Journal of Polymer Research最新文献

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Optically clear pressure sensitive adhesives with multiple hydrogen bond cross-linking
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2025-03-20 DOI: 10.1007/s10965-025-04328-w
Shuanghao Kang, Tianle Li, Han Jiang, Ziheng Fu, Renjin Gao, Qinhui Chen, Jianrong Xia
{"title":"Optically clear pressure sensitive adhesives with multiple hydrogen bond cross-linking","authors":"Shuanghao Kang,&nbsp;Tianle Li,&nbsp;Han Jiang,&nbsp;Ziheng Fu,&nbsp;Renjin Gao,&nbsp;Qinhui Chen,&nbsp;Jianrong Xia","doi":"10.1007/s10965-025-04328-w","DOIUrl":"10.1007/s10965-025-04328-w","url":null,"abstract":"<div><p>Optically transparent pressure-sensitive adhesives (PSAs) present several challenges. Conventional PSAs typically improve cohesive strength through chemical crosslinking; however, this approach not only reduces adhesion but also diminishes light transmittance. In this study, we explored hydrogen bonding crosslinking as a replacement for conventional chemical crosslinking and successfully synthesized the crosslinker UPyHCBA, which contains UPy units capable of forming self-complementary dimers through quadruple hydrogen bonds. A transparent acrylic PSAs incorporating the UPyHCBA monomer was then synthesized via solution polymerization. By modifying the ratio of UPyHCBA, we thoroughly investigated the impact of multiple hydrogen bonds on the molecular weight distribution, adhesive properties, thermal properties, light transmission, rheological behavior, and photoluminescence spectral properties of a specific optically transparent pressure-sensitive adhesive (PSAs).</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":"32 4","pages":""},"PeriodicalIF":2.6,"publicationDate":"2025-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143655207","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of natural weathering on aesthetics, structural, morphological, and mechanical properties of the palm petiole fibers/LLDPE composites
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2025-03-19 DOI: 10.1007/s10965-025-04324-0
Nedjla Debabeche, Hamida Boussehel, Amina Hachaichi, Mohd Rehan Khan, Othman Alothman, Oumkeltoum Kribaa, Belhi Guerira, Mohammad Jawaid
{"title":"Influence of natural weathering on aesthetics, structural, morphological, and mechanical properties of the palm petiole fibers/LLDPE composites","authors":"Nedjla Debabeche,&nbsp;Hamida Boussehel,&nbsp;Amina Hachaichi,&nbsp;Mohd Rehan Khan,&nbsp;Othman Alothman,&nbsp;Oumkeltoum Kribaa,&nbsp;Belhi Guerira,&nbsp;Mohammad Jawaid","doi":"10.1007/s10965-025-04324-0","DOIUrl":"10.1007/s10965-025-04324-0","url":null,"abstract":"<div><p>This study explores the impact of natural weathering on the mechanical, structural, morphological, and aesthetic properties of linear low-density polyethylene (LLDPE) composites reinforced with 15% palm petiole fibers (PPF) subjected to successive chemical treatments. Composites were exposed to Biskra, Algeria’s arid conditions for 360 days. FTIR analysis identified carbonyl peak formation, signifying oxidation, while weight loss measurements revealed enhanced biodegradability in treated composites, with weight loss proportional to exposure duration. SEM micrographs demonstrated pronounced surface deterioration in sodium hydroxide and hydrogen peroxide-treated composites compared to acetylated variants, which exhibited better resistance. Notably, UV-induced cross-linking in the polymer matrix and fiber recrystallization improved tensile strength and Young’s modulus. These findings highlight the potential of chemically treated PPF/LLDPE composites for sustainable applications in arid environments, balancing enhanced mechanical performance with biodegradability.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":"32 4","pages":""},"PeriodicalIF":2.6,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143645497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Graphene reinforced UHMWPE fibers
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2025-03-19 DOI: 10.1007/s10965-025-04319-x
ZhiJing Xue, Kenneth R. Brown, Timothy M. Harrell, Xiaodong Li
