{"title":"Bioaugmentation and phytoremediation wastewater treatment process as a viable alternative for pesticides removal: case of pentachlorophenol","authors":"Rim Werheni Ammeri, Soulwene Kouki, Wafa Hassen, Maroua Oueslati, Najla Sadfi-Zouaoui, Abdennaceur Hassen","doi":"10.1007/s40201-023-00865-y","DOIUrl":"10.1007/s40201-023-00865-y","url":null,"abstract":"<div><p>This study focused on the potential for pentachlorophenol removal by a biological process in secondary treated wastewater (STWW). The proposed process is a combined method of phytoremediation using a native plant, Polypogon maritimus and Lemna minor, and bioaugmentation using a fungus. The bioaugmentation process was performed by a fungal isolate capable of removing PCP, isolated from the compost. The identification of the fungus was performed by morphological, biochemical, and molecular methods. A biological treatment system by bioaugmentation and phytoremediation was set up to estimate the capacity of this process to eliminate a high concentration of PCP. physico-chemical parameters, such as pH, COD, and BOD were tested at experimentation times T0 (initial) and Tf (final). The concentration of PCP is controlled by the HPLC method. Thus, the growth of the fungus was determined by spectrophotometry and enumeration on the agar medium. The results obtained show that the isolated and selected fungus is identified by <i>Penicillium Ilerdanum</i>. The fungal strain used has a significant capacity for tolerance and elimination of PCP. The results of the physico-chemical parameters showed an improvement in the quality of wastewater after the treatment was carried out. The elimination of PCP came with a release of Common law- and an important decrease in the DOC value in the STWW. The results obtained show that the Polypogon treatment shows a significant elimination of PCP by a percentage of the order of 92.01% and 23.58 g. L<sup>− 1</sup> chloride concentration. The macrophytes used showed a better ability to tolerate and eliminate PCP with an increase of chlorophyll and its longer sheets.</p></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"21 2","pages":"373 - 387"},"PeriodicalIF":3.4,"publicationDate":"2023-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40201-023-00865-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47882253","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Kinetic coefficients of cell growth and removal of organic substances for modeling Anaerobic-anoxic-aerobic method","authors":"Mojtaba Darzi Daronkola, Bahman Ramavandi, Seyed Enayat Hashemi, Fazel Amiri, Amir Hossein Mahvi","doi":"10.1007/s40201-023-00871-0","DOIUrl":"10.1007/s40201-023-00871-0","url":null,"abstract":"<div><h2>Abstract\u0000</h2><div><h3>Purpose</h3><p>Anaerobic-anoxic-aerobic process is one of the biological removal processes of nutrients in wastewater treatment. Phosphorus removal by biological method is a new and developed technique that is done by changing the design of suspended growth systems.</p><h3>Methods</h3><p>This is a cross-sectional descriptive study, which is a pilot workshop based in the first module, and chemistry, physics and microbiological tests were carried out at the wastewater treatment plant laboratory in one of the cities (Pardis) of Tehran province in 2020–2021 during a period of 12 months. Was completed. In this research, a total of 500 samples were taken from raw wastewater, aeration pond, effluent, secondary sedimentation and return activated sludge.</p><h3>Results</h3><p>In this research, the internal decay coefficient and the growth efficiency coefficient are equal to d<sup>−1</sup> 0.1264 and 0.6579 gVSS/gCOD, respectively. And the maximum specific rate of consumption of food substance and the semi-saturation constant of food substance respectively were gCOD/gVSS.d 3.3467 gCOD/m 25.305. If the specific rate of consumption of food substance or efficiency factor in our research is 0.27 gCOD/gVSS.d and the semi-constant Ks saturation equal to 27.9 gCOD/m has been obtained, this actually shows that the organic matter (COD) in the waste water of Pardis city had a higher degradability (sbCOD).</p><h3>Conclusion</h3><p>According to the obtained results, the synthetic coefficients in the Lineweaver–Burk and Hanes models are suitable, but in the Hofstee model, the amount of K and K<sub>d</sub> is less than the optimal amount for the proper exploitation of the pilot.</p></div></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"21 2","pages":"455 - 462"},"PeriodicalIF":3.4,"publicationDate":"2023-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40201-023-00871-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43073580","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J. Labrag, M. Abbadi, M. Hnini, C. El Bekkali, A. Bouziani, D. Robert, J. Aurag, A. Laghzizil, J.-M. Nunzi
