Journal of Coatings Technology and Research最新文献

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Study on the antibacterial properties of UV-cured multifunctional fluorinated acrylic resin 紫外光固化多功能氟化丙烯酸树脂的抗菌性能研究
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-02-20 DOI: 10.1007/s11998-025-01224-2
Xiwen Cui, Zhengtao Wu, Changzheng Chen, Bingbin Zhang, Shupeng Wu, Haitao Wu, Li Jiang, Susu Cui, Yan Yuan
{"title":"Study on the antibacterial properties of UV-cured multifunctional fluorinated acrylic resin","authors":"Xiwen Cui,&nbsp;Zhengtao Wu,&nbsp;Changzheng Chen,&nbsp;Bingbin Zhang,&nbsp;Shupeng Wu,&nbsp;Haitao Wu,&nbsp;Li Jiang,&nbsp;Susu Cui,&nbsp;Yan Yuan","doi":"10.1007/s11998-025-01224-2","DOIUrl":"10.1007/s11998-025-01224-2","url":null,"abstract":"<p>As people’s living standards continue to improve, the harassment of humans by microorganisms, such as diseases caused by bacteria, fungi, and other microorganisms, has increasingly come into public view. Therefore, the development of coatings with antibacterial properties is necessary. In this paper, fluorine-containing resins were synthesized using isophorone diisocyanate (IPDI), polyethylene glycol-1000 (PEG-1000), pentaerythritol triacrylate (PETA), and 1H,1H,2H,2H-perfluoro-1-octanol as raw materials. The fluorine-containing resin was combined with different proportions of <i>p</i>-anisaldehyde and D-(+)− 3-phenyllactic acid to prepare various UV-curable formulations. The study investigated the double-bond conversion rate during the resin curing process, the glass transition temperature, and the antibacterial and hydrophobic properties of the cured resin. The results indicate that through testing of different UV-curable hydrophobic resin formulations, the optimal comprehensive performance of the coating was achieved with a fluorine-containing hydrophobic resin mass fraction of 35%, a modified bisphenol A epoxy diacrylate (6215-100) mass fraction of 40%, a trimethylolpropane triacrylate (TMPTA) mass fraction of 10%, an tripropylene glycoldiacrylate (EM-223) mass fraction of 10%, and a photoinitiator mass fraction of 5%. Finally, by blending various types and contents of mold inhibitors with the matrix resin, UV-curable mold-resistant hydrophobic coatings were prepared and subjected to antibacterial and mold resistance tests, hydrophobic angle measurements, real-time infrared analysis, and DSC testing. In this study, the diameter of the inhibition zone of coatings containing different antibacterial agents against three types of microorganisms was measured. The results showed that the blank formulation exhibited no antibacterial activity. Among the tested antibacterial agents, <i>p</i>-anisaldehyde (with a maximum addition amount of 15 wt%) and D-(+)− 3-phenyllactic acid (with a maximum addition amount of 8 wt%) showed the best antibacterial effects; the former had better activity due to its good compatibility with the coating matrix. The antifungal activity of the coatings against <i>Aspergillus flavus</i> was much higher than their antibacterial activity against bacteria. Specifically, the optimal antibacterial activity against bacteria was achieved when the addition amount of <i>p</i>-anisaldehyde was 15 wt%, while the optimal antifungal activity was obtained when the addition amount of <i>p</i>-anisaldehyde was 10 wt%.</p>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 4","pages":"1927 - 1938"},"PeriodicalIF":3.4,"publicationDate":"2026-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148519472","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Harnessing the bioactive potential of curcumin-based edible coatings: a natural strategy for enhancing shelf life and reducing post-harvest losses in horticultural produce 利用基于姜黄素的可食用涂层的生物活性潜力:提高园艺产品的保质期和减少收获后损失的自然策略
IF 2.8 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-02-18 DOI: 10.1007/s11998-025-01216-2
Anjali Upadhaya, Yengkhom Disco Singh, Senpon Ngomle
