Journal of Thermal Analysis and Calorimetry最新文献

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Improvement of vibration resistance of slag blended cement mortar using C-S-H seeds
IF 3 3区 工程技术
Journal of Thermal Analysis and Calorimetry Pub Date : 2024-11-21 DOI: 10.1007/s10973-024-13807-z
Wenjie Li, Jiangfeng Long, Sijia Liu, Peng Wang, Linglin Xu, Yong Lai
{"title":"Improvement of vibration resistance of slag blended cement mortar using C-S-H seeds","authors":"Wenjie Li,&nbsp;Jiangfeng Long,&nbsp;Sijia Liu,&nbsp;Peng Wang,&nbsp;Linglin Xu,&nbsp;Yong Lai","doi":"10.1007/s10973-024-13807-z","DOIUrl":"10.1007/s10973-024-13807-z","url":null,"abstract":"<div><p>To assess the feasibility of using C-S–H seeds to boost the anti-mechanical vibration capabilities of concrete, this work evaluated the mechanical properties, hydration kinetics, phase assemblage of hydrates, and pore structure of Portland cement (PC) and slag cement mortars, at varying dosages of C-S–H seeds. Results reveal that the incorporation of C-S–H seeds negatively affects the vibration resistance of neat PC, while it effectively enhances the vibration resistance of slag cement. The addition of these seeds facilitates cement hydration and improves the early mechanical properties, which is evident in the shortened appearance time of the hydration exothermic peak by almost 50%. The remarkable vibration resistance observed in slag cement primarily stems from the synergistic effect between C-S–H seeds and slag. However, the premature formation of the internal microstructure in neat PC due to C-S–H seeds disrupts the stability of mutual construction between hydration products. The findings indicate that C-S–H seeds can be used in engineering to enhance concrete lifespan, reduce road repair expenses, and enhance construction efficiency.</p></div>","PeriodicalId":678,"journal":{"name":"Journal of Thermal Analysis and Calorimetry","volume":"149 23","pages":"13759 - 13771"},"PeriodicalIF":3.0,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757976","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modeling heat generation in polymer–polymer interfaces under ultrasonic vibration: a coupled friction and viscoelastic approach
IF 3 3区 工程技术
Journal of Thermal Analysis and Calorimetry Pub Date : 2024-11-21 DOI: 10.1007/s10973-024-13803-3
Wangqing Wu, Changyuan Jia, Bingyan Jiang, Yang Zou
{"title":"Modeling heat generation in polymer–polymer interfaces under ultrasonic vibration: a coupled friction and viscoelastic approach","authors":"Wangqing Wu,&nbsp;Changyuan Jia,&nbsp;Bingyan Jiang,&nbsp;Yang Zou","doi":"10.1007/s10973-024-13803-3","DOIUrl":"10.1007/s10973-024-13803-3","url":null,"abstract":"<div><p>To quantify the interfacial friction and volumetric viscous heating contribution of polymers during ultrasonic plasticization is of great significance for optimizing plasticization process parameters. This paper presents a coupled numerical analysis model considering multiple heat sources in a simplified ultrasonic plasticizing system. The contribution of contact position angles and ultrasonic process parameters to interfacial friction and volumetric viscous heating of polymers was considered, and the accuracy of the model was verified by infrared experiment and simulation. The following conclusions were summarized: the interface temperature increases first and then decreases during the experiment, and the heat generation mainly occurs in the first second of plasticization. The effects of process parameters on polymer heating, dynamic parameters, and energy were studied by simulation. It was found that the contact position angle and ultrasonic process parameters controlled the heat generation process by influencing the friction force and slip velocity between pellets. Under standard processing conditions, when the contact position angle ranges from 0°to 90°, both the heat production rate and total heat initially increase before subsequently decreasing, reaching a maximum at approximately 40°. At this optimal angle, the friction force is around 27.5 N, the slip rate is about 2250 mm s<sup>−1</sup>, and the heat production rate measures 11 K ms<sup>−1</sup>. The results indicate that when the amplitude is set at 40 μm, the frequency at 30 kHz, and the contact angle at 40°, the ultrasonic plasticizing effect is optimized. This configuration ensures a higher rate of heat generation while minimizing material degradation. The interfacial friction heat is significantly higher than the volumetric viscous heat under each condition. The interfacial friction heat is usually 3–5 times higher than the volumetric viscous heat. This study provides a basis for the high-quality molding of polymer ultrasonic plasticization.