Petroleum Chemistry最新文献_第2页

Reducing the Ni2P Particle Size Through the Silicon–Aluminium Coordination for Efficient Hydrogenation Saturation of Naphthalene

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2025-01-28 DOI: 10.1134/S096554412408019X

Honggang Zhao, Zhe Wang, Houxiang Sun, Sha Cui

{"title":"Reducing the Ni2P Particle Size Through the Silicon–Aluminium Coordination for Efficient Hydrogenation Saturation of Naphthalene","authors":"Honggang Zhao, Zhe Wang, Houxiang Sun, Sha Cui","doi":"10.1134/S096554412408019X","DOIUrl":"10.1134/S096554412408019X","url":null,"abstract":"Though alumina and silica are well-known and widely used supports, they have notable drawbacks, such as the formation of the AlPO4 phase and inadequate metal–support interactions with nickel phosphide. This study investigates the synergistic effects of silica and alumina on the physicochemical properties and catalytic performance of nickel phosphide catalysts. Catalysts supported by alumina (Al2O3), silica (SiO2), and a composite silica-alumina (ASA) have been simultaneously prepared using a straightforward isopyknic co-impregnation method in order to eliminate the influence of preparation conditions. The results indicated that Ni2P/SiO2 exhibited poor dispersion, while Ni2P/Al2O3 showed a larger particle size along with the formation of the AlPO4 phase. The coordination between silicon and aluminum facilitated the reduction of nickel phosphate to nickel phosphide (Ni2P) and inhibited the formation of AlPO4. Ni2P/ASA demonstrated an improved dispersion and smaller particle size. Therefore, a comparative study of the Ni2P/SiO2, Ni2P/ASA, and Ni2P/Al2O3 performance revealed the superior catalytic efficacy of the SiO2–Al2O3 supported Ni2P in the naphthalene hydrogenation.","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"64 10","pages":"1202 - 1212"},"PeriodicalIF":1.3,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143109634","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A Novel Approach to the Extraction of Clusters from ZSM-5 Zeolite for Quantum-Chemical Search for Zn2+ Cation-Exchange Sites 一种从ZSM-5沸石中提取团簇的新方法用于Zn2+阳离子交换位的量子化学搜索

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2024-12-27 DOI: 10.1134/S0965544124080012

V. A. Koveza, A. S. Giliazutdinova, O. V. Potapenko

引用次数: 0

Identification of Signals from Individual Crystallographic T-Sites of HBEA Zeolite Framework in 27Al MAS NMR Spectra 27Al - MAS核磁共振光谱中HBEA分子筛框架单个晶体t位信号的识别

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2024-12-26 DOI: 10.1134/S0965544124080024

I. A. Kostyukov, Yu. G. Kolyagin, A. A. Rybakov, A. V. Larin, I. I. Ivanova

引用次数: 0

Physical-Chemical and Catalytic Properties of MEL and MFI Zeolites Obtained by Steam-Assisted Crystallization 蒸汽辅助结晶制备MEL和MFI沸石的理化性质和催化性能

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2024-12-26 DOI: 10.1134/S0965544124070077

V. A. Vorobkalo, A. G. Popov, A. V. Efimov, D. O. Bachurina, A. I. Nikiforov, I. I. Ivanova

{"title":"Physical-Chemical and Catalytic Properties of MEL and MFI Zeolites Obtained by Steam-Assisted Crystallization","authors":"V. A. Vorobkalo, A. G. Popov, A. V. Efimov, D. O. Bachurina, A. I. Nikiforov, I. I. Ivanova","doi":"10.1134/S0965544124070077","DOIUrl":"10.1134/S0965544124070077","url":null,"abstract":"Two series of zeolites, vis., the MEL and MFI types, with different Si/Al molar ratios were synthesized by a steam-assisted crystallization method, specifically dry gel conversion (DGC). Their physicochemical properties were characterized by low-temperature nitrogen adsorption, scanning electron microscopy, and X-ray fluorescence analysis. The acidic properties were examined by IR spectroscopy of adsorbed pyridine and 2,6-di-tert-butylpyridine as well as by ammonia temperature-programmed desorption. The DGC-synthesized zeolites were distinguished by high crystallinity, small crystal size, and well-developed surface. All the samples exhibited high activity and deactivation resistance in the oligomerization of a butane–butylene fraction. A comparative assessment of the catalytic performance the MEL and MFI samples demonstrated that the structural difference between the MEL and MFI types barely affects their deactivation resistance. Therefore, MEL zeolite is a valid alternative to the MFI type in the development of oligomerization catalysts.","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"64 9","pages":"1070 - 1078"},"PeriodicalIF":1.3,"publicationDate":"2024-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142889907","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Prediction of the Viscosity of Saturated Liquid and Unsaturated Gaseous Chlorofluorocarbons as Well as Hydrocarbon Mixtures Using the Peng–Robinson Equation of State