{"title":"Harnessing the bioactive potential of curcumin-based edible coatings: a natural strategy for enhancing shelf life and reducing post-harvest losses in horticultural produce","authors":"Anjali Upadhaya,&nbsp;Yengkhom Disco Singh,&nbsp;Senpon Ngomle","doi":"10.1007/s11998-025-01216-2","DOIUrl":"10.1007/s11998-025-01216-2","url":null,"abstract":"<div><p>In each year, post-harvest loss of fruits and vegetables accounts to almost half of its production causing a major challenge for food security and sustainability. To minimize the loss, different attempts have been made including use of an edible coating for shelf-life enhancement. Curcumin-based edible coating, a natural compound derived from turmeric (<i>Curcuma longa</i>), has gained significant attention as it has remarkable antioxidant, antimicrobial, antifungal, and bioactive properties. Curcumin as a functional component in edible coating emphasizes its role in reducing spoilage, extending freshness, and maintaining the quality of horticulture produce. Additionally, the development of natural and nanotechnology-based curcumin coatings and their encapsulation techniques show beneficial impact on food safety and security. The nanoformulation comprising nanocurcumin with other polymers is used for extending the shelf life of horticultural fruits and vegetables. However, the use of nanomaterials in the food industry is not encouraged by the scientific community. Therefore, there is always a concern of safety issues in formulations which can be leveraged by checking its bio efficacy and cell toxicity effect. The aim of this review is to describe the current and potential research and development of curcumin-based edible coating in horticultural fruits and vegetables towards food safety and security.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 3","pages":"1181 - 1196"},"PeriodicalIF":2.8,"publicationDate":"2026-02-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147757218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Feasibility and durability of a first-of-a-kind, sustainable biologic paint using bacterial pigment and protein binder 使用细菌色素和蛋白质粘合剂的第一种可持续生物涂料的可行性和耐久性
IF 2.8 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-02-17 DOI: 10.1007/s11998-025-01220-6
Rathan Duggirala, Aubrey Berger, Manuela Oviedo, Prasamsi Mikkilineni, Venkateswarlu Kondragunta, Ivana T Croghan
{"title":"Feasibility and durability of a first-of-a-kind, sustainable biologic paint using bacterial pigment and protein binder","authors":"Rathan Duggirala,&nbsp;Aubrey Berger,&nbsp;Manuela Oviedo,&nbsp;Prasamsi Mikkilineni,&nbsp;Venkateswarlu Kondragunta,&nbsp;Ivana T Croghan","doi":"10.1007/s11998-025-01220-6","DOIUrl":"10.1007/s11998-025-01220-6","url":null,"abstract":"<div><p>Conventional paints present notable health and environmental hazards due to the presence of heavy metal-based pigments and the emission of volatile organic compounds (VOCs) from synthetic binders. Prior research has shown that genetically engineered microorganisms, such as <i>Escherichia coli</i>, can biosynthesize pigments that offer reduced environmental impact. However, biologically derived pigments to date have been formulated with VOC-emitting binders. Casein, a natural, VOC-free binder used since antiquity, represents a promising alternative, though its compatibility with biologically derived pigments has not been systematically evaluated. Bacterial pigments and protein binders are sustainable because they are derived from renewable biological sources. This study investigates a novel paint formulation combining <i>E. coli</i>–derived pigment with a casein-based binder and compares its spectral durability to two mineral-based commercial paints under varied environmental conditions. Spectral intensity analysis demonstrated that biologic paint retained color stability comparable to both commercial standards; although four statistically significant differences were observed, all were below the threshold of human visual perception. These results demonstrate that coupling biologically derived pigments with a casein binder can yield an effective, environmentally safer alternative to conventional paint systems.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 3","pages":"1721 - 1726"},"PeriodicalIF":2.8,"publicationDate":"2026-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147757176","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Self-cleaning vegetable-tanned leather: photocatalytic activity of ZnO and BiOI nanoparticles immobilized by succinic acid 自清洁植物鞣革:琥珀酸固定ZnO和BiOI纳米颗粒的光催化活性