{"title":"Antibiotic photocatalysis and antimicrobial activity of low-cost multifunctional Fe3O4@HAp nanocomposites","authors":"J. Labrag, M. Abbadi, M. Hnini, C. El Bekkali, A. Bouziani, D. Robert, J. Aurag, A. Laghzizil, J.-M. Nunzi","doi":"10.1007/s40201-023-00869-8","DOIUrl":"10.1007/s40201-023-00869-8","url":null,"abstract":"<div><p>Water contamination by multiple pollutants is a serious environmental issue originating from the many diverse sources of pollution. It has worsened with the appearance of new contaminants, named emerging micropollutants, such as drug residues which are considered a potential threat to human health and/or ecosystems. These require prior treatment before release into the environment. Simultaneous adsorption and photocatalysis as well as solid-liquid separation are promising technologies for water treatment. In order to obtain low cost photoactive nanocomposites, porous and magnetic Fe<sub>3</sub>O<sub>4</sub>-hydroxyapatite (wFeHAp) nanocomposites were prepared by soft chemistry from the dissociation of natural phosphate into Ca<sup>2+</sup> and H<sub>3</sub>PO<sub>4</sub> precursors, further neutralized by ammonia in the presence of preformed Fe<sub>3</sub>O<sub>4</sub> particles. The magnetic nanocomposites were characterized and examined as effective antibacterial agents. Fe<sub>3</sub>O<sub>4</sub> association with apatite modifies the surface properties of the wFeHAp nanocomposite materials, yielding efficient antimicrobial activity for S. aureus, B. subtilis, E. coli and K. pneumoniae strains. The photocatalytic removal of ciprofloxacin (CPF) and oxytetracyclin (OXT) antibiotics in water was also evaluated. The wFeHAp nanocomposites adsorbed and degraded the selected antibiotics successfully. Toxicity evaluation of the treated water after photodegradation using the four strains demonstrates the absence of toxic by-products at the end of the reaction. Therefore, Fe<sub>3</sub>O<sub>4</sub>@HAp nanoparticles are valuable for antimicrobial and photocatalysis applications.</p></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"21 2","pages":"429 - 440"},"PeriodicalIF":3.4,"publicationDate":"2023-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40201-023-00869-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42331869","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Wafa Sassi, Radhia Msaadi, Najeh Ardhaoui, Salah Ammar, Ayman Nafady
{"title":"Selective/simultaneous batch adsorption of binary textile dyes using amorphous perlite powder: aspects of central composite design optimization and mechanisms","authors":"Wafa Sassi, Radhia Msaadi, Najeh Ardhaoui, Salah Ammar, Ayman Nafady","doi":"10.1007/s40201-023-00870-1","DOIUrl":"10.1007/s40201-023-00870-1","url":null,"abstract":"<div><h2>Abstract\u0000</h2><div><p>Herein, the selectivity/simultaneously adsorption associated with Congo Red (CR) and Methylene Blue (MB) has been efficiently undertaken via amorphous perlite. Under optimum conditions of 38 min, 96 mg/L and 312°K for the contact time, the dye concentration, and the temperature, respectively, the optimization study using central composite design (CCD) matrix gave rise to high adsorption yields of 82.22 and 96.65% for CR and MB, respectively. Importantly, kinetic and isotherm studies attested that the batch adsorption occurs as intra-diffusional mass transport onto porous material. The obtained thermodynamic parameters are indicative of an endothermic/spontaneous physisorption process. Whereas SEM–EDS characterization revealed the superficial adsorption process of both CR and MB onto perlite. In addition, the FTIR analysis suggests that the adsorption process disrupted the short-range compounds order of perlite samples, revealing the marked crystallinity decrease of the adsorbent after adsorption. Finally, application of these optimum conditions tests on real industrial wastewater show that the adsorption was simultaneous at neutral pH and at 312°K, whereas CR and MB can be selectively adsorbed at pH 4 and 9, respectively.