Journal of Solid State Electrochemistry最新文献_第2页

Zirconium phenylphosphonate reinforced Ni–B composite coatings: comprehensive analysis of enhanced mechanical properties and corrosion resistance 苯基膦酸锆增强 Ni-B 复合涂层：增强机械性能和耐腐蚀性的综合分析

IF 2.5 4区化学

Journal of Solid State Electrochemistry Pub Date : 2024-09-06 DOI: 10.1007/s10008-024-06057-4

Xiangshan Hou, Jinxue Song, Shijun Xu, Yi He, Yang Bai, Yi Sun, Han Liu, Qing Yuan, Quangang Chen, Kaijun Wei

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Investigation on the performance of phenyl-rich silicon oxycarbide (SiCO) ceramics as electrode material for voltammetric detection of carbendazim 富苯基碳氧硅（SiCO）陶瓷作为伏安法检测多菌灵的电极材料的性能研究

IF 2.5 4区化学

Journal of Solid State Electrochemistry Pub Date : 2024-09-05 DOI: 10.1007/s10008-024-06052-9

Maria de Almeida Silva, Daniela Martins Fernandes de Oliveira, César Ricardo Teixeira Tarley, Mariana Gava Segatelli

{"title":"Investigation on the performance of phenyl-rich silicon oxycarbide (SiCO) ceramics as electrode material for voltammetric detection of carbendazim","authors":"Maria de Almeida Silva, Daniela Martins Fernandes de Oliveira, César Ricardo Teixeira Tarley, Mariana Gava Segatelli","doi":"10.1007/s10008-024-06052-9","DOIUrl":"https://doi.org/10.1007/s10008-024-06052-9","url":null,"abstract":"This paper demonstrated the feasibility of phenyl-rich oxycarbide (SiCO) ceramics as electrode materials in voltammetric measures of carbendazim using cyclic voltammetry. Ceramics were prepared from pyrolysis of poly(dimethylsiloxane-co-diphenyl-siloxane) divinyl terminated, crosslinked with divinylbenzene, 1,3,5,7-tetramethyl-1,3,5,7-tetravinylcyclotetrasiloxane, and in the absence of crosslinking agent, using argon atmosphere up to 1500 °C during 1, 3, and 5 h. Silicon carbide (SiC) crystallites and graphitic carbon domains were produced in the non-crystalline matrices and the phase crystallization was improved as the annealing time increased, mainly in the presence of organic crosslinker. SiCO-based electrode materials were used as a paste (ceramic and mineral oil in 80:20 wt.% proportion), and carbendazim’s voltammetric behavior was compared to commercial glassy carbon electrode (GCE). The electrochemical performance of ceramic electrodes showed a dependence on both polymer chemistry and annealing time, in which organic crosslinker-derived SiCO at 3h annealing displayed the best voltammetric response for carbendazim when compared to other ceramics and commercial GCE. Larger semiconductive SiC crystallites, better graphitization of residual carbon phase, lower charge transfer resistance and higher porosity developed into ceramics derived from organic crosslinker played a crucial role on electrochemical performance of SiCO materials. Apart from the improved performance for carbendazim detection, the unmodified produced ceramics, and their direct use as electrode materials, bring substantial advantages for the preparation of sensors avoiding time-consuming and skills to properly prepare, as usually observed in the modified electrodes.","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142207554","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Facile treatment to eliminate carbon-rich layer in TiO2 nanotube photoanodes 轻松消除 TiO2 纳米管光阳极中的富碳层

IF 2.5 4区化学

Journal of Solid State Electrochemistry Pub Date : 2024-09-05 DOI: 10.1007/s10008-024-06063-6

Ah-yeong Lee, Rin Jung, JeongEun Yoo, Kiyoung Lee

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Disintegrated carbon nanofibers derived from plasma treatment for highly stable sodium metal batteries 用于高稳定性钠金属电池的等离子处理分解纳米碳纤维

IF 2.5 4区化学

Journal of Solid State Electrochemistry Pub Date : 2024-09-02 DOI: 10.1007/s10008-024-06059-2

Qiaorui Jiang, Jianxiang Luo, Tongshuo Zhang, Chengkai Liang, Yuwen Zhao, Tingting Liu, Zilong Li, Jun Wang, Yong Zheng, Zhijia Zhang

