Trends in Environmental Analytical Chemistry最新文献_第5页

Molecularly imprinted polymers as highly selective sorbents in sample preparation techniques and their applications in environmental water analysis 分子印迹聚合物作为高选择性吸附剂在样品制备技术及其在环境水分析中的应用

IF 11.2 2区化学

Trends in Environmental Analytical Chemistry Pub Date : 2023-03-01 DOI: 10.1016/j.teac.2022.e00193

S. Irem Kaya , Ahmet Cetinkaya , Sibel A. Ozkan

{"title":"Molecularly imprinted polymers as highly selective sorbents in sample preparation techniques and their applications in environmental water analysis","authors":"S. Irem Kaya , Ahmet Cetinkaya , Sibel A. Ozkan","doi":"10.1016/j.teac.2022.e00193","DOIUrl":"10.1016/j.teac.2022.e00193","url":null,"abstract":"<div><p><span>Recently, the importance of sample preparation methods<span> has been increasing due to the fact that more complex experiments take place in the extraction and determination processes and the need for advanced results. Several sample preparation techniques, such as solid-phase extraction (SPE) and associated procedures, such as solid-phase microextraction (SPME) and magnetic solid-phase extraction (MSPE), provide analyte concentration, matrix effect elimination, sample media stabilization, and sample clean-up. To improve sample extraction efficiency, there is a need for suitable sorbents. Molecular imprinting technology and </span></span>molecularly imprinted polymers (MIPs) are used to develop highly selective sorbents, thanks to their specially designed binding sites. Additionally, the high preferability of MIPs is related to their affordability, simplicity, and stability. MIPs-based sample preparation can be integrated with various methods and applied to numerous samples (environmental, biological, food, etc.). This review study overviews the latest applications and new trends in MIPs-based sample preparation in environmental water samples covering the last five years.</p></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":11.2,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42759784","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 14

Analytical methods for the determination of antidepressants, antipsychotics, benzodiazepines and their metabolites through wastewater-based epidemiology 基于废水的流行病学方法测定抗抑郁药、抗精神病药、苯二氮卓类药物及其代谢物

IF 11.2 2区化学

Trends in Environmental Analytical Chemistry Pub Date : 2023-03-01 DOI: 10.1016/j.teac.2022.e00192

Maria Laimou-Geraniou , David Heath , Ester Heath

{"title":"Analytical methods for the determination of antidepressants, antipsychotics, benzodiazepines and their metabolites through wastewater-based epidemiology","authors":"Maria Laimou-Geraniou , David Heath , Ester Heath","doi":"10.1016/j.teac.2022.e00192","DOIUrl":"10.1016/j.teac.2022.e00192","url":null,"abstract":"<div><p>The wastewater-based epidemiology approach, popular for estimating illicit drug use, has been used to evaluate lifestyle habits such as alcohol, tobacco and caffeine consumption, health biomarkers including pharmaceuticals, plasticizers and flame retardants, and recently to track SARS-CoV-2 at the population level. Equally, the number of WBE studies investigating psychoactive pharmaceuticals such as antidepressants, antipsychotics and benzodiazepines has also increased, which can be connected to the overall growth of psychological disorders worldwide. This review aims to discuss novelties in sampling techniques and analytical methodologies, including sample preparation and analysis, developed for estimating the consumption of psychoactive pharmaceuticals in defined populations. Seventy-four peer-reviewed studies monitoring psychoactive pharmaceutical consumption published since 2010 have been systematically reviewed. Its findings show that a broad range of bioanalytical methodologies is used to simultaneously measure several antidepressants, antipsychotics, benzodiazepines, and their metabolites from influent wastewater samples in low concentrations and different time periods. The application of WBE commenting on the temporal and spatial variations worldwide, showing widespread consumption, is also discussed. Despite much progress and excellent studies, there remains a need for research, and deeper knowledge is needed to reduce method uncertainty, especially since excretion rates, their transformation, and in-sewer and in-sample stability for many psychoactive pharmaceutical biomarkers are not available.</p></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":11.2,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47459613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 5

Revisiting the analytical determination of PAHs in environmental samples: An update on recent advances 环境样品中PAHs分析测定方法的修订：最新进展

IF 11.2 2区化学

Trends in Environmental Analytical Chemistry Pub Date : 2023-03-01 DOI: 10.1016/j.teac.2023.e00195

