Journal of Solution Chemistry最新文献_第3页

Solid–Liquid Equilibrium of TKX-50 in Three Binary Solvents: Experiments, Correlation, Thermodynamic Analysis, Hansen Solubility Parameter and Molecular Simulation TKX-50在三种二元溶剂中的固液平衡：实验、相关性、热力学分析、Hansen溶解度参数和分子模拟

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2025-06-20 DOI: 10.1007/s10953-025-01469-w

Bo Wang, Jun Wang, Xiao Ma, Guan-chao Lan, Jian-long Wang, Li-zhen Chen

{"title":"Solid–Liquid Equilibrium of TKX-50 in Three Binary Solvents: Experiments, Correlation, Thermodynamic Analysis, Hansen Solubility Parameter and Molecular Simulation","authors":"Bo Wang, Jun Wang, Xiao Ma, Guan-chao Lan, Jian-long Wang, Li-zhen Chen","doi":"10.1007/s10953-025-01469-w","DOIUrl":"10.1007/s10953-025-01469-w","url":null,"abstract":"<div><p>The solubility of dihydroxylammonium 5,5’-bistetrazole-1,1’-diolate (TKX-50) in three binary mixed solvents (ethanol + H<sub>2</sub>O, DMSO + H<sub>2</sub>O, and DMF + H<sub>2</sub>O) was determined using a laser dynamic monitoring technique at various temperatures ranging from 293.15 to 333.15 K and at atmospheric pressure (P = 0.1 MPa). The results show that the solubility of TKX-50 in mixed solvents increases with temperature, decreases with increasing water content in DMSO + H<sub>2</sub>O and DMF + H<sub>2</sub>O, and increases with increasing water content in ethanol + H<sub>2</sub>O. The experimental solubility data were used for correlation analysis using the Modified Apelblat equation, van’t Hoff equation, CNIBS/R-K equation, and Jouyban–Acree–Apelblat equation. All of these models yielded satisfactory results in binary solvents. Subsequently, the effects of hydrogen bonding, solvent polarity, and intermolecular interaction forces on the dissolution behavior of TKX-50 were analysed using Hansen solubility parameter (HSPs), Hirshfeld surface analysis (HS), and molecular electrostatic potentials (MEPs). In addition, the thermodynamic properties enthalpy, entropy, and Gibbs energy were calculated and discussed based on experimental data.</p></div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"54 8","pages":"1103 - 1136"},"PeriodicalIF":1.3,"publicationDate":"2025-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145167822","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Structural Effect of Potassium Dihydrogen Citrate on the Interactions of Imidazolium Based Ionic Liquids with Water 柠檬酸二氢钾对咪唑基离子液体与水相互作用的结构影响

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2025-06-19 DOI: 10.1007/s10953-025-01465-0

Braja B. Nanda, Sudhansu Sekhar Pattnaik, Binita Nanda, Malabika Talukdar

{"title":"Structural Effect of Potassium Dihydrogen Citrate on the Interactions of Imidazolium Based Ionic Liquids with Water","authors":"Braja B. Nanda, Sudhansu Sekhar Pattnaik, Binita Nanda, Malabika Talukdar","doi":"10.1007/s10953-025-01465-0","DOIUrl":"10.1007/s10953-025-01465-0","url":null,"abstract":"<div><p>The main objective of this study is to understand the effect of a bio medically important organic salt on molecular interactions of ionic liquids. Volumetric and ultra-acoustic studies of two immidazolium based ionic liquids, 1-butyl-3 methyl imidazolium chloride and 1-ethyl-3-methyl imidazolium ethyl sulphate are carried out in presence of potassium dihydrogen citrate. Experimentally obtained and derived parameters are analysed in the light of ionic, hydrophilic, and hydrophobic interactions taking place between different ionic, polar, and nonpolar segments of the ILs and the citrate salt. The effect of the said salt on the interactions of the ILs with water are explored in terms of apparent molar volume <span>({(V}_{phi }))</span>, partial molar volume <span>(({V}_{phi }^{0})</span>), and partial molar expansibility <span>({(E}_{phi }^{0}))</span>, compressibility and apparent compressibility behaviour of solution at different concentrations <span>({{(K}_{s} text{and} K}_{phi ,s}))</span> and at infinite dilution <span>(({{K}_{s }^{0} text{and} K}_{phi ,s}^{0})</span>). Transfer values are calculated to understand the solute–co-solute interactions and overlapping of hydration co-spheres. Hydration numbers are calculated to reinforce the compressibility data. Structural changes of water induced by the solute–co-solute and solute–solvent interactions are determined by the magnitude and sign of well-known Hepler’s constant.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"54 8","pages":"1061 - 1102"},"PeriodicalIF":1.3,"publicationDate":"2025-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145167378","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Thermodynamic and Computational Studies of Binary Liquid Systems of Benzyl Acetate with 1-Alcohols at Varying Temperatures 变温度下醋酸苄酯与1-醇二元液体体系的热力学和计算研究