{"title":"Disintegrated carbon nanofibers derived from plasma treatment for highly stable sodium metal batteries","authors":"Qiaorui Jiang, Jianxiang Luo, Tongshuo Zhang, Chengkai Liang, Yuwen Zhao, Tingting Liu, Zilong Li, Jun Wang, Yong Zheng, Zhijia Zhang","doi":"10.1007/s10008-024-06059-2","DOIUrl":"https://doi.org/10.1007/s10008-024-06059-2","url":null,"abstract":"Carbon-based materials have been widely used in anodes for sodium metal batteries (SMBs). Surface modification of carbon-based materials is an effective method to improve the de-embedding behavior of sodium metal, which can increase the battery life, whereas SMBs need simpler and more efficient modification methods for practical-grade application. In this paper, novel disintegrated carbon nanofibers (D-CNFs) with rough surfaces were obtained by plasma treatment. D-CNFs exhibited highly reversible sodium deposition characteristics and were able to operate at a low polarization potential of 0.023 V for 800 h. The coulombic efficiency of the D-CNFs was stabilized above 97% after the third cycle. This excellent electrochemical performance is attributed to the disintegration of CNFs as a result of the plasma treatment. The CNFs expose richer vacancies, providing more active sites for sodium metal deposition. This implies that the prepared D-CNFs have better sodium storage properties. Meanwhile, this surface modification facilitates the further application of carbon-based materials in SMBs.","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142207557","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Electrodeposition of Cu2FeSnS4 thin films for solar cell applications: mechanism of deposition and influence of Fe2+ concentration 用于太阳能电池的 Cu2FeSnS4 薄膜的电沉积：沉积机理和 Fe2+ 浓度的影响

IF 2.5 4区化学

Journal of Solid State Electrochemistry Pub Date : 2024-09-02 DOI: 10.1007/s10008-024-06060-9

Omar Ait Layachi, Abderrazzak Boudouma, Hala Hrir, Sara Azmi, Yousra Fariat, Imane Battiwa, Asmaa Moujib, El Mati Khoumri

{"title":"Electrodeposition of Cu2FeSnS4 thin films for solar cell applications: mechanism of deposition and influence of Fe2+ concentration","authors":"Omar Ait Layachi, Abderrazzak Boudouma, Hala Hrir, Sara Azmi, Yousra Fariat, Imane Battiwa, Asmaa Moujib, El Mati Khoumri","doi":"10.1007/s10008-024-06060-9","DOIUrl":"https://doi.org/10.1007/s10008-024-06060-9","url":null,"abstract":"In this study, we successfully synthesized semiconductor thin films of Cu2FeSnS4 (CFTS) using the electrodeposition method. We delved into the mechanisms of electrochemical nucleation and growth, shedding light on these processes. Utilizing potentiostatic current-density-time transient measurements and in situ electrochemical impedance spectroscopy (EIS), we explored the nucleation and growth mechanisms of Cu2FeSnS4 (CFTS) thin films, deposited from an aqueous solution under various applied potentials. Cyclic voltammetry was employed to investigate the electrochemical behaviors of Cu-Fe-Sn-S precursors in a trisodium citrate medium. Chronoamperometry and EIS analysis were conducted to delve deeply into the deposition mechanism and surface electrode-electrolyte phenomena. Furthermore, the study explored the impact of Fe2+ concentration on structural morphology and optical properties. X-ray diffraction and Raman analysis unveiled the stannite structure within the obtained Cu2FeSnS4 thin film, alongside the presence of secondary phases in the CFTS elaborated at both lower and higher concentrations of Fe2+. SEM images reveal that the sulfurized CFTS C2 (0.01 M of Fe2+) sample has a surface morphology with irregular particles. EDS mapping and EDX analysis confirm that the elemental concentrations of Cu, Fe, Sn, and S in the CFTS C2 thin films closely match the desired stoichiometry for Cu2FeSnS4. UV-visible spectroscopy revealed a suitable bandgap energy within the range of 1.5 eV for the film deposited with a Fe2+ concentration of 0.01 M.<h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>\u0000","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142207556","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Stabilizer-free preparation of titanium-based nanowires combined with copper for sensitive detection of 2,4,5-trihydroxybenzoic acid: application in edible oil samples 无稳定剂制备结合铜的钛基纳米线，用于灵敏检测 2,4,5-三羟基苯甲酸：在食用油样品中的应用

IF 2.5 4区化学

Journal of Solid State Electrochemistry Pub Date : 2024-08-29 DOI: 10.1007/s10008-024-06046-7

Jeovana C. Pacheco, Scarllett L. Lima, Liying Liu, Alan S. de Menezes, Marco A. S. Garcia, Flávio S. Damos, Rita C. S. Luz