{"title":"Graphene reinforced UHMWPE fibers","authors":"ZhiJing Xue,&nbsp;Kenneth R. Brown,&nbsp;Timothy M. Harrell,&nbsp;Xiaodong Li","doi":"10.1007/s10965-025-04319-x","DOIUrl":"10.1007/s10965-025-04319-x","url":null,"abstract":"<div><p>Thermoplastic polymers are increasingly used in electric vehicles, hydrogen fuel cell vehicles, and other decarbonization applications due to their lightweight and formability. Higher-strength polymers are needed to supplant metals in the vehicle structure, thereby reducing mass and improving efficiency. Ultra-high molecular weight polyethylene (UHMWPE) fibers possess one of the highest strength-to-weight ratios of technical polymers, and further improvement via reinforcement by nanofillers, such as graphene, will expand their performance envelope. In this work, UHMWPE/graphene nanocomposite fibers were gel spun and characterized for their morphological, microstructural, thermal, and mechanical properties. The addition of a low fraction of graphene improved the tensile strength of the fibers by 25% and tensile modulus by 32%. Differential scanning calorimetry showed an increase in melting temperature and degree of crystallinity, which indicates improved coordination of the molecular chains induced by the addition of graphene. The reinforcement also affected the cross-sectional shape of the fibers; the aspect ratio of the fibers’ elliptical shape declined with increasing graphene content showing the skeletal effect of the graphene nanofillers in the polymer matrix. The reinforcing effect of graphene declined above a threshold concentration, and theoretical modeling was applied to demonstrate that increased agglomerates led to reduced properties. This work demonstrates a simple, effective method to produce graphene-reinforced UHMWPE fibers and lays a foundation for understanding the potential for leveraging graphene to form ultra-high-performance nanocomposite fibers for myriad engineering applications.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":"32 4","pages":""},"PeriodicalIF":2.6,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143645543","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chemical modification of starch-based nanoparticles for Pickering emulsions: a review
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2025-03-19 DOI: 10.1007/s10965-025-04326-y
Zhiying Wang, Da Deng, Xiaopeng Pei, Luoluo Li, Qingquan Tian, Mingquan Wang, Xianping Yao, Ying Tan
{"title":"Chemical modification of starch-based nanoparticles for Pickering emulsions: a review","authors":"Zhiying Wang,&nbsp;Da Deng,&nbsp;Xiaopeng Pei,&nbsp;Luoluo Li,&nbsp;Qingquan Tian,&nbsp;Mingquan Wang,&nbsp;Xianping Yao,&nbsp;Ying Tan","doi":"10.1007/s10965-025-04326-y","DOIUrl":"10.1007/s10965-025-04326-y","url":null,"abstract":"<div><p>Pickering emulsions, stabilized by solid particles, have gained prominence over conventional surfactant-based emulsions due to their superior stability, reduced emulsifier requirements, biocompatibility, and safety. Among potential stabilizers, starch-based nanoparticles (SNPs) have emerged as promising natural alternatives to synthetic counterparts, owing to their unique properties including cost-effectiveness, biocompatibility, renewability, and biodegradability. Chemical modification has proven to be an effective approach for altering starch properties. This review provides a comprehensive and critical analysis of the chemical modification processes employed to produce SNPs for use as Pickering emulsion stabilizers. The discussion encompasses the fabrication of SNPs and primary chemical modifications. These modifications introduce various hydrophobic functional groups onto starch particles, thereby enhancing their wetting properties and fulfilling the requirements for effective particle stabilizers. The review emphasizes the significant impact of modified functional group types, degree of substitution, and particle fabrication methods on the wetting characteristics of the resulting particles. This critical examination of recent advancements in starch-based Pickering emulsion stabilizers provides valuable insights for future research directions and potential industrial applications in this rapidly evolving field.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":"32 4","pages":""},"PeriodicalIF":2.6,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143645495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative study on the effect of carbon nanotubes (CNTs), aminosilane-functionalized CNTs, TESPT-functionalized CNTs and 1-octadecanol-functionalized CNTs on the mechanical properties and swelling resistance of EPDM/SBR nanocomposites
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2025-03-19 DOI: 10.1007/s10965-025-04335-x
S. Vishvanathperumal, K. N. Ramu, J. Vasantheroy, K. A. V. Roossvelt Prabhu