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2025-06-17 DOI: 10.1007/s10953-025-01463-2

Ramachandra Rao Panem, Sreenu Dharavath, Kavitha Siddoju, Satheesh Bolloju, Savitha Jyostna Tangeda

{"title":"Thermodynamic and Computational Studies of Binary Liquid Systems of Benzyl Acetate with 1-Alcohols at Varying Temperatures","authors":"Ramachandra Rao Panem, Sreenu Dharavath, Kavitha Siddoju, Satheesh Bolloju, Savitha Jyostna Tangeda","doi":"10.1007/s10953-025-01463-2","DOIUrl":"10.1007/s10953-025-01463-2","url":null,"abstract":"<div><p>Thermophysical properties such as density, and speed of sound of binary liquid systems of benzyl acetate (BZA) with 1-alkanols (1-propanol (PPL), 1-butanol (BTL), 1-pentanol (PTL), 1-hexanol (HXL), and 1-heptanol (HPL) at <i>T</i> = (298.15 to 308.15) K under atmospheric pressure, were reported complete composition of benzyl acetate. Using experimental data, thermodynamic properties like molar volume (<span>({V}_{text{m}})</span>), excess molar volume (<span>({V}_{text{m}}^text{E})</span>), apparent molar volumes (<span>({V}_{text{m},varnothing ,1})</span> and <span>({V}_{text{m},varnothing ,2})</span>), acoustic impedance (<i>Z</i>), isentropic compressibility (<span>({k}_{text{s}})</span>), intermolecular free length (<i>L</i><sub>f</sub>), excess isentropic compressibility (<span>({k}_{text{s}}^{text{E}})</span>), and excess intermolecular free length (<span>({L}_{text{f}}^{text{E}})</span>) were considered. Using these data, we may forecast the formation of new molecular interactions between dissimilar components, as well as explain how temperature influences those interactions. Further, the <span>({V}_{text{m}}^{text{E}})</span>, and <i>∆κ</i><sub>s</sub> variables were fitted using the Redlich–Kister (R–K) equation. Furthermore, the geometrical structure of the monomer and all conceivable H-bonded (molecular interaction) dimers is fully optimized using density functional theory with the Lee–Yang–Parr correlation function (B3LYP) and the 6-311++G(d, p) basis set. An extensive examination of the computational results is carried out to confirm the complex formation through H-bonding.</p></div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"54 8","pages":"1026 - 1060"},"PeriodicalIF":1.3,"publicationDate":"2025-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145166188","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Physicochemical Properties, Computational Chemistry and Molecular Interactions of 1,2-Propanediamine + Hexylene Glycol Binary System 1,2-丙二胺+己二醇二元体系的物理化学性质、计算化学及分子相互作用

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2025-06-03 DOI: 10.1007/s10953-025-01461-4

Bo Zhang, Yingyue Teng, Mengchao Feng, Enna Wang, Liming Chai, Qiang Li, Jianbin Zhang

