Journal of Coatings Technology and Research最新文献

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Silver-coated copper mesh: an effective oil–water separator with excellent fouling rejection property 镀银铜网:具有优异防污性能的高效油水分离器
IF 2.3 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2024-05-22 DOI: 10.1007/s11998-024-00944-1
Tianlong Yu, Gendi Song, Wenjie Tian, Tingting Liu, Mengying Yan, Bei Wu, Shixiang Lu
{"title":"Silver-coated copper mesh: an effective oil–water separator with excellent fouling rejection property","authors":"Tianlong Yu,&nbsp;Gendi Song,&nbsp;Wenjie Tian,&nbsp;Tingting Liu,&nbsp;Mengying Yan,&nbsp;Bei Wu,&nbsp;Shixiang Lu","doi":"10.1007/s11998-024-00944-1","DOIUrl":"10.1007/s11998-024-00944-1","url":null,"abstract":"<div><p>Superwetting materials play a crucial part in the fields of chemistry and materials science and draw increasing attention. Among the various applications, superwetting materials demonstrated up-and-coming potential in oil spill remediation. Herein, we report on the preparation of silver-coated copper mesh via a facile chemical deposition and annealing treatment approach that requires neither complex devices nor modification with toxic organic molecules. The resulting sample exhibited remarkable water repulsion (water contact angle of ~ 158° and sliding angle of ~ 1°) and oil affinity (oil contact angle of ~ 0°), contributing to superior separation ability toward various oil–water mixtures (hexane, toluene, benzene, chloroform, tetrachloromethane, kerosene, gasoline, diesel) or effectively cleaning up the floating or underwater oil spill. Moreover, the resulting silver-coated superhydrophobic/superoleophilic copper (Ag-coated SS Cu) mesh demonstrated great durability upon the water flow impact or the abrasion test and was able to continuously separate the toluene–water mixtures over 20 times with an efficiency over 97%. In addition, the sample readily prevented surface fouling via self-cleaning process and exhibited antibacterial ability toward <i>Escherichia coli</i>, <i>Staphylococcus aureus</i>, and <i>Bacillus subtilis</i> as witnessed by the corresponding bacteriostatic circle (11.38 ± 0.76 mm, 12.65 ± 0.68 mm, and 12.87 ± 0.72 mm, respectively) in the Petri dish.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"21 5","pages":"1843 - 1856"},"PeriodicalIF":2.3,"publicationDate":"2024-05-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141113443","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fluorine-free approaches to impart photovoltaic systems with self-cleaning and anti-icing features 赋予光伏系统自清洁和防结冰功能的无氟方法
IF 2.3 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2024-05-20 DOI: 10.1007/s11998-024-00936-1
Diana F. Alves, Juliana P. S. Sousa
{"title":"Fluorine-free approaches to impart photovoltaic systems with self-cleaning and anti-icing features","authors":"Diana F. Alves,&nbsp;Juliana P. S. Sousa","doi":"10.1007/s11998-024-00936-1","DOIUrl":"10.1007/s11998-024-00936-1","url":null,"abstract":"<div><p>Dust deposition on photovoltaic systems has a significant impact on the transmittance, temperature, and roughness, causing reductions in their power generation efficiency and lifetime. A promising approach to deal with this problem relies on the use of superhydrophobic coatings to impart the surfaces of these devices with self-cleaning properties. In this work, materials with different chemistry and morphology were added to an acrylic dispersion to create hydrophobic surfaces using a non-fluorinated coating simple strategy for glass substrates. Results showed that materials with more complex morphology, namely the spherical shape of silica nanoparticles, and the needle-like and prism-like structures of zinc oxide, imparted the glass with higher water contact angles. All coatings prepared displayed self-cleaning features and good adhesion to the glass substrate. Coatings comprising silica nanoparticles, zirconia and alumina modified with HDMTS were the best ones to prevent ice formation. In terms of chemical stability, all the coatings resisted acidic conditions close to acid rain pH and solvents with mild polarity. Therefore, the coatings proposed hold great potential to expel dust contaminants and prevent ice formation of photovoltaic devices, increasing their lifetime and power generation efficiency.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"21 6","pages":"1907 - 1919"},"PeriodicalIF":2.3,"publicationDate":"2024-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11998-024-00936-1.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141119478","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High stability, high solid content, low viscosity titanium dioxide dispersion 高稳定性、高固含量、低粘度二氧化钛分散体
