Journal of Polymer Research最新文献

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Enhanced thermal stability and mechanical performance of epoxy resin with amine-terminated aromatic amide oligomer: unveiling the ring-opening curing phenomenon 用胺端芳香族酰胺低聚物增强环氧树脂的热稳定性和机械性能:揭示开环固化现象
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2024-10-24 DOI: 10.1007/s10965-024-04163-5
M. Tariq Qamar, Ali Bahadur, Shahid Iqbal, Ammar Zidan, Sajid Mahmood, D. Ahmed, Nadia Akram, H. Abid, Muhammad Abdul Qayyum, Nasser S. Awwad, Hala A. Ibrahium, Toheed Akhter
{"title":"Enhanced thermal stability and mechanical performance of epoxy resin with amine-terminated aromatic amide oligomer: unveiling the ring-opening curing phenomenon","authors":"M. Tariq Qamar,&nbsp;Ali Bahadur,&nbsp;Shahid Iqbal,&nbsp;Ammar Zidan,&nbsp;Sajid Mahmood,&nbsp;D. Ahmed,&nbsp;Nadia Akram,&nbsp;H. Abid,&nbsp;Muhammad Abdul Qayyum,&nbsp;Nasser S. Awwad,&nbsp;Hala A. Ibrahium,&nbsp;Toheed Akhter","doi":"10.1007/s10965-024-04163-5","DOIUrl":"10.1007/s10965-024-04163-5","url":null,"abstract":"<p>Amine-terminated aromatic amide oligomer (ATAAO) was used to cure diglycidyl ether of bisphenol A epoxy resin. P-phenylenediamine (PPDA) and isophthaloyl chloride (IPC) underwent a condensation reaction to synthesize the oligomer using dimethyl acetamide (DMAc) as the solvent. The successful synthesis and semi-crystalline nature of oligomer was confirmed using <sup>1</sup>HNMR, FT-IR, and X-ray diffraction, respectively. The curing reaction was carried out by mixing ATAAO and diglycidyl ether of bisphenol A (DGEBA) epoxy resin in DMAc, followed by curing at 363.15 K and 393.15 K for 30, 60, 90 and 120 min, respectively. Moreover, the ring-opening curing phenomenon in epoxy was confirmed by <sup>1</sup>HNMR and FT-IR. XRD analysis revealed the amorphous nature of the cured epoxy. Thermal analysis revealed an increase in thermal stability (553.21 K to 580.32 K) and glass transition temperature (423.21 K to 481.61 K) with increasing curing temperature (363.15 K to 393.15 K) and curing duration (30 min to 120 min). Stress–strain analysis revealed an increase in Young’s modulus (5.93 MPa to 41.09 MPa) and stress at the break (7.79 MPa to 31.92 MPa) of cured epoxy films with changing curing conditions. Moreover, a homogeneous surface of cured epoxy films containing slight bumps and small globular without any phase separation was observed in scanning electron micrographs.</p>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142518696","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Calamus tenuis fiber reinforced epoxy composites: effect of fiber loading on the tensile, structural, crystalline, thermal and morphological characteristics 菖蒲纤维增强环氧树脂复合材料:纤维负载对拉伸、结构、结晶、热和形态特征的影响
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2024-10-24 DOI: 10.1007/s10965-024-04162-6
Arup Kar, Dip Saikia, Sivasubramanian Palanisamy, Narayanasamy Pandiarajan
{"title":"Calamus tenuis fiber reinforced epoxy composites: effect of fiber loading on the tensile, structural, crystalline, thermal and morphological characteristics","authors":"Arup Kar,&nbsp;Dip Saikia,&nbsp;Sivasubramanian Palanisamy,&nbsp;Narayanasamy Pandiarajan","doi":"10.1007/s10965-024-04162-6","DOIUrl":"10.1007/s10965-024-04162-6","url":null,"abstract":"<div><p>This study utilized <i>Calamus tenuis</i> fiber as reinforcement in fiber-reinforced polymer composites, focusing on the structural, crystalline, thermal, tensile, and morphological properties of <i>Calamus tenuis</i> fiber-reinforced epoxy composites (CTF/Epoxy composites). The composites were fabricated using the hand lay-up method, incorporating fiber weight fractions ranging from 0 wt% (neat epoxy) to 25 wt%, increasing in 5 wt% increments. FTIR spectroscopy identified the chemical compounds and functional groups, while XRD analysis confirmed that the crystalline structure of the composites remained unchanged with the addition of <i>Calamus tenuis</i> fibers. Thermogravimetric analysis (TGA) revealed that the 10 wt% CTF/Epoxy composite exhibited the highest thermal stability among the tested compositions. Differential Scanning Calorimetry (DSC) analysis indicated an increased glass transition temperature (T<sub>g</sub>) in the 10 wt% CTF/Epoxy composite, further confirming improved thermal stability. Notably, the 10 wt% fiber content led to significant improvements in tensile properties, with tensile strength increasing from 17.5 ± 1.42 MPa to 21.08 ± 1.03 MPa, and Young’s modulus rising from 2.53 ± 0.12 GPa to 2.84 ± 0.09 GPa. Scanning Electron Microscopy (SEM) demonstrated enhanced fiber-epoxy bonding, while Atomic Force Microscopy (AFM) indicated increased roughness with higher fiber loadings. Overall, the 10 wt% CTF/Epoxy composite shows substantial potential for structural and infrastructure applications.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142518632","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polymer blend compositions reliant comprehensive study on optical, thermal, structural, and broadband dielectric and electrical properties of P(VDF-HFP)/PMMA films 基于聚合物混合成分的 P(VDF-HFP)/PMMA 薄膜光学、热学、结构、宽带介电和电学特性综合研究
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2024-10-23 DOI: 10.1007/s10965-024-04176-0
Chandra Prabha Charan, R. J. Sengwa
{"title":"Polymer blend compositions reliant comprehensive study on optical, thermal, structural, and broadband dielectric and electrical properties of P(VDF-HFP)/PMMA films","authors":"Chandra Prabha Charan,&nbsp;R. J. Sengwa","doi":"10.1007/s10965-024-04176-0","DOIUrl":"10.1007/s10965-024-04176-0","url":null,"abstract":"<div><p>In developing flexible type advanced electrical and electronic devices, rationally designed excellent performance polymer dielectrics are highly admired in technological industries. To contribute in this field, herein, the entire composition ratios polymer blend (PB) films of poly(vinylidenefluoride-co-hexafluoropropylene) (P(VDF-HFP)) and poly(methyl methacrylate) (PMMA) are prepared following the solution-cast procedure. The prepared PB films are designated as <i>x</i>P(VDF-HFP)/(100-<i>x</i>)PMMA, where <i>x</i> is varied, in steps, as 100, 80, 50, 20, and 00 wt%. The optical, thermal, structural, and broadband dielectric and electrical properties of these PB films are characterized in detail employing advanced instruments and interpreted meaningfully with blend compositions. The ultraviolet–visible (UV–Vis) spectroscopic results confirmed predominantly composition tunable UV absorbance as well as energy bandgap values of these PB films, which decreased when the P(VDF-HFP) amount was relatively reduced. Differential scanning calorimetry (DSC) measurements explained the reduction in the degree of crystallinity and crystallite thermal stability on decreasing the P(VDF-HFP) amount in the blend and also their transformation to amorphous type miscible blend for the compositions having PMMA amount exceeding 60 wt%. The Fourier transform infrared (FTIR) spectra also elucidated the formation of miscible blends for PMMA-rich compositions owing to a large increase in heterogeneous hydrogen bonding. The broadband dielectric spectroscopic measurements over the nine decades of harmonic electric field frequency (20 Hz to 1 GHz range) unveiled the contribution of various polarization processes and their alteration with frequencies that govern the dielectric permittivity and its dispersion, and different relaxations related to the structural dynamics of the blended polymers. The outcome provides a facile strategy to realize the composition reliant dielectric and optical properties of P(VDF-HFP)/PMMA blend films and helps in proposing their feasible applications as innovative optical and dielectric materials for flexible technologies.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142518999","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pyrazine substituted chitosan: an adsorbent material for the efficient removal of anionic dyes from aqueous solutions 吡嗪取代壳聚糖:一种从水溶液中高效去除阴离子染料的吸附材料
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2024-10-23 DOI: 10.1007/s10965-024-04173-3
S. M Anush, C. S Kaliprasad, Gangadhar Gowda P H, B. H Gayathri, Y. R Girish, K Prashantha, Subramaniyan Ramasundaram, Mohammad Altaf, Tae Hwan Oh, Mani Durai