{"title":"Physicochemical Properties, Computational Chemistry and Molecular Interactions of 1,2-Propanediamine + Hexylene Glycol Binary System","authors":"Bo Zhang, Yingyue Teng, Mengchao Feng, Enna Wang, Liming Chai, Qiang Li, Jianbin Zhang","doi":"10.1007/s10953-025-01461-4","DOIUrl":"10.1007/s10953-025-01461-4","url":null,"abstract":"<div><p>This study measured the density (<i>ρ</i>) and viscosity (<i>η</i>) of the binary system at pressures of 1005 hPa (Tianjin, China) over the temperature range of 298.15 K to 318.15 K, with 5 K increments, and systematically analyzed its thermophysical properties and intermolecular interactions. The excess molar volume (<span>({{V}}_{text{m}}^{text{E}})</span>) was calculated based on the density data, and the most stable molar ratio of 1,2-PDA to HG was determined to be 2:3. The viscosity deviation (Δ<i>η</i>) and thermodynamic properties were calculated based on the viscosity data, and the molecular dynamic characteristics were analyzed. Spectroscopic characterization (FTIR and <sup>1</sup>H NMR) and density functional theory (DFT) calculations confirmed the presence of hydrogen bonding between 1,2-PDA and HG in the form of [–OH···NH<sub>2</sub>–]. This study fills a research gap in the thermodynamic and dynamic properties of the 1,2-PDA and HG binary system, providing new insights into intermolecular interactions in complex molecular systems and offering valuable guidance for applications in the chemical and materials fields.</p></div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"54 8","pages":"998 - 1025"},"PeriodicalIF":1.3,"publicationDate":"2025-06-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145161560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Design and Sensing Properties of New Dicyanoisophorone-based Conjugated Azo Dyes: Solvatochromism and Cyanide Ion Detection 新型双氰异膦酮偶氮染料的设计与传感性能：溶剂变色与氰化物离子检测

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2025-05-29 DOI: 10.1007/s10953-025-01457-0

Kajal R. Gaikwad, Pramod B. Thakur

引用次数: 0

Investigation of the Influence of Solvent Polarity and Temperature on the Vibrational Spectra, Photophysical Properties, Optical, and Thermodynamic Characteristics of 1-Benzofuran: A Density Functional Theory Approach 溶剂极性和温度对1-苯并呋喃的振动光谱、光物理性质、光学和热力学特性影响的研究：密度泛函方法

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2025-05-27 DOI: 10.1007/s10953-025-01454-3

Shallo Fekadu, Alemu Kebede, Abebe Belay, Umer Sherefedin, Kebede Shenkute, Diriba Tsegaye, Mintesinot Tesfaye, Yeshanew Fikre

{"title":"Investigation of the Influence of Solvent Polarity and Temperature on the Vibrational Spectra, Photophysical Properties, Optical, and Thermodynamic Characteristics of 1-Benzofuran: A Density Functional Theory Approach","authors":"Shallo Fekadu, Alemu Kebede, Abebe Belay, Umer Sherefedin, Kebede Shenkute, Diriba Tsegaye, Mintesinot Tesfaye, Yeshanew Fikre","doi":"10.1007/s10953-025-01454-3","DOIUrl":"10.1007/s10953-025-01454-3","url":null,"abstract":"<div><p>1-Benzofuran is a heterocyclic compound with fused benzene and furan rings that is used in materials science, nonlinear optics, drug development and pharmacology. This study investigated how solvent polarity and temperature affect vibrational spectra, photophysical properties, and thermodynamic behavior. Using semiempirical, Hartree–Fock, and DFT (B3LYP) methods with basis sets such as 6–31 + G (d,p), 6–311 + G (d,p), and aug-cc-pVDZ, it was found that solvent polarity influenced bond angles, bond lengths, dipole moments, HOMO‒LUMO gaps, and thermodynamic properties. Solvation effects in water were observed in the FT-IR and FT-Raman spectra, with peak shifts due to hydrogen bonding. The electrostatic potential map revealed electrophilic and nucleophilic regions important for receptor binding. The nonlinear optical properties increased significantly with increasing solvent polarity, reaching α = 230.14 a.u. and β = 314.02 a.u. in polar solvents. As the temperature increased from 100 to 1000 K, the heat capacity, enthalpy, and entropy increased, leading to instability. The absorption spectra showed peaks at 240–300 nm in polar solvents, with a bathochromic shift of 5.11 nm. This study offers insights into the photophysical and optical properties of 1-benzofuran in different solvents and at different temperatures.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"54 8","pages":"951 - 984"},"PeriodicalIF":1.3,"publicationDate":"2025-05-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145170712","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Micellar-Assisted Oxidation of D-Glucose by Imidazolium Fluorochromate in a 50% (v/v) Aqueous Acetic Acid Medium: A Kinetic and Mechanistic Approach 在50% （v/v）醋酸水溶液中咪唑氟铬酸盐胶束辅助氧化d -葡萄糖：动力学和机理研究

