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Effect of yield stress on two-phase flow characteristics of gangue cemented backfill slurry in straight horizontal pipeline 屈服应力对直水平管道中矸石胶结充填体两相流动特性的影响
IF 4.2 2区 工程技术
Advanced Powder Technology Pub Date : 2025-04-30 DOI: 10.1016/j.apt.2025.104899
Zehua Wang , Guorui Feng , Tingye Qi , Haochen Wang , Mengnan Zhan
{"title":"Effect of yield stress on two-phase flow characteristics of gangue cemented backfill slurry in straight horizontal pipeline","authors":"Zehua Wang ,&nbsp;Guorui Feng ,&nbsp;Tingye Qi ,&nbsp;Haochen Wang ,&nbsp;Mengnan Zhan","doi":"10.1016/j.apt.2025.104899","DOIUrl":"10.1016/j.apt.2025.104899","url":null,"abstract":"<div><div>The pipeline transportation is widely employed in mine backfill for delivering high concentration slurry. Based on the Euler-Euler two-fluid model, gangue cemented backfill slurry was abstracted as a dual-component structure consisting of fine gangue slurry (carrier fluid) and coarse gangue aggregates (transported particles). The influence of yield stress on the distribution of coarse aggregates, flow velocity, granular pressure, and pressure drop in GCB slurry is simulated. The results indicated that: 1) The coarse aggregates distribution was divided into coarse aggregate volume increasing zone (CG-VIZ), stable flow zone (SFZ), and coarse aggregate volume increasing zone (CG-VIZ). Increasing the yield stress can significantly reduce the coarse aggregate content and the extent of CG-VIZ resulting from segregation. 2) As the yield stress increases, the flow velocity transitions from an asymmetric ‘arch’ distribution to an asymmetric ‘plunger’ distribution in the vertical direction, while the asymmetry gradually diminishes. 3) The granular pressure distribution demonstrated a ‘U’ shape, with the maximum granular pressure occurring at the bottom of the pipeline. 4) The pressure loss of pipelines increases linearly with the increase of yield stress.</div></div>","PeriodicalId":7232,"journal":{"name":"Advanced Powder Technology","volume":"36 6","pages":"Article 104899"},"PeriodicalIF":4.2,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143887976","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Direct surface modification of a silica-based adsorbent for CO2 capture from coir fibers dissolved in a sulfur-free alkali-urea system 二氧化硅基吸附剂的直接表面改性,用于从溶解在无硫碱-尿素体系中的椰子纤维中捕获二氧化碳
IF 4.2 2区 工程技术
Advanced Powder Technology Pub Date : 2025-04-30 DOI: 10.1016/j.apt.2025.104912
Hendrix Abdul Ajiz , W. Widiyastuti , Heru Setyawan , Tantular Nurtono , Ni Made Intan Putri Suari , Lailatul Qomariyah , Yogi Wibisono Budhi , S. Suherman
{"title":"Direct surface modification of a silica-based adsorbent for CO2 capture from coir fibers dissolved in a sulfur-free alkali-urea system","authors":"Hendrix Abdul Ajiz ,&nbsp;W. Widiyastuti ,&nbsp;Heru Setyawan ,&nbsp;Tantular Nurtono ,&nbsp;Ni Made Intan Putri Suari ,&nbsp;Lailatul Qomariyah ,&nbsp;Yogi Wibisono Budhi ,&nbsp;S. Suherman","doi":"10.1016/j.apt.2025.104912","DOIUrl":"10.1016/j.apt.2025.104912","url":null,"abstract":"<div><div>The direct surface modification of silica using cellulose-based organosilane dissolved in a sulfur-free NaOH/urea solvent system was further investigated as a selective CO<sub>2</sub> adsorbent. Cellulose was dissolved at a low temperature of − 5°C, followed by mixing a silicate precursor as a silica source. Cellulose–carbamat complex grafting was carried out through a silica monomer condensation reaction using the sol–gel method. The anionic surfactant sodium lauryl sulfate (SLS) was added at various concentrations as a template to improve the particles’ physical characteristics. The process of particle formation and template removal was carried out in one stage in a spray drying system that followed the one droplet to one particle rule. Increasing the SLS concentration indicates a change in particle morphology from spherical to hollow, followed by an increase in particle size with a more uniform size distribution. The surface area and porosity of silica particles increased by up to fivefold when the SLS concentration was increased to 3 CMC. The physical characteristics that significantly increase show a linear influence on their ability to adsorb CO<sub>2</sub>. At a pressure of 6 bar, the CO<sub>2</sub> gas adsorption capacity of the silica adsorbent with the SLS 3 CMC template was almost eight times greater than that with the SLS 3 CMC template, reaching 12.85 mmol/g silica.