{"title":"Pyrazine substituted chitosan: an adsorbent material for the efficient removal of anionic dyes from aqueous solutions","authors":"S. M Anush,&nbsp;C. S Kaliprasad,&nbsp;Gangadhar Gowda P H,&nbsp;B. H Gayathri,&nbsp;Y. R Girish,&nbsp;K Prashantha,&nbsp;Subramaniyan Ramasundaram,&nbsp;Mohammad Altaf,&nbsp;Tae Hwan Oh,&nbsp;Mani Durai","doi":"10.1007/s10965-024-04173-3","DOIUrl":"10.1007/s10965-024-04173-3","url":null,"abstract":"<div><p>In the present work, a novel pyrazine based chitosan material was synthesized by functionalizing chitosan with chloroacetyl chloride and further modification with ethylene 1,2 diamine, thus a polymer matrix is obtained. Further the adsorbent material was characterized and verified using analytical techniques such as XRD, SEM, FTIR and TGA. The adsorbent material was analyzed for the adsorptive take-up process with a initial dye concentration varying from 20–100 mgL<sup>−1</sup> and the adsorptive process occurred due to the electrostatic interaction between the nitrogen atom of chitosan and the methyl orange dye molecule. The equilibrium adsorptive capacity obtained for the synthesized adsorbent material was 45.45 mg g<sup>−1</sup>. The adsorptive mechanism predicted the electrostatic interaction between the two atoms and the increased in the adsorption efficiency is contributed by the increased number of hetero atoms in the chitosan structure and the adsorption kinetics was found to be pseudo-second-order kinetics and with a monolayer coverage process indicating the Langmuir adsorption isothermal fit. Further, the evaluated thermodynamic parameters showed the adsorption process to be non-spontaneous and endothermic in nature. A regeneration and reusability study was achieved for the composite material using convenient stripping solutions and the adsorbent was successfully regenerated.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10965-024-04173-3.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142518997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of shear resistance of dendritic hydrophobic association polymers 评估树枝状疏水缔合聚合物的抗剪切性
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2024-10-21 DOI: 10.1007/s10965-024-04177-z
Shijie Zhu, Mei Xu, Shuanglai Yang, Zhuangzhuang Huang, Yang Wang, Yong Zhu
{"title":"Evaluation of shear resistance of dendritic hydrophobic association polymers","authors":"Shijie Zhu,&nbsp;Mei Xu,&nbsp;Shuanglai Yang,&nbsp;Zhuangzhuang Huang,&nbsp;Yang Wang,&nbsp;Yong Zhu","doi":"10.1007/s10965-024-04177-z","DOIUrl":"10.1007/s10965-024-04177-z","url":null,"abstract":"<div><p>Enhancing the shear resistance of polymer systems is crucial for advancing oil recovery in the realm of chemical flooding technology. This article presents a comparative analysis of the rheological curves, hydrodynamic dimensions, dynamic adsorption, and permeation characteristics of two independently synthesized dendritic hydrophobic association polymers (DHAP) and linear polyacrylamide (HPAM), both before and after exposure to shear in porous media. The research findings indicate that linear polymer solutions exhibit inadequate shear resistance. Through the synergistic effects of association and branching structures, dendritic hydrophobic polymer solutions can partially recover their spatial configuration, thereby mitigating the impact of shear on their solution properties, including viscoelasticity, hydrodynamic size, and adsorption capacity. These polymers can achieve high dynamic retention in porous media and establish flow control capabilities through the residual resistance coefficient. Consequently, further optimization of the molecular structure and the application of non-covalent bonding forces to enhance shear resistance and adsorption retention capacity represent key directions for the future development of polymer systems.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142452975","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of the excellent adsorption performance for lead ions of (sodium alginate/ waste para-aramid)-based polymer composite functionalized by ethylene diamine tetra (methylene phosphonic acid) 评估由乙二胺四乙酸(亚甲基膦酸)功能化的(海藻酸钠/废对位芳纶)基聚合物复合材料对铅离子的优异吸附性能