IF 2.8 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-02-17 DOI: 10.1007/s11998-025-01218-0
F. V. Silva, M. A. Lansarin, M. Griebler
{"title":"Self-cleaning vegetable-tanned leather: photocatalytic activity of ZnO and BiOI nanoparticles immobilized by succinic acid","authors":"F. V. Silva,&nbsp;M. A. Lansarin,&nbsp;M. Griebler","doi":"10.1007/s11998-025-01218-0","DOIUrl":"10.1007/s11998-025-01218-0","url":null,"abstract":"<div><p>In this work, succinic acid was evaluated for the first time as a chemical binder to immobilize ZnO and BiOI nanoparticles on a vegetable-tanned crust leather surface to confer self-cleaning properties through photocatalytic activity. In a previous work, a new methodology for collagen esterification using polycarboxylic acids was developed. The effects of ZnO concentration and curing temperature on photocatalytic performance were systematically evaluated using a factorial design and Minitab 18 software. The optimal conditions were obtained at a concentration of 0.5 (wt%) and a curing temperature of 30 °C. These parameters were used in the BiOI immobilization methodology. Photocatalytic activity was assessed using methylene blue photocatalytic activity indicator ink (PAII) under simulated solar radiation. Statistical analysis revealed that ZnO concentration was the most significant parameter affecting photocatalytic efficiency. However, higher concentrations (0.75 wt%) promoted nanoparticle agglomeration, reducing the availability of active sites, as evidenced by SEM analysis. Comparatively, BiOI showed lower photocatalytic performance, attributed to its lower specific surface area (6.65 m<sup>2</sup> g<sup>-1</sup>) relative to ZnO (10–25 m<sup>2</sup> g<sup>-1</sup>) and TiO<sub>2</sub> (35–65 m<sup>2</sup> g<sup>-1</sup>). Additionally, contact angle analysis revealed that immobilization of photocatalysts significantly increased the hydrophobicity of the leather surface, with contact angles rising from 53° for untreated leather to 137° for BiOI-modified samples. These changes in surface wettability contribute to improved self-cleaning functionality. Overall, these findings validate the effectiveness of this novel succinic acid-mediated immobilization strategy for producing self-cleaning leather materials and highlight the critical role of optimizing nanoparticle concentration to maximize performance.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 3","pages":"1711 - 1720"},"PeriodicalIF":2.8,"publicationDate":"2026-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147757197","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring waste cooking oils as renewable feedstock for alkyd resin production 探索废食用油作为可再生原料生产醇酸树脂
IF 2.8 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-02-17 DOI: 10.1007/s11998-025-01209-1
Pelin Parisa Aksoy  (, ), Ayse Aytac
{"title":"Exploring waste cooking oils as renewable feedstock for alkyd resin production","authors":"Pelin Parisa Aksoy \u0000 (,&nbsp;),&nbsp;Ayse Aytac","doi":"10.1007/s11998-025-01209-1","DOIUrl":"10.1007/s11998-025-01209-1","url":null,"abstract":"<div><p>The increasing demand for environmentally sustainable materials has increased interest in renewable raw materials for polymer synthesis. Among these sources, waste cooking oil (WCO) has been considered a promising alternative due to its abundance, low cost and rich triglyceride content suitable for polymeric applications. This review examines the use of WCO in the synthesis of alkyd resins, highlighting significant improvements in raw material processing, resin formulation development and resulting physicochemical properties. The addition of WCO not only addresses waste disposal concerns but also offers a path toward the development of high-performance, bio-based coating materials. The effects of oil pretreatment, polyol selection and reaction parameters on resin properties are discussed in this study. Comparison with conventional alkyds shows that WCO-derived resins exhibit competitive drying behavior, mechanical stability and adhesion properties, although they have some limitations in oxidative resistance. The review also examines recent innovations aimed at improving the quality and durability of WCO-based alkyds, with the aim of positioning them as sustainable candidates in the coatings industry.