Z. Ebrahimi-Khusfi, A. R. Nafarzadegan, M. Ebrahimi-Khusfi, A. H. Mosavai
{"title":"Machine Learning approaches for identifying factors influencing dust sensitivity in the Gavkhouni Basin, Central Iran","authors":"Z. Ebrahimi-Khusfi, A. R. Nafarzadegan, M. Ebrahimi-Khusfi, A. H. Mosavai","doi":"10.1007/s13762-024-06183-6","DOIUrl":"10.1007/s13762-024-06183-6","url":null,"abstract":"<div><p>This study identifies key factors affecting dust susceptibility in Gavkhouni Basin, central Iran, using three feature selection algorithms and a perceptual neural network model. Accuracy assessment statistics were used to evaluate the prediction capabilities of the models. The aerosol optical depth dataset validated the dust-generating area map, with the permutation feature importance method prioritizing factors controlling dust events. Using the variables selected by the genetic algorithm improved the coefficient of explanation by 31% compared to relief, and 19% compared to ElasticNet algorithm. The genetic algorithm proved effective in identifying variables that significantly enhanced model accuracy in high-risk zones (precision = 0.75, recall = 0.71, and F1 = 0.73). The study found that topographic diversity, geology, soil sand content, precipitation, wind speed, soil salinity, soil subsidence, vegetation cover, slope, and soil moisture were key environmental factors. These findings are very important for the formulation of specific measures for improving air quality and limiting dust-related effects as a key factor in the sustainable management of vulnerable ecosystems.</p></div>","PeriodicalId":589,"journal":{"name":"International Journal of Environmental Science and Technology","volume":"22 6","pages":"4619 - 4638"},"PeriodicalIF":3.0,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143466032","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
T. F. Souza, L. N. Louzada, F. S. Martinho, G. M. D. Ferreira, G. M. D. Ferreira
{"title":"Heating rate effect on the sorptive properties of biochars from NaOH-modified sugarcane bagasse residues","authors":"T. F. Souza, L. N. Louzada, F. S. Martinho, G. M. D. Ferreira, G. M. D. Ferreira","doi":"10.1007/s13762-024-06157-8","DOIUrl":"10.1007/s13762-024-06157-8","url":null,"abstract":"<div><p>The modification of the operational parameters of pyrolysis, such as the heating rate (HR), to produce adsorbent biochar (BC) has been little explored, especially regarding materials obtained from premodified biomass. Consequently, some fundamental aspects in this field remain not understood, which can limit more targeted syntheses of these materials in environmental application. This study investigated the effect of HR on the pyrolysis of sugarcane bagasse premodified with NaOH. BC was produced in a muffle furnace with HR of 5, 10, 15, or 20 °C min<sup>−1</sup>, at final temperature of 400 °C, and characterized by FTIR, N<sub>2</sub> adsorption, SEM, EDS, conductometric titration, and determination of the point of zero charge. The methylene blue (MB) adsorption kinetics and equilibria on the produced materials were studied to elucidate the influence of HR on the adsorption. The results showed that the surface chemistry and physical properties of the materials were not influenced by different HR. However, equilibrium times for MB adsorption of 10 and 5 h were observed for HR of 5 and 10 °C min<sup>−1</sup>, respectively, while an equilibrium time greater than 48 h was observed for the highest HR; MB intraparticle diffusion played an important role in these different behaviors. The adsorption isotherms were better fit by the Konda model. The fitted parameters suggested that the distribution of sites within pores of different sizes was also determined by the HR. The results showed that the use of MB can help identify structural changes induced by pyrolysis parameters that have a minor effect on the properties of adsorbent BC, such as HR.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":589,"journal":{"name":"International Journal of Environmental Science and Technology","volume":"22 9","pages":"7983 - 7998"},"PeriodicalIF":3.0,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143904805","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
G. Vragkalis, O. Piperagkas, H. Mela, H. Karayanni
{"title":"Microfiber emissions through domestic laundry; an estimation of microfiber release and their fate in a medium-sized city","authors":"G. Vragkalis, O. Piperagkas, H. Mela, H. Karayanni","doi":"10.1007/s13762-024-06186-3","DOIUrl":"10.1007/s13762-024-06186-3","url":null,"abstract":"<div><p>Microfibers (MF) are described as ubiquitous environmental contaminants. They usually emanate from textiles and domestic laundry is a major source of MF in the environment. This study aims to investigate MF emissions through domestic laundry in a hypothesized town in real-life conditions. For this, MF samples were collected from the effluent of the washing cycles in two households, and an anonymous questionnaire was released (> 500 responses) to determine the