Functional Composite Materials最新文献

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Importance of dielectric constant in the development of stretchable electronics materials 介电常数在可拉伸电子材料发展中的重要性
Functional Composite Materials Pub Date : 2026-09-01 DOI: 10.1186/s42252-026-00105-0
Ankush Patel, Debashis Kundu
{"title":"Importance of dielectric constant in the development of stretchable electronics materials","authors":"Ankush Patel,&nbsp;Debashis Kundu","doi":"10.1186/s42252-026-00105-0","DOIUrl":"10.1186/s42252-026-00105-0","url":null,"abstract":"<div><p>Stretchable electronics require materials that maintain their electrical performance even under significant mechanical strain. The dielectric constant is important for figuring out device sensitivity, operating voltage, and energy density. However, there is extensive research on stretchable polymers, elastomers, energy harvesting devices, and composite dielectrics, and the dielectric constant, but data remain inconsistent and fragmented to predict materials and device design. This review examines the role of the dielectric constant in stretchable electronic materials, as well as measurement approaches and modelling strategies. It includes contributions to the key classes of materials, composite dielectrics, elastomers, and stretchable polymers and examines the relationships among materials, dielectrics, device sensitivity, operating voltage, and energy density as they are mechanically strained. Several studies have measured the dielectric constants of stretchable electronic materials. These studies demonstrate the variety of differences in dielectric constant that occur due to different conditions of the test or different compositions of the materials and indicate the need to have a more unified understanding of the structure-property relationships. However, limited open access data and the lack of standardised measurement methods make accurate analysis challenging and affect device performance. Solving these challenges through standardised measurement practices and the sharing of open datasets will play a crucial role in advancing the rational design of future stretchable, electronic, and energy-harvesting devices.</p></div>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1186/s42252-026-00105-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148926445","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ceramic composites derived from rice husk silica: influence of a low amount of steel fibres 稻壳硅基陶瓷复合材料:低量钢纤维的影响
Functional Composite Materials Pub Date : 2026-08-24 DOI: 10.1186/s42252-026-00104-1
M. A. D. Tier, A. S. Nunes, M. C. D. Cabral, J. C. Quevedo, G. E. Azolim, E. Marangon
{"title":"Ceramic composites derived from rice husk silica: influence of a low amount of steel fibres","authors":"M. A. D. Tier,&nbsp;A. S. Nunes,&nbsp;M. C. D. Cabral,&nbsp;J. C. Quevedo,&nbsp;G. E. Azolim,&nbsp;E. Marangon","doi":"10.1186/s42252-026-00104-1","DOIUrl":"10.1186/s42252-026-00104-1","url":null,"abstract":"<div><p>The development of sustainable refractory ceramics requires alternative silica sources capable of reducing the consumption of conventional raw materials without compromising thermo-mechanical performance. Although rice husk silica (RHS) has been investigated as a silica source, the combined effect of high RHS replacement levels and low steel fibre (SF) contents on the mechanical and thermal behaviour of refractory ceramics remains poorly understood. This study investigates refractory ceramic composites produced by replacing refractory clay with 10, 20 and 30% RHS and incorporating a low content of short steel fibres (1%). The influence of RHS and fibres on phase evolution, physical properties, flexural behaviour and thermal shock resistance was experimentally evaluated. The incorporation of RHS promoted matrix densification, increasing bulk density and reducing apparent porosity, which resulted in improved flexural strength up to 20% replacement. At 30% RHS, despite the lower porosity, flexural strength decreased, indicating that phase evolution, particularly the increased formation of cristobalite, also influences the mechanical response. The addition of steel fibres slightly increased porosity and reduced peak flexural strength, while introducing post-crack load-carrying capacity and changing the fracture behaviour from brittle to quasi-brittle. This change also significantly improved thermal shock resistance, increasing the number of thermal cycles to failure by approximately six times compared with unreinforced ceramics. X-ray diffraction confirmed the formation of mullite, quartz and cristobalite after sintering. The composite containing 20% RHS and 1% steel fibres exhibited the best overall balance between strength, ductility and thermal shock resistance, demonstrating that agricultural waste combined with a low fibre content provides an effective strategy for developing sustainable refractory ceramics with improved performance.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1186/s42252-026-00104-1.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148837358","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanical performance of recycled bovine leather/epoxy composites 再生牛皮/环氧复合材料的力学性能