</p></div>","PeriodicalId":678,"journal":{"name":"Journal of Thermal Analysis and Calorimetry","volume":"149 23","pages":"13865 - 13878"},"PeriodicalIF":3.0,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757977","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Feasibility of waste-to-hydrogen generation system based on gasification/pyrolysis: a comprehensive review of experimental studies
IF 3 3区 工程技术
Journal of Thermal Analysis and Calorimetry Pub Date : 2024-11-19 DOI: 10.1007/s10973-024-13776-3
Gaurav Sharma, Ashok Kumar Dewangan, Ashok Kumar Yadav, Aqueel Ahmad
{"title":"Feasibility of waste-to-hydrogen generation system based on gasification/pyrolysis: a comprehensive review of experimental studies","authors":"Gaurav Sharma,&nbsp;Ashok Kumar Dewangan,&nbsp;Ashok Kumar Yadav,&nbsp;Aqueel Ahmad","doi":"10.1007/s10973-024-13776-3","DOIUrl":"10.1007/s10973-024-13776-3","url":null,"abstract":"<div><p>The reliance on fossil fuels has propelled technological growth but has led to pressing global challenges, including waste accumulation, resource depletion, and environmental degradation due to greenhouse gas emissions. With annual production of 464 million metric tons of biomass and 321.5 billion metric tons of plastic waste, innovative waste management strategies are essential. This study explores the co-pyrolysis of biomass and plastic waste as a promising approach to convert these materials into biofuels, particularly hydrogen. The paper emphasizes hydrogen’s role as an energy carrier and feedstock, assessing eleven pathways for hydrogen generation while analyzing their environmental impacts, energy efficiency, and risks to ecological and human health. Although acid gas production ranks as the least impactful method, biomass gasification exhibits a larger ecological footprint. Additionally, the review highlights hydrogen generation via gasification and pyrolysis, emphasizing the importance of operational conditions, including temperature management and gas-cleaning systems. While gasification, operating at higher temperatures (800–1200 °C), produces more hydrogen, pyrolysis offers greater feedstock versatility and simpler residue management. The findings underscore the potential of waste-to-hydrogen technologies in advancing sustainability and reducing waste, advocating for effective hydrogen storage and transportation solutions.</p></div>","PeriodicalId":678,"journal":{"name":"Journal of Thermal Analysis and Calorimetry","volume":"149 23","pages":"13629 - 13651"},"PeriodicalIF":3.0,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757959","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sintering studies on Ni–Ti–Fe elemental powder mixtures using differential scanning calorimetry
IF 3 3区 工程技术
Journal of Thermal Analysis and Calorimetry Pub Date : 2024-11-19 DOI: 10.1007/s10973-024-13770-9
Tea Bertilsson, Srinivasan Iyengar, Hossein Sina
{"title":"Sintering studies on Ni–Ti–Fe elemental powder mixtures using differential scanning calorimetry","authors":"Tea Bertilsson,&nbsp;Srinivasan Iyengar,&nbsp;Hossein Sina","doi":"10.1007/s10973-024-13770-9","DOIUrl":"10.1007/s10973-024-13770-9","url":null,"abstract":"<div><p>Shape memory alloys based on the Ni–Ti system derive their versatile properties from the non-stoichiometric intermetallic compound NiTi. The transformation temperature associated with its shape memory effect is dependent on composition, which can be controlled by minor additions of a third element like iron. This work considers the formation of various intermetallic compounds and the evolution of phases during the sintering of ternary Ni–Ti–Fe powder compacts. Elemental powder mixtures of nickel, titanium and iron were prepared by adding 0–20 at.