washing habits of Greek households. More than 6.3 ± 1.9 × 10<sup>4</sup> MF were released during each wash cycle and could occasionally exceed 90 × 10<sup>4</sup> MF. All samples contained synthetic fibers whose relative abundance ranged between 1.7 and 66%. Statistically significant changes in total and synthetic MF were found between seasons attributed to changes in textiles used. Considering the minimum observed MF emissions, it was estimated that in a city of 100,000 inhabitants, annual emissions of microfibers were > 359 × 10<sup>9</sup> or 1.2 t. If all households were connected to a sewage network and a wastewater treatment plant with a 99.9% microplastic retention rate, approximately 5.2 kg of microfibers would enter the aquatic environment annually in a medium-sized city. These results underscore human intervention in the environment and emphasize the necessity for more research into methods for reducing the release of microfibers into the environment.</p></div>","PeriodicalId":589,"journal":{"name":"International Journal of Environmental Science and Technology","volume":"22 9","pages":"8025 - 8032"},"PeriodicalIF":3.0,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143904807","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
W. Hameed, M. Farooq, I. J. Shah, J. Ihsan, H. Ullah, M. Siddiq, L. A. Shah, R. M. K. Mohamed
{"title":"Novel graphene oxide@aluminum oxide@manganeseoxide-based ternary nanocomposites: facile synthesis and characterization for catalytic treatment of targeted industrial effluents","authors":"W. Hameed, M. Farooq, I. J. Shah, J. Ihsan, H. Ullah, M. Siddiq, L. A. Shah, R. M. K. Mohamed","doi":"10.1007/s13762-024-06167-6","DOIUrl":"10.1007/s13762-024-06167-6","url":null,"abstract":"<div><p>Herein, graphene oxide anchored Aluminum Oxide doped Manganese Oxide nanoparticles based ternary nanocomposites were prepared via simple dispersion method to catalytically reduce organic dyes in aqueous media. Structural, morphological, and thermal stability features of the prepared nanocomposite was investigated through various characterization techniques, for example, X-ray Diffraction, Fourier Transform Infrared. Spectroscopy, Energy Dispersive X-ray Spectroscopy and Thermal Gravimetric Analysis. The catalytic potential of the nanocomposite was investigated against catalytic degradation of Methylene Blue, and Methyl Orange. Results indicate that the ternary nanocomposites provide agreeable catalytic capacity towards Methylene Blue reduction, whereas, remarkably efficient towards Methyl Orange degradation. In addition, the effect of catalyst dose on the reduction rate of the targeted dyes was studied. The evaluated kinetic parameters, for example, reduction rate constant and R<sup>2</sup> values recommend the usability of the fabricated nanocomposites in industrial domain.</p></div>","PeriodicalId":589,"journal":{"name":"International Journal of Environmental Science and Technology","volume":"22 9","pages":"7971 - 7982"},"PeriodicalIF":3.0,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143904801","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. A. Yaqoob, N. N. M. Daud, M. H. Hussin, M. N. M. Ibrahim, M. K. Al-Sadoon, R. M. I. Abdulrahman
{"title":"Role of dragon fruit waste (DFW) in microbial fuel cell to treat metal-polluted wastewater with electricity generation","authors":"A. A. Yaqoob, N. N. M. Daud, M. H. Hussin, M. N. M. Ibrahim, M. K. Al-Sadoon, R. M. I. Abdulrahman","doi":"10.1007/s13762-024-06166-7","DOIUrl":"10.1007/s13762-024-06166-7","url":null,"abstract":"<div><p>Green technology, known as the microbial fuel cell (MFC), offers wastewater treatment and sustainable power simultaneously. Although there have been substantial advancements, there are still a number of important problems with this technique. Our study presented here has covered the organic substrate challenge of MFC. In prior studies, there was a strong recommendation that fruit waste be used as a source of carbon. In light of this, the waste from dragon fruit was used as a substrate in the present investigation. In 22 days, the study achieved a voltage of 165 mV and a power density of 1.98 mW/m<sup>2</sup>. Additionally, the removal percentage of Cr<sup>3+</sup> and Pb<sup>2+</sup> is around 85.39–87.91%, respectively. The operation was carried out with constant 1000 ῼ resistance at all times, whereas the determination of the internal resistance was 694 ῼ. Furthermore, bacterial identification from anodic biofilm indicated that <i>Bacillus</i>-type species such as <i>Bacillus nitratireducens, Pseudoneobacillus rhizosphaerae</i>, and <i>Bacillus paramobilis</i> are the dominant species in the present MFC operation. Furthermore, a thorough description of the investigation’s proposed mechanism—which centers on the metal ion removal process—is given. Finally, mechanism, challenges, and future comments are also included.</p></div>","PeriodicalId":589,"journal":{"name":"International Journal of Environmental Science and Technology","volume":"22 9","pages":"7945 - 7956"},"PeriodicalIF":3.0,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143904780","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
