Korea-Australia Rheology Journal最新文献_第2页

Enhanced thermal, mechanical, and optical properties of cellulose nanocrystal embedded cyclic olefin copolymer composite film 增强纤维素纳米晶嵌入环烯烃共聚物复合薄膜的热性能、机械性能和光学性能

IF 2.2 4区工程技术

Korea-Australia Rheology Journal Pub Date : 2024-06-17 DOI: 10.1007/s13367-024-00095-0

Ha Jeong Kang, Naeun Yang, Young Seok Song

引用次数: 0

Fabrication of functional hybrid carbon fiber-reinforced plastics with imparted surface concentrated electrical conductivity via multi-drop filling 通过多滴填充制造具有表面集中导电性的功能性混合碳纤维增强塑料

IF 2.2 4区工程技术

Korea-Australia Rheology Journal Pub Date : 2024-06-04 DOI: 10.1007/s13367-024-00094-1

Seung In Kang, Min Gyoung Kim, Dong Gi Seong

{"title":"Fabrication of functional hybrid carbon fiber-reinforced plastics with imparted surface concentrated electrical conductivity via multi-drop filling","authors":"Seung In Kang, Min Gyoung Kim, Dong Gi Seong","doi":"10.1007/s13367-024-00094-1","DOIUrl":"10.1007/s13367-024-00094-1","url":null,"abstract":"<div><p>Carbon fiber-reinforced plastics (CFRPs) have attracted attention as lightweight materials with exceptional properties, making them suitable for applications in industries where enhanced fuel efficiency and vibration-damping effects are required. However, as CFRP applications expand beyond the mobility sector, the demand for additional functionalities, particularly electrical conductivity, has emerged. In this study, we employed a multi-drop filling process (MDF) to produce hybrid CFRP with imparted electrical conductivity. This approach enables precise resin drop and simultaneous curing, addressing the challenges associated with conventional CFRP production processes. Based on filtering effects during MDF, additives, such as carbon nanotubes (CNTs) and graphene, could concentrate on the surface while resin impregnated the fiber reinforcement, resulting in CFRP with surface-concentrated electrical conductivity (ScEC). We dispersed CNTs and graphene in the resin to induce a bridge effect between the additives. Resin dispersion was achieved using surfactants and solvents, preserving the enhanced electrical conductivity and mechanical properties of the CFRP. The structure, electrical conductivity, and mechanical properties of the fabricated CFRP were evaluated. The results show that the hybrid CFRPs possess the intended structure and exhibit ScEC. This study paves the way for the fabrication of CFRPs with different functionalities, thereby promoting their applications in various industries.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":683,"journal":{"name":"Korea-Australia Rheology Journal","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2024-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141253444","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Reptation theory-similar deep learning model for polymer characterization from rheological measurement 根据流变测量建立用于聚合物表征的重演理论--类似深度学习模型

IF 2.2 4区工程技术

Korea-Australia Rheology Journal Pub Date : 2024-04-10 DOI: 10.1007/s13367-024-00091-4

Javad Rahmannezhad, Heon Sang Lee

{"title":"Reptation theory-similar deep learning model for polymer characterization from rheological measurement","authors":"Javad Rahmannezhad, Heon Sang Lee","doi":"10.1007/s13367-024-00091-4","DOIUrl":"10.1007/s13367-024-00091-4","url":null,"abstract":"<div><p>The use of machine learning to predict rheological properties of polymers has great potential to facilitate the characterization of novel materials. Here, we have suggested the analogy between the double reptation (DR) and the deep neural network model. The double reptation model itself can be the special case of the deep learning method; linear activation function, and identical sets of weights for the two hidden layers are the characteristics of the double reptation model. The identical sets of weights in the double reptation model are related with the molecular weight distribution (MWD). We first generated ground truth data based on double reptation model. Then, we analyzed the dataset with reptation-guided deep neural network (RGDNN). We showed that the RGDNN model is available to determine entanglement molecular weight (plateau modulus), and monomeric friction factors from the simulated experimental rheological data (prepared using DR model) without any additional information. Overall, a noteworthy conceptual improvement in the determination of major factors that determine the rheological behavior of ultrahigh molecular weight polyethylene (UHMWPE) gels has been achieved.</p></div>","PeriodicalId":683,"journal":{"name":"Korea-Australia Rheology Journal","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2024-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140588954","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Deformation capacity of fresh cement pastes 新拌水泥浆的变形能力