IF 2.3 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2024-05-13 DOI: 10.1007/s11998-024-00937-0
Xiaoying Sun, Huidong Wang, Zhenyu Lai, Zhihui Zhang, Zican Zhang, Jianzhong Hang, Liyi Shi
{"title":"High stability, high solid content, low viscosity titanium dioxide dispersion","authors":"Xiaoying Sun,&nbsp;Huidong Wang,&nbsp;Zhenyu Lai,&nbsp;Zhihui Zhang,&nbsp;Zican Zhang,&nbsp;Jianzhong Hang,&nbsp;Liyi Shi","doi":"10.1007/s11998-024-00937-0","DOIUrl":"10.1007/s11998-024-00937-0","url":null,"abstract":"<div><p>Achieving stable dispersion of titanium dioxide (TiO<sub>2</sub>) particles is crucial for their practical applications in various fields. However, stabilizing pigment TiO<sub>2</sub> (200–300 nm) in aqueous systems with low viscosity (~ 10 cP) presents a significant challenge. In this work, we proposed a simple strategy using dispersant Disuper S9100 as dispersant and polyethylene glycol (PEG) as wetting agent to achieve single-dispersed TiO<sub>2</sub> particles with long storage stability and good re-dispersibility in low viscosity systems. The effect of PEG average molecular weight on the stability and re-dispersion performance of TiO<sub>2</sub> dispersion was investigated. Our study showed that PEG molecules were adsorbed on the surface of TiO<sub>2</sub> particles through hydrogen bonding, and synergized with nonionic polymeric dispersant Disuper S9100 to increase the steric hindrance between the particles. Due to the different adsorption conformations of PEG molecules, the dispersion stability and re-dispersibility of TiO<sub>2</sub> particles was gradually improved with increasing PEG average molecular weight. However, PEG molecules with excessively high molecular weight weakened the dispersion stability of TiO<sub>2</sub> particles. Overall, our findings suggest that the proposed strategy offers a promising approach to achieving stable TiO<sub>2</sub> particles in low viscosity systems.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"21 5","pages":"1795 - 1804"},"PeriodicalIF":2.3,"publicationDate":"2024-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140942456","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Specific, nondestructive, and durable adhesion primer for polyolefins 用于聚烯烃的特殊、无损、耐久的附着底漆
IF 2.3 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2024-05-10 DOI: 10.1007/s11998-024-00938-z
Giulia Morgese, Konstantin Siegmann, Martin Winkler
{"title":"Specific, nondestructive, and durable adhesion primer for polyolefins","authors":"Giulia Morgese,&nbsp;Konstantin Siegmann,&nbsp;Martin Winkler","doi":"10.1007/s11998-024-00938-z","DOIUrl":"10.1007/s11998-024-00938-z","url":null,"abstract":"<div><p>Gluing polyolefins [e.g., polyethylene (PE) and polypropylene (PP)] results in a very challenging task. The main reason relies on their low surface energy, which reduces the affinity between the polyolefin surface and the chosen adhesive. To tackle this problem, the most commonly used solutions are physical surface treatments, such as plasma, corona, and flame, which introduce hydrophilic moieties on the plastics surface, thus increasing their surface energy. These approaches require special setups, are unspecific, and can induce material degradation. Furthermore, they provide a transient solution, making the storage of pretreated substrates not recommended. In this work, we developed an easy-to-apply primer for durable bonding of adhesives on PE and PP, as robust alternative to physical treatments. Our primer contains a surface-anchoring moiety and an adhesive-binding group to covalently react with the polyolefin substrate and with the glue. As a surface-anchoring moiety, we chose the perfluorophenylazide (PFPA), which is known to undergo a C–H insertion reaction upon UV activation, while as adhesive-binding groups, we selected OH functions, which can covalently react with the most common commercially available glues. When these two features (i.e., PFPA and OH) are combined in a single molecule, the reaction with the substrate does not occur and the molecule is only physisorbed, inducing no adhesion improvement. Chemisorption only occurs with bicomponent formulations, comprising a hydrophobic trifunctional PFPA and a polymer bearing OH and PFPA groups. Those induced improved adhesion on PP compared to the golden standard plasma with polyurethane-based and two-component epoxy adhesives. Storing the coated substrates at room temperature for up to two months did not alter the adhesion performance, thus further ascribing the developed primers as a promising alternative to plasma treatment.