Functional Composite Materials Pub Date : 2026-08-24 DOI: 10.1186/s42252-026-00102-3
B. Jaouachi, S. Tabib, D. C. Adolphe, A. Nedri
{"title":"Mechanical performance of recycled bovine leather/epoxy composites","authors":"B. Jaouachi,&nbsp;S. Tabib,&nbsp;D. C. Adolphe,&nbsp;A. Nedri","doi":"10.1186/s42252-026-00102-3","DOIUrl":"10.1186/s42252-026-00102-3","url":null,"abstract":"<div><p>This study evaluates the mechanical performance and fractured behavior of recycled bovine leather fiber (RBLF)/epoxy (ER) composites produced using industrial post-consumer leather waste as a sustainable reinforcement for epoxy. Composites containing 5–10 wt% RBLF were fabricated and their properties were compared with those of neat epoxy. The developed composites exhibited the following properties: tensile strengths ranging from 14.22 to 41.73 MPa, flexural strengths from 76.54 to 125.92 MPa, flexural moduli from 1.46 to 2.50 GPa, compressive strengths from 74.13 to 126.46 MPa, and compressive moduli from 2.67 to 4.03 GPa. These values compare favorably with those reported in the literature for conventional natural and synthetic fiber-reinforced composites, including jute/epoxy and flax/epoxy systems, which were tested under similar conditions. Water absorption increased from 0.85–1.34% after 24 hours to 1.18–4.33% after 384 hours, reaching an almost constant value after 96 hours. The composites were further characterized using several methods: Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), energy-dispersive X-ray spectroscopy (EDX), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and three-dimensional surface topography analysis. The FTIR spectra confirmed effective cross-linking within the leather fiber/epoxy composites, as evidenced by the characteristic absorption bands at 2923–2924, 2852–2854, and 1455–1460 cm<sup>− 1</sup>, corresponding to CH/CH₂ stretching vibrations. In addition, EDX analysis revealed that chromium, nitrogen, sodium, phosphorus, aluminum, and silicon, which were detected in the raw leather, were no longer observed in the composites, indicating that the leather fibers were effectively encapsulated by the epoxy matrix. Overall, these results demonstrate that recycled bovine leather fiber/epoxy composites represent a promising lightweight material for weight-sensitive applications.</p></div>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1186/s42252-026-00102-3.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148837359","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Data driven approach for topological data of polyelectrolytes assembly 聚电解质组装拓扑数据的数据驱动方法
Functional Composite Materials Pub Date : 2026-08-19 DOI: 10.1186/s42252-026-00103-2
Aleksei V. Meshkov, Olesya V. Khoroshilova, Vladimir V. Potapov, Timur A. Aliev, Anna A. Nikitina, Dmitrii A. Kozodaev, Ekaterina V. Skorb
{"title":"Data driven approach for topological data of polyelectrolytes assembly","authors":"Aleksei V. Meshkov,&nbsp;Olesya V. Khoroshilova,&nbsp;Vladimir V. Potapov,&nbsp;Timur A. Aliev,&nbsp;Anna A. Nikitina,&nbsp;Dmitrii A. Kozodaev,&nbsp;Ekaterina V. Skorb","doi":"10.1186/s42252-026-00103-2","DOIUrl":"10.1186/s42252-026-00103-2","url":null,"abstract":"<div><p>Layer-by-layer (LbL) assembly of polyelectrolytes is a universal method for controlling composite coatings. When combined with atomic force microscopy (AFM), it is useful strategy to analyze morphology. Optimisation of the LbL technique is bottlenecked by manual sample preparation, and there is also a lack of standardised analytical pipelines to convert characterisation data into machine-readable descriptors. We address both bottlenecks by combining a collaborative robotic dip-coating platform with an automated feature-extraction backend for AFM topography. The robotic arm handles the substrate (Si wafer), immerses it in polyelectrolyte solution, and prepares samples for AFM study without operator intervention. Resulting AFM scans are transferred into a reproducible pipeline that applies a logged preprocessing chain and computes twelve groups of physically interpretable descriptors per sample: ISO 25,178 areal roughness, height-distribution statistics, radial power spectrum with Hurst and fractal exponents, two-dimensional autocorrelation, local-patch minima/maxima distributions, persistent homology of patch point clouds, gliding-box lacunarity, and a recipe-derived block of layer composition, sequence k-grams and RDKit monomer descriptors. Every descriptor