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2024-12-26 DOI: 10.1134/S0965544124070132

Yashar Tahmasbi, Mojtaba Saei Moghaddam, Mohammad Fani Kheshti

{"title":"Prediction of the Viscosity of Saturated Liquid and Unsaturated Gaseous Chlorofluorocarbons as Well as Hydrocarbon Mixtures Using the Peng–Robinson Equation of State","authors":"Yashar Tahmasbi, Mojtaba Saei Moghaddam, Mohammad Fani Kheshti","doi":"10.1134/S0965544124070132","DOIUrl":"10.1134/S0965544124070132","url":null,"abstract":"In order to determine the viscosity of liquid and gaseous chlorofluorocarbons, various experimental approaches and graphs have been developed, but they had a limited use. In this study, the viscosity of chlorofluorocarbons and hydrocarbon mixtures has been determined by applying a reliable model based n the Peng–Robinson cubic equation of state and the mixing rule for hydrocarbon mixtures. Finally, the Fminsearch algorithm has been used to optimize the result of 531 data points including 451 points for pure chlorofluorocarbons (167 points for saturated liquid chlorofluorocarbons, 284 points for unsaturated gaseous chlorofluorocarbons (R13, R32) and 80 points for binary mixtures. In this study, a large chlorofluorocarbon data set obtained for a wide pressure (3237–5805 kPa), and temperature (301.84–487.40 K) ranges has been used. The results show a similarity between the experimental data and the model results. For 17 pure chlorofluorocarbons considered in this study, the calculated average absolute deviation is 1.92%, and the average relative error for four two-component hydrocarbon mixtures is 5.28%. A difference between the predicted and the experimental viscosity for R13 and R32 was mainly 0.1. In general, the analyzed model is accurate and does not require the bulk density that represents its main advantage.","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"65 1","pages":"72 - 81"},"PeriodicalIF":1.3,"publicationDate":"2024-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143655381","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Composition and Performance of Modern Antistatic Additives for Diesel and Jet Fuels

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2024-12-26 DOI: 10.1134/S0965544124080115

D. R. Aleksanyan, V. D. Savelenko, N. O. Burov, M. A. Ershov, E. D. Gorbatyuk, U. A. Makhova, N. A. Klimov, E. S. Donskaya, A. V. Nizovtsev, E. O. Tikhomirova, D. Yu. Mukhina, A. A. Shevtsov, A. S. Lyadov

引用次数: 0

Kazakhstan Heavy Oils for Bitumen Production

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2024-12-26 DOI: 10.1134/S0965544124080140

S. K. Bukanova

引用次数: 0

Experimental Evaluation of Cetyltrimethylammonium Bromide and Arabic Gum Combined with Nanoparticles for Enhanced Oil Recovery Application in a Carbonate Oil Reservoir 十六烷基三甲基溴化铵和阿拉伯胶与纳米颗粒结合用于碳酸盐岩油藏提高石油采收率的实验评估

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2024-12-26 DOI: 10.1134/S0965544124080097