% Fe to equiatomic Ni–Ti. The powders were compacted into discs and sintered by heating to 1200 °C in a differential scanning calorimeter. In separate experiments, heating was interrupted to identify the phases present in the partially sintered samples at various temperatures. The microstructures of the sintered samples were characterized using scanning electron microscopy. The distribution of nickel, titanium and iron in the samples was studied with EDS mapping and the phases present were identified using XRD. In the equiatomic Ni–Ti powder compact, NiTi<sub>2</sub>, NiTi and Ni<sub>3</sub>Ti were formed in the solid state (&lt; 942 °C) through diffusion. At 942 °C a strong reaction between the remaining titanium and NiTi<sub>2</sub> takes place, leading to the formation of a liquid. At 1120 °C, NiTi and Ni<sub>3</sub>Ti combine to form a liquid. These reactions are affected by the addition of iron to the powder mixture. The results show that at 20 at.% iron in the ternary compact, the first reaction occurred at 999 °C, instead of 942 °C for the binary composition and iron did not form any compound with nickel or titanium. Instead, the iron could replace nickel in NiTi<sub>2</sub> and in NiTi, forming (Fe, Ni)Ti<sub>2</sub> and (Fe,Ni)Ti. This leads to more Ni<sub>3</sub>Ti formation and explains why the reaction at 1120 °C is more prominent at high iron contents. A linear dependence on the iron content in the sample was also observed for the onset temperatures for two split exothermic peaks in the DSC curves. The results also suggest that the temperatures associated with the β-Ti + (Fe, Ni)Ti<sub>2</sub> → L and (Fe, Ni)Ti<sub>2</sub> → (Fe,Ni)Ti + L reactions depend on the ratio of iron to nickel in (Fe, Ni)Ti<sub>2</sub>.</p></div>","PeriodicalId":678,"journal":{"name":"Journal of Thermal Analysis and Calorimetry","volume":"149 23","pages":"13745 - 13758"},"PeriodicalIF":3.0,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757960","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research progress on efficient battery thermal management system (BTMs) for electric vehicles using composite phase change materials with liquid cooling and nanoadditives
IF 3 3区 工程技术
Journal of Thermal Analysis and Calorimetry Pub Date : 2024-11-19 DOI: 10.1007/s10973-024-13752-x
Madhu Jhariya, Ashok Kumar Dewangan, Syed Quadir Moinuddin, Sunil Kumar, Aqueel Ahmad, Ashok Kumar Yadav
{"title":"Research progress on efficient battery thermal management system (BTMs) for electric vehicles using composite phase change materials with liquid cooling and nanoadditives","authors":"Madhu Jhariya,&nbsp;Ashok Kumar Dewangan,&nbsp;Syed Quadir Moinuddin,&nbsp;Sunil Kumar,&nbsp;Aqueel Ahmad,&nbsp;Ashok Kumar Yadav","doi":"10.1007/s10973-024-13752-x","DOIUrl":"10.1007/s10973-024-13752-x","url":null,"abstract":"<div><p>The increasing demand for electric vehicles (EVs) has brought new challenges in managing battery thermal conditions, particularly under high-power operations. This paper provides a comprehensive review of battery thermal management systems (BTMSs) for lithium-ion batteries, focusing on conventional and advanced cooling strategies. The primary objective of this study is to assess and compare the effectiveness of various cooling approaches, including air-based, liquid-based, phase change material (PCM)-based, and hybrid systems. This review paper reveals that while traditional air- and liquid-based systems offer certain benefits such as simplicity and cooling efficiency, they are constrained by limitations in thermal conductivity and energy consumption. In contrast, PCM-based systems, despite their poor thermal conductivity, provide stable temperature regulation without requiring additional energy input. To overcome these limitations, the integration of thermal conductivity enhancers (TCEs) like carbon fibers, expanded graphite, and metal foams into PCMs significantly improves their performance. For instance, composite PCM (CPCM) enhanced with expanded graphite shows a marked improvement in thermal conductivity, increasing from 0.2 Wm<sup>−1</sup> K<sup>−1</sup> to 16.6 Wm<sup>−1</sup> K<sup>−1</sup>, resulting in battery temperature reductions by up to 28%. Additionally, hybrid systems that combine active cooling with CPCMs, particularly when using nanoenhanced PCM with additives