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"21 6","pages":"1921 - 1930"},"PeriodicalIF":2.3,"publicationDate":"2024-05-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11998-024-00938-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140940308","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrosion behavior and antibacterial adhesion of superhydrophobic composite coatings on AZ31 magnesium alloys AZ31 镁合金上超疏水复合涂层的腐蚀行为和抗菌附着力
IF 2.3 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2024-05-06 DOI: 10.1007/s11998-024-00923-6
Huanlin Zhang, Shu Cai, Hang Zhang, Lei Ling, You Zuo, Hao Tian, Tengfei Meng, Guohua Xu, Xiaogang Bao, Mintao Xue
{"title":"Corrosion behavior and antibacterial adhesion of superhydrophobic composite coatings on AZ31 magnesium alloys","authors":"Huanlin Zhang,&nbsp;Shu Cai,&nbsp;Hang Zhang,&nbsp;Lei Ling,&nbsp;You Zuo,&nbsp;Hao Tian,&nbsp;Tengfei Meng,&nbsp;Guohua Xu,&nbsp;Xiaogang Bao,&nbsp;Mintao Xue","doi":"10.1007/s11998-024-00923-6","DOIUrl":"10.1007/s11998-024-00923-6","url":null,"abstract":"<div><p>To improve the corrosion resistance and antibacterial adhesion properties of AZ31 magnesium alloy as an orthopedic implant material, superhydrophobic hydroxyapatite/lauric acid composite coatings (HA/LA) were successfully fabricated on AZ31 magnesium alloy utilizing the hydrothermal method and followed by immersion treatment in lauric acid solution. The underlying HA coating synthesized by hydrothermal technique presents a micro-/nanohierarchical structure, appearing superhydrophilic, while the composite coatings (HA/LA) obtained by subsequent treatment with lauric acid exhibited excellent superhydrophobic properties with a contact angle of 152.5 ± 1.2° and a rolling angle of 1.5 ± 0.3°. Electrochemical measurements and long-term corrosion resistance test conducted in simulated body fluid (SBF) indicate a significant enhancement in the corrosion resistance of the HA/LA composite coating. Meanwhile, in vitro bacterial experiments demonstrated that the superhydrophobic composite coating surface was able to reduce the adhesion of adherent <i>Escherichia coli</i> and <i>Staphylococcus aureus</i> by more than 98%, showing excellent antibacterial adhesion properties, indicating that the superhydrophobic HA/LA composite coating in this work grants magnesium alloy with excellent corrosion resistance and antibacterial properties.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"21 5","pages":"1663 - 1675"},"PeriodicalIF":2.3,"publicationDate":"2024-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140885703","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Coatings with high solar reflectivity: heat build-up in laboratory and real conditions 高太阳反射率涂层:实验室和实际条件下的热量积累
IF 2.3 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2024-05-06 DOI: 10.1007/s11998-024-00935-2
Ewa Langer, Małgorzata Zubielewicz, Bartosz Kopyciński
{"title":"Coatings with high solar reflectivity: heat build-up in laboratory and real conditions","authors":"Ewa Langer,&nbsp;Małgorzata Zubielewicz,&nbsp;Bartosz Kopyciński","doi":"10.1007/s11998-024-00935-2","DOIUrl":"10.1007/s11998-024-00935-2","url":null,"abstract":"<div><p>Excessive heat build-up of painted surfaces due to solar radiation and the resulting increase in interior temperatures is undesirable and even dangerous for roofing, facades, and other structural elements. One way to reduce surface temperature is to apply suitably pigmented organic coatings exhibiting high solar reflectance properties. The use of high solar reflectance pigments in paints resulted in coatings with high total solar reflectance (TSR) values, and thus with the ability to reduce the temperature of the painted substrate. The coatings were tested under laboratory and outdoor conditions on two livestock farms. It was found that the developed coatings exhibit significantly higher TSR values than commercial coatings of the same colors designed for painting roofs. The TSR values do not change when the coatings are exposed to the weather.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"21 5","pages":"1783 - 1793"},"PeriodicalIF":2.3,"publicationDate":"2024-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140885949","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of hydrophobic/hydrophilic and antireflective coatings for photovoltaic panels 光伏电池板疏水/亲水涂层和抗反射涂层的评估
