikh
{"title":"Janus Nanocomposite for Enhanced Bone Tissue Engineering: Polyurethane Nanofibers with Zoledronic Acid–Silk Fibroin and Silver-Infused Chitosan Hydrogel","authors":"Rumysa Saleem Khan,&nbsp;Taha Umair Wani,&nbsp;Maida Lateef Tramboo,&nbsp;Anees Ellahi Khan,&nbsp;Anjum Hamid Rather,&nbsp;Hasham Shafi,&nbsp;Muheeb Rafiq,&nbsp;Sami-ullah Rather,&nbsp;Faheem A. Sheikh","doi":"10.1002/adem.202402466","DOIUrl":"https://doi.org/10.1002/adem.202402466","url":null,"abstract":"<p>This work presents a hybrid material composed of a physically cross-linked poly(vinyl alcohol)/chitosan hydrogel with a pore size of 35 ± 10 nm loaded with silver (Ag) nanoparticles (NPs) with a diameter of 83.4 nm. This hydrogel is physically integrated with polyurethane (PU) nanofibers with an average diameter of 0.93 ± 0.5 μm that is preloaded with silk fibroin (SF)-encapsulated zoledronic acid (ZA) NPs (99.11 nm). However, the hybrid composites are hydrophilic, showing contact angles of &lt;90<sup>o</sup> due to incorporating hydrogel and NPs. Ultraviolet-visible spectrophotometry demonstrates a burst release of ZA from SF NPs within the first 6 h, followed by sustained release up to 48 h, after which the release rate declined. The degradation of hybrid composites in phosphate-buffered saline (PBS), protease type XIV, and human plasmin shows an increased degradation in the enzyme solutions of protease type XIV (42.6 ± 1.4%) and plasmin (52.6 ± 1.1%) than PBS (27.5 ± 1.9%) after 40 days. Biocompatibility is assessed using 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyl tetrazolium bromide and staining, revealing viability of &gt;300% and a higher cell density than the pure PU scaffold. These results suggest that the composite scaffolds offer a highly effective release of loaded NPs are suitable for healthcare products and devices for tissue engineering applications, especially deep wound defects involving bone injuries.</p>","PeriodicalId":7275,"journal":{"name":"Advanced Engineering Materials","volume":"27 9","pages":""},"PeriodicalIF":3.4,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143909074","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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