like graphene and metallic nanoparticles, demonstrate superior cooling efficiency, with temperature reductions of up to 50% compared to traditional systems. The uniqueness of this paper lies in its detailed comparison of the various BTMS strategies, including a thorough evaluation of hybrid systems that merge passive and active cooling techniques. We also explore the potential of nanoenhanced PCMs and hybrid CPCM systems, which offer significant advantages for high-power battery applications by providing both efficient heat dissipation and improved battery longevity. By synthesizing recent advancements in this field, this review highlights the most promising thermal management strategies, paving the way for future innovation in BTMS design for electric vehicles.</p></div>","PeriodicalId":678,"journal":{"name":"Journal of Thermal Analysis and Calorimetry","volume":"149 23","pages":"13653 - 13680"},"PeriodicalIF":3.0,"publicationDate":"2024-11-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757958","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Innovative impinging jet methods for performance enhancement: a review
IF 3 3区 工程技术
Journal of Thermal Analysis and Calorimetry Pub Date : 2024-11-18 DOI: 10.1007/s10973-024-13777-2
Ayushman Srivastav, Rajesh Maithani, Sachin Sharma
{"title":"Innovative impinging jet methods for performance enhancement: a review","authors":"Ayushman Srivastav,&nbsp;Rajesh Maithani,&nbsp;Sachin Sharma","doi":"10.1007/s10973-024-13777-2","DOIUrl":"10.1007/s10973-024-13777-2","url":null,"abstract":"<div><p>This paper explores diverse techniques aimed at enhancing the heat transfer performance of solar air heaters, with a primary emphasis on impinging jet arrays. The discussion includes an examination of available standards governing the manufacturing, evaluation, and certification of solar air heaters. Traditional approaches, such as the use of turbulators (ribs, baffles, and dimples), improve thermo-hydraulic performance but often lead to thermal stress due to nonuniform cooling. In contrast, jet impingement heat transfer has gained attention for its ability to provide enhanced and consistent cooling even in confined spaces. The study examines key geometric and operational parameters that influence jet impingement heat transfer, such as nozzle-to-target plate spacing, jet diameters, jet arrangement, and jet angle. Among these, the nozzle-to-target spacing and jet diameters are identified as critical factors in optimizing heat transfer. The paper also highlights the superior performance of pipe jets over orifice jets, as pipe jets generate higher fluid velocity on the target plate, resulting in enhanced heat transfer and more uniform cooling. This research underscores the growing importance of jet impingement technology in improving the efficiency of SAH and opens avenues for its application in other thermal management systems, including concentrated solar power and electric vehicle cooling systems.</p></div>","PeriodicalId":678,"journal":{"name":"Journal of Thermal Analysis and Calorimetry","volume":"149 23","pages":"13581 - 13627"},"PeriodicalIF":3.0,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757956","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of thermal, crystal and magnetic behavior of addition of Nd rare earth element effect on CuAlMn shape memory alloy
IF 3 3区 工程技术
Journal of Thermal Analysis and Calorimetry Pub Date : 2024-11-18 DOI: 10.1007/s10973-024-13823-z
Muhammed Sait Kanca
{"title":"Investigation of thermal, crystal and magnetic behavior of addition of Nd rare earth element effect on CuAlMn shape memory alloy","authors":"Muhammed Sait Kanca","doi":"10.1007/s10973-024-13823-z","DOIUrl":"10.1007/s10973-024-13823-z","url":null,"abstract":"<div><p>In this study, CuAlMn alloys, a popular Cu-based shape memory alloy, were chosen because they exhibit superior shape memory properties and improved ductility compared to other Cu-based SMAs. The rare earth element Nd (neodymium) was added to CuAlMn alloy at the specified atomic percentages in the composition Cu<sub>70-x</sub>Al<sub>24</sub>Mn<sub>6</sub>Nd<sub>x</sub>(x = 0,2,4,8) and their thermal behavior, crystal structure, surface morphology and magnetic properties were investigated after