IF 2.3 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2024-05-03 DOI: 10.1007/s11998-024-00929-0
Yadav Narendra Kumar Rajbahadur, Avinash Kumar, Sushant Negi, Simanchal Kar
{"title":"Evaluation of hydrophobic/hydrophilic and antireflective coatings for photovoltaic panels","authors":"Yadav Narendra Kumar Rajbahadur, Avinash Kumar, Sushant Negi, Simanchal Kar","doi":"10.1007/s11998-024-00929-0","DOIUrl":"https://doi.org/10.1007/s11998-024-00929-0","url":null,"abstract":"<p>Photovoltaic modules have emerged as a crucial technology for generating electricity from renewable sources to advance toward achieving neutrality in carbon emissions. Nevertheless, the efficacy and overall effectiveness of solar PV cells are significantly affected by various aspects, including ecological conditions and operation and maintenance practices. These factors directly impact the outcome, energy utilization efficacy, productivity, and lifespan of the PV cells, ultimately influencing the economic aspects of power generation. A highly effective method for mitigating ecological factors is applying a self-cleaning and antireflective coating, which utilizes micro–nano structures and surface wettability to facilitate cleaning and enhance light transmission. This study investigates the influence of ecological and operational factors on solar PV cell effectiveness. Further, a brief summary of the basic principles and development of self-cleaning and antireflective coating is presented by examining recent research. The review reveals that soiling, humidity, and temperature negatively influence the performance of PV modules. In humid conditions, dust deposition leads to the formation of adhesive mud on PV cells, resulting in a reduction of power generation by as high as ~ 70%. In addition, it is also suggested that the application of self-cleaning and antireflection coating on PV modules enhances its efficiency by ~ 11% compared to uncoated modules. Lastly, a comparative analysis of hydrophobic and hydrophilic coatings, various coating methods, and their durability and life expectancy are summarized, and a few effective processes are highlighted for their promising research outcomes.</p>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"22 1","pages":""},"PeriodicalIF":2.3,"publicationDate":"2024-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140886113","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Testing for biofilm release as a function of simulated ship speed using a calibrated water jet device 使用校准喷水装置测试生物膜释放与模拟船速的函数关系
IF 2.3 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2024-04-30 DOI: 10.1007/s11998-024-00934-3
Zachary Shepard, D. M. L. Meyer, Kayla Kurtz, Asa Julien, Vinka Oyanedel-Craver, Lucie Maranda
{"title":"Testing for biofilm release as a function of simulated ship speed using a calibrated water jet device","authors":"Zachary Shepard,&nbsp;D. M. L. Meyer,&nbsp;Kayla Kurtz,&nbsp;Asa Julien,&nbsp;Vinka Oyanedel-Craver,&nbsp;Lucie Maranda","doi":"10.1007/s11998-024-00934-3","DOIUrl":"10.1007/s11998-024-00934-3","url":null,"abstract":"<div><p>Biofouling release coatings (BRCs) have received attention for their potential to limit the negative impacts of biofouling on marine shipping. The calibrated water jet (CWJ, patent # US 8,984,958 B1) can be used to study the effectiveness of BRCs as a function of ship speed. Using a balance of force and linear momentum, we examined the theory and application of the CWJ for simulating the effect of ship speed on biofilm release for surfaces fouled under (1) laboratory and (2) natural conditions. Greater fouling release corresponded with an increase in CWJ pressure and, therefore, simulated ship speed for the surfaces coated with HullKote. The effectiveness of the CWJ was further confirmed for biofilm release from glass fouled naturally by submersion in flow-through seawater. A scaling analysis confirms that the results of these small-scale experiments are applicable to larger-scale biofouling release from ship hulls. This study is the first to utilize the pressure of a CWJ to quantify biofouling release as a function of simulated ship speed.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"21 5","pages":"1773 - 1781"},"PeriodicalIF":2.3,"publicationDate":"2024-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11998-024-00934-3.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140829088","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermal insulating superhydrophobic composite coating for building thermal management 用于建筑热管理的隔热超疏水复合涂层