X. Xu, L. Zhu, C. Chen, C. Luo, Z. Jin, Z. Sun, Z.T Fu
{"title":"Performance and mechanism of NiO/La-KTaO3 composite photocatalysts for UV degradation of isoamyl xanthate in synthetic flotation wastewater","authors":"X. Xu, L. Zhu, C. Chen, C. Luo, Z. Jin, Z. Sun, Z.T Fu","doi":"10.1007/s13762-024-06180-9","DOIUrl":"10.1007/s13762-024-06180-9","url":null,"abstract":"<div><p>The study employed a direct hydrothermal method to synthesize NiO/La-KTaO<sub>3</sub> heterojunction photocatalysts. The photocatalytic efficiency of the composites was assessed by their ability to destroy isoamyl xanthate in the presence of Ultraviolet light, mimicking the conditions seen in flotation wastewater. The results showed a significantly greater photocatalytic activity when comparing the composite catalyst to KTaO<sub>3</sub>. A photocatalytic reaction was performed utilizing a 40 mg NiO/K<sub>1−x</sub>La<sub>x</sub>TaO<sub>3</sub> (x = 0.04) photocatalyst at pH = 3. The reaction was carried out using 50 mL of isoamyl xanthate synthesis wastewater, which had a concentration of 20 mg/L. The degradation rate achieved after 30 min was 87.28%. The addition of nickel oxide (NiO) and the introduction of La into the K lattice position were thought to facilitate charge separation, migration, and the generation of additional active sites, hence augmenting the catalytic impact. The findings from radical capture tests indicated that the ·O<sup>2−</sup> (superoxide ion) served as the principal active species in the photocatalytic process, playing a substantial role. The process of photodegradation of isoamyl xanthate was determined through the utilization of different analytical and testing methods. This work introduces a direct and effective approach for the eco-friendly decomposition of xanthate flotation wastewater.</p></div>","PeriodicalId":589,"journal":{"name":"International Journal of Environmental Science and Technology","volume":"22 9","pages":"7957 - 7970"},"PeriodicalIF":3.0,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143904782","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Synergistic effects of process parameters on methylene blue degradation by cold plasma","authors":"R. R. Targhi, F. Qaderi","doi":"10.1007/s13762-024-06115-4","DOIUrl":"10.1007/s13762-024-06115-4","url":null,"abstract":"<div><p>Eliminating dye pollutants from water systems is essential to prevent long-term environmental damage, as these substances can hinder photosynthesis, reduce water quality, and introduce harmful chemicals into aquatic ecosystems. This study explores the potential of non-thermal plasma technology, specifically the Dielectric Barrier Discharge configuration, for the degradation of Methylene Blue dye in aqueous solutions. A systematic investigation was conducted to assess the influence of key operational parameters such as applied voltage, initial Methylene Blue concentration, treatment time, and pH on the removal efficiency of Methylene Blue. Using Response Surface Methodology in conjunction with Design Expert software, optimal conditions were identified, including a voltage of 15 kV, a Methylene Blue concentration of 20 mg/L, a treatment time of 42.6 min, and a pH of 9, achieving a removal efficiency of 67.54%. Additionally, under specific condition, a maximum RE of 91.7% was achieved. The study demonstrates the efficacy of the cold plasma process in efficiently degrading Methylene Blue dye, offering a scalable and environmentally friendly solution for treating dye-laden wastewater in industrial applications.</p></div>","PeriodicalId":589,"journal":{"name":"International Journal of Environmental Science and Technology","volume":"22 6","pages":"4559 - 4570"},"PeriodicalIF":3.0,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143466019","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
I. Purnama, F. M. Malhat, A. Mutamima, B. Rusdiarso, S. Noegrohati
{"title":"Enhanced dissipation of azoxystrobin in loam soil under direct sunlight exposure","authors":"I. Purnama, F. M. Malhat, A. Mutamima, B. Rusdiarso, S. Noegrohati","doi":"10.1007/s13762-024-06152-z","DOIUrl":"10.1007/s13762-024-06152-z","url":null,"abstract":"<div><p>While the impact of solar radiation on azoxystrobin degradation is known, the influence of temperature fluctuations on this process remains poorly understood. This study investigates the factors influencing azoxystrobin dissipation in soil, with a particular focus on the impact of solar radiation and temperature variations on photodegradation kinetics. Our objective was to assess, for the first time, the influence of temperature fluctuations on azoxystrobin photodegradation kinetics in loam soil. High-performance liquid chromatography was utilized to analyze dissipation rates under sunlight and dark conditions, with a quantitation limit of 0.05 mg/kg. Sampling intervals of 0, 1, 7, 15, 21, and 28 days were employed during incubation. Azoxystrobin dissipation rates were determined using first-order kinetic modeling. Results indicate a significantly accelerated dissipation rate under sunlight conditions (0.2018/day, t ½ = 3.4 days) compared to darkness (0.0912/day, t ½ = 7.6 days), highlighting the substantial impact of photodegradation and temperature fluctuations. These findings provide novel insights into azoxystrobin behavior in agricultural soils, enabling more accurate risk assessments and the development of targeted mitigation strategies to protect ecosystems from pesticide contamination.