fabrication. As a result of the thermal analysis measurements, it was observed that for low Nd ratios, the austenite phase transformation initial temperature of the CuAlMn alloy was increased, while at high Nd ratios, a decrease in the shape memory property was detected. Martensitic phase and precipitate phase α phase were observed in the crystal structure properties of CuAlMn alloys without and with Nd doping. These results were also detected in surface morphology observations. In addition, the crystal size decreased from 135 to 105 nm with Nd doping. As a result of magnetic measurements, CuAlMn ternary shape memory alloy was found to be paramagnetic at room temperature. Magnetic susceptibility values of the alloys showing paramagnetic magnetic properties were calculated as 11.5 × 10<sup>–6</sup>, 12.5 × 10<sup>–6</sup>, 9.15 × 10<sup>–6</sup> and 6.15 × 10<sup>–6</sup> emu.Oe<sup>−1</sup>.g<sup>−1</sup>, respectively. According to these results, the magnetic susceptibility value decreased with increasing Nd ratio.</p></div>","PeriodicalId":678,"journal":{"name":"Journal of Thermal Analysis and Calorimetry","volume":"149 23","pages":"13737 - 13743"},"PeriodicalIF":3.0,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757955","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermal and hydration properties of 3D printing gypsum materials incorporated with accelerators
IF 3 3区 工程技术
Journal of Thermal Analysis and Calorimetry Pub Date : 2024-11-18 DOI: 10.1007/s10973-024-13726-z
Zhenzhen Zhi, Yanfei Guo, Zihao Jin, Xiaohong Ru, Xinya Yang, Baoguo Ma
{"title":"Thermal and hydration properties of 3D printing gypsum materials incorporated with accelerators","authors":"Zhenzhen Zhi,&nbsp;Yanfei Guo,&nbsp;Zihao Jin,&nbsp;Xiaohong Ru,&nbsp;Xinya Yang,&nbsp;Baoguo Ma","doi":"10.1007/s10973-024-13726-z","DOIUrl":"10.1007/s10973-024-13726-z","url":null,"abstract":"<div><p>3D printing technology, as a landmark technology for significant changes in modern manufacturing industry, has become an important means to lead the future of construction to achieve convenient, personalised, functional integration. In this study, alpha hemihydrate gypsum (<i>α</i>-HH) was used as the 3D printing matrix material, and the accelerators were introduced to match the slurry-based 3D printing process. The hydration heat and thermogravimetric changes were characterised to analyse the effect of accelerators on the thermal properties via thermogravimetry–differential scanning calorimetry (TG-DSC) analysis. Further, X-ray diffraction analysis (XRD) and morphological observations of the hardened gypsum were conducted to assess the impact of accelerators on the hydration process of <i>α</i>-HH. The results showed that all accelerators considerably reduced the hydration reaction time of <i>α</i>-HH, with the maximum exothermic peak observed in the order lithium sulphate (LS, 6.78 min) &gt; sodium sulphate (NS, 11.33 min) &gt; potassium sulphate (KS, 15.64 min) &gt; control sample (26.43 min). Under the influence of KS, the proportion of dihydrate gypsum crystals reached 50.5% within 5 min of <i>α</i>-HH hydration. The addition of accelerators was shown to be effective for slurry-based 3D printing gypsum process.</p></div>","PeriodicalId":678,"journal":{"name":"Journal of Thermal Analysis and Calorimetry","volume":"149 23","pages":"13813 - 13824"},"PeriodicalIF":3.0,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757910","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mathematical formulation of the machine learning backpropagation network and regression modelling of the chemical stability and thermal properties of PLA/HKUST-1 fabricated porous membranes
IF 3 3区 工程技术
Journal of Thermal Analysis and Calorimetry Pub Date : 2024-11-18 DOI: 10.1007/s10973-024-13801-5
Zaid Abdulhamid Alhulaybi, Abdulrazak Jinadu Otaru
