A review on rheological approaches as a perfect tool to monitor thermal degradation of biodegradable polymers

IF 2.2 4区工程技术 Q2 MECHANICS

Korea-Australia Rheology Journal Pub Date : 2024-10-21 DOI:10.1007/s13367-024-00111-3

Reza Salehiyan, Sanaz Soleymani Eil Bakhtiari

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引用次数: 0

Abstract

This review provides an in-depth analysis of the thermal degradation of biodegradable polymers through rheological methods. Focusing on key techniques such as time sweep tests, frequency sweep tests, and nonlinear rheological analyses gained at higher shear tests, the review highlights how these approaches offer critical insights into polymer stability and degradation kinetics. It entails an understanding of how molecular weight reduction, a common degradation mechanism, significantly impacts the performance of biodegradable polymers, and how the use of appropriate fillers can enhance thermal stability by mitigating chain scission. The review also discusses the application of the Arrhenius equation in modelling thermal degradation, helping predict degradation rates and optimize processing conditions. Time sweep tests are particularly emphasized for their ability to monitor polymer stability under various environmental conditions, while frequency sweep tests provide insights into the effects of processing/thermal history on material degradation. Tests at higher shear rates, which simulate real-world processing conditions such as extrusion and injection moulding, are explored for their role in understanding how processing-induced shear forces accelerate polymer degradation. Various biodegradable polymers are considered in this review, with polylactic acid (PLA) being the dominant polymer studied across most research, providing a clear picture of its degradation behaviour and strategies for enhancing its thermal stability. Therefore, it is expected that this review will be a comprehensive guide for researchers and engineers looking to optimize the thermal stability and performance of biodegradable polymers in various industrial applications.

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来源期刊

Korea-Australia Rheology Journal 工程技术-高分子科学

CiteScore

2.80

自引率

0.00%

发文量

审稿时长

>12 weeks

期刊介绍： The Korea-Australia Rheology Journal is devoted to fundamental and applied research with immediate or potential value in rheology, covering the science of the deformation and flow of materials. Emphases are placed on experimental and numerical advances in the areas of complex fluids. The journal offers insight into characterization and understanding of technologically important materials with a wide range of practical applications.