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 2","pages":"643 - 658"},"PeriodicalIF":2.8,"publicationDate":"2026-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147352849","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances in marine biomimetic antifouling technology based on microstructured surfaces inspired by aquatic organisms 基于受水生生物启发的微结构表面的海洋仿生防污技术的最新进展
IF 2.8 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-02-17 DOI: 10.1007/s11998-025-01219-z
Feifei Yang, Zhenyi Pan, Lida Shen, Dazhi Huang, Huan Gao, Xiaoli Wang, Yachao Song
{"title":"Recent advances in marine biomimetic antifouling technology based on microstructured surfaces inspired by aquatic organisms","authors":"Feifei Yang,&nbsp;Zhenyi Pan,&nbsp;Lida Shen,&nbsp;Dazhi Huang,&nbsp;Huan Gao,&nbsp;Xiaoli Wang,&nbsp;Yachao Song","doi":"10.1007/s11998-025-01219-z","DOIUrl":"10.1007/s11998-025-01219-z","url":null,"abstract":"<div><p>Marine biofouling poses a significant challenge to the marine industry, resulting in substantial economic losses due to increased drag, corrosion, and higher maintenance costs in shipping, aquaculture, and offshore infrastructure. Conventional antifouling coatings exhibit poor durability and pose environmental risks due to their inherent toxicity. With increasing environmental awareness and sustainability demands, research has shifted toward eco-friendly alternatives combining durability with nontoxic mechanisms. Bioinspired antifouling strategies have emerged as a transformative solution over the past decade, particularly in microstructural surface designs that mimic of the surfaces of aquatic organisms such as shark skin, lotus leaves, and coral surfaces. This paper reviews the biochemical formation mechanisms and adverse effects of marine biofouling, systematically examines various bionic antifouling strategies inspired by aquatic organisms, advances in biomimetic microstructural fabrication and performance limitations of single-mechanism approaches in dynamic marine environments. Current challenges—such as reconciling mechanical robustness with cost-effective scalability—are critically analyzed. A key conclusion is the necessity of multifunctional synergy: combining mechanical, chemical, and biological antifouling strategies to address the limitations of individual bionic antifouling technologies. This review outlines future research directions for biomimetic microstructures, leveraging artificial intelligence to optimize structural design, establish a multifunctional collaborative platform integrating diversified biomimetic strategies, and enable on-demand fabrication of long-lasting, cost-effective antifouling coatings. It is anticipated that this work will provide valuable insights for developing efficient, durable, and environmentally sustainable marine antifouling coatings.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 3","pages":"1197 - 1216"},"PeriodicalIF":2.8,"publicationDate":"2026-02-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147757219","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Application of epoxy-based nano-modified composites as cement mortar coating against sulfuric acid attack 环氧基纳米改性复合材料在水泥砂浆抗硫酸侵蚀涂层中的应用
IF 2.8 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-02-13 DOI: 10.1007/s11998-025-01197-2
Navid Gorji Nejad, S. Yasin Mousavi, Foad Haghdadi, Mehdi Ghaffari