{"title":"Comparative study on the effect of carbon nanotubes (CNTs), aminosilane-functionalized CNTs, TESPT-functionalized CNTs and 1-octadecanol-functionalized CNTs on the mechanical properties and swelling resistance of EPDM/SBR nanocomposites","authors":"S. Vishvanathperumal,&nbsp;K. N. Ramu,&nbsp;J. Vasantheroy,&nbsp;K. A. V. Roossvelt Prabhu","doi":"10.1007/s10965-025-04335-x","DOIUrl":"10.1007/s10965-025-04335-x","url":null,"abstract":"<div><p>The present study examines the effects of carbon nanotubes (CNTs), 3-aminopropyltriethoxysilane (APTES)-functionalized CNTs (sCNTs), bis(triethoxysilylpropyl) tetrasulfide (TESPT)-functionalized CNTs (tCNTs), and 1-octadecanol-functionalized CNTs (cCNTs) on the rheometric behavior, mechanical properties, morphology, abrasion resistance, swelling resistance, compression set, and crosslinking density of ethylene-propylene-diene monomer/styrene-butadiene rubber (EPDM/SBR) composites. The filler content was varied from 0 to 8 phr (parts per hundred rubber). In terms of rheometric behavior, properties such as minimum torque, maximum torque, delta torque, and cure rate index increased with higher filler content, while scorch time and optimum cure time decreased. Regardless of the filler type, increasing the filler content led to higher compound viscosity, reduced cure time, enhanced crosslink density, and improved abrasion resistance and hardness of the vulcanizates. For all filler types, tear strength, compression set, and swelling resistance showed a consistent increase with rising filler content. However, tensile strength increased with filler content up to 5 phr but declined noticeably beyond this threshold for all filler types. At any given filler content, CNTs demonstrated superior compression set performance compared to sCNTs, tCNTs, and cCNTs.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":"32 4","pages":""},"PeriodicalIF":2.6,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143645496","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A general strategy for enhancing the migration resistance of plasticizer in poly(vinyl chloride)
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2025-03-17 DOI: 10.1007/s10965-025-04323-1
Dekai Liu, Pingping Jiang, Nan Wang, Xuewen Li, Yuanyuan Qin, Jia Liu, Zhenhua Li, Yuchao Li
{"title":"A general strategy for enhancing the migration resistance of plasticizer in poly(vinyl chloride)","authors":"Dekai Liu,&nbsp;Pingping Jiang,&nbsp;Nan Wang,&nbsp;Xuewen Li,&nbsp;Yuanyuan Qin,&nbsp;Jia Liu,&nbsp;Zhenhua Li,&nbsp;Yuchao Li","doi":"10.1007/s10965-025-04323-1","DOIUrl":"10.1007/s10965-025-04323-1","url":null,"abstract":"<div><p>Due to the tendency of plasticizers like di-2-ethylhexyl phthalate (DOP) and bis(2-ethylhexyl)adipate (DOA) to migrate from PVC products, which pose serious health risks, and have therefore been increasingly restricted in many countries. Enhancing the migration resistance of plasticizers in PVC remains a critical challenge. Based on the molecular design concept of plasticizers, ester-branched epoxidized oleic acid plasticizers (E-ECD, E-EOD, and E-EHD) with excellent migration resistance in PVC were synthesized through esterification, Claisen condensation, and epoxidation reactions. The structural characteristics of the synthesized plasticizers were determined using FT-IR and <sup>1</sup>H NMR. During a 10-day migration resistance test, PVC plasticized with E-ECD exhibited a weight loss of less than 5 wt% in both polar and non-polar environments, with a migration rate of only 0.6 wt% in oily media. The potential plasticizing mechanisms of these plasticizers in PVC are elaborated in detail. This study offers a practical and generalizable strategy for the development of high-performance plasticizers with improved migration resistance.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":"32 4","pages":""},"PeriodicalIF":2.6,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143632467","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tailoring monosize molecularly imprinted solid phase extraction polymers for selective stigmasterol isolation from soybean oil
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2025-03-15 DOI: 10.1007/s10965-025-04318-y
Bürge Çelebi, Kardelen Cemek Şahin, Burcu Eren Yüngeviş, Gözde Baydemir Peşint