Vasiliki Soursou, Julián Campo, Yolanda Picó

引用次数: 2

Colorimetric sensing of heavy metals on metal doped metal oxide nanocomposites: A review 金属掺杂金属氧化物纳米复合材料对重金属的比色传感研究进展

IF 11.2 2区化学

Trends in Environmental Analytical Chemistry Pub Date : 2023-03-01 DOI: 10.1016/j.teac.2022.e00187

Zainab Ali , Rooh Ullah , Mustafa Tuzen , Saif Ullah , Abdur Rahim , Tawfik A. Saleh

{"title":"Colorimetric sensing of heavy metals on metal doped metal oxide nanocomposites: A review","authors":"Zainab Ali , Rooh Ullah , Mustafa Tuzen , Saif Ullah , Abdur Rahim , Tawfik A. Saleh","doi":"10.1016/j.teac.2022.e00187","DOIUrl":"10.1016/j.teac.2022.e00187","url":null,"abstract":"<div><p>Heavy metal ion-containing pollution has drawn a lot of attention. It presents thoughtful risks to the human situation and environmental system. Nanotechnologies can control, create, and measure objects on a molecular and atomic size between 1 and 100 nm. Their surface area to volume ratio is high. These are the most practical and are to blame for the easy accessibility, particularly for environmental cleanup. The nanocomposites have proven to offer remarkable qualities as platforms for heavy metal detection sensing. Monitoring the water quality is one of the key concerns of researchers in the modern period. Heavy metal contamination is a significant issue and poses a risk to ecological preservation. Due to this, several efforts are being made in present to develop sensitive, quick, and selective sensors. Reversibility, high specificity, and sensitivity are three unique and intriguing characteristics of colorimetric sensors that have grown in popularity. The particular features of nanomaterials, such as those based on metal and metal oxide, polymers, and carbon, make them beneficial for cleaning up the environment. We examined the most recent (2010–2022) advancements in metal composites for the treatment of metal ions in contaminated water in this review study.</p></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":11.2,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41815917","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 22

Current and emerging analytical techniques for the determination of PFAS in environmental samples 环境样品中PFAS测定的当前和新兴分析技术

IF 11.2 2区化学

Trends in Environmental Analytical Chemistry Pub Date : 2023-03-01 DOI: 10.1016/j.teac.2023.e00198

Abd Ur Rehman , Michelle Crimi , Silvana Andreescu

{"title":"Current and emerging analytical techniques for the determination of PFAS in environmental samples","authors":"Abd Ur Rehman , Michelle Crimi , Silvana Andreescu","doi":"10.1016/j.teac.2023.e00198","DOIUrl":"10.1016/j.teac.2023.e00198","url":null,"abstract":"<div><p>Per- and polyfluoroalkyl substances (PFAS) are a large group of synthetic chemicals used in many commercial products and applications such as polymers, fire-retarding foams, cookware and food packaging. PFAS pose significant threats to the environment and human health because of their high stability, potential toxicity and persistence in the environment. This review summarizes the status of analytical methods for detection of the broad spectrum of PFAS. Conventional analytical techniques are first described with focus on chromatographic/mass spectrometry methods, semi-quantitative approaches and passive samplers. Emerging colorimetric, spectrofluorometric and electrochemical methods, and field-deployable sensors are then reviewed, highlighting novel detection mechanisms, analytical performance and potential towards achieving low cost detection in environmental samples. Their low cost and portability can enable greater spatial and temporal data resolution and provide a more comprehensive characterization and screening of PFAS-containing samples, but require further development to reach detection at the regulatory permissible limits. Potential applications and a critical assessment of future needs and opportunities to translate these technologies into the field are discussed.</p></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":11.2,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44379223","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 8

Current trends in sample preparation for the determination of primary aromatic amines in environmental samples 测定环境样品中伯芳香胺的样品制备现状

IF 11.2 2区化学

Trends in Environmental Analytical Chemistry Pub Date : 2023-03-01 DOI: 10.1016/j.teac.2023.e00197

Natalia González, Maite V. Aguinaga Martínez, Claudia E. Domini, Carolina C. Acebal

