Advanced Industrial and Engineering Polymer Research最新文献

{"title":"Advancements in Poly(ionic liquid) composites with carbon nanomaterials","authors":"Hui Li ,&nbsp;Jie Gao ,&nbsp;Zhiyong Li ,&nbsp;Yan Zhang ,&nbsp;Jun Zhang ,&nbsp;Shiguo Zhang","doi":"10.1016/j.aiepr.2024.08.001","DOIUrl":"10.1016/j.aiepr.2024.08.001","url":null,"abstract":"<div><div>Carbon nanomaterials have become essential in modern daily life. Their porous nature and good electrical conductivity are critical for composite applications. However, their inherent van der Waals forces and π-π interactions often result in spontaneous aggregation, which significantly hinders the uniform dispersion of carbon materials in polymer matrices. Establishing interactions between poly(ionic liquid) (PIL) and carbon materials ensures excellent compatibility. Integrating carbon materials with PIL markedly enhances mechanical strength, electrical conductivity, and thermal stability, benefiting the electronics, energy storage, and automotive industries. A thorough understanding of the physical and chemical properties of PILs is crucial for tailoring composite materials to specific applications, enhancing processing capabilities, and boosting performance. This article reviews recent advancements in PIL composites incorporating carbon nanomaterials and outlines future challenges in their development.</div></div>","PeriodicalId":7186,"journal":{"name":"Advanced Industrial and Engineering Polymer Research","volume":"8 2","pages":"Pages 196-210"},"PeriodicalIF":9.9,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143852253","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Phase separation behavior of polymer modified asphalt by molecular dynamics and phase field method: A review","authors":"Lin Chen ,&nbsp;Ming Liang ,&nbsp;Xin Wang ,&nbsp;Xue Xin ,&nbsp;Zhenchao Chen ,&nbsp;Yuepeng Jiao ,&nbsp;Jianjiang Wang ,&nbsp;Yunfeng Zhang ,&nbsp;Linping Su ,&nbsp;Zhanyong Yao","doi":"10.1016/j.aiepr.2024.12.002","DOIUrl":"10.1016/j.aiepr.2024.12.002","url":null,"abstract":"<div><div>The research on the micro-compatibility mechanisms of polymer-modified asphalt is crucial for the field of road engineering. In-depth exploration and understanding in this area is highly challenged due to the current lack of sophistication in research tools and the lack of precision in research results. This paper reviews the research progress on phase separation in modified asphalt from the perspectives of phase field theory and molecular dynamics theory, while thoroughly analyzing the strengths and weaknesses of both approaches. Explore a new simulation method using phase field theory coupled with molecular dynamics parameters to more comprehensively and accurately model the phase separation behavior and characteristics of modified asphalt. This paper summarizes the simulation process of phase separation in modified asphalt based on phase field theory. By combining this with fluorescence microscopy experiments, it establishes and tracks the evolution of micro and mesoscopic phase states in modified asphalt over time. By utilizing molecular dynamics to construct molecular models of modified asphalt, this paper identifies key parameters, i.e. interaction parameters and migration coefficients, that control the phase field model of modified asphalt. It reveals the laws of phase behavior in modified asphalt from both micro and mesoscopic perspectives. By comparing fluorescence microscopy experiments and analyzing the degree of image overlap with image analysis technology, the consistency of simulation results can be demonstrated. This approach provides a theoretical reference for studying phase separation phenomena in the field of polymer science.</div></div>","PeriodicalId":7186,"journal":{"name":"Advanced Industrial and Engineering Polymer Research","volume":"8 2","pages":"Pages 157-167"},"PeriodicalIF":9.9,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143852251","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis of an environmentally friendly P–N synergistic flame retardant and its effect on the properties of epoxy resin","authors":"Hao Wang,&nbsp;Yinjie Wang,&nbsp;Chuang Yu,&nbsp;Xiaohui Xing,&nbsp;Peng Lin,&nbsp;Jiping Liu,&nbsp;Ye-Tang Pan","doi":"10.1016/j.aiepr.2024.12.001","DOIUrl":"10.1016/j.aiepr.2024.12.001","url":null,"abstract":"<div><div>Additive flame retardants are increasingly frequently used in the current research on flame retardant techniques for polymer materials. In this work, 2-aminopyrazine and spiro-phosphorus oxychloride (SPDPC) were combined to create an environmentally friendly flame-retardant aminopyrazine spiro pentanol bisphosphonate (APPC). This solution addressed the issues of conventional flame retardant dispersion and low flame-retardant efficiency. The LOI value can reach 29.7 % with the addition of 7 wt% APPC, and the UL-94 test was able to achieve the V-0 rating. Furthermore, a remarkable decrease of 62.23 % in the peak heat release rate (pHRR), 51.23 % in the peak value of the CO production rate, and 63.57 % in the peak value of the CO₂ production rate was shown by the cone calorimeter experiment. The heat insulation and smoke suppression effect is also exceptional. According to the analysis of TG-FTIR, IR, XPS and SEM results, there is sufficient evidence that APPC as a phosphorus-nitrogen intumescent flame retardant (IFR), can produce beneficial effects in both catalyzing char formation and inhibiting toxic smoke production.