</p><h3>Graphical abstract</h3>\u0000 <div><figure><div><div><picture><source><img></source></picture></div></div></figure></div>\u0000 </div></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"21 2","pages":"441 - 454"},"PeriodicalIF":3.4,"publicationDate":"2023-06-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40201-023-00870-1.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42961056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Bhagvan P. Kamaliya, Pragnesh N. Dave, Lakha V. Chopda
{"title":"Synthesis of GG-g-P(NIPAM-co-AA)/GO and evaluation of adsorption activity for the diclofenac and metformin","authors":"Bhagvan P. Kamaliya, Pragnesh N. Dave, Lakha V. Chopda","doi":"10.1007/s40201-023-00867-w","DOIUrl":"10.1007/s40201-023-00867-w","url":null,"abstract":"<div><p>The grafting of biopolymer gum ghatti (GG) over the PNIPAM and PAA was done and loaded with graphene oxide (GO). Aim of this work is carried out combine adsorption of sodium diclofenac (SD) and metformin (MF) by the prepared hydrogels under influence of various parameters. The adsorbent GG-<i>g-</i>P(NIPAM-<i>co</i>-PAA)/GO(3 mg) chosen for adsorption activity as it displayed highest swelling capacity. The effect of amount of both adsorbents GG-<i>g-</i>P(NIPAM-<i>co</i>-PAA and GG-<i>g-</i>P(NIPAM-<i>co</i>-PAA)/GO(3 mg) showed that highest adsorption capacity found at 40 mg of adsorbents for both drugs at conditions: 100 mg/L concentration, 30 °C, 24 h and pH 6 and subsequently became stable. Both the drugs were removed in greater amount at 25 mg/L concentration, 24 h of contact time, 30 °C, 40 mg amount of both adsorbents and pH 6. Effect of time revealed that as time elevated from 2 h to 12 (100 mg/L concentration,, 30 °C, 40 mg amount of both adsorbents and pH 6) led to increase adsorption efficiency and after that increase time did not much impact on adsorption activity. Adsorption activity of hydrogels declined with increase of temperature (100 mg/L concentration, 12 h, 40 mg amount of both adsorbents and pH 6). The acidic conditions favored adsorption of SD while MF adsorbed under the weak acidic(100 mg/L concentration, 30 °C, 12 h, 40 mg amount of both adsorbents). However, basic conditions did not much influence on adsorption of MF but effected on adsorption activity of SD. Adsorption isotherm and kinetic model suggested that adsorption is homogenous and chemical in nature. The maximum adsorption capacity (q<sub>m</sub>) found to be 289.01 and 154.55 mg/g for SD and MF respectively.</p><h3>Graphical abstract</h3>\u0000 <div><figure><div><div><picture><source><img></source></picture></div></div></figure></div>\u0000 </div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"21 2","pages":"403 - 416"},"PeriodicalIF":3.4,"publicationDate":"2023-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40201-023-00867-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47911049","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A comparison of endosulfan removal by photocatalysis process under UV-A and visible light irradiation: optimization, degradation byproducts and reuse","authors":"Mehmet Turkyilmaz, Sezen Kucukcongar","doi":"10.1007/s40201-023-00864-z","DOIUrl":"10.1007/s40201-023-00864-z","url":null,"abstract":"<div><p>In this study, the removal efficiency of endosulfan as a persistent organic pollutant and formation of its metabolites were investigated using Ag/TiO<sub>2</sub>/Fe<sub>3</sub>O<sub>4</sub> photocatalyst under visible and UV-A light. Light intensity, catalyst amount, initial endosulfan concentration, initial pH and time were determined as controllable factors for Taguchi experimental design. The highest removal efficiencies of endosulfan were achieved as 86.14% and 85.46% for visible and UV–A light sources, respectively. According to the greatest best criterion, the level at which the highest S/N ratio was obtained for each parameter