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Exploring phosphorous dynamics within soil aggregate after 17 years long-term manuring in lateritic Inceptisols in rice paddies 稻田红壤壤17年长期施肥后土壤团聚体磷动态研究
IF 3.1 2区 农林科学
Geoderma Regional Pub Date : 2024-12-13 DOI: 10.1016/j.geodrs.2024.e00908
Nafid Cheekilote , Prasanna Kumar Samant , Sanat Kumar Dwibedi , Bandita Jena , Kiran Kumar Mohapatra , Hari Sankar Nayak , Saheed Garnaik
{"title":"Exploring phosphorous dynamics within soil aggregate after 17 years long-term manuring in lateritic Inceptisols in rice paddies","authors":"Nafid Cheekilote ,&nbsp;Prasanna Kumar Samant ,&nbsp;Sanat Kumar Dwibedi ,&nbsp;Bandita Jena ,&nbsp;Kiran Kumar Mohapatra ,&nbsp;Hari Sankar Nayak ,&nbsp;Saheed Garnaik","doi":"10.1016/j.geodrs.2024.e00908","DOIUrl":"10.1016/j.geodrs.2024.e00908","url":null,"abstract":"<div><div>Understanding phosphorous dynamics can provide valuable insights for sustainable nutrient management and long-term fertilizer experiments are better source for elucidating such mechanism. In this study, eight distinct nutrient management treatments (combination of N, P, K fertilizer along with FYM and lime) were evaluated in an ongoing long-term fertilizer experiment. The experiment investigated the prolonged effects of both balanced and imbalanced fertilizer applications, the combined use of organic manure and inorganic fertilizers, and the application of liming material in a rice-rice cropping system on yield attributes and changes in soil properties. Integrated use of organic manure with NPK fertilizers and lime application (100% NPK + FYM + Lime) positively influenced soil properties and significantly increased yield by 41.4% and P-uptake by 88.4% compared to sole NPK application. The long-term fertilization contributed to significant relative accumulation of Ca<img>P fraction (∼240% increase) in 100% NPK + FYM + Lime in comparison to initial Ca<img>P fraction. The distribution pattern of inorganic phosphorus fractions varied with following sequence: Fe-P &gt; Red-P &gt; Al-P &gt; Ca-P &gt; Occl-P &gt; Sal-P. Among these fractions, Ca<img>P (<em>r</em> = 0.949**), Occl-P (<em>r</em> = 0.884**), and Sal-P (<em>r</em> = 0.866**) were correlated with available P. The mean weight diameter (MWD) exhibited the strongest correlation with Occl-P (<em>r</em> = 0.936**), whereas the geometric mean diameter (GMD) and water stable aggregate (WSA) had the strongest correlation with Ca<img>P (0.893** and 0.875**, respectively). The adjusted R<sup>2</sup> values indicated that the total contribution of all inorganic P fractions accounted for 99.9% of the variability in available P, 80.6 % in P uptakes, and 67.9% in grain yield. This study underscores the critical relationship among soil structure, crop yield, and P availability, emphasizing that macroaggregates play a crucial role in improving soil health and enhancing P retention and availability.</div></div>","PeriodicalId":56001,"journal":{"name":"Geoderma Regional","volume":"40 ","pages":"Article e00908"},"PeriodicalIF":3.1,"publicationDate":"2024-12-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143144991","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Soil carbon benchmarks and cropland management effects: Insights from the Bavarian soil organic matter monitoring 土壤碳基准和农田管理效果:来自巴伐利亚土壤有机质监测的见解
IF 3.1 2区 农林科学
Geoderma Regional Pub Date : 2024-12-12 DOI: 10.1016/j.geodrs.2024.e00909
Manuel Sümmerer , Christopher Just , Martin Wiesmeier
{"title":"Soil carbon benchmarks and cropland management effects: Insights from the Bavarian soil organic matter monitoring","authors":"Manuel Sümmerer ,&nbsp;Christopher Just ,&nbsp;Martin Wiesmeier","doi":"10.1016/j.geodrs.2024.e00909","DOIUrl":"10.1016/j.geodrs.2024.e00909","url":null,"abstract":"<div><div>Soil organic carbon (SOC) is a key property for soil productivity and functionality. According to the Federal Soil Protection Act in Germany, site-specific SOC contents need to be maintained in the course of agricultural land use in order to ensure soil fertility and the performance of soils as a natural resource. In this study, representative SOC benchmarks have been derived for arable mineral soils in Bavaria on the basis of a comprehensive soil organic matter (SOM) monitoring program as reference values for farmers and other stakeholders. Data from 283 representative study sites across Bavaria has been stratified according to the most influential site factors on SOC, particularly clay content and the elevation above sea level as a proxy for climate (temperature and precipitation). Due to an evaluation of the study sites in terms of agricultural management according to the principles of good agricultural practice combined with statistical exclusion of 25 % of extreme SOC contents, the benchmarks presented here can be regarded as representative reference values