阳光直射下氮氧化物在壤土中的耗散增强

IF 3 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES
I. Purnama, F. M. Malhat, A. Mutamima, B. Rusdiarso, S. Noegrohati
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引用次数: 0

摘要

虽然太阳辐射对偶氮嘧菌酯降解的影响是已知的,但温度波动对这一过程的影响仍然知之甚少。本研究探讨了氮嘧菌酯在土壤中耗散的影响因素,重点研究了太阳辐射和温度变化对其光降解动力学的影响。我们的目的是首次评估温度波动对氮氧化物酶在壤土中光降解动力学的影响。采用高效液相色谱法分析光照和黑暗条件下的耗散率,定量限为0.05 mg/kg。孵育期间取样间隔为0、1、7、15、21和28天。采用一级动力学模型确定了偶氮菌酯的耗散速率。结果表明,与黑暗条件(0.0912/天,t½= 7.6天)相比,光照条件下(0.2018/天,t½= 3.4天)的耗散速率显著加快,这突出了光降解和温度波动的实质性影响。这些发现对农业土壤中偶氮嘧菌酯的行为提供了新的见解,有助于更准确地进行风险评估,并制定有针对性的缓解战略,以保护生态系统免受农药污染。图形抽象
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Enhanced dissipation of azoxystrobin in loam soil under direct sunlight exposure

Enhanced dissipation of azoxystrobin in loam soil under direct sunlight exposure

While the impact of solar radiation on azoxystrobin degradation is known, the influence of temperature fluctuations on this process remains poorly understood. This study investigates the factors influencing azoxystrobin dissipation in soil, with a particular focus on the impact of solar radiation and temperature variations on photodegradation kinetics. Our objective was to assess, for the first time, the influence of temperature fluctuations on azoxystrobin photodegradation kinetics in loam soil. High-performance liquid chromatography was utilized to analyze dissipation rates under sunlight and dark conditions, with a quantitation limit of 0.05 mg/kg. Sampling intervals of 0, 1, 7, 15, 21, and 28 days were employed during incubation. Azoxystrobin dissipation rates were determined using first-order kinetic modeling. Results indicate a significantly accelerated dissipation rate under sunlight conditions (0.2018/day, t ½ = 3.4 days) compared to darkness (0.0912/day, t ½ = 7.6 days), highlighting the substantial impact of photodegradation and temperature fluctuations. These findings provide novel insights into azoxystrobin behavior in agricultural soils, enabling more accurate risk assessments and the development of targeted mitigation strategies to protect ecosystems from pesticide contamination.

Graphical abstract

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来源期刊
CiteScore
5.60
自引率
6.50%
发文量
806
审稿时长
10.8 months
期刊介绍: International Journal of Environmental Science and Technology (IJEST) is an international scholarly refereed research journal which aims to promote the theory and practice of environmental science and technology, innovation, engineering and management. A broad outline of the journal''s scope includes: peer reviewed original research articles, case and technical reports, reviews and analyses papers, short communications and notes to the editor, in interdisciplinary information on the practice and status of research in environmental science and technology, both natural and man made. The main aspects of research areas include, but are not exclusive to; environmental chemistry and biology, environments pollution control and abatement technology, transport and fate of pollutants in the environment, concentrations and dispersion of wastes in air, water, and soil, point and non-point sources pollution, heavy metals and organic compounds in the environment, atmospheric pollutants and trace gases, solid and hazardous waste management; soil biodegradation and bioremediation of contaminated sites; environmental impact assessment, industrial ecology, ecological and human risk assessment; improved energy management and auditing efficiency and environmental standards and criteria.
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