is stored with the originating method version and parameters, supporting idempotent recomputation and side-by-side methodological evolution. The pipeline was applied to polyethyleneimine (PEI)/polystyrene sulfonate (PSS) assemblies on Si substrates, and an unsupervised principal component projection of the scalar descriptors already separates samples by the number of deposited layers, demonstrating that the resulting feature vectors carry coating-state information at a level useful for downstream machine learning. This work establishes a traceable, data‑driven bridge from synthesis instructions to high‑dimensional surface descriptors, demonstrating for the first time an end‑to‑end pipeline where robotic LbL assembly, versioned AFM processing, and hybrid topological‑chemical feature extraction converge into a single machine‑learning‑ready dataset.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1186/s42252-026-00103-2.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148782613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multifunctional segmented thermoplastic polyurethane nanocomposites reinforced with graphene-based two-dimensional nanofillers in special reference to gas barrier and electrical properties 以石墨烯基二维纳米填料增强的多功能分段热塑性聚氨酯纳米复合材料,特别参考了气密性和电性能
Functional Composite Materials Pub Date : 2026-05-11 DOI: 10.1186/s42252-026-00089-x
Ramya Devi, Piyush Gupta, Kinsuk Naskar, Santanu Chattopadhyay
{"title":"Multifunctional segmented thermoplastic polyurethane nanocomposites reinforced with graphene-based two-dimensional nanofillers in special reference to gas barrier and electrical properties","authors":"Ramya Devi,&nbsp;Piyush Gupta,&nbsp;Kinsuk Naskar,&nbsp;Santanu Chattopadhyay","doi":"10.1186/s42252-026-00089-x","DOIUrl":"10.1186/s42252-026-00089-x","url":null,"abstract":"<div><p>This study focuses on the evaluation of the mechanical, thermal, gas barrier, and electrical properties of segmented polyester-based TPU coatings with a low loading of 2D- graphene nanofillers, namely graphene oxide (GO), reduced graphene oxide (RGO), and graphene nanoplatelets (GNP), respectively. TPUs have a unique segmented structure featuring soft and hard segment alternation, which contributes to their inherent tailor-made flexibility and strength. Incorporation of the graphene fillers enhanced the thermal stability, mechanical performance, and electrical conductivity by virtue of their large surface area. TPU at 0.5 wt% GO displayed a tensile strength of 30.4 MPa and 800% elongation at break while preserving flexibility. GO and RGO decreased oxygen permeability by approximately 70% and 46%, respectively. RGO exhibited enhanced mechanical and electrical properties attributed to reduced oxygen content and increased π–π interactions. At 1.0 wt%, GNP established a percolated conductive network exhibiting an electrical conductivity of approximately 9.0 × 10<sup>− 5</sup> S/m, which is 66% greater than that of RGO filled composites. The various oxidation levels and morphologies of these fillers provide unique benefits, facilitating multifunctional TPU nanocomposites. This study clarifies the interactions between graphene and TPU, contributing to applications such as flexible electronics, packaging, protective coatings, and lighter-than-air vehicles.</p><div><figure><div><div><picture><source><img></source></picture><span>The alternative text for this image may have been generated using AI.</span></div></div></figure></div></div>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-05-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1186/s42252-026-00089-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147938220","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing wear resistance of styrene-butadiene rubber composites through graphene nanoplatelets reinforcement 石墨烯纳米片增强丁苯橡胶复合材料的耐磨性
Functional Composite Materials Pub Date : 2026-05-01 DOI: 10.1186/s42252-026-00097-x
Moises Xavier Guimarães Valentim, Dalton Daniel de Lima, Caroline Raquel Bender, Janaína da Silva Crespo, Natália de Freitas Daudt
{"title":"Enhancing wear resistance of styrene-butadiene rubber composites through graphene nanoplatelets reinforcement","authors":"Moises Xavier Guimarães Valentim,&nbsp;Dalton Daniel de Lima,&nbsp;Caroline Raquel Bender,&nbsp;Janaína da Silva Crespo,&nbsp;Natália de Freitas Daudt","doi":"10.1186/s42252-026-00097-x","DOIUrl":"10.1186/s42252-026-00097-x","url":null,"abstract":"<div><p>Styrene–butadiene rubber (SBR) is widely employed in applications requiring a balance of mechanical strength, processability, and wear resistance, such as vehicle track pads. However, conventional fillers such as carbon black and silica present limitations in simultaneously enhancing multiple performance attributes. In this study, graphene nanoplatelets were incorporated at low loadings (0.1, 0.3, and 0.5 phr) into