{"title":"Stabilizer-free preparation of titanium-based nanowires combined with copper for sensitive detection of 2,4,5-trihydroxybenzoic acid: application in edible oil samples","authors":"Jeovana C. Pacheco, Scarllett L. Lima, Liying Liu, Alan S. de Menezes, Marco A. S. Garcia, Flávio S. Damos, Rita C. S. Luz","doi":"10.1007/s10008-024-06046-7","DOIUrl":"https://doi.org/10.1007/s10008-024-06046-7","url":null,"abstract":"2,4,5-Trihydroxybenzoic acid (THBA) is a synthetic antioxidant used in the food industry that has attracted attention due to the potential risks it may pose to human health; thus, ensuring compliance with legal standards is essential. In this regard, the present study describes the development of an electrochemical platform based on a carbon-printed electrode (SPE) modified with titanium (Ti)-based nanowires (NWs) for THBA detection. However, the synthesis of Ti-based NWs involved varying copper (Cu) quantities, resulting in few morphological changes compared to the unmodified counterpart. Interestingly, the syntheses were carried out without organic stabilizers, resulting in the preparation of cleaner nanostructures; such an approach was planned to enhance the electrochemical sensing performance, reduce costs, and promote environmental friendliness. Moreover, it improves charge transfer efficiency, making the synthesis process ideal for sustainable nanomaterial production. XRD analyses indicate that the addition of the metal affected the structure of the Ti-based NWs. Also, SEM images revealed that the unmodified SPE exhibited a smooth surface, whereas the Cu-modified Ti-based NWs/SPE showed a dense network of such material. In addition, the electrochemical studies have shown an enhancing of the electrocatalytic properties after the introduction of copper. Under optimized conditions, it was found that THBA can be determined over a wide working range from 500 pmol L−1 to 5000 µmol L−1. The applicability of the sensor was verified by detecting THBA in soybean oil and sunflower oil samples, showing excellent recovery values between 96.30 and 101.87%, suggesting that the proposed sensor demonstrates good accuracy and can be successfully applied to edible oil samples.","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-08-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142207558","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Electrochemical applications of fly ash as surface modifier: sustainable mitigation of industrial residue 粉煤灰作为表面改性剂的电化学应用：可持续地缓解工业残留物问题

IF 2.5 4区化学

Journal of Solid State Electrochemistry Pub Date : 2024-08-28 DOI: 10.1007/s10008-024-06049-4

Shubhangi Shukla, Sachin Kadian, Roger J. Narayan

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Bimetallic MOF-derived manganese-cobalt composite oxide as high-performance zinc-ion batteries cathode 作为高性能锌离子电池阴极的双金属 MOF 衍生锰钴复合氧化物

IF 2.5 4区化学

Journal of Solid State Electrochemistry Pub Date : 2024-08-26 DOI: 10.1007/s10008-024-06050-x

Bingzhe Ma, Youfeng Zhang, Yaping Feng, Sikai Wang, Yinling Wang, Wenzhu Zhang

{"title":"Bimetallic MOF-derived manganese-cobalt composite oxide as high-performance zinc-ion batteries cathode","authors":"Bingzhe Ma, Youfeng Zhang, Yaping Feng, Sikai Wang, Yinling Wang, Wenzhu Zhang","doi":"10.1007/s10008-024-06050-x","DOIUrl":"https://doi.org/10.1007/s10008-024-06050-x","url":null,"abstract":"The designing cathode materials of aqueous zinc-ion batteries (AZIBs) with high performance is significant challenges in the development of AZIBs. Metal–organic frameworks (MOFs) are considered prime candidates for cathode modification and high-performance cathode materials. Herein, a two-step hydrothermal method was employed to fabricate a bimetallic metal–organic framework MnCo-MOF on carbon cloth. The resulting precursor was calcined to produce a cathode composite MnCo2O4. As a cathode for AZIBs, MnCo2O4/CC exhibited an average specific capacity of 280.6 mAh/g. Upon completion of the cycle at a current density of 0.2 A/g, the specific capacity measured 275.1 mAh/g (retaining 98% of its initial capacity), while maintaining a coulombic efficiency of approximately 98.5%. The excellent cycling performance, superior specific capacity, and superb coulombic efficiency are ascribed to the concerted influence of the polymetallic ions. The micro and nano scale interconnected block structure of MnCo2O4 facilitates interaction between electrode substance and the electrolyte. This research broadens the selection of cathode material and offers valuable guidance for designing high-performance cathode materials for AZIBs.","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142207560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Electrodeposited binder-free Cu-Mn-S nanosheets for high-performance asymmetric supercapacitor devices 电沉积无粘结剂铜锰硒纳米片用于高性能不对称超级电容器设备