IF 2.3 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2024-04-29 DOI: 10.1007/s11998-024-00925-4
Meihui Tang, Lin Su, Zhimeng Zhao, Siyu Wu, Pengfei Li, Xiaofeng Zhao, Fei Zhou, Yuxiang Li, Shanlin Wang
{"title":"Thermal insulating superhydrophobic composite coating for building thermal management","authors":"Meihui Tang,&nbsp;Lin Su,&nbsp;Zhimeng Zhao,&nbsp;Siyu Wu,&nbsp;Pengfei Li,&nbsp;Xiaofeng Zhao,&nbsp;Fei Zhou,&nbsp;Yuxiang Li,&nbsp;Shanlin Wang","doi":"10.1007/s11998-024-00925-4","DOIUrl":"10.1007/s11998-024-00925-4","url":null,"abstract":"<div><p>Thermal insulating coatings have important potential for energy saving in the field of building thermal management, but they are difficult to apply on a large scale due to the problem of being waterproof and moistureproof. Herein, we design a two-step spray process to fabricate a thermal insulating superhydrophobic composite coating using epoxy resin mixed with hollow glass microsphere as primer coating and fluorine-modified SiO<sub>2</sub> nanocoating as a waterproof layer. The composite coating shows durable superhydrophobicity and low thermal conductivity [0.051 W/(m·k)], which is endowed with excellent thermal insulating properties under light and heat, contact heat conduction (− 20 to 70 °C), and boiling water scouring environment. These multiple key properties that have been integrated into our composite film are expected to provide unique advantages for applications in building thermal management.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"21 5","pages":"1691 - 1702"},"PeriodicalIF":2.3,"publicationDate":"2024-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140829080","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation and coating properties of alkyd polyol-based autoxidizable waterborne polyurethane dispersions with high fatty acid content, long storage stability, and low viscosity 具有高脂肪酸含量、长储存稳定性和低粘度的醇酸多元醇基可自氧化水性聚氨酯分散体的制备和涂料性能
IF 2.3 4区 材料科学
Journal of Coatings Technology and Research Pub Date : 2024-04-29 DOI: 10.1007/s11998-024-00928-1
Zecheng Lin, Qingyuan Zeng, Yucheng Zhang, Yongbo Ding, Shuai Chen, Yongluo Qiao, Liang Shen
{"title":"Preparation and coating properties of alkyd polyol-based autoxidizable waterborne polyurethane dispersions with high fatty acid content, long storage stability, and low viscosity","authors":"Zecheng Lin,&nbsp;Qingyuan Zeng,&nbsp;Yucheng Zhang,&nbsp;Yongbo Ding,&nbsp;Shuai Chen,&nbsp;Yongluo Qiao,&nbsp;Liang Shen","doi":"10.1007/s11998-024-00928-1","DOIUrl":"10.1007/s11998-024-00928-1","url":null,"abstract":"<div><p>In order to increase the concentrations of bio-based alkyd polyols (or fatty acids) in self-crosslinking polyurethane dispersions, herein, a series of novel alkyd polyol-based autoxidizable waterborne polyurethane dispersions (AWPUDs) with different fatty acid contents, long storage stability, and low viscosity were successfully prepared by adding dimethylol propionic acid (DMPA) self-emulsifier in the late stage of their synthesis. They and their corresponding curing films were characterized by Fourier transform infrared spectroscopy (FTIR), particle size analysis, rheology measurement, storage stability evaluation, thermogravimetric analysis, dynamic thermomechanical analysis (DMA), etc. The results showed that the addition process of DMPA played a critical role for the excellent features of AWPUDs. Additionally, the crosslinking density, gel contents, and water contact angles of AWPUD films increased with the enlarged fatty acid contents, whereas their water uptake capability decreased. Moreover, a series of AWPUD coatings were prepared, and their properties like drying times, hardness development, pencil hardness, adhesion capability, impact resistance, flexibility, and water resistances were all effectively improved with the increased fatty acid contents, significantly superior to those of waterborne alkyd coatings and waterborne polyurethane coatings without fatty acids.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"21 5","pages":"1713 - 1727"},"PeriodicalIF":2.3,"publicationDate":"2024-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140836013","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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