</div></div>","PeriodicalId":7232,"journal":{"name":"Advanced Powder Technology","volume":"36 6","pages":"Article 104912"},"PeriodicalIF":4.2,"publicationDate":"2025-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143887979","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Innovative separation strategies for low-rank coal flotation: Filling self-generated pores with gutter oil collectors to enhance hydrophobic sites 低阶煤浮选的创新分离策略:用地沟油收集器填充自生孔隙以增强疏水部位
IF 4.2 2区 工程技术
Advanced Powder Technology Pub Date : 2025-04-29 DOI: 10.1016/j.apt.2025.104908
Chun-chen Nie , Xi-guang Li , Wen-tao Zhou , Haipei Dong , Xiang-nan Zhu
{"title":"Innovative separation strategies for low-rank coal flotation: Filling self-generated pores with gutter oil collectors to enhance hydrophobic sites","authors":"Chun-chen Nie ,&nbsp;Xi-guang Li ,&nbsp;Wen-tao Zhou ,&nbsp;Haipei Dong ,&nbsp;Xiang-nan Zhu","doi":"10.1016/j.apt.2025.104908","DOIUrl":"10.1016/j.apt.2025.104908","url":null,"abstract":"<div><div>Low-rank coal (LRC) has strong hydrophobicity, which leads to low efficiency in conventional flotation that coal particles need to be mixed with water first, making it difficult for collector molecules to replace water molecules. An innovative technology for microwave heating to remove moisture and dry adsorption of gutter oil collectors was proposed to make the collectors efficient in adsorbing on coal surface. Firstly, the particle morphology and phase composition of LRC were analysed through SEM and XRD to clarify the impact of particle morphology and mineral composition on floatability. Furthermore, the functional group composition and hydrophobic group content of the modified LRC were analysed by FTIR and XPS, respectively. Contact angle analysis and wrap angle analysis were used to investigate the stability of particle-bubble adhesion. Finally, flotation experiments and flotation kinetics analysis were conducted to verify the flotation characteristics of modified LRC. The SEM analysis results indicate that the high porosity of LRC can intercept more water and form a thick water film. The XPS analysis results indicate that the content of hydrophobic groups in LRC is only 61.69 %, which is the core reason why it is difficult for LRC to float. The content of hydrophobic groups C–C/C–H in modified LRC increases to 86.05 % after collector adsorption. In addition, the contact angle increases from 13.71° to 74.63°, further improving the adhesion stability between LRC particles and bubbles, while the wrap angle increases from 18° to 131° for 0.5–0.25 mm. Compared to raw coal, the combustible recovery of modified LRC increases from 23.13 % to 66.89 % with a collector dosage of 9000 g/t. The flotation kinetics results demonstrate that the flotation characteristics of various particle sizes of modified LRC have been significantly improved. Research provides an innovative and sustainable way to improve the flotation efficiency of LRC.</div></div>","PeriodicalId":7232,"journal":{"name":"Advanced Powder Technology","volume":"36 6","pages":"Article 104908"},"PeriodicalIF":4.2,"publicationDate":"2025-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143887978","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental and numerical study on the suppression of methane/coal dust hybrid explosion by DMMP water mist DMMP水雾抑制甲烷/煤尘混合爆炸的实验与数值研究
IF 4.2 2区 工程技术
Advanced Powder Technology Pub Date : 2025-04-29 DOI: 10.1016/j.apt.2025.104894
Mengjiao Xu , Shuangming Wei , Weidong Lu , Minggao Yu , Zhifeng Chen