IF 2.5 4区化学

Journal of Solid State Electrochemistry Pub Date : 2024-08-26 DOI: 10.1007/s10008-024-06024-z

Yanqin Xu, Wucui Ren, Hong Wu, Yu Song, Chengyong Huang, Menghao Liu, Biemin Sun, Min Liu, Changguo Chen, Xueming Li

{"title":"Electrodeposited binder-free Cu-Mn-S nanosheets for high-performance asymmetric supercapacitor devices","authors":"Yanqin Xu, Wucui Ren, Hong Wu, Yu Song, Chengyong Huang, Menghao Liu, Biemin Sun, Min Liu, Changguo Chen, Xueming Li","doi":"10.1007/s10008-024-06024-z","DOIUrl":"https://doi.org/10.1007/s10008-024-06024-z","url":null,"abstract":"In this study, three-dimensional interconnected nanosheet-like binder-free Cu-Mn-S@NF composites were efficiently fabricated on nickel foam by one-step electrochemical deposition and optimized for metal ion deposition concentration to improve the problem of electrochemical performance degradation due to volume expansion of supercapacitor electrode materials. Owing to the unique structure that provides many active sites and a stable skeleton structure that fully promotes the diffusion of ions from the electrolyte into the electrode material, the three-dimensional interconnected nanosheet Cu-Mn-S@NF electrode material exhibits excellent electrochemical properties, and the structure prevents agglomeration and volume expansion during charge/discharge cycles, alleviating active material shedding. Under the three-electrode system, Cu-Mn-S@NF exhibits excellent electrochemical performance with a high specific capacitance of 2468.8 F g−1 at a current density of 2 A g−1, and it still maintains a specific capacitance of 1940 F g−1 at a high specific capacitance of 10 A g−1, with a multiplier performance of 78.58%. The assembled Cu-Mn-S@NF//AC HSC can obtain a maximum specific capacitance of 153.1 F g−1 (1 A g−1), an energy density as high as 54.47 Wh kg−1 at a power density of 800 W kg−1, and 70.23% capacitance retention after 6000 cycles.","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142207561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Dual-coated single-crystal LiNi0.6Co0.2Mn0.2O2 as high-performance cathode materials for lithium-ion batteries 作为高性能锂离子电池正极材料的双涂层单晶 LiNi0.6Co0.2Mn0.2O2

IF 2.5 4区化学

Journal of Solid State Electrochemistry Pub Date : 2024-08-24 DOI: 10.1007/s10008-024-06048-5

Wanmin Liu, Sisha Zeng, Piaopiao Wang, Jing Huang, Bin Shen, Mulan Qin, Weigang Wang, Zexun Tang

{"title":"Dual-coated single-crystal LiNi0.6Co0.2Mn0.2O2 as high-performance cathode materials for lithium-ion batteries","authors":"Wanmin Liu, Sisha Zeng, Piaopiao Wang, Jing Huang, Bin Shen, Mulan Qin, Weigang Wang, Zexun Tang","doi":"10.1007/s10008-024-06048-5","DOIUrl":"https://doi.org/10.1007/s10008-024-06048-5","url":null,"abstract":"Due to its superior high discharge capacity and cycling stability, single-crystal LiNi0.6Co0.2Mn0.2O2 cathode materials are rapidly gaining traction in the realm of electric vehicle power batteries. Nevertheless, the deterioration of surface structure in single-crystal LiNi1−x−yCoxMnyO2 cathode materials is further exacerbated when operating at higher cutoff voltages (exceeding 4.5 V). In this work, a unique single-crystal LiNi0.6Co0.2Mn0.2O2 with ZnO and AlPO4 dual-coating modification has been synthesized. The similar crystal structure of ZnO and NCM results in a more compact coating, while the incorporation of AlPO4 enhances both the electronic conductivity (through the formation of conductive oxide Al-doped ZnO) and lithium-ion conductivity (via the formation of Li3PO4) within the coating. The coated SC-NCM cathode material exhibits excellent electrochemical performance even when operated at a higher cutoff voltage of 4.5 V. After 100 cycles (1 C, 2.75–4.5 V), the capacity retention for the ZnO and AlPO4 coated SC-NCM sample reaches 91.2%, significantly surpassing that of the pristine samples (40.0%). Specifically, it exhibited an outstanding rate property, maintaining a discharge capacity of 150.8 mA h g−1 at 8 C. The exceptional electrochemical properties can be attributed to the distinctive coating layer, which serves not only as a physical barrier to mitigate electrolyte side reactions but also facilitates rapid conduction of electrons and lithium ions.","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":null,"pages":null},"PeriodicalIF":2.5,"publicationDate":"2024-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142226504","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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