</div></div>","PeriodicalId":7186,"journal":{"name":"Advanced Industrial and Engineering Polymer Research","volume":"8 2","pages":"Pages 279-288"},"PeriodicalIF":9.9,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143852257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"The role of polysaccharide-based biodegradable soft polymers in the healthcare sector","authors":"Zia Ullah Arif","doi":"10.1016/j.aiepr.2024.05.001","DOIUrl":"10.1016/j.aiepr.2024.05.001","url":null,"abstract":"<div><div>Bio-based polymers have garnered significant interest across the manufacturing industry, global economy, and various engineering disciplines such as packaging, tissue engineering, controlled drug delivery, wound dressing, and textiles. In the current era, bio-based polymers, notably polysaccharides, offer a promising platform for constructing intricate and versatile structures in the biomedical sector. These structures encompass applications in tissue engineering and regenerative medicine (TERM), drug delivery devices, coatings for biomedical devices, and wearable sensors, thanks to their distinctive features such as inherent biocompatibility, flexibility, stretchability, mechanical strength, renewability, physiological activity, and favorable biological environment. This review offers a concise overview of diverse types of polysaccharide-based polymers and their composites, properties, and interactions with specific cells and tissues. The review also encompasses recent progress in tissue scaffolds designed for cartilage, skin, neural, vascular, cardiac, and bone regeneration, employing both conventional and modern manufacturing techniques. Additionally, it delves into the development of other biodegradable biomedical devices, including drug delivery systems (DDSs), antibacterial coatings on medical devices, wearable sensors, and electronic devices for the healthcare sector. Furthermore, it also elucidates research directions and future perspectives while emphasizing the importance of regulatory approvals and commitment to environmental sustainability. Finally, this well-organized and critical review is expected to assist practitioners and researchers in gaining a deeper understanding of current trends, challenges, and potential solutions, thereby harnessing the immense potential of polysaccharide-based biomaterials in the healthcare system. Additionally, the utilization of polysaccharides in the biomedical sector aligns with principles of nature, contributing to the reduction of carbon dioxide emissions and supporting the Sustainable Development Goals of the United Nations.</div></div>","PeriodicalId":7186,"journal":{"name":"Advanced Industrial and Engineering Polymer Research","volume":"8 1","pages":"Pages 132-156"},"PeriodicalIF":9.9,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141032764","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"PDMS microspheres as rheological additives for PDMS-based DIW inks","authors":"Utkarsh Ramesh ,&nbsp;Jonathan Miller ,&nbsp;Bryce Stottelmire ,&nbsp;James Beach ,&nbsp;Steven Patterson ,&nbsp;Laura Cumming ,&nbsp;Sabrina Wells Torres ,&nbsp;Dakota Even ,&nbsp;Petar Dvornic ,&nbsp;Cory Berkland","doi":"10.1016/j.aiepr.2024.06.001","DOIUrl":"10.1016/j.aiepr.2024.06.001","url":null,"abstract":"<div><div>Direct Ink Writing holds vast potential for additive manufacturing with broad material compatibility as long as appropriate rheological properties are exhibited by the material of choice. Additives are often included to attain the desired rheological properties for printing, but these same additives can yield products with undesirable mechanical properties. For example, silica fillers are used to create silicone inks appropriate for printing but yield cured structures that are too stiff. In this work, we investigate the applicability of PDMS microspheres as a rheological and thixotropic additive for PDMS based DIW inks. We utilize a facile oil-in-water emulsion method to reproducibly obtain small (∼5 μm) PDMS microspheres, which are then incorporated into PDMS-based inks. More traditional inks with fumed silica and thixotropic additive were compared with inks containing PDMS microspheres at equal volume loadings to determine whether the PDMS microspheres could impart the desired rheological properties for DIW. Inks including PDMS microspheres exhibited surprising thixotropic effects, which enabled prints with fidelity analogous to traditional ink employing silica filler, while producing mechanically softer prints.