{"title":"Tailoring monosize molecularly imprinted solid phase extraction polymers for selective stigmasterol isolation from soybean oil","authors":"Bürge Çelebi,&nbsp;Kardelen Cemek Şahin,&nbsp;Burcu Eren Yüngeviş,&nbsp;Gözde Baydemir Peşint","doi":"10.1007/s10965-025-04318-y","DOIUrl":"10.1007/s10965-025-04318-y","url":null,"abstract":"<div><p>Stigmasterol (Stg) is a member of the phytosterol family, which is found naturally in plants in the form of free alcohol or their sediments, especially vegetable oils, and has positive effects on health such as anti-inflammatory, anti-osteoarthritis, anti-atherogenic, antioxidant, and lowering plasma cholesterol level, and protective effects such as anti-cancer. In this study, we aimed to prepare monosize Stg-imprinted solid phase extraction polymers (Stg-Mip-MSPEs) for direct separation of Stg from soybean oil extract. The synthesized polymers were characterized by scanning electron microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR). Stg-Mip-MSPE has maximum Stg adsorption capacity as 73.2 mg/g while NIP-MSPE has as 8 mg/g. Selectivity studies showed that Stg-Mip-MSPEs can recognize Stg 1.45 and 2.73 times more selective than cholesterol and ergosterol molecules, respectively. The Stg rebinding capacity from soybean oil was calculated as 63.69% and also showed the selective Stg binding ability of Stg-Mip-MSPEs from real samples. The reusability studies showed that the Stg adsorption capacity of Stg-Mip-MSPEs remains 96% at the end of the tenth cycle.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":"32 3","pages":""},"PeriodicalIF":2.6,"publicationDate":"2025-03-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143622087","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation and properties of acrylic acid grafted onto chitosan derivative-based superabsorbent polymers
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2025-03-14 DOI: 10.1007/s10965-025-04315-1
Qingshan Liu, Lei Ji, Wenjing Lin, Yingjuan Sun, Xiaofeng Lin, Yanqing Xie, Jinting Xie, Guobin Yi
{"title":"Preparation and properties of acrylic acid grafted onto chitosan derivative-based superabsorbent polymers","authors":"Qingshan Liu,&nbsp;Lei Ji,&nbsp;Wenjing Lin,&nbsp;Yingjuan Sun,&nbsp;Xiaofeng Lin,&nbsp;Yanqing Xie,&nbsp;Jinting Xie,&nbsp;Guobin Yi","doi":"10.1007/s10965-025-04315-1","DOIUrl":"10.1007/s10965-025-04315-1","url":null,"abstract":"<div><p>Superabsorbent polymers (SAPs) with improved absorbency under mechanical load (AUL) and enhanced antimicrobial properties in hygiene applications are still challenging. In this study, chitosan was modified to prepare quaternized carboxymethyl chitosan (QCMC) to improve water solubility and antimicrobial properties and then used it as backbone to obtain a novel type of superabsorbent polymers (P(AA-AMPS/QCMC)) by introducing acrylic acid (AA) and 2-acryloylamino-2-methylpropanesulfonic acid (AMPS) monomers through grafted copolymerization. FT-IR, XRD, SEM, and TG were used to analyze and characterize the structure of samples. Different factors influencing the absorption capacity, such as neutralization degree, monomer concentration, and crosslinker content, were optimized. Conventional SAPs exhibited low AUL and slow absorption rates due to gel blockage. To overcome these limitations, surface crosslinking was applied to improve both AUL and absorption rates. The SAPs showed absorption capacities of 634 g/g in deionized water and 78.8 g/g in 0.9 wt.% NaCl solution, and reached swelling equilibrium within 30 min. With only a 3% QCMC dosage, the inhibition rates against <i>Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli)</i> were 88.9% and 87.7%, respectively. Exploratory biodegradability tests indicated that these polymers possess degradable properties. This study demonstrates the potential applications of these polymers in hygiene.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":"32 3","pages":""},"PeriodicalIF":2.6,"publicationDate":"2025-03-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143612289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
PVP incorporation effects on the structural, thermal, electrical, and mechanical properties of PVDF-HFP/PVP blend
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2025-03-13 DOI: 10.1007/s10965-025-04321-3
Pratiksha Gami, Manish Badole, Asish Kumar Das, Hari Narayanan Vasavan, Samriddhi Saxena, Neha Dagar, Sunil Kumar