{"title":"Current trends in sample preparation for the determination of primary aromatic amines in environmental samples","authors":"Natalia González, Maite V. Aguinaga Martínez, Claudia E. Domini, Carolina C. Acebal","doi":"10.1016/j.teac.2023.e00197","DOIUrl":"10.1016/j.teac.2023.e00197","url":null,"abstract":"<div><p><span>Primary aromatic amines<span> (PAAs) are a large group of organic compounds characterized by the presence of an amino group attached to one or more aryl substituents. These compounds are released into the environment from diverse sources, and have been of concern because of its carcinogenic<span> and mutagenic activity. Therefore, their quantification is essential to obtain information on their presence and, therefore, to reduce the harmful effects on humans. Sample preparation techniques play an outstanding role in the development of analytical methods to achieve this goal. Mainly, sorbent-based extraction and solvent-based microextraction techniques have been applied for the sensitive determination of PAAs in environmental matrices. This review covers articles based on the development and application of such techniques for the extraction and </span></span></span>preconcentration of these compounds in water, soil and air samples, published between 2010 and 2022. In addition, the recent advances and future challenges in applying these techniques for extracting PAAs are discussed.</p></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":11.2,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43023608","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Analysis of paralytic shellfish toxins in seafood by liquid chromatography: A critical review of the methodologies developed 液相色谱法分析海产品中麻痹性贝类毒素的研究进展

IF 11.2 2区化学

Trends in Environmental Analytical Chemistry Pub Date : 2023-03-01 DOI: 10.1016/j.teac.2022.e00190

Sergio Santana-Viera, Pablo A. Lara-Martin

{"title":"Analysis of paralytic shellfish toxins in seafood by liquid chromatography: A critical review of the methodologies developed","authors":"Sergio Santana-Viera, Pablo A. Lara-Martin","doi":"10.1016/j.teac.2022.e00190","DOIUrl":"10.1016/j.teac.2022.e00190","url":null,"abstract":"<div><p><span><span>Paralytic shellfish toxins (PSTs) are natural toxins produced by some microorganisms, especially during harmful algal blooms (HABs). Molluscs and other marine animals can accumulate significant amounts of these toxins, causing food poisoning. Due to the seriousness of this poisoning, the European Union has established a concentration limit and an official method based on liquid chromatography for their analysis. PSTs are very challenging analytes due to their very high polarity and occurrence of different isomers with varying toxicity towards humans. Current available </span>extraction methods are adapted from a previous existing bioassay and not fully validated yet. Recovery efficiencies of the extraction procedure are occasionally low, and further clean-up can lead to highly variable results depending on the toxin and the matrix analysed. Detection of PSTs by mass spectrometry offers the ability to identify all toxins in a single analysis, which is an improvement over the current official method based on fluorescence detection prior </span>derivatisation<span>. As a drawback, normal phase chromatography is required, which tend to be less robust that more conventionally used reversed-phase chromatography used in the official method. New extraction techniques and recent advances in the mass spectrometry field (e.g., high-resolution mass spectrometry and ion mobility) have been barely applied yet to the analysis of PSTs. An increase in the frequency and extension of HABs due to global warming will lead to more severe impacts on health, environment and economy in coastal areas. An improvement of current existing analytical methods is therefore needed to allow for a faster and more accurate monitoring of PSTs.</span></p></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":11.2,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41701018","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

A greenness evaluation and environmental aspects of solidified floating organic drop microextraction for metals: A review 金属固化漂浮有机滴微萃取的绿色评价及环境研究进展

IF 11.2 2区化学

Trends in Environmental Analytical Chemistry Pub Date : 2023-03-01 DOI: 10.1016/j.teac.2022.e00194

Asim Ridha Hussein , Muna Shakir Gburi , Nadia Mahdi Muslim , Ebaa Adnan Azooz

{"title":"A greenness evaluation and environmental aspects of solidified floating organic drop microextraction for metals: A review","authors":"Asim Ridha Hussein , Muna Shakir Gburi , Nadia Mahdi Muslim , Ebaa Adnan Azooz","doi":"10.1016/j.teac.2022.e00194","DOIUrl":"10.1016/j.teac.2022.e00194","url":null,"abstract":"<div><p><span>In the past 20 years, green analytical procedures have attracted much attention from all walks of life, including analytical chemistry<span>. The conversion to green analytical chemistry (GAC) requires the establishment of novel, more effective procedures compared to conventional methods. Improving sample preparation, design procedures, solvent quantities, and accurate assessment are the best ways to follow the principles of GAC. The current review focuses on the influential factors in greenness, like the design, applications, instrumentals, green features, and greenness measurement of the solidified floating organic drop microextraction (SFODME) method for toxic metals. Using various solvents, such as </span></span>ionic liquids<span>, deep eutectic solvents, and biomolecules, we formed more environmentally solidified floating organic drop microextraction modes. The green analytical procedure index (GAPI) and analytical greenness (AGREE) are two green assessment tools used to evaluate and compare the greenness of a solidified floating organic drop microextraction for various modes. The two scales (GAPI and AGREE) are very simple and accurate. They focus on several factors, such as the collection of samples, chemical amounts, time analysis, energy, occupational danger, waste, and others. Future developments were also investigated.</span></p></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":11.2,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48154699","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 12