{"title":"Experimental and numerical study on the suppression of methane/coal dust hybrid explosion by DMMP water mist","authors":"Mengjiao Xu ,&nbsp;Shuangming Wei ,&nbsp;Weidong Lu ,&nbsp;Minggao Yu ,&nbsp;Zhifeng Chen","doi":"10.1016/j.apt.2025.104894","DOIUrl":"10.1016/j.apt.2025.104894","url":null,"abstract":"<div><div>To investigate the effect of DMMP (dimethyl methyl phosphonate) water mist on the suppression of methane/coal dust hybrid explosion, a series of experiments on methane/coal dust hybrid explosion suppressed by varying DMMP water mist (0 % DMMP-2.0 % DMMP) were carried out in a 20 L spherical device. The experimental results show that the flame propagation speed, maximum explosion pressure rise rate (<em>dP/dt</em>)<sub>max</sub> and explosion index <em>K</em><sub>G</sub> first increase and then decrease with the increase of DMMP concentration. The optimal explosion suppression concentration of DMMP water mist for methane/coal dust hybrid explosion is 1.2 %. Besides, a new kinetic model of methane/coal dust hybrid explosion suppressed by DMMP water mist was established to analyze the chemical kinetics of the elementary reaction under different initial temperature (<em>T</em><sub>0</sub> = 1250–1600 K) and initial pressures (<em>P</em><sub>0</sub> = 0.08–0.13 MPa). The numerical results revealed that the elementary reaction R1: H + O<sub>2</sub> = O + OH is the dominant elementary reaction to enhance adiabatic flame temperature. Phosphorus containing small molecules HOPO and HOPO<sub>2</sub> are important intermediate products in the DMMP reaction process, playing a crucial role in the suppression of methane/coal dust hybrid explosion by DMMP water mist.</div></div>","PeriodicalId":7232,"journal":{"name":"Advanced Powder Technology","volume":"36 6","pages":"Article 104894"},"PeriodicalIF":4.2,"publicationDate":"2025-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143887977","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mangifera indica phytochemical enriched ZnO-Amphotericin B Nanoconjugates: Enhanced hydrophilicity, reduced toxicity and pH-sensitive release for targeted anti-Candida therapy 芒果植物化学富集锌-两性霉素B纳米偶联物:增强亲水性,降低毒性和ph敏感释放靶向抗念珠菌治疗
IF 4.2 2区 工程技术
Advanced Powder Technology Pub Date : 2025-04-25 DOI: 10.1016/j.apt.2025.104895
Divya Mathew , Benny Thomas , N.M. Sudheep , Surya Nair , E.K. Radhakrishnan
{"title":"Mangifera indica phytochemical enriched ZnO-Amphotericin B Nanoconjugates: Enhanced hydrophilicity, reduced toxicity and pH-sensitive release for targeted anti-Candida therapy","authors":"Divya Mathew ,&nbsp;Benny Thomas ,&nbsp;N.M. Sudheep ,&nbsp;Surya Nair ,&nbsp;E.K. Radhakrishnan","doi":"10.1016/j.apt.2025.104895","DOIUrl":"10.1016/j.apt.2025.104895","url":null,"abstract":"<div><div>Amphotericin B (AmB) faces limitations in antifungal applications due to toxicity and poor solubility. This study developed AmB conjugate with green-synthesized zinc oxide nanoparticles (gZnONPs) using <em>Mangifera indica</em> leaf extract (MLE) to enhance pH sensitivity and hydrophilicity. FTIR analysis confirmed AmB conjugation and MLE phytocore on the surface of the gZnONPs, while UV–Vis spectroscopy showed a red shift from 362 to 394 nm after AmB conjugation, indicating successful binding. The conjugate showed increased solubility from 0.31 to 125 µg/mL and enhanced hydrophilicity (contact angle reduced from 53° to 34°). The enhanced saturation solubility might be due to NP size effects, reduced crystallinity, phytochemical-induced hydrophilicity, and effective drug encapsulation, collectively improving the bioavailability and therapeutic efficacy of AmB at the target site. The AmB release profile showed pH-sensitive, sustained release, with higher rates at infection-site (pH 5.5), ensuring prolonged therapeutic effects. Antifungal tests demonstrated significant zone of inhibition for the conjugate (47 mm) against <em>Candida albicans</em>, outperforming MLE (34 mm), AmB (41 mm) and ZnONPs (37 mm) alone. The conjugate showed 2.4-fold higher LC<sub>50</sub> (446.51 μg/mL) over AmB (186.39 μg/mL), suggesting reduced toxicity, likely due to phytochemical capping minimizing non-specific interactions with healthy cells and pH-sensitive, targeted release. Further, the hemolysis study demonstrated that ZnONPs significantly reduced AmB-induced RBC lysis (4.1 % at 24 h vs. 18.1 % for pure AmB), outperforming lipid-based formulations (9–14 %), highlighting their potential as a safer nanocarrier for AmB delivery while mitigating dose-dependent hemolysis. These findings highlight the potential of gZnONPs as an effective nanocarrier for AmB, offering enhanced solubility, targeted antifungal activity, and reduced toxicity, making it a promising alternative to conventional formulations.