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2025-05-24 DOI: 10.1007/s10953-025-01455-2

Ashish Tomar, Unik Arora, Jai Veer Singh

{"title":"Micellar-Assisted Oxidation of D-Glucose by Imidazolium Fluorochromate in a 50% (v/v) Aqueous Acetic Acid Medium: A Kinetic and Mechanistic Approach","authors":"Ashish Tomar, Unik Arora, Jai Veer Singh","doi":"10.1007/s10953-025-01455-2","DOIUrl":"10.1007/s10953-025-01455-2","url":null,"abstract":"<div><p>This work examined the impact of sodium dodecyl sulfate (SDS) surfactant on the oxidation kinetics of D-glucose employing imidazolium fluorochromate (IFC) as the oxidant. The experiments were conducted under pseudo-first-order conditions at 30 °C, with D-glucose in a significantly higher concentration than IFC. The solvent medium used was 50% (v/v) aqueous acetic acid. The reaction demonstrated a first-order dependence on [IFC] and [HClO<sub>4</sub>]. The order for [D-glucose] oxidation kinetics was slightly less than one. Perchloric acid acted as a catalyst in this process. The addition of acrylonitrile had no effect on rate constants (<i>k</i><sub>obs</sub>). <i>k</i><sub>obs</sub> decreased with an increase in the concentration of Mn(II) ions. An increase in the dielectric constant of the medium had an inverse effect on <i>k</i><sub>obs</sub>. The initial increase in [SDS] led to a corresponding rise in <i>k</i><sub>obs</sub>, though a saturation in <i>k</i><sub>obs</sub> was observed for elevated [SDS]. The Menger-Portnoy and Piszkiewicz models were used to quantitatively assess the experimental results. The binding constant (<i>K</i><sub>p</sub>), cooperativity index (<i>n</i>), and various thermodynamic parameters in the presence of SDS were calculated. Infrared and mass spectroscopy were used to ascertain D-gluconolactone as the primary product of the reaction. Based on these findings, a reaction scheme has been suggested.</p></div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"54 7","pages":"881 - 905"},"PeriodicalIF":1.3,"publicationDate":"2025-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145144740","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Experimental and Theoretical Investigation of Triethylamine Hydrochloride Solubility in Acetonitrile–Dimethyl Carbonate Mixtures 盐酸三乙胺在乙腈-碳酸二甲酯混合物中溶解度的实验与理论研究

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2025-05-22 DOI: 10.1007/s10953-025-01444-5