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2024-10-21 DOI: 10.1007/s10965-024-04158-2
Wansong Zhang, Feifei Li, Ping Yin, Zhenglong Yang, Yanbin Xu, Feng Wang, Ying Wang, Wenjuan Sun, Honglan Cai
{"title":"Evaluation of the excellent adsorption performance for lead ions of (sodium alginate/ waste para-aramid)-based polymer composite functionalized by ethylene diamine tetra (methylene phosphonic acid)","authors":"Wansong Zhang,&nbsp;Feifei Li,&nbsp;Ping Yin,&nbsp;Zhenglong Yang,&nbsp;Yanbin Xu,&nbsp;Feng Wang,&nbsp;Ying Wang,&nbsp;Wenjuan Sun,&nbsp;Honglan Cai","doi":"10.1007/s10965-024-04158-2","DOIUrl":"10.1007/s10965-024-04158-2","url":null,"abstract":"<div><p>With the rapid development of industry, efficient removal of heavy metal ions such as lead ions in wastewater has been attracted much attention in the fields of water treatment and environmental remediation. Herein, a novel polymer composite adsorbent material EDTMPA-P/A has been successfully prepared through the combination of sodium alginate and waste para aramid using low-temperature esterification method, and the subsequent modification of EDTMPA (ethylene diamine tetra (methylene phosphonic acid)). The static saturation adsorption experiment verified that EDTMPA-P/A had significant adsorption performance for lead ions, hence, EDTMPA-P/A has been employed to adsorb lead ions from aqueous solutions, and the relevant adsorption behaviors of the polymer composite adsorbent for lead ions have been investigated in detail. The adsorption isotherm of EDTMPA-P/A was consistent with the Langmuir isotherm model, and the corresponding kinetics data were well fitted by the pseudo-second-order kinetic model. The maximum adsorption capacity of EDTMPA-P/A obtained by Langmuir isotherm for lead ions was 315.46 mg/g at 35 °C, which was much higher than other adsorbents reported in the literatures. Moreover, the adsorption thermodynamic parameters Δ<i>G</i>, Δ<i>H</i> and Δ<i>S</i> of EDTMPA-P/A for lead ions were 1.92 kJ mol<sup>−1</sup> (35 °C), 14.69 kJ mol<sup>−1</sup>, and 41.74 J K<sup>−1</sup> mol<sup>−1</sup>, respectively. The research results indicated that EDTMPA-P/A could be evaluated as a novel efficient adsorbent with high efficiency in wastewater treatment and removal of lead ions, and it is great application prospect that EDTMPA-P/A with facile esterification synthesis at low temperature, modification process and excellent adsorption performance, therefore, could be used as a high efficient adsorbent for lead ions removal, which also has simultaneously achieved the reuse object of waste para aramid.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-10-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142452983","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nanofillers tailored polymers and enhanced synergistic properties for engineering applications: A review 纳米填料定制聚合物和增强工程应用的协同性能:综述
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2024-10-16 DOI: 10.1007/s10965-024-04165-3
Biniam Tamrea Gebretsadik, Addisu Negash Ali
{"title":"Nanofillers tailored polymers and enhanced synergistic properties for engineering applications: A review","authors":"Biniam Tamrea Gebretsadik,&nbsp;Addisu Negash Ali","doi":"10.1007/s10965-024-04165-3","DOIUrl":"10.1007/s10965-024-04165-3","url":null,"abstract":"<div><p>Polymers tailored with different nanofillers are potentially used to fill the gaps of conventional materials for various engineering applications. This can be done because of the exceptional synergistic properties of nanofillers and polymers. Nanofillers have unique mechanical, electrical, and thermal properties. They can be reinforced with the flexible polymer matrix to develop advanced polymer nanocomposites and achieve great engineering performance. The nanofillers tailored nanocomposite have enhanced synergistic properties and functionality, which make it suitable for various engineering applications such as automotive, structural health monitoring, aerospace, coating, electronics devices, biomedical devices, and others. Polymer nanocomposites synthesized using techniques such