{"title":"Mathematical formulation of the machine learning backpropagation network and regression modelling of the chemical stability and thermal properties of PLA/HKUST-1 fabricated porous membranes","authors":"Zaid Abdulhamid Alhulaybi,&nbsp;Abdulrazak Jinadu Otaru","doi":"10.1007/s10973-024-13801-5","DOIUrl":"10.1007/s10973-024-13801-5","url":null,"abstract":"<div><p>As part of the ongoing quest to optimize the application and operational performance of biodegradable polymer materials, mathematical models have been developed to predict the chemical stability and thermal properties of PLA/HKUST-1 mixed matrix biopolymer composites, utilizing machine learning deep neural networks and regression modelling. These models were constructed by integrating a single-entry input that encompasses the percentage mass composition of PLA and HKUST-1, immersion time, casting thickness, and immersion temperature into a test function designed to predict behavior characterized by the chemical stability and thermal properties of these materials. Leveraging experimental datasets available in the literature, the models were trained to derive arbitrary constants and empirical constants that are instrumental in forecasting the chemical stability and thermal properties of the materials. With error estimates ranging from 0.01 to 2.16%, the formulated models accurately represented most output signals, including thermal stability at 5.0 and 50.0% mass loss, glass transition temperature, crystallization temperature, and melting point temperature of mixed matrix biopolymer materials. The application of this methodology may prove beneficial for the design and fabrication of novel polymer/composite materials with diverse engineering applications.</p><h3>Graphical abstract</h3><p>Plots of experimental and (a) DNN predictive values of reduced Chemical stability at 5 °C against reduced values of X and (b) linear and quadratic regression model predictive values of chemical stability at 5% [<sup>o</sup>C] against <i>X</i> = <i>(x</i><sub>3</sub><i>*x</i><sub>4</sub><i>*x</i><sub>5</sub><i>)/(x</i><sub>a</sub><i>-x</i><sub>b</sub><i>)</i>.</p><div><figure><div><div><picture><img></picture></div></div></figure></div></div>","PeriodicalId":678,"journal":{"name":"Journal of Thermal Analysis and Calorimetry","volume":"149 23","pages":"13851 - 13864"},"PeriodicalIF":3.0,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757912","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Shape-stabilized, thermally conductive phase-change composites for thermal energy storage
IF 3 3区 工程技术
Journal of Thermal Analysis and Calorimetry Pub Date : 2024-11-18 DOI: 10.1007/s10973-024-13821-1
Guanyue Zeng, Yihang Li, Yuzhu Xiong
{"title":"Shape-stabilized, thermally conductive phase-change composites for thermal energy storage","authors":"Guanyue Zeng,&nbsp;Yihang Li,&nbsp;Yuzhu Xiong","doi":"10.1007/s10973-024-13821-1","DOIUrl":"10.1007/s10973-024-13821-1","url":null,"abstract":"<div><p>Phase-change materials (PCMs) with three-dimensional thermally conductive skeletons show promise for thermal energy storage, but they have poor stability. Therefore, based on hydrogen bonding between graphene oxide and polyvinyl alcohol, a shape-stable thermally conductive graphene oxide/graphene nanoplates/polyvinyl alcohol (GO/GNP/PVAs) 3D porous skeleton was prepared by a simple vacuum freeze–drying method in this paper. To further improve the thermal conductivity of the GO/GNP/PVAs 3D porous skeleton, so carbonization is applied on it. After encapsulating polyethylene glycol (PEG) in the skeleton, a thermally conductive phase-change composite with good shape stability was obtained, even at a PEG loading as high as 96.1%. The carbonized C-GO/GNP/PVAs/PEG phase-change composites exhibited higher thermal conductivity (1.57 W m<sup>−1</sup> K<sup>−1</sup>) than uncarbonized GO/GNP/PVAs/PEG phase-change composites (0.52 W m<sup>−1</sup> K<sup>−1</sup>). This was mainly due to the low thermal conductivity GO annealing into high thermal conductivity reduced graphene oxide (rGO), which formed a conductive three-dimensional network. Meanwhile, the formation of a carbon skeleton by PVA chains after annealing also improved the thermal conductivity of the composites. The C-GO/GNP/PVAs/PEG phase-change composites also showed excellent solar-to-heat conversion properties.</p></div>","PeriodicalId":678,"journal":{"name":"Journal of Thermal Analysis and Calorimetry","volume":"149 23","pages":"13839 - 13849"},"PeriodicalIF":3.0,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142757911","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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