</div></div>","PeriodicalId":7232,"journal":{"name":"Advanced Powder Technology","volume":"36 6","pages":"Article 104895"},"PeriodicalIF":4.2,"publicationDate":"2025-04-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143874254","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Double perovskite of Ca3WO6 supported Ni-based catalysts for hydrogen production via auto-thermal reforming of acetic acid Ca3WO6双钙钛矿负载的镍基醋酸自热重整制氢催化剂
IF 4.2 2区 工程技术
Advanced Powder Technology Pub Date : 2025-04-24 DOI: 10.1016/j.apt.2025.104888
Jianhong Li , Qi Chen , Mao Gan , Jinbo Liu , Ying Su , Lihong Huang
{"title":"Double perovskite of Ca3WO6 supported Ni-based catalysts for hydrogen production via auto-thermal reforming of acetic acid","authors":"Jianhong Li ,&nbsp;Qi Chen ,&nbsp;Mao Gan ,&nbsp;Jinbo Liu ,&nbsp;Ying Su ,&nbsp;Lihong Huang","doi":"10.1016/j.apt.2025.104888","DOIUrl":"10.1016/j.apt.2025.104888","url":null,"abstract":"<div><div>Acetic acid (HAc) derived from biomass is a rich resource for production of green hydrogen via auto-thermal reforming (ATR), while Ni-based catalysts for ATR of HAc are hindered by concerns of coke deposition, oxidation and sintering of active components. Herein, Ni-Ca-W-O catalysts with double perovskite structure were prepared by the Pechini method and employed in ATR reaction. The characterization results indicated that phase of Ca<sub>3</sub>WO<sub>6</sub> with double perovskite structure was formed via introducing W species into CaO phase, while oxygen defect sites and abundant oxygen vacancies were found and effective to constrain coke deposition during ATR. Furthermore, with Ni species entering the Ca<sub>3</sub>WO<sub>6</sub> lattice, there was strong interaction within Ni/Ca<sub>3</sub>WO<sub>6</sub>, forming stable Ni-Ca-W-O active centers with improved resistance to either oxidation or sintering of Ni<sup>0</sup>. As a result, the preferred Ni<sub>0.08</sub>Ca<sub>0.32</sub>W<sub>0.07</sub>O<sub>0.61±δ</sub> catalyst maintained high HAc conversion at 100 % and H<sub>2</sub> yield near 2.52 mol-H<sub>2</sub>/mol-HAc, showing potential for hydrogen production via ATR of HAc.</div></div>","PeriodicalId":7232,"journal":{"name":"Advanced Powder Technology","volume":"36 6","pages":"Article 104888"},"PeriodicalIF":4.2,"publicationDate":"2025-04-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143868292","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Facile synthesis of silver loaded bioactive glass ceramic and reinforced composite scaffold using acrylic polymer for bone tissue engineering applications 用于骨组织工程的载银生物活性玻璃陶瓷和丙烯酸增强复合支架的简易合成
IF 4.2 2区 工程技术
Advanced Powder Technology Pub Date : 2025-04-23 DOI: 10.1016/j.apt.2025.104892
K. Venkatesan , Kotikalapudi Sreeramachandra Karthik , Ann Mary Mathew , P.V. Sreya , Sarada P Mallick , Deepak K. Pattanayak
{"title":"Facile synthesis of silver loaded bioactive glass ceramic and reinforced composite scaffold using acrylic polymer for bone tissue engineering applications","authors":"K. Venkatesan ,&nbsp;Kotikalapudi Sreeramachandra Karthik ,&nbsp;Ann Mary Mathew ,&nbsp;P.V. Sreya ,&nbsp;Sarada P Mallick ,&nbsp;Deepak K. Pattanayak","doi":"10.1016/j.apt.2025.104892","DOIUrl":"10.1016/j.apt.2025.104892","url":null,"abstract":"<div><div>Bioactive glasses are mainly used in tissue engineering applications such as fabrication of resorbable scaffolds, bioactive composite bone cements, etc., as they release Na<sup>+</sup>, Ca<sup>2+</sup>, Mg<sup>2+</sup>, PO<sub>4</sub><sup>3-</sup> ions, which aid in repairing and regenerating damaged tissues. The inability of fabricated composite scaffolds or bone cements to impart antimicrobial activity may lead to bacterial infection and other inflammatory responses. This work attempted to develop acrylic polymer and bioactive glass composite bone cement with antibacterial activity. Initially, bioactive glass powders were synthesized