IF 2.2 4区工程技术

Korea-Australia Rheology Journal Pub Date : 2024-04-09 DOI: 10.1007/s13367-024-00090-5

Y. El Bitouri

引用次数: 0

All-biomass-based strong nanocomposite fibers of agar and cellulose nanocrystals and their dye removal applications 基于全生物质的琼脂和纤维素纳米晶体强纳米复合纤维及其染料去除应用

IF 2.2 4区工程技术

Korea-Australia Rheology Journal Pub Date : 2024-03-27 DOI: 10.1007/s13367-024-00089-y

Youngeun Lee, Hyo Jeong Kim, Min Woo Kim, Jin Miyawaki, Han Gi Chae, Youngho Eom

{"title":"All-biomass-based strong nanocomposite fibers of agar and cellulose nanocrystals and their dye removal applications","authors":"Youngeun Lee, Hyo Jeong Kim, Min Woo Kim, Jin Miyawaki, Han Gi Chae, Youngho Eom","doi":"10.1007/s13367-024-00089-y","DOIUrl":"10.1007/s13367-024-00089-y","url":null,"abstract":"<div><p>Fiber-based commodities represent a substantial fraction of plastic waste, leading to environmental harm. Discarded sanitary masks and fishing equipment undergo degradation, generating microfiber plastics, thereby presenting a notable hazard to both human health and the ecosystem. In this study, mechanically strong and environmentally friendly nanocomposite fibers were prepared by dry-jet wet spinning. The all-biomass-based fibers comprised agar and cellulose nanocrystals (CNC) as the matrix and nanofiller, respectively, and were highly miscible in deionized water as a cosolvent. Based on rheological characterization, the optimal spinning concentration and temperature were set to 13% (w/v) and 95 °C, respectively. The dry-jet wet-spun agar-based fibers exhibited remarkable mechanical performance compared with previously reported agar-based materials. In particular, the 1 wt% CNC (with respect to the agar amount) simultaneously improved the Young’s modulus, strength, and toughness by 8.3, 4.8, and 16.4% (2.6 GPa, 93.5 MPa, and 7.8 MJ m<sup>−3</sup>), respectively, compared to those of the control agar fibers (2.4 GPa, 89.2 MPa, and 6.7 MJ m<sup>−3</sup>), overcoming the trade-off of stiffness-toughness for conventional nanocomposite systems. In addition, the agar/CNC nanocomposite fibers rapidly adsorbed Methylene blue within 90 min, which is significantly faster than that of the film-type agar adsorbent. Therefore, all-biomass-based agar/CNC fibers are a promising remedy for alleviating water pollution.</p></div>","PeriodicalId":683,"journal":{"name":"Korea-Australia Rheology Journal","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2024-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140315977","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Simulation of drop deformation and breakup in simple shear flow 模拟简单剪切流中液滴的变形和破裂

IF 2.2 4区工程技术

Korea-Australia Rheology Journal Pub Date : 2024-03-09 DOI: 10.1007/s13367-023-00085-8

Saeed Derakhshan, Ata Allah Kamyabi, Ali Mohebbi

{"title":"Simulation of drop deformation and breakup in simple shear flow","authors":"Saeed Derakhshan, Ata Allah Kamyabi, Ali Mohebbi","doi":"10.1007/s13367-023-00085-8","DOIUrl":"10.1007/s13367-023-00085-8","url":null,"abstract":"<div><p>The behavior of drops in the emulsion is significant in transport phenomena and the oil and the petrochemical industry. In this study, the behavior of drops that are close to each other was investigated. These drops were studied at two viscosity ratios (0.5 and 0.9, which are the viscosity ratio of drops to fluid) and six capillary numbers (0.05, 0.11, 0.17, 0.42, 0.28, and 0.36). The results demonstrate the effect of drops on each other at a range of volume fractions. Also, at capillary numbers of 0.42, 0.82, and 0.36, there were volume fractions at which drops stuck to each other and broke after combining. In contrast, the single drop at these new capillary numbers after merging was not broken. At the capillary number of 0.84, and volume fraction of 0.001495, the drops did not stick to each other, but they were broken under the influence of each other. For each capillary number, a specified volume fraction was achieved, at which the drops behave as a single drop. Therefore, in each capillary number, a volume fraction can be found so that in volume fractions less than that, drops behave individually and do not interact with each other.</p></div>","PeriodicalId":683,"journal":{"name":"Korea-Australia Rheology Journal","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2024-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140099208","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Rheological study on lower critical solution temperature behavior of organo-soluble cyano-substituted p-aramid in isotropic phase 各向同性相中有机可溶氰基取代对芳纶低临界溶液温度行为的流变学研究