was accepted as the optimum value. As a result of the validation experiments, 94.2% and 91.9% efficiency were obtained for visible and UV-A light, respectively. The metabolite formations of endosulfan (endosulfan sulfate, ether, and lactone) remained below 7% in all experiments on a concentration basis. In the reuse experiments of the magnetically recovered photocatalyst, high removal efficiency of around 80% was obtained after four cycles. The removal efficiencies were found to be 86.7% and 84.8%, for real samples taken from the drinking water treatment plant inlet and the spring water network injected with endosulfan under optimal photocatalysis experimental conditions, respectively. It has been shown that nitrate and sulfate anions, which are in significant concentrations in raw water samples, have very little effects on endosulfan removal. The overall results showed that the Ag/TiO<sub>2</sub>/Fe<sub>3</sub>O<sub>4</sub> photocatalyst was produced successfully, the catalyst was highly effective in the mineralization of endosulfan in synthetic and real water samples under UV and visible light, and effective yields could be obtained even with reuse.</p></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"21 2","pages":"355 - 371"},"PeriodicalIF":3.4,"publicationDate":"2023-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40201-023-00864-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49694858","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Samaneh Ghaderi, Roxana Taleb Lahafchi, Sona Jamshidi
{"title":"Performance evaluation of PdO/ CuO TiO2 photocatalytic membrane on ceramic support for removing pharmaceutical compounds from water","authors":"Samaneh Ghaderi, Roxana Taleb Lahafchi, Sona Jamshidi","doi":"10.1007/s40201-023-00866-x","DOIUrl":"10.1007/s40201-023-00866-x","url":null,"abstract":"<div><p>This study investigated photocatalytic degradation of pharmaceutical compound using CuO or PdO–TiO<sub>2</sub> membrane. The synthesized membranes were characterized by some techniques including X-ray powder diffraction (XRD), dynamic light scattering (DLS), scanning electron microscopy (SEM), and Fourier-transform infrared spectroscopy (FT-IR). The structural properties confirmed that the photocatalytic membranes were successfully prepared on ceramic supports. The PdO-TiO<sub>2</sub> and CuO-TiO<sub>2</sub> membranes were employed as photocatalytic membranes to degrade metronidazole (MNZ) and diphenhydramine (DPH) in aqueous solutions, respectively. Some parameters affecting the photocatalytic reaction such as pH, initial concentration, and light source were also investigated. The maximum degradation for both pharmaceutical compounds was obtained at basic pH (pH = 10), low initial concentration (C<sub>0</sub> = 10 ppm) under UV irradiation. At high transmembrane pressure (ΔP = 3 bar), the flow rate across the membrane increased up 0.0078 and 0.0082 cc/s.cm<sup>2</sup> for CuO-TiO<sub>2</sub> and PdO-TiO<sub>2</sub> photocatalytic membrane respectively while not affected on degradation efficiency (DE). At the same condition operation (C<sub>0</sub> = 10 ppm, pH = 10, ΔP = 2 bar under UV irradiation), the MNZ and DPH degradation of the PdO-TiO<sub>2</sub> membrane was 94 and 95% respectively that relatively higher than the CuO-TiO<sub>2</sub> membrane. It is probably due to the lower energy band gap of PdO-TiO<sub>2</sub> (2.5 eV) than CuO-TiO<sub>2</sub> (2.7 eV). The membrane stability tests confirmed the high performance of the prepared membranes.\u0000</p></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"21 2","pages":"389 - 401"},"PeriodicalIF":3.4,"publicationDate":"2023-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40201-023-00866-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46986003","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shervin Adabi, Ahmadreza Yazdanbakhsh, Abbas Shahsavani, Amir Sheikhmohammadi, Mahdi Hadi