as in-situ polymerization, the melt intercalation method, the solution intercalation method, and the mixing method showed improved properties. To obtain the polymer nanocomposite with the required quality and performance, we need to consider essential design parameters such as nanofiller types, concentrations, shapes, dispersity, sizes and interfacial relations during the design and optimization processes. The performance and properties of polymer nanocomposites evaluated by using the rheological tests, thermogravimetric analysis (TGA), micromechanical analysis, and dynamic mechanical analysis (DMA) showed the enhanced synergistic properties compared to the pure polymer material.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142438676","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Toward a green economy: Lignin-based hybrid materials as functional additives in flame-retardant polymer coatings 迈向绿色经济:木质素基杂化材料作为阻燃聚合物涂料中的功能添加剂
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2024-10-16 DOI: 10.1007/s10965-024-04169-z
Marta Goliszek, Beata Podkościelna, Przemysław Rybiński, Izabela Klapiszewska, Tomasz Klepka, Anna Masek, Łukasz Klapiszewski
{"title":"Toward a green economy: Lignin-based hybrid materials as functional additives in flame-retardant polymer coatings","authors":"Marta Goliszek,&nbsp;Beata Podkościelna,&nbsp;Przemysław Rybiński,&nbsp;Izabela Klapiszewska,&nbsp;Tomasz Klepka,&nbsp;Anna Masek,&nbsp;Łukasz Klapiszewski","doi":"10.1007/s10965-024-04169-z","DOIUrl":"10.1007/s10965-024-04169-z","url":null,"abstract":"<div><p>This study describes the combination of unique properties of lignin with TiO<sub>2</sub> as an innovative and effective preparation method for high-performance flame-retardant additives that may be utilized as polymer coatings. The use of lignin resulted in numerous advantages including an increased number of functional groups, satisfactory biocompatibility, low toxicity, and high carbon content. The major benefit of lignin is associated with the reduced carbon footprint of the manufactured product. Lignin can be classified as a natural flame-retardant agent owing to the high amount of char formed during combustion. In turn, TiO<sub>2</sub> exhibits high chemical stability and low operating costs and is considered a non-toxic and environmentally friendly material. During the experiments, commercial TiO<sub>2</sub> in anatase crystallographic form, TiO<sub>2</sub> synthesized from titanyl sulfate hydrate, and kraft lignin as well as organic–inorganic hybrid materials composed of these materials were evaluated as functional additives in epoxy-resin-based polymer coatings (Epidian 601) and their properties were investigated in detail. The cone colorimetry test confirmed that the obtained hybrids are effective flame-retardant additives for polymer coatings, with a notable fire hazard reduction observed for samples containing a synergistic system of titanium oxide and lignin. The coating with lignin was the most effective in fire suppression processes. The conducted thermal and mechanical investigations confirmed good performance properties of the coatings indicating thermal resistance up to 360 °C and Shore D hardness in a range of 80.36–86.28°Sh, accordingly. Optical profilometry investigations show that the lignin/TiO<sub>2</sub> hybrids exhibit a stable topological surface shape as well as good dispersion and uniformity in the polymer matrix. All the conducted tests allowed confirmation that the presence of functional additives in polymer coatings in the form of lignin and TiO<sub>2</sub> can be a promising alternative to non-biodegradable synthetic materials which improve flame-retardant properties.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10965-024-04169-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142438674","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of pyridine based porous organic polymers as new adsorbents to remove Congo red dye from aqueous media 制备吡啶基多孔有机聚合物,作为从水介质中去除刚果红染料的新型吸附剂
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2024-10-16 DOI: 10.1007/s10965-024-04166-2
Farshad Dastyar, Mohammad Dinari