IF 2.2 4区工程技术

Korea-Australia Rheology Journal Pub Date : 2024-03-08 DOI: 10.1007/s13367-024-00088-z

Hyo Jeong Kim, Yeamsuksawat Thanakorn, Dae Eon Jung, Youngho Eom

{"title":"Rheological study on lower critical solution temperature behavior of organo-soluble cyano-substituted p-aramid in isotropic phase","authors":"Hyo Jeong Kim, Yeamsuksawat Thanakorn, Dae Eon Jung, Youngho Eom","doi":"10.1007/s13367-024-00088-z","DOIUrl":"10.1007/s13367-024-00088-z","url":null,"abstract":"<div><p>Poly(2-cyano-<i>p</i>-phenylene terephthalamide) (CY-PPTA) has garnered significant interest as a promising precursor for super <i>p</i>-aramid fibers because of its organosolubility in <i>N</i>,<i>N</i>-dimethyl acetamide/lithium chloride (DMAc/LiCl) while conserving the superior properties of the resultant fibers. However, CY-PPTA has been reported to exhibit abnormal phase behavior owing to the strong dipole–dipole interactions induced by the cyano groups. Herein, we rheologically study the isotropic phases of CY-PPTA/DMAc solutions with respect to the concentration and temperature and compare them with those of CY-PPTA/sulfuric acid (H<sub>2</sub>SO<sub>4</sub>) solutions. In the isotropic region, the CY-PPTA solutions yield a higher power-law exponent of the dynamic viscosity (<i>η'</i>) versus concentration of 6.0 (<i>ηʹ</i> ~ <i>c</i><sup>6.0</sup>) in the DMAc system than that in H<sub>2</sub>SO<sub>4</sub> (<i>ηʹ</i> ~ <i>c</i><sup>3.2</sup>). Moreover, the CY-PPTA/DMAc solutions exhibit a lower critical solution temperature (LCST) behavior with increasing temperature, in contrast with the upper critical solution temperature in H<sub>2</sub>SO<sub>4</sub>. Consequently, the viscosity and exponent of the CY-PPTA/DMAc solutions increase at elevated temperatures. As shown by the Cole–Cole plot, the heterogeneity in the DMAc system becomes worse. The LCST of the CY-PPTA solution is ascribed to the intermolecular interactions between the highly polar cyano groups, which are negligible in H<sub>2</sub>SO<sub>4</sub>.</p></div>","PeriodicalId":683,"journal":{"name":"Korea-Australia Rheology Journal","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2024-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140075096","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A low-Reynolds-number k–ε model for polymer drag-reduction prediction in turbulent pipe flow 用于预测湍流管道流动中聚合物阻力降低情况的低雷诺数 k-ε 模型

IF 2.2 4区工程技术

Korea-Australia Rheology Journal Pub Date : 2024-02-17 DOI: 10.1007/s13367-024-00087-0