by a simple sol–gel method with different concentrations of silver (Ag) to induce antibacterial properties. The physicochemical properties, like thermal stability and phase change, etc. with respect to the concentration of Ag loading were evaluated. The results showed that no significant structural and compositional change occurred due to heat treatment and the amorphous phase could be maintained upto 700°C. Electrochemical analysis (Differential Pulse Voltammetry) of bioactive glass in simulated body fluid showed the peak current signifying the gradual release of Ag<sup>+</sup> ions. The released Ag<sup>+</sup> ions from the bioactive glass powders showed inhibition against Gram-positive <em>Staphylococcus aureus</em> and Gram-negative <em>Escherichia coli</em> bacterial systems. The cytocompatibility study of Ag-loaded bioactive glasses in MG-63 human osteoblast like cell lines showed no toxic effect for all the concentration ranges attempted. The developed Ag-loaded bioactive glass powder with optimum antimicrobial property and good cell viability was subsequently used as reinforcement in Poly Methyl Methacrylate (PMMA) matrix to develop porous composite scaffold using porogen leaching technique. Mechanical study (compression test) proved that the fabricated scaffolds have sufficient rigidity, and the thermal degradation phenomenon could be controlled by the addition of bioactive glass powders to the PMMA matrix. This interconnected porous scaffold with good bioactivity, antimicrobial property, mechanical rigidity and cell compatibility is expected to be potent in bone tissue engineering applications.</div></div>","PeriodicalId":7232,"journal":{"name":"Advanced Powder Technology","volume":"36 6","pages":"Article 104892"},"PeriodicalIF":4.2,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143863313","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Impact of particle compositions on screening performance: Modeling and prediction via data segmentation approach 颗粒组成对筛分性能的影响:通过数据分割方法建模和预测
IF 4.2 2区 工程技术
Advanced Powder Technology Pub Date : 2025-04-23 DOI: 10.1016/j.apt.2025.104901
Jinpeng Qiao, Yanze Wang, Jinshuo Yang, Wei Wang, Chenlong Duan
{"title":"Impact of particle compositions on screening performance: Modeling and prediction via data segmentation approach","authors":"Jinpeng Qiao,&nbsp;Yanze Wang,&nbsp;Jinshuo Yang,&nbsp;Wei Wang,&nbsp;Chenlong Duan","doi":"10.1016/j.apt.2025.104901","DOIUrl":"10.1016/j.apt.2025.104901","url":null,"abstract":"<div><div>Variations in particle composition along the screen pose significant challenges for modeling screening dynamics. This study examines the influence of feeding conditions on screening efficiency through a segmental approach and investigates various machine-learning algorithms for predictive modeling. Segmentation and transformation of passing rate curves were clearly observed and discussed. A novel algorithm was developed to predict screening efficiency for screens of varying lengths, and a method for segmenting simulated data for machine learning modeling is proposed. Results show that the mass content of easy-to-sieve particles affects segmental screening efficiency oppositely to that of difficult-to-sieve particles. Specifically, increasing the mass content of easy-to-sieve particles narrows the crowded screening region while enhancing overall screening efficiency. For particles of different sizes, K-Nearest Neighbors Regression, Multilayer Perceptron Regression, and Support Vector Regression provide effective prediction models. For screens of varying lengths, Support Vector Regression outperforms the others, achieving an average deviation of less than 3%.</div></div>","PeriodicalId":7232,"journal":{"name":"Advanced Powder Technology","volume":"36 6","pages":"Article 104901"},"PeriodicalIF":4.2,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143863403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In-depth analysis of surface selective adsorption and interfacial mechanisms in the efficient flotation separation of magnesite and dolomite with the environmentally friendly inhibitor baicalin 黄芩苷在菱镁矿与白云石浮选分离中的表面选择性吸附及界面机理研究
IF 4.2 2区 工程技术