{"title":"Preparation of pyridine based porous organic polymers as new adsorbents to remove Congo red dye from aqueous media","authors":"Farshad Dastyar,&nbsp;Mohammad Dinari","doi":"10.1007/s10965-024-04166-2","DOIUrl":"10.1007/s10965-024-04166-2","url":null,"abstract":"<div><p>Existence of pollutants in water sources is a global worry that needs the expansion of novel and efficient solutions. This study aimed to synthesize porous organic polymers (POPs) from triazine and di-aminopyridine to effectively eliminate the Congo red (CR) dye from water environments. Two porous organic polymers based on imine (POP-IB) and amine (POP-AB) groups were synthesized from the reaction of diamino-pyridine with trialdehyde for POP-IB and cyanuric chloride for POP-AB. The synthesized POPs were charactized by different techniques and exhibit good thermal and chemical stability, rendering them ideal for the removal of CR dye from aqueous solutions. Additionally, our study examined the optimization process, which involved adjusting various parameters such as pH, time duration, initial dye concentration, and the amount of adsorbent. The study showed that the maximum adsorption capacities for the CR dye were 104 mg g<sup>−1</sup> with POP-IB at pH 6 over 240 min, and 63 mg g<sup>−1</sup> with POP-AB at pH 5 over 180 min, respectively. Kinetic models suggest that the adsorption of CR dye onto these adsorbents is most accurately described by the pseudo-second-order. Moreover, the Langmuir isotherm provides the closest correlation with the adsorption isotherms for both POPs.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142438675","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sugarcane bagasse for sustainable development of thermoset biocomposites 甘蔗渣促进热固性生物复合材料的可持续发展
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2024-10-16 DOI: 10.1007/s10965-024-04168-0
Resego Phiri, Sanjay Mavinkere Rangappa, Suchart Siengchin
{"title":"Sugarcane bagasse for sustainable development of thermoset biocomposites","authors":"Resego Phiri,&nbsp;Sanjay Mavinkere Rangappa,&nbsp;Suchart Siengchin","doi":"10.1007/s10965-024-04168-0","DOIUrl":"10.1007/s10965-024-04168-0","url":null,"abstract":"<div><p>Lignocellulosic natural fibers are increasingly utilized as reinforcements in thermoset matrix composites, driven by economic and environmental demands. Sugarcane bagasse, a byproduct of the sugar industry, is a particularly promising source of these fibers. This study thus explores the development of sustainable composites by incorporating sugarcane bagasse fibers into bio-epoxy and unsaturated polyester resin matrices. Chemical treatments, including alkali, silane and oxalic acid, were applied to enhance fiber-matrix adhesion and improve mechanical, thermal and physical properties. The physical measurements revealed that chemical modifications of the bagasse have a significant impact on the density, water absorption and wettability of both thermosetting matrices. Additionally, SEM analysis revealed variations in composite morphology, such as brittle matrix failure, fiber breakage, fiber pullouts and voids, with the alkali-treated fibers exhibiting the best fiber-matrix interface for both types of resins. The mechanical testing of the composites reinforced with untreated and chemically treated sugarcane bagasse particulates revealed distinct variations in tensile strength and modulus, flexural strength and modulus, impact strength and hardness cross the different treatments. Superior mechanical performance was observed for the alkali treated specimen. Similarly, from the degradation temperatures and activation energies from the thermal analysis, the alkali treated fibers provided better thermal stability. These findings highlight the potential of sugarcane bagasse in eco-friendly composite design, though further research is needed to optimize treatments for better performance.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":null,"pages":null},"PeriodicalIF":2.6,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142438677","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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