Yang Chen, Meiyu Zhang, A. R. Valeev, Changjun Li, A. M. Nechval, Peng Yang

{"title":"A low-Reynolds-number k–ε model for polymer drag-reduction prediction in turbulent pipe flow","authors":"Yang Chen, Meiyu Zhang, A. R. Valeev, Changjun Li, A. M. Nechval, Peng Yang","doi":"10.1007/s13367-024-00087-0","DOIUrl":"10.1007/s13367-024-00087-0","url":null,"abstract":"<div><p>Pipeline transport at high Reynolds number can result in significant turbulent losses. One of the most effective methods for turbulent drag reduction is adding a very small amount of polymer drag-reducing agent to the pipeline. However, due to the complex interaction between polymers and turbulence, turbulence models incorporating polymer additives remain to be studied and developed. In the present work, we investigated the turbulence model using Reynolds averaged numerical simulation (RANS) to describe polyacrylamide drag reduction flow. A low-Reynolds-number <i>k</i>–<i>ε</i> model in turbulent flow has been developed by considering the concentration and type of polymers, which can be applied for polymer drag reduction prediction in the pipe. Mean velocity profile <i>U</i><sub><i>f</i></sub>, turbulent intensity, turbulent kinetic energy <i>k</i>, and turbulent dissipation rate <i>ε</i> in the regions of viscous sublayer, buffer layer and logarithmic layer have been predicted with various concentration <i>θ</i>, Reynolds number Re, degradation degrees, and changing laws of these factors have been revealed with wall distance. The developed turbulence model showed a good capability to qualitatively forecast mean velocity profile, turbulent intensity, turbulent kinetic energy, and turbulent dissipation rate, and the prediction error between the experimental and simulated values falls along the <i>y</i> = <i>x</i> curve, which can be used for the investigation and prediction of varies water-soluble, oil-soluble polymers in turbulent drag reduction flow in pipes with other parameters such as pipe diameter, pipe length, and the Reynolds number.</p></div>","PeriodicalId":683,"journal":{"name":"Korea-Australia Rheology Journal","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2024-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139903902","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Application of Post–Widder inversion formula to the calculation of relaxation spectrum from relaxation modulus 应用后维德反演公式从松弛模量计算松弛谱

IF 2.2 4区工程技术

Korea-Australia Rheology Journal Pub Date : 2024-02-02 DOI: 10.1007/s13367-023-00086-7

Gyuhyeon Cho, Jehyeok Choi, Junghaeng Lee, Kwang Soo Cho

引用次数: 0

Synthesis of bioadhesive PHEA hydrogels without crosslinkers through in situ polymerization and sustained mechanical mixing 通过原位聚合和持续机械混合合成不含交联剂的生物粘性 PHEA 水凝胶

IF 2.2 4区工程技术

Korea-Australia Rheology Journal Pub Date : 2024-01-16 DOI: 10.1007/s13367-023-00084-9

Seo Yoon Kim, Ji-Won Kang, Eun Hui Jeong, Taeho Kim, Ha Lim Jung, Jang-Ung Park, Jinhan Cho, Jun Dong Park, Byoung Soo Kim

{"title":"Synthesis of bioadhesive PHEA hydrogels without crosslinkers through in situ polymerization and sustained mechanical mixing","authors":"Seo Yoon Kim, Ji-Won Kang, Eun Hui Jeong, Taeho Kim, Ha Lim Jung, Jang-Ung Park, Jinhan Cho, Jun Dong Park, Byoung Soo Kim","doi":"10.1007/s13367-023-00084-9","DOIUrl":"10.1007/s13367-023-00084-9","url":null,"abstract":"<p>This study presents a novel methodology for the fabrication of bioadhesives composed of poly(2-hydroxyethyl acrylate) (PHEA), which demonstrate superior mechanical properties. Hydrogels based on PHEA were effectively synthesized through a strategy that obviates the need for crosslinkers, utilizing in situ polymerization of high-concentration 2-hydroxyethyl acrylate (HEA) monomers under persistent agitation. Optimal operational conditions, such as polymerization duration and HEA monomer concentration, were screened through rheological evaluations. In addition, the introduction of glycerol to the PHEA hydrogels yielded improvements in water-retention capacity, thus resolving limitations frequently observed in conventional aqueous-based hydrogels. Tests assessing adhesive properties indicated that the PHEA hydrogels, synthesized without crosslinkers, exhibited exceptional adhesion capabilities that exceeded those of commercially available tissue sealants. This economically viable and readily scalable fabrication technique provides a compelling pathway for the creation of robust, biocompatible bioadhesives well-suited for biomedical utilization.</p>","PeriodicalId":683,"journal":{"name":"Korea-Australia Rheology Journal","volume":null,"pages":null},"PeriodicalIF":2.2,"publicationDate":"2024-01-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139476708","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0