Unravelling plant protection product analysis: Use of chromatography techniques (GC and LC) and high resolution mass spectrometry 植物保护产品分析:使用色谱技术(GC和LC)和高分辨率质谱

IF 11.2 2区化学

Trends in Environmental Analytical Chemistry Pub Date : 2023-03-01 DOI: 10.1016/j.teac.2022.e00191

Rosalía López-Ruiz , Antonio Jesús Maldonado-Reina , Jesús Marín-Sáez , Roberto Romero-González , José Luis Martínez-Vidal , Antonia Garrido Frenich

{"title":"Unravelling plant protection product analysis: Use of chromatography techniques (GC and LC) and high resolution mass spectrometry","authors":"Rosalía López-Ruiz , Antonio Jesús Maldonado-Reina , Jesús Marín-Sáez , Roberto Romero-González , José Luis Martínez-Vidal , Antonia Garrido Frenich","doi":"10.1016/j.teac.2022.e00191","DOIUrl":"10.1016/j.teac.2022.e00191","url":null,"abstract":"<div><p>This study proposes a methodology for the characterization of plant protection products (PPPs) based on suspect and unknown analyses. This was divided in three main stages: sample preparation, separation and detection, and data analysis. Sample preparation was based on dilute and shoot strategies employing different solvents depending on both the type of compounds and the type of PPPs to be analyzed. Chromatographic techniques, as liquid (LC) and gas chromatography (GC), coupled with high resolution mass spectrometry (HRMS) analyzers are used for the separation and detection stage. HRMS allowed a huge number of possibilities in terms of data acquisition, and this work reveals the most suitable options and the principal parameters to maximize the number of features and to perform an accurate detection. Finally, tips and recommendations to perform data analysis are indicated, providing the pre-processing and processing strategies to perform suspect screening and unknown analysis.</p></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":11.2,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41693970","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 5

Recent progress of nanomaterials for colorimetric and fluorescence sensing of reactive oxygen species in biological and environmental samples 纳米材料用于生物和环境样品中活性氧的比色和荧光传感的最新进展

IF 11.2 2区化学

Trends in Environmental Analytical Chemistry Pub Date : 2023-03-01 DOI: 10.1016/j.teac.2023.e00196

Suresh Kumar Kailasa , Ghinaiya Nirav Vajubhai , Janardhan Reddy Koduru , Tae Jung Park

{"title":"Recent progress of nanomaterials for colorimetric and fluorescence sensing of reactive oxygen species in biological and environmental samples","authors":"Suresh Kumar Kailasa , Ghinaiya Nirav Vajubhai , Janardhan Reddy Koduru , Tae Jung Park","doi":"10.1016/j.teac.2023.e00196","DOIUrl":"10.1016/j.teac.2023.e00196","url":null,"abstract":"<div><p><span>Incomplete reduction of oxygen produces reactive oxygen species (ROS) or intermediates. Hydrogen peroxide (H</span><sub>2</sub>O<sub>2</sub>), superoxide (O<sub>2</sub><sup>•−</sup><span>), hydroxyl radical (</span><sup>•</sup>OH), and hypochlorite (ClO<sup>-</sup><span>) are examples of ROS. Peroxynitrite (ONOO</span><sup>−</sup><span><span><span><span>) belongs to reactive nitrogen species. Recent studies are evidenced that they play crucial roles in cell signaling and tissue homeostasis. Further, ROS are recognized as oxidizing </span>chemical species for various biochemical pathways (oxidative stress and damage of organisms) and as scavengers for various environmental applications. Herein, the recent progress of </span>nanomaterials as </span>optical sensors for colorimetric and fluorescence sensing of reactive oxygen species is discussed. This review also provides the analytical features of nanomaterials-based colorimetric and fluorescent sensors for sensing of ROS in real samples (biological and environmental samples). Additionally, the future prospects of nanomaterials-based colorimetric and fluorescent sensors for the detection of ROS are discussed.</span></p></div>","PeriodicalId":56032,"journal":{"name":"Trends in Environmental Analytical Chemistry","volume":null,"pages":null},"PeriodicalIF":11.2,"publicationDate":"2023-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48292759","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 10