</div></div>","PeriodicalId":7186,"journal":{"name":"Advanced Industrial and Engineering Polymer Research","volume":"8 1","pages":"Pages 1-9"},"PeriodicalIF":9.9,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141397230","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Towards a new era of 2D materials-based multifunctional composite films: From innovation to evolution","authors":"Muhammad Yasir Khalid ,&nbsp;Rehan Umer","doi":"10.1016/j.aiepr.2024.04.002","DOIUrl":"10.1016/j.aiepr.2024.04.002","url":null,"abstract":"<div><div>Novel 2D materials are now at the forefront of developing advanced multifunctional composite films, due to their fascinating properties. Particularly, graphene and MXene-based 2D materials are recognized as promising candidates for multifunctional materials, due to their ability to enhance structure–function relationships and integrate with laminated composites. As expected, high mass production from low-cost and facile fabrication techniques for multifunctional composite films plays a pivotal role in their practical applications. Herein, we have covered a broad spectrum of 2D materials overview, covering all contributions to this field and summarizing the most pertinent literature available for developing multifunctional composite films which are attractive for advanced aircraft applications. Moreover, the integrated functions of the 2D materials-based multifunctional composite films such as sensing and actuation behaviour, thermal conductivity, and electromagnetic interference (EMI) shielding effectiveness are explored and their mechanisms for superior performance are elucidated. Additionally, we critically discuss the prevailing challenges and offer perspectives on this rapidly advancing field.</div></div>","PeriodicalId":7186,"journal":{"name":"Advanced Industrial and Engineering Polymer Research","volume":"8 1","pages":"Pages 76-112"},"PeriodicalIF":9.9,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140762307","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Highly-efficient flame-retarding unsaturated polyester resin via the designation of an expansive flame retardant","authors":"Ying-Ming Li,&nbsp;Shuang-Lin Hu,&nbsp;Hang-Ping Fang,&nbsp;Yao Deng,&nbsp;Chang-De Yang","doi":"10.1016/j.aiepr.2024.04.001","DOIUrl":"10.1016/j.aiepr.2024.04.001","url":null,"abstract":"<div><div>Unsaturated polyester resins (UPR) are commonly used in electronics manufacturing and traditional construction, but their inherent flammability greatly limits their use. An expansive flame retardant EZ was prepared via the simple ionic reaction between the 2-Aminothiazole (AMZ) and ethylene diamine tetra methylene phosphoric acid (EDTMP). The thermal decomposition process of EZ and UPR/EZ and the flame retardancy of the compound were studied. The flame retardancy mechanism of EZ in UPR was analyzed in detail. When the EZ content was 15 wt%, the flame-retardant grade of the composite reached V-0. The flame-retardant efficiency was very high mainly through the interaction of gas phase and condensed phase. Interestingly, flame retardant EZ can perform expansion crosslinking in UPR, which can effectively promote carbon formation in UPR. Moreover, EZ itself can also expand to form dense and continuous carbon layers in UPR, which further elucidates the flame-retardant mechanism.</div></div>","PeriodicalId":7186,"journal":{"name":"Advanced Industrial and Engineering Polymer Research","volume":"8 1","pages":"Pages 10-19"},"PeriodicalIF":9.9,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140778858","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synergistic enhancement in mechanical properties of graphene/MWCNT reinforced Polyaryletherketone – carbon fiber multi-scale composites: Experimental studies and finite element analysis","authors":"Sarath Kumar Painkal ,&nbsp;Meera Balachandran ,&nbsp;Karingamanna Jayanarayanan ,&nbsp;Nagaarjun Sridhar ,&nbsp;Sanjeev Kumar","doi":"10.1016/j.aiepr.2024.02.002","DOIUrl":"10.1016/j.aiepr.2024.02.002","url":null,"abstract":"<div><div>This investigation focuses on the synergistic performance improvement in graphene/MWCNT reinforced Polyaryletherketone (PAEK) - carbon fiber (CF) multi-scale composites. FTIR revealed the chemical interactions while HRTEM, XRD and 3D X-ray microscopy gave insight into nanofiller dispersion and microstructural features. The functional groups on nanofillers along with structural features integrated various components of the multi-scale composites by formation of graphene/MWCNT/CF complex network that provided larger interfacial area, bridging effect and physico-chemical interaction with PAEK while restricting its segmental mobility. Multi-scale composites displayed significantly improved strength, fracture toughness, interlaminar shear strength, glass transition temperature and tribological performance. Under dynamic load, graphene/MWCNT reinforcement of matrix and CF synergistically increases the storage modulus and energy absorption characteristics. Wear and fracture surface morphology of nano and multi-scale composites showed ductile failure confirming interfacial adhesion. The failure behavior in experimental studies was supported by Abaqus/Explicit-based FEM models of fracture toughness response. This work provides a promising avenue to develop next generation high performance thermoplastic composites for structural applications.