{"title":"Removal of heavy metals from the aqueous solution by nanomaterials: a review with analysing and categorizing the studies","authors":"Shervin Adabi, Ahmadreza Yazdanbakhsh, Abbas Shahsavani, Amir Sheikhmohammadi, Mahdi Hadi","doi":"10.1007/s40201-023-00863-0","DOIUrl":"10.1007/s40201-023-00863-0","url":null,"abstract":"<div><p>With the development of nanotechnology and its application in various sciences, scientists have investigated the use of nanoparticles as adsorbents to remove heavy metals from aqueous solutions all over the world. So far, the results of many of these studies have been published in reputable journals. Obviously, reviewing these articles and summarizing the results of these studies from different aspects will provide new perspectives for the development of this technology for heavy metals removal from water. So the current study was performed to review the results of the published studies between 1/January/1980 to 1/January/2022. The focus of the study is on the analysis of these studies and their classification. In addition, a more detailed investigation was carried out. Among the 5155 articles, 576 articles were included based on Cochrane protocols. Results show that most of the studies (90.8%) were conducted on a laboratory scale and used synthetic solutions. Most studies were performed for Pb, Cd and Cu, removal respectively. Compared to other countries, authors with affiliation from China and Iran have published more articles. The ranking of the use of various nanomaterials were: nanocomposites > metal oxide nanomaterials > metal-based nanomaterials > carbon-based nanomaterials > dendrimers, with the wide range of sizes from less than 10 nm to several hundreds of nanometers. The required amount of carbon-based nanoparticles to remove many heavy metals were lower than other nanoparticles. In most studies, pH ≤ 7 has been reported as optimal. Most studies have been followed pseudo second-order and pseudo first-order reactions and have been more agreement with Langmuir and Freundlich adsorption isotherms respectively. The results of studies show that the synthesis and optimization of new nanomaterials can be considered as a new and competitive technology. However, more studies are needed to investigate the removal of heavy metals in real samples and to overcome some challenges in the full-scale application.</p></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"21 2","pages":"305 - 318"},"PeriodicalIF":3.4,"publicationDate":"2023-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40201-023-00863-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47507950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Narges Mehrab, Mostafa Chorom, Mojtaba Norouzi Masir, Jayanta Kumar Biswas, Marcella Fernandes de Souza, Erik Meers
{"title":"Impact of soil treatment with Nitrilo Triacetic Acid (NTA) on Cd fractionation and microbial biomass in cultivated and uncultivated calcareous soil","authors":"Narges Mehrab, Mostafa Chorom, Mojtaba Norouzi Masir, Jayanta Kumar Biswas, Marcella Fernandes de Souza, Erik Meers","doi":"10.1007/s40201-023-00857-y","DOIUrl":"10.1007/s40201-023-00857-y","url":null,"abstract":"<div><h3>Purpose</h3><p>The aim of this study was to evaluate the effectiveness of nitrilotriacetic acid (NTA) on cadmium (Cd) fractions and microbial biomass in a calcareous soil spiked with Cd under cultivated (<i>Zea</i> <i>mays</i> L.) and uncultivated regime subject to soil leaching condition. Expanding investigations related to soil–plant interactions on metal-contaminated soils with insights on microbial activity and associated soil toxicity perspective provides novel perspectives on using metal-chelating agents for soil remediation.</p><h3>Methods</h3><p>The experimental factors were three levels of Cd contamination (0, 25, and 50 mg kg<sup>−1</sup> soil) and three levels of NTA (0, 15, and 30 mmol L<sup>−1</sup>) in loamy soil under maize-cultured and non-cultured conditions. During the experiment, the adding NTA and leaching processes were performed three times.