{"title":"PVP incorporation effects on the structural, thermal, electrical, and mechanical properties of PVDF-HFP/PVP blend","authors":"Pratiksha Gami,&nbsp;Manish Badole,&nbsp;Asish Kumar Das,&nbsp;Hari Narayanan Vasavan,&nbsp;Samriddhi Saxena,&nbsp;Neha Dagar,&nbsp;Sunil Kumar","doi":"10.1007/s10965-025-04321-3","DOIUrl":"10.1007/s10965-025-04321-3","url":null,"abstract":"<div><p>Flexible free-standing membranes (thickness ~ 60 µm) of poly (vinylidene fluoride-co-hexafluoropropylene)/polyvinyl pyrrolidone (PVDF-HFP/PVP) blends with various weight fractions of PVP were fabricated by the solution casting technique. The inclusion of PVP enhanced the semi-crystalline polymer PVDF-HFP's amorphous region, as confirmed by X-ray diffraction (XRD). Fourier transform infrared microscopy (FT-IR) investigations of the macromolecular blend membranes revealed interactions between the PVP and PVDF-HFP. The impact of adding PVP to PVDF-HFP on the miscibility of the resulting blends was examined using scanning electron microscopy (SEM). The results of thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) confirmed a complete miscibility of PVDF-HFP with PVP. Additionally, the Coats-Redfern model was used to calculate the activation energies of all samples. The uniform dispersion of PVP significantly boosted the thermal stability of the PVDF-HFP-based blend. The PVDF-HFP: PVP (75:25) blend polymer showed the minimum electrical conductivity (σ<sub>DC</sub>) of ~ 1.23 × 10<sup>−14</sup> S cm<sup>−1</sup>. Adding PVP to the polymer causes additional relaxation because of the PVP/PVDF-HFP interface, which increases the blend's dielectric constant <i>ε</i><sub><i>r</i></sub> to 9.6 for the sample with 25% PVP. Dynamic mechanical analysis (DMA) showed an improvement in the storage modulus of blended polymer, with the 25% PVP sample exhibiting a storage modulus of ~ 0.23 GPa at ~ 45 °C. These advantageous improvements suggest that the PVDF-HFP/PVP blend is well-suited for insulating applications.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":"32 3","pages":""},"PeriodicalIF":2.6,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143602320","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Condensation polymerization of 2-[(para-tolyl) oxy]-4,6-dichlorotriazine with ethylenediamine and application in metal anchoring
IF 2.6 4区 化学
Journal of Polymer Research Pub Date : 2025-03-13 DOI: 10.1007/s10965-025-04316-0
Farag M. A. Altalbawy, Fedhil F. Seed, Vicky Jain, Rekha M. M., Mayank Kundlas, Kattela Chennakesavulu, Piyus Kumar Pathak, Kamal Kant Joshi, Maryam Mir
{"title":"Condensation polymerization of 2-[(para-tolyl) oxy]-4,6-dichlorotriazine with ethylenediamine and application in metal anchoring","authors":"Farag M. A. Altalbawy,&nbsp;Fedhil F. Seed,&nbsp;Vicky Jain,&nbsp;Rekha M. M.,&nbsp;Mayank Kundlas,&nbsp;Kattela Chennakesavulu,&nbsp;Piyus Kumar Pathak,&nbsp;Kamal Kant Joshi,&nbsp;Maryam Mir","doi":"10.1007/s10965-025-04316-0","DOIUrl":"10.1007/s10965-025-04316-0","url":null,"abstract":"<div><p>Metal anchoring is essential for stabilizing nanoparticles in various industrial and environmental applications. This study presents the synthesis of a novel polymer, 2-[(para-tolyl) oxy]-4,6-dichlorotriazine, functionalized with ethylenediamine, and its application in metal anchoring. The polymer’s amine-rich structure allows for effective coordination with metal ions, specifically palladium nanoparticles (Pd NPs). The synthesis process involves the substitution of cyanuric chloride followed by the formation of the polymer through a two-step reaction with ethylenediamine. Pd NPs were successfully anchored onto the polymer matrix, with the interaction between the polymer and Pd confirmed via UV–Vis spectroscopy. The particle size of the Pd-anchored polymer composite was determined by Dynamic Light Scattering (DLS), showing an average diameter of approximately 140 nm. Transmission Electron Microscopy (TEM) revealed the morphology of the nanocomposite, which consists of interconnected fibers with Pd NPs dispersed on the surface. X-ray Diffraction (XRD) confirmed the crystalline nature of the Pd nanoparticles, while Thermogravimetric Analysis (TGA) demonstrated the thermal stability of the nanocomposite. In addition to the application of polymer-metal nanocomposite in the pharmaceutical and agricultural industries, they can be used in fields such as environmental catalysis for the degradation of pollutants, as a catalyst in the synthesis of fine chemicals, and in energy-related applications such as fuel cells. The stability and catalytic efficiency of polymer-supported Pd NPs make them suitable for various industrial and environmental applications.</p></div>","PeriodicalId":658,"journal":{"name":"Journal of Polymer Research","volume":"32 3","pages":""},"PeriodicalIF":2.6,"publicationDate":"2025-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143612317","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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