</div></div>","PeriodicalId":7186,"journal":{"name":"Advanced Industrial and Engineering Polymer Research","volume":"8 1","pages":"Pages 20-36"},"PeriodicalIF":9.9,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140083228","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Fullerene-containing modifier of magnetoactive elastomer","authors":"М.A. Vasilyeva,&nbsp;F.Yu. Sharikov,&nbsp;I.A. Bogdanov","doi":"10.1016/j.aiepr.2024.02.001","DOIUrl":"10.1016/j.aiepr.2024.02.001","url":null,"abstract":"<div><div>Magnetoactive elastomer is a functional material whose properties are controlled by the parameters of the external magnetic field. A modifier that creates ordered structures with controlled nanoscale morphology is capable of intensifying the ability of a material to transfer charge.</div><div>The modifier was obtained by dissociating C₆₀ fullerene in eugenol at an elevated temperature in a water bath for 6 h. The fullerene content in the samples was 3.5 g/L. The preparation of 3 groups of modifier solutions to study their properties took 60 days. Two groups included solutions obtained through diffuse dissolution, one group - with an additional mechanical action. A study of rheological, optical and electrical conductivity properties was carried out to assess changes in the structure of the solutions. During the studies, thixotropic deposition of the air capsule was noted in some samples. To describe the hydraulic size of deposited objects, a nonlinear dependence is formulated. Spectral analysis of the solutions revealed differences in the optical properties of the samples obtained by various methods. The optical activity of those that have not been subjected to an additional impact is increasing over time. This causes a change in the solution structure and the conformation of the complexes of the solvent molecular structure and C₆₀. Ultimately, this leads to noticeable changes in electrical conductivity properties. The change in the resistivity values of some samples relative to the solvent is associated with the influence of the formed structural aggregation of fullerene molecules, as well as with several types of polarization interactions. Classification of the influence of conformational and electronic characteristics of solvent molecules made it possible to systematize the factors influencing the solvent dissolving ability. The formation of non-centrosymmetric structures in solutions in the form of fractal aggregates of dissociated fullerene was noted. The approach to describing the model for the formation of a cluster structure is based on the principle of increasing the fractional dimension during the dissociation process. Aggregation, limited by diffusion processes, proceeds to limit the reaction rate; at the final stage, spatial limitation dominates.</div><div>Studying the molecular dynamics of aggregates formation in various solutions allows improved understanding the principles of a fractal structure formation. The results obtained will be used in the development of conductive functional polymers with controlled properties.</div></div>","PeriodicalId":7186,"journal":{"name":"Advanced Industrial and Engineering Polymer Research","volume":"8 1","pages":"Pages 63-75"},"PeriodicalIF":9.9,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139872244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Magnetic-responsive triple shape memory polymer from bio-based benzoxazine/urethane polymer alloys with iron oxide nanoparticles","authors":"Kullanard Ruenpanya ,&nbsp;Phattarin Mora ,&nbsp;Panagiotis Karagiannidis ,&nbsp;Kittipon Bunyanuwat ,&nbsp;Sarawut Rimdusit","doi":"10.1016/j.aiepr.2024.07.001","DOIUrl":"10.1016/j.aiepr.2024.07.001","url":null,"abstract":"<div><div>Novel magnetic-responsive triple shape memory polymers (SMPs) derived from bio-based benzoxazine-urethane (V-fa/PU) polymer alloys containing iron oxide nanoparticles (Fe₃O₄ NPs) were developed in this work. Shape memory effect and curing behavior of the alloys were investigated at various bio-based PU contents. The polymerization of V-fa/PU polymer alloys with a heterogeneous network generated a broad glass transition temperature, which is a crucial feature for the development of triple SMPs. The influence of Fe₃O₄ NPs incorporation into the polymer nanocomposites on the SMP performance triggered by magnetic fields was also investigated. It was found that the addition of Fe₃O₄ NPs can enhance the dynamic mechanical properties and magnetic characteristics of the V-fa/PU polymer alloys thanks to the superparamagnetic property of Fe₃O₄ NPs. Moreover, the performance of the SMPs based on V-fa/PU polymer nanocomposites filled with Fe₃O₄ NPs showed high shape fixity of up to 98%, a shape recovery of 98%, and a recovering time of 8 s. Furthermore, bio-based V-fa/PU polymer alloys containing Fe₃O₄ NPs were developed as magnetic responsive triple SMPs with shape fixity in the range of 95–97% and shape recovery in the range of 85–95%. The results suggested that magnetic responsive triple SMPs from bio-based V-fa/PU polymer alloys filled with Fe₃O₄ NPs are promising candidate for advanced applications.</div></div>","PeriodicalId":7186,"journal":{"name":"Advanced Industrial and Engineering Polymer Research","volume":"8 1","pages":"Pages 37-47"},"PeriodicalIF":9.9,"publicationDate":"2025-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141842332","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}