{"title":"Application of epoxy-based nano-modified composites as cement mortar coating against sulfuric acid attack","authors":"Navid Gorji Nejad,&nbsp;S. Yasin Mousavi,&nbsp;Foad Haghdadi,&nbsp;Mehdi Ghaffari","doi":"10.1007/s11998-025-01197-2","DOIUrl":"10.1007/s11998-025-01197-2","url":null,"abstract":"<div><p>This study aims to assess the performance of epoxy-based nano-modified composites as surface treatment for mortar samples under H<sub>2</sub>SO<sub>4</sub> acid attack. Besides neat epoxy and epoxy/solvent mixture, nano-clay and nano-SiO<sub>2</sub> at three different dosages (i.e., 0.5%, 1.5%, and 3%) were dispersed in the epoxy/solvent mixture and applied to the mortar surface. The changes in the mass and crushing load of the coated samples after immersion in 5% H<sub>2</sub>SO<sub>4</sub> solution for 14, 28, and 42 days were compared with those of uncoated mortars. The results of this study were found through SEM observation, EDS element mapping, and rheological measurements. Visual observation of the mortar samples showed that the uncoated samples suffered the most deterioration during immersion in 5% H<sub>2</sub>SO<sub>4</sub> solution, indicating a beneficial effect of the mortar surface treatments. Furthermore, the epoxy/solvent mixture, due to its lower viscosity, can fill surface holes and defects and compared to neat epoxy, improve the acid resistance of the mortars. Additionally, mortars coated with 1.5% nano-clay, or nano-SiO<sub>2</sub> modified epoxy/solvent mixtures had the highest resistance against H<sub>2</sub>SO<sub>4</sub> acid attack. As confirmed by SEM/EDS observation, using nanoparticles at 3%, because of the tendency to agglomerate in epoxy/solvent mixture is not an appropriate mixing dosage.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 3","pages":"1519 - 1533"},"PeriodicalIF":2.8,"publicationDate":"2026-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147757204","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Durable highly hydrophobic coating for solar panel with benefits of self-cleaning, thermal insulation and increased energy harvesting 用于太阳能电池板的耐用高疏水性涂层,具有自清洁,隔热和增加能量收集的优点
IF 2.8 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-02-13 DOI: 10.1007/s11998-025-01201-9
Pouya Jafari, Ali Asghar Sabbagh Alvani, Hassan Sameie, Federico Rosei, Junfei Ou
{"title":"Durable highly hydrophobic coating for solar panel with benefits of self-cleaning, thermal insulation and increased energy harvesting","authors":"Pouya Jafari,&nbsp;Ali Asghar Sabbagh Alvani,&nbsp;Hassan Sameie,&nbsp;Federico Rosei,&nbsp;Junfei Ou","doi":"10.1007/s11998-025-01201-9","DOIUrl":"10.1007/s11998-025-01201-9","url":null,"abstract":"<div><p>The urgent transition to solar energy is hindered by efficiency losses in photovoltaic (PV) panels due to dust accumulation and overheating. Conventional mitigation strategies, including fluorinated hydrophobic coatings, face challenges of environmental persistence, poor durability, and limited scalability. This study presents a fluorine-free, industrially scalable coating that synergistically enhances dust repellency, mechanical resilience, and thermal regulation for PV panels. The coating integrates UV-curable silicone-modified acrylate resin with surface-modified SiO<sub>2</sub> and ZnO nanoparticles, achieving a hierarchical microstructure that delivers high hydrophobicity (WCA &gt; 140°) alongside strong infrared reflectivity. The coating reduces panel temperatures by up to 10 °C under solar irradiation while demonstrating exceptional mechanical durability and chemical stability under UV/thermal exposure and acidic/alkaline conditions. Controlled environmental tests revealed that the coated PV panels exhibit up to a 45% increase in power output compared to uncoated panels under simulated dusty conditions, resulting in significantly retained performance under soiling stress. By eliminating fluorinated compounds and utilizing scalable spin-coating processes combined with a high-speed UV-curing system, this work addresses critical gaps in eco-compatibility and industrial integration. The dual-functionality design—simultaneously mitigating fouling and thermal stress—offers a transformative pathway to enhance the efficiency and longevity of solar farms in harsh climates, aligning with global decarbonization goals.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture><span>The alternative text for this image may have been generated using AI.</span></div></div></figure></div></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 3","pages":"1579 - 1600"},"PeriodicalIF":2.8,"publicationDate":"2026-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147757187","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A diamino double-decker silsesquioxane as a reactive nanoadditive to enhance the corrosion resistance of an epoxy coating 二氨基双层硅氧烷作为反应性纳米添加剂,增强环氧涂料的耐腐蚀性