Samaneh Nodehi, Hossein Ali Akhlaghi Amiri, Ali Ahmadpour, Ramin Mohammadipour

{"title":"Experimental Evaluation of Cetyltrimethylammonium Bromide and Arabic Gum Combined with Nanoparticles for Enhanced Oil Recovery Application in a Carbonate Oil Reservoir","authors":"Samaneh Nodehi, Hossein Ali Akhlaghi Amiri, Ali Ahmadpour, Ramin Mohammadipour","doi":"10.1134/S0965544124080097","DOIUrl":"10.1134/S0965544124080097","url":null,"abstract":"Surfactants are known as potential candidates for enhancing oil recovery by affecting interfacial tension and wettability in different types of oil reservoirs including sandstones and carbonates. The performance of these agents, may be improved (in terms of stability and activity) by addition of nanoparticles. In this study, titanium dioxide (TiO2) and silica (SiO2) nanoparticles taken at different concentrations, were combined with two types of surfactants including cetyltrimethylammonium bromide (CTAB) and arabic gum (GA) and evaluated as the agents providing an enhanced oil recovery in a carbonate oil reservoir in Iran. The CTAB + SiO2, CTAB + TiO2, GA + SiO2, and GA + TiO2 combinations were analyzed in terms of stability (zeta potential test), surfactant adsorption (UV-visible analysis, interfacial tension (IFT), and rock wettability alteration), and oil recovery (spontaneous imbibition experiment). TiO2 nanoparticles improved the stability of surfactant suspensions. Moreover, they reduced adsorption of surfactants on a crushed carbonate powder. The visualization of the water film thickness in the presence of oil and rock powder confirmed that the addition of nanoparticles modified the wettability to be more water-wet. In addition, the GA + TiO2 combination was proved to be the most effective in enhancing the oil recovery in the studied carbonate oil reservoir, showing a significant increase (up to 17%) compared to other studied suspensions in the spontaneous imbibition processes.","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"65 1","pages":"43 - 56"},"PeriodicalIF":1.3,"publicationDate":"2024-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143655380","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Regeneration of Waste Motor Oils Using Membranes (A Review) 利用膜再生废机油（综述）

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2024-12-19 DOI: 10.1134/S0965544124080139

A. S. Lyadov, A. A. Kochubeev, A. P. Nebesskaya

引用次数: 0

Catalytic Cracking of n-Dodecane over P-Modified MFI Zeolites Synthesized by Steam-Assisted Conversion: Effect of SiO2/Al2O3 Ratio 蒸汽催化合成p改性MFI沸石上正十二烷的催化裂化：SiO2/Al2O3的影响

IF 1.3 4区工程技术

Petroleum Chemistry Pub Date : 2024-12-19 DOI: 10.1134/S0965544124060203

D. O. Bachurina, A. S. Giliazutdinova, O. V. Potapenko, I. I. Ivanova

{"title":"Catalytic Cracking of n-Dodecane over P-Modified MFI Zeolites Synthesized by Steam-Assisted Conversion: Effect of SiO2/Al2O3 Ratio","authors":"D. O. Bachurina, A. S. Giliazutdinova, O. V. Potapenko, I. I. Ivanova","doi":"10.1134/S0965544124060203","DOIUrl":"10.1134/S0965544124060203","url":null,"abstract":"The paper describes the physicochemical characterization and catalytic testing of MFI zeolites with different SiO2/Al2O3 ratios synthesized by steam-assisted crystallization (SAC) and modified with phosphorus (4 wt % loading). Their physicochemical properties were characterized by X-ray diffraction analysis, X-ray fluorescence analysis, scanning electron microscopy, low-temperature nitrogen adsorption, ammonia temperature-programmed desorption, and MAS NMR spectroscopy. Both the parent and P-modified MFI zeolites were then subjected to catalytic tests in cracking of n-dodecane. The yield of light olefins was enhanced only in two cases: when MFI zeolites with SiO2/Al2O3 ratios of 30–70 were modified with 4 wt % phosphorus and when parent MFI zeolites with SiO2/Al2O3 ratios of 100–220 were used. It was further found that, in terms of catalytic performance in the cracking of n-dodecane, the MFI zeolites synthesized by SAC were comparable to a commercially available MFI zeolite synthesized under hydrothermal conditions. Moreover, in contrast to the commercially available zeolite, phosphorus modification of the SAC-synthesized zeolite enhanced the yield of C2–C4 olefins.","PeriodicalId":725,"journal":{"name":"Petroleum Chemistry","volume":"64 9","pages":"1096 - 1105"},"PeriodicalIF":1.3,"publicationDate":"2024-12-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142889974","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0