</p><h3>Results</h3><p>The results showed that the amount of leached Cd decreased in cultivated soil compared to uncultivated soil due to partial uptake of soluble Cd by plant roots and changes in Cd fractions in soil, so that Cd leached in Cd<sub>50</sub>NTA<sub>30</sub> was 9.2 and 6.1 mg L<sup>−1</sup>, respectively, in uncultivated and cultivated soils. Also, Cd leached in Cd<sub>25</sub>NTA<sub>30</sub> was 5.7 and 3.1 mg L<sup>−1</sup> respectively, in uncultivated and cultivated soils. The best treatment in terms of chemical and microbial characteristics of the soil with the high percentage of Cd removed from the soil was Cd<sub>25</sub>NTA<sub>30</sub> in cultivated soil. In Cd<sub>25</sub>NTA<sub>30</sub> compared to Cd<sub>25</sub>NTA<sub>0</sub> in cultivated soil, pH (0.25 unit), microbial biomass carbon (MBC, 65.0 mg kg<sup>−1</sup>), and soil respiration (27.5 mg C-CO<sub>2</sub> kg<sup>−1</sup> 24 h<sup>−1</sup>) decreased, while metabolic quotient (qCO<sub>2</sub>, 0.05) and dissolved organic carbon (DOC, 20.0 mg L<sup>−1</sup>) increased. Moreover, the changes of Cd fractions in Cd<sub>25</sub>NTA<sub>30</sub> in cultivated soil compared to uncultivated soil were as follows; the exchangeable Cd (F<sub>1</sub>, 0.27 mg kg<sup>−1</sup>) and Fe/Mn-oxide-bounded Cd (F<sub>4</sub>, 0.15 mg kg<sup>−1</sup>) fractions increased, in contrast, carbonate-Cd (F<sub>2</sub>, 2.67 mg kg<sup>−1</sup>) and, organically bounded Cd (F<sub>3</sub>, 0.06 mg kg<sup>−1</sup>) fractions decreased. NTA had no significant effect on the residual fraction (F<sub>5</sub>).</p><h3>Conclusion</h3><p>The use of NTA, especially in calcareous soils, where most of the Cd is bound to calcium carbonate, was able to successfully convert insoluble fractions of Cd into soluble forms and increase the removal efficiency of Cd in the phytoremediation method. NTA is a non-toxic chelating agent to improve the accumulation of Cd in maize.</p></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"21 2","pages":"319 - 332"},"PeriodicalIF":3.4,"publicationDate":"2023-06-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43233847","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Assessing capabilities of conducted ambient air pollution health effects studies in 22 Eastern Mediterranean countries to adopt air quality standards: a review","authors":"Adel Mokammel, Mazen Malkawi, Fatemeh Momeniha, Heba Adel Moh’d Safi, Sadegh Niazi, Fatemeh Yousefian, Faramarz Azimi, Kazem Naddafi, Mansour Shamsipour, Vahid Roostaei, Sasan Faridi, Mohammad Sadegh Hassanvand","doi":"10.1007/s40201-023-00862-1","DOIUrl":"10.1007/s40201-023-00862-1","url":null,"abstract":"<div><h3>Purpose</h3><p>The Eastern Mediterranean Region (EMR) countries suffer from exposure to high levels of ambient air pollutants due to dust storms and have unique climatic as well as topographic and socio-economic conditions which lead to adverse health effects on humans. The purpose of the review was to evaluate the quantity and quality of published articles on air pollution and health-based studies in 22 EMR countries to determine if they can be applied to adopting air quality standards.</p><h3>Methods</h3><p>We designed a review based on a broad search of the literature in the Scopus, PubMed, and web of science (WOS) databases published from January 1, 2000, to January 2, 2022, using combinations of the following relevant terms: air pollution, health, and EMR countries. The generic eligibility criteria for this review were based on the population, exposure, comparator, outcome, and study design (PECOS) statement.</p><h3>Results</h3><p>The search results showed that following the PRISMA approach, of 2947 identified articles, 353 studies were included in this review. The analysis of the types of studies showed that about 70% of the studies conducted in EMR countries were Health Burden Estimation studies (31%), Ecological and time trend ecological studies (23%), and cross-sectional studies (16%). Also, researchers from Iran participated in the most published relevant studies in the region 255 (~ 63%) and just 10 published documents met all the PECOS criteria.</p><h3>Conclusion</h3><p>The lack of sufficient studies which can meet the PECOS appraising criteria and the lack of professionals in this field are some of the issues that make it impossible to use as potential documents in the WHO future studies and adopt air quality standards.</p></div>","PeriodicalId":628,"journal":{"name":"Journal of Environmental Health Science and Engineering","volume":"21 2","pages":"295 - 304"},"PeriodicalIF":3.4,"publicationDate":"2023-06-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40201-023-00862-1.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42975811","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}