SBR to evaluate their effect on vulcanization behavior, thermal stability, hardness, and wear resistance. Graphene incorporation increased the crosslink density of SBR by up to 17% but did not significantly affect curing kinetics, with all formulations showing an optimum cure time of approximately 18 min. Thermal analysis revealed no significant changes in the main degradation pathways of SBR, although the increase in glass transition temperature suggests restricted chain mobility. Shore D hardness increased with increasing graphene content, rising from 31 at 0 phr to 33.4 at 0.5 phr, confirming the reinforcing effect of graphene nanoplatelets at low concentrations. Wear performance, evaluated by both mass-loss and volume-loss abrasion tests, demonstrated a clear reduction in wear with increasing graphene content. The best performance was observed for 0.5 phr graphene, where mass loss decreased up to 26% compared to neat SBR. These results contrast with previous studies that reported deterioration in abrasion resistance at higher graphene loadings, supporting the hypothesis that graphene acts as a reinforcing filler only at low concentrations. Overall, the findings highlight the potential of graphene nanoplatelets to improve hardness and abrasion resistance in SBR without compromising curing or thermal stability.</p></div>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1186/s42252-026-00097-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147796778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The influence of processing temperature on characteristic features of AgI-MCM48-ZnI2 hybrid powders 加工温度对AgI-MCM48-ZnI2杂化粉体特性的影响
Functional Composite Materials Pub Date : 2026-04-29 DOI: 10.1186/s42252-026-00098-w
Anastasiia Averkina, Natalia Kondrashova, Igor Valtsifer, Viktor Valtsifer, Vladimir Strelnikov
{"title":"The influence of processing temperature on characteristic features of AgI-MCM48-ZnI2 hybrid powders","authors":"Anastasiia Averkina,&nbsp;Natalia Kondrashova,&nbsp;Igor Valtsifer,&nbsp;Viktor Valtsifer,&nbsp;Vladimir Strelnikov","doi":"10.1186/s42252-026-00098-w","DOIUrl":"10.1186/s42252-026-00098-w","url":null,"abstract":"<div>\u0000 \u0000 <p>AgI-MCM48-ZnI<sub>2</sub> hybrid powders (HPs) based on mesoporous silica and silver/zinc iodides were synthesized via the hydrothermal template co-condensation (HTC) method. Particular attention was paid to the post-synthetic treatment, specifically the annealing stage. The primary objective was to determine the optimal annealing temperature that enables the full development of the composite’s structural and textural properties while preserving the metal iodide crystals. The physicochemical characteristics of the HPs were evaluated using various analytical methods, with the retention of AgI and ZnI<sub>2</sub> phases, specific surface area, and pore parameters serving as key control indicators.The results confirm that the morphology of the AgI-MCM48-ZnI<sub>2</sub> HPs is governed by the structural features of the unmodified MCM-48 matrix. It was demonstrated that reducing the annealing temperature to 550 °C allows for a 25 wt% increase in the zinc iodide content within the HPs while effectively preventing the formation of undesired zinc oxide. Furthermore, this optimized temperature regime contributed to a 1.5–2.0-fold increase in both specific surface area and pore diameter. The incorporation of zinc iodide was shown to significantly enhance the thermal stability of silver iodide. These findings suggest that the synthesized AgI-MCM48-ZnI<sub>2</sub> composites are highly promising for weather modification technologies, specifically for hail suppression and rainfall enhancement.</p>\u0000 </div>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-04-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1186/s42252-026-00098-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147797140","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
UV-resistant, hydrophobic and self-healable polymer containing MOF (PcMOF) composite for multi-functional coating application 含MOF (PcMOF)复合材料的耐紫外线、疏水、自愈高分子多功能涂料
Functional Composite Materials Pub Date : 2026-04-01 DOI: 10.1186/s42252-026-00093-1
Payel Maity, Nikhil Kumar, Atif Ansari, Santanu Chattopadhyay, Rahul Mitra, Nikhil K. Singha