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":589,"journal":{"name":"International Journal of Environmental Science and Technology","volume":"22 6","pages":"4521 - 4534"},"PeriodicalIF":3.0,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143466018","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Matias-Gutierres, E. I. García-Otamendi, H. D. Sánchez-Chávez
{"title":"Seasonal persistence of the nitrogen oxides production in Mexico City","authors":"S. Matias-Gutierres, E. I. García-Otamendi, H. D. Sánchez-Chávez","doi":"10.1007/s13762-024-06153-y","DOIUrl":"10.1007/s13762-024-06153-y","url":null,"abstract":"<div><p>This study investigates the seasonal influence on the nitrogen oxide <i>NO</i><sub><i>x</i></sub> pollution records at four monitoring sites in Mexico City from 2010 to 2018. The analysis employs the second-order structure function to examine the trends in <i>NO</i><sub><i>x</i></sub> concentration fluctuations. The findings reveal that the fluctuations follow a power law pattern characterized by Hurst exponents, predominantly in the statistical persistence regime, with a scaling range spanning three orders of magnitude. Specifically, the autumn period exhibits fluctuations with an exponent of <span>(overline{H}=0.72)</span>, indicating relatively smaller fluctuations compared to other seasons, but with the potential for <i>NO</i><sub><i>x</i></sub> concentrations to surpass those in other periods. In contrast, for spring, summer, and winter, the fluctuations are characterized by exponents of<span>(overline{H}=0.59)</span>,<span>(overline{H}=0.61)</span>, and<span>(overline{H}=0.62)</span>, respectively, demonstrating greater fluctuations with lower <i>NO</i><sub><i>x</i></sub> concentrations compared to autumn. These results are consistent with various studies conducted worldwide. Additionally, a negative correlation between <i>NO</i><sub><i>x</i></sub> and ozone (<i>O</i><sub><i>3</i></sub>) has been established during the winter season, as <i>NO</i><sub><i>x</i></sub> and <i>O</i><sub><i>3</i></sub> fluctuations display persistent and anti-persistent behavior, respectively.</p></div>","PeriodicalId":589,"journal":{"name":"International Journal of Environmental Science and Technology","volume":"22 9","pages":"7507 - 7518"},"PeriodicalIF":3.0,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s13762-024-06153-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143904759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. H. Yazdi, M. Robati, S. Samani, F. Z. Hargalani
{"title":"Assessment of groundwater sustainability in arid and semi-arid regions using a fuzzy Delphi method","authors":"S. H. Yazdi, M. Robati, S. Samani, F. Z. Hargalani","doi":"10.1007/s13762-024-06092-8","DOIUrl":"10.1007/s13762-024-06092-8","url":null,"abstract":"<div><p>There is significant reliance on groundwater sources in arid and semi-arid regions worldwide. Ensuring the sustainable use of this vital resource is imperative and requires evaluating various attributes through appropriate indicators. While traditional methods of indicator selection often struggle with uncertainty and may overlook essential factors, this study introduces an innovative approach by employing the Fuzzy Delphi Method. This method not only refines indicator selection by addressing uncertainties but also enhances the relevance and accuracy of sustainability assessments. In the context of Iran’s Houmand Absard, where groundwater is the primary source of freshwater, this approach has proven particularly effective. Initially, 86 pragmatic indicators were identified, and a global survey of 155 researchers, combined with fuzzy analysis, reduced these to 27 critical indicators. Notably, environmental indicators emerged as the most significant, with the 'percentage of aquifer area with groundwater overexploitation problem' receiving the highest score of 0.750. This research contributes to the global discourse on groundwater sustainability by providing a more reliable and context-specific framework for indicator selection, especially in arid and semi-arid regions, thereby ensuring better-informed decision-making.</p></div>","PeriodicalId":589,"journal":{"name":"International Journal of Environmental Science and Technology","volume":"22 1","pages":"341 - 362"},"PeriodicalIF":3.0,"publicationDate":"2024-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142939055","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}