Advanced Powder Technology Pub Date : 2025-04-23 DOI: 10.1016/j.apt.2025.104903
Xiaoqi Ban , Jin Yao , Wanzhong Yin , Taozhong Zhang , Wenju Sun , Weifan Du , Yulian Wang
{"title":"In-depth analysis of surface selective adsorption and interfacial mechanisms in the efficient flotation separation of magnesite and dolomite with the environmentally friendly inhibitor baicalin","authors":"Xiaoqi Ban ,&nbsp;Jin Yao ,&nbsp;Wanzhong Yin ,&nbsp;Taozhong Zhang ,&nbsp;Wenju Sun ,&nbsp;Weifan Du ,&nbsp;Yulian Wang","doi":"10.1016/j.apt.2025.104903","DOIUrl":"10.1016/j.apt.2025.104903","url":null,"abstract":"<div><div>Due to the similarities in crystal structure and chemical composition, the surface electric properties, wettability, and interfacial characteristics of magnesite and dolomite are highly similar, posing significant challenges in flotation separation. This study investigates the selective inhibition mechanism of the environmentally friendly depressant baicalin (BA) on dolomite in a sodium oleate (NaOl) flotation system, focusing on interfacial behavior control. Micro-flotation tests showed successful separation of magnesite and dolomite under optimal reagent conditions (pH 10.0, BA concentration of 60 mg/L, NaOl concentration of 120 mg/L). Zeta potential and contact angle measurements indicated that BA increased the negative charge on dolomite and significantly reduced its hydrophobicity, with minimal impact on magnesite. FTIR and XPS analyses revealed strong chemisorption of BA’s hydroxyl groups on calcium sites of dolomite, with weaker affinity for magnesium sites. AFM imaging showed a notable increase in the surface roughness of dolomite after BA treatment, further confirming selective adsorption. A flotation separation model was developed based on micro-flotation and characterization results, shedding light on the separation mechanism and the differences in surface adsorption and interfacial behavior of magnesite and dolomite.</div></div>","PeriodicalId":7232,"journal":{"name":"Advanced Powder Technology","volume":"36 6","pages":"Article 104903"},"PeriodicalIF":4.2,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143863404","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Prediction of acoustic agglomeration enhanced by solid seed particles using the DSMC method 用DSMC方法预测固体种子颗粒增强的声团聚
IF 4.2 2区 工程技术
Advanced Powder Technology Pub Date : 2025-04-23 DOI: 10.1016/j.apt.2025.104902
Junxu Su , Zhihao Wu , Fengxian Fan , Xiaohong Hu , Mingxu Su
{"title":"Prediction of acoustic agglomeration enhanced by solid seed particles using the DSMC method","authors":"Junxu Su ,&nbsp;Zhihao Wu ,&nbsp;Fengxian Fan ,&nbsp;Xiaohong Hu ,&nbsp;Mingxu Su","doi":"10.1016/j.apt.2025.104902","DOIUrl":"10.1016/j.apt.2025.104902","url":null,"abstract":"<div><div>Acoustic agglomeration enhanced by large-sized solid seed particles is investigated using the direct simulation Monte Carlo (DSMC) method. The process of acoustic agglomeration is revealed in terms of temporal evolution of velocities, diameters, and number weights of simulated particles, as well as normalized concentration and average diameter of small particles. Furthermore, the enhancement of acoustic agglomeration by the solid seed particles is evaluated at varying parameters. The results show that the agglomeration performance is enhanced within a shorter residence time when the solid seed particles are present. Increasing acoustic intensity or solid seed particle concentration leads to more efficient acoustic agglomeration, while the acoustic frequency, particularly beyond 2 kHz, has little effect on agglomeration performance. Moreover, a noticeable increase in agglomeration efficiency is observed when the seed particle diameter increases from 20 to 40 µm. However, once it exceeds 40 µm, the increase in agglomeration efficiency diminishes.</div></div>","PeriodicalId":7232,"journal":{"name":"Advanced Powder Technology","volume":"36 6","pages":"Article 104902"},"PeriodicalIF":4.2,"publicationDate":"2025-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143863563","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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