{"title":"UV-resistant, hydrophobic and self-healable polymer containing MOF (PcMOF) composite for multi-functional coating application","authors":"Payel Maity,&nbsp;Nikhil Kumar,&nbsp;Atif Ansari,&nbsp;Santanu Chattopadhyay,&nbsp;Rahul Mitra,&nbsp;Nikhil K. Singha","doi":"10.1186/s42252-026-00093-1","DOIUrl":"10.1186/s42252-026-00093-1","url":null,"abstract":"<div><p>In recent years, the development of hydrophobic, UV-resistant, and self-healable polymer/metal organic framework (MOF) composites has attracted considerable scientific interest for advanced coating applications. In this study, a copolymer of glycidyl methacrylate and lauryl methacrylate, P(GMA-<i>co</i>-LMA) (PGL), was synthesized to impart hydrophobicity, mechanical flexibility, and heat-induced self-healing behaviour, while a Ti-based MOF was incorporated to introduce antimicrobial activity and UV-blocking functionality. The resulting polymer-containing MOF (PcMOF) composite demonstrated significantly enhanced multifunctional performance. Notably, the PcMOF exhibited a high water contact angle (WCA) of approximately 120°, indicating strong hydrophobicity, along with nearly zero UV transmittance, confirming excellent UV-shielding capability. Comprehensive characterization of the PcMOF composites was carried out using FTIR, scanning electron microscopy (SEM), UV-Vis spectroscopy, WCA measurements, and antibacterial assays. The PcMOF coating was successfully applied to both cotton fabric and glass substrates, demonstrating effective self-cleaning behaviour, UV resistance, and antibacterial activity. Owing to its combined hydrophobic, UV-protective, self-healing, and antimicrobial properties, the developed PcMOF composite shows potential for high-performance multifunctional coatings.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1186/s42252-026-00093-1.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147606776","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Agriculture waste derived biochar based polyvinyl alcohol composites for structural applications 结构应用的农业废物衍生生物炭基聚乙烯醇复合材料
Functional Composite Materials Pub Date : 2026-03-30 DOI: 10.1186/s42252-026-00095-z
Kunal Joshi, Tanuja Arya, Neelam Rawat, Kundan Singh Rawat, Rajkumari Linthoinganbi, Pushpa Bhakuni Negi, Chetna Tewari, Yong Chae Jung, Nanda Gopal Sahoo
{"title":"Agriculture waste derived biochar based polyvinyl alcohol composites for structural applications","authors":"Kunal Joshi,&nbsp;Tanuja Arya,&nbsp;Neelam Rawat,&nbsp;Kundan Singh Rawat,&nbsp;Rajkumari Linthoinganbi,&nbsp;Pushpa Bhakuni Negi,&nbsp;Chetna Tewari,&nbsp;Yong Chae Jung,&nbsp;Nanda Gopal Sahoo","doi":"10.1186/s42252-026-00095-z","DOIUrl":"10.1186/s42252-026-00095-z","url":null,"abstract":"<div>\u0000 \u0000 <p>The sustainable development of high-performance materials from renewable resources has gained substantial attention in recent years. In this study, biochar was synthesized from agricultural waste i.e. bamboo waste (WBB) via a green route and subsequently functionalized with ammonium persulfate (APS) to improve dispersion and interfacial bonding. The functionalized bamboo waste biochar was incorporated into a polyvinyl alcohol (PVA) matrix to fabricate nanocomposites with enhanced structural properties. Comprehensive characterization was carried out using FTIR, XRD, FE-SEM, XPS, and Raman spectroscopy to confirm successful functionalization and uniform distribution of WBB within the PVA matrix. Mechanical testing revealed significant improvements in tensile strength, Young’s modulus, and toughness, demonstrating the reinforcing effect of APS-functionalized waste bamboo biochar (WBFB). Thermal stability analysis confirmed enhanced resistance to degradation, further validating the material’s suitability for engineering applications. The results revealed that the incorporation of WBFB significantly enhanced the performance of PVA. At an optimal biochar loading of 5 wt%, tensile strength increased by approximately 62.43% compared to pure PVA and Young’s modulus increased from 3088 MPa (pure PVA) to 7496 MPa, respectively. Thermal stability also increased from 325.70 °C (T<sub>50%</sub>) for pure PVA to 384.81 °C (T<sub>50%</sub>) for the 5% biochar functionalized composite. DSC analysis revealed enhancement in the thermal characteristics T<sub>m</sub> and T<sub>c</sub> by 8.79 °C and 13.02 °C at an optimal biochar loading of 5 wt%. The synergistic combination of bamboo waste derived biochar and PVA establishes a cost-effective, eco-friendly, and mechanically robust nanocomposite with strong potential for use in advanced structural and sustainable material applications.</p>\u0000 </div>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2026-03-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1186/s42252-026-00095-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147606987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
An emerging liquid thermoplastic resin based structural composite through VARTM: a comprehensive comparison of the mechanical performance with conventional epoxy based composites at ambient and elevated temperature 一种新兴的液体热塑性树脂基结构复合材料,通过VARTM:与传统环氧基复合材料在室温和高温下的机械性能进行全面比较
Functional Composite Materials Pub Date : 2026-03-26 DOI: 10.1186/s42252-026-00092-2
Tanmoy Adhikary, Parimal Jana, Ganesh Rao Junnoori, Rajender Shanigarapu, Rajesh Kumar Prusty, Bankim Chandra Ray
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