IF 3.4 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-02-13 DOI: 10.1007/s11998-025-01221-5
Kaili Wang, Liangrong Qin, Qiang Dong, Pengfei Shi, Liqiang Wan, Yan Zhou, Lingfeng Mao, Jianhua Qian, Zuozhen Liu, Farong Huang
{"title":"A diamino double-decker silsesquioxane as a reactive nanoadditive to enhance the corrosion resistance of an epoxy coating","authors":"Kaili Wang,&nbsp;Liangrong Qin,&nbsp;Qiang Dong,&nbsp;Pengfei Shi,&nbsp;Liqiang Wan,&nbsp;Yan Zhou,&nbsp;Lingfeng Mao,&nbsp;Jianhua Qian,&nbsp;Zuozhen Liu,&nbsp;Farong Huang","doi":"10.1007/s11998-025-01221-5","DOIUrl":"10.1007/s11998-025-01221-5","url":null,"abstract":"<div><p>A diamino double-decker silsesquioxane (DA-DDSQ) was synthesized and introduced into an epoxy coating in different mass fractions. Results show that the introduction of the DA-DDSQ enhances the hydrophobic performance and improves the wear resistance and corrosion resistance of the epoxy coating, but slightly reduces the toughness. The water contact angle of the coatings increases from 91.5 without DA-DDSQ to 95.6° with 6% DA-DDSQ content. The abrasion value of the coatings after 1000 friction cycles decreases from 26 to 19 mg, and the impact toughness of the coatings decreases from 45 to 40 cm with the increase in DA-DDSQ content from 0 to 6%. After being soaked in 3.5 wt% sodium chloride solution for 25 days, the epoxy coating with 6% DA-DDSQ content still has a relatively high impedance value with |Z<sub>|f= 0.01 Hz</sub> of 3.09 × 10<sup>8</sup> Ω cm<sup>2</sup>, which is much higher than that of the epoxy coating without DA-DDSQ (3.70 × 10<sup>7</sup> Ω cm<sup>2</sup>). These developed properties would make the epoxy coatings with DA-DDSQ promising for application in the corrosion resistance field.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 4","pages":"1897 - 1908"},"PeriodicalIF":3.4,"publicationDate":"2026-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148519500","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and performance analysis of tannic acid and polyphenylene methylene containing acrylic resin for protective coatings 防护涂料用单宁酸和聚苯亚甲基丙烯酸树脂的合成及性能分析
IF 2.8 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2026-02-13 DOI: 10.1007/s11998-025-01176-7
Tirthankar Jana, Tapan Kumar Dhar
{"title":"Synthesis and performance analysis of tannic acid and polyphenylene methylene containing acrylic resin for protective coatings","authors":"Tirthankar Jana,&nbsp;Tapan Kumar Dhar","doi":"10.1007/s11998-025-01176-7","DOIUrl":"10.1007/s11998-025-01176-7","url":null,"abstract":"<div><p>A tannic acid-polyphenylene methylene modified acrylic resin was synthesized by solution polymerization technique. The synthesis route involved reaction of tannic acid with suitable acrylic monomers to form tannic acid modified acrylic resin followed by in situ polymerization of this modified acrylic with benzyl chloride in presence of catalyst. The formation of such modified acrylic structure was confirmed by FTIR and <sup>1</sup>H NMR spectroscopic analysis. The novelty of this work is in the synthetic approach to incorporate tannic acid and polyphenylene methylene in acrylic resin matrix to utilize the properties of phenolic hydroxyl and π orbital system of polyphenylene methylene moiety to improve mechanical and anticorrosive properties of coating film. Polyurethane coating based on this modified acrylic resin was evaluated. It was found that the coating with 2 wt% tannic acid containing resin exhibited excellent mechanical properties like flexibility, adhesion, hardness, impact resistance along with anticorrosive performance. Such coating has potential for usage as in high-performance protective coating.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 2","pages":"899 - 910"},"PeriodicalIF":2.8,"publicationDate":"2026-02-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147352826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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