Junfeng Teng, Fang Zong, Lili Wang, Xiaoyan Sun, Shuguang Xiang

{"title":"Experimental and Theoretical Investigation of Triethylamine Hydrochloride Solubility in Acetonitrile–Dimethyl Carbonate Mixtures","authors":"Junfeng Teng, Fang Zong, Lili Wang, Xiaoyan Sun, Shuguang Xiang","doi":"10.1007/s10953-025-01444-5","DOIUrl":"10.1007/s10953-025-01444-5","url":null,"abstract":"<div><p>This study investigates the solubility of triethylamine hydrochloride (TEA·HCl) in acetonitrile (ACN) and dimethyl carbonate (DMC) mixtures, crucial for optimizing TEA·HCl separation during vinylene carbonate (VC) synthesis. Solubility was measured experimentally at 0.1 MPa from 308.15 K to 343.15 K across ACN mass fractions (<span>({w}_{1})</span>) from 0.1 to 1.0. Results reveal a positive correlation between TEA·HCl solubility, temperature, and <span>({w}_{1})</span>. The Jouyban–Acree, Van’t Hoff–Jouyban–Acree, and Apelblat–Jouyban–Acree models were employed to correlate the solubility data. While generally accurate (average ARD ≈ 8.3%), these models exhibited substantial errors at <span>({w}_{1})</span> = 0.1 (<i>ARD</i> > 40%). Thermodynamic analysis revealed an endothermic, enthalpy-driven dissolution process. Density Functional Theory (DFT) calculations identified a sharp change in solvation free energy at <span>({w}_{1})</span> = 0.1, correlating with the observed solubility deviations and model inaccuracies. This study provides essential solubility data and thermodynamic insights for enhancing TEA·HCl crystallization and separation during VC production, emphasizing the critical role of solvent composition.</p></div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"54 7","pages":"817 - 833"},"PeriodicalIF":1.3,"publicationDate":"2025-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145144299","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Conductometric Study on Potassium Chloride in Aqueous Solutions of Sucrose at Different Temperatures 不同温度下蔗糖水溶液中氯化钾的电导研究

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2025-05-19 DOI: 10.1007/s10953-025-01460-5

Parisa Ghasemi Ilkhechi, Rahman Salamat-Ahangari

引用次数: 0

Adsorption and Desorption of Phenol onto Granular Activated Carbon: Kinetics and Thermodynamic Studies 苯酚在颗粒活性炭上的吸附和解吸：动力学和热力学研究

IF 1.3 4区化学

Journal of Solution Chemistry Pub Date : 2025-05-07 DOI: 10.1007/s10953-025-01458-z

Meriem Sadi, Abdelkader Namane, Yamina Mounia Azri, Insaf Tou

{"title":"Adsorption and Desorption of Phenol onto Granular Activated Carbon: Kinetics and Thermodynamic Studies","authors":"Meriem Sadi, Abdelkader Namane, Yamina Mounia Azri, Insaf Tou","doi":"10.1007/s10953-025-01458-z","DOIUrl":"10.1007/s10953-025-01458-z","url":null,"abstract":"<div><p>Modelization of adsorption and desorption of phenol from granular activated carbon (GAC) by organic solvent acetone and green solvent limonene and then by mixture of both solvents is investigated in this paper. The results showed that the pseudo-second-order kinetic model more appropriately described the phenol adsorption and desorption. The adsorption isotherms at 20, 30, and 40 °C indicated that the Langmuir model better expressed adsorption, while desorption isotherms revealed that desorption is well fitted by Freundlich model. Following adsorption isotherms, the surface occupied with phenol could be calculated indicating that not the whole surface was covered with phenol molecules due to the acidic surface. The negative Δ<i>H</i>° showed that adsorption (− 0.0144 kJ·mol<sup>−1</sup>) and desorption (acetone: − 0.0179 kJ·mol<sup>−1</sup> limonene: − 0.0174 kJ·mol<sup>−1</sup>) were exothermic processes. In addition, the negative Δ<i>S</i>° showed that adsorption (− 0.0178 kJ·mol<sup>−1</sup>·K<sup>−1</sup>) implies the non-affinity of the surface for phenol; however, the positive Δ<i>S</i>° in desorption (acetone: 0.0157 kJ·mol<sup>−1</sup>·K<sup>−1</sup> limonene: 0.0182 kJ·mol<sup>−1</sup>·K<sup>−1</sup>) means an affinity between adsorbent surface and adsorbate. The negative values of free energy Δ<i>G</i>° obtained for adsorption and desorption indicate the feasibility and spontaneous nature of adsorption and desorption process.</p></div>","PeriodicalId":666,"journal":{"name":"Journal of Solution Chemistry","volume":"54 7","pages":"906 - 932"},"PeriodicalIF":1.3,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145142796","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0