under specific environmental conditions. However, different management measures within the principles of good agricultural practice also influenced SOC, as organic fertilization and the cultivation of perennial forage crops positively affected SOC contents. In contrast, the cultivation of root crops negatively influenced SOC contents, while the proportion of corn within the crop rotation of up to 50 % did not affect SOC negatively. We further evaluated the suitability of the SOC/clay ratio as alternative SOC and soil structure indicator. However, the SOC/clay ratio seems to be inappropriate due to a high number of degraded sites and a systematic bias towards degradation with high clay contents. The SOC benchmarks presented here provide valuable reference values for farmers policymakers and agricultural stakeholders in optimizing cropland management practices for sustainable soil health and fertility in Bavaria and beyond. However, further research is required regarding the stratification approach and the calculation method for a widespread implementation of SOC benchmarks. Furthermore, the shifting baseline syndrome has to accounted for, so up to date SOC benchmarks remain within a range in which soils are considered healthy and fertile.</div></div>","PeriodicalId":56001,"journal":{"name":"Geoderma Regional","volume":"40 ","pages":"Article e00909"},"PeriodicalIF":3.1,"publicationDate":"2024-12-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143144990","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sources of soil organic carbon under Eucalyptus silvopastures and other land-use systems in Brazilian Oxisols 巴西奥索索州桉树林场和其他土地利用系统下土壤有机碳的来源
IF 3.1 2区 农林科学
Geoderma Regional Pub Date : 2024-12-11 DOI: 10.1016/j.geodrs.2024.e00907
Felipe M. Pinheiro , P.K. Ramachandran Nair , Vimala D. Nair , Rafael G. Tonucci , Regis P. Venturin
{"title":"Sources of soil organic carbon under Eucalyptus silvopastures and other land-use systems in Brazilian Oxisols","authors":"Felipe M. Pinheiro ,&nbsp;P.K. Ramachandran Nair ,&nbsp;Vimala D. Nair ,&nbsp;Rafael G. Tonucci ,&nbsp;Regis P. Venturin","doi":"10.1016/j.geodrs.2024.e00907","DOIUrl":"10.1016/j.geodrs.2024.e00907","url":null,"abstract":"<div><div>Silvopastoral systems (SPS) incorporating non-native tree species such as Eucalyptus are increasingly being adopted in the Cerrado region of Brazil. The climate-change mitigation potential of the practice, although hypothesized, has not been assessed vigorously. The objective of this research was to measure the extent of SOC accumulation under SPS involving C3 and C4 plants and other prevalent land-use systems in an Oxisol-dominated location in Minas Gerais, Brazil. We determined the overall δ13C in three soil fraction-size groups within six land-use systems. These systems consisted of 8-year-old planted forests, native forest, managed pastures, and three variations of 8-year-old SPS with diverse tree-planting layouts. In the SPS and planted forest treatments, the tree species was Eucalyptus hybrid, and <em>Urochloa decumbens</em> was the grass species in the SPS and pasture treatments. For each treatment, soil samples were collected at depths of 0–10, 10–30, 30–60, and 60–100 cm. These samples were fractionated into three size classes (2000-250 μm, 250-53 μm, and &lt;53 μm) and analyzed for δ13C. The native forest had higher C3 contribution in the topsoil layers. The highest C3 derived SOC stock up to 1 m depth was in the pasture (137 Mg ha<sup>-1</sup>), and the lowest in the forest (74 Mg ha<sup>-1</sup>). The pasture also had the highest C4 derived SOC stock and the forest the lowest, but not significantly. The SPS had intermediate values. We infer that the study site had a mixed vegetation in the past, and after the conversion of the land to planted forest/SPS/pasture, the “native” SOC stock could be maintained better in a well-managed pasture than in a degraded native forest. The higher C3-derived SOC stock in the pasture treatment suggests that managed SPS could help retain more soil C in a stable form than in degraded forests.</div></div>","PeriodicalId":56001,"journal":{"name":"Geoderma Regional","volume":"40 ","pages":"Article e00907"},"PeriodicalIF":3.1,"publicationDate":"2024-12-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143144989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Superior nutrient recovery and release by chicken manure-derived biochar over hydrochar and compost for soil fertilization 在土壤施肥中,鸡粪生物炭比碳氢化合物和堆肥具有更好的养分回收和释放
IF 3.1 2区 农林科学
Geoderma Regional Pub Date : 2024-12-10 DOI: 10.1016/j.geodrs.2024.e00906
Mahmudul Islam Piash , Takanori Itoh , Kazusa Abe , Kazunori Iwabuchi
{"title":"Superior nutrient recovery and release by chicken manure-derived biochar over hydrochar and compost for soil fertilization","authors":"Mahmudul Islam Piash ,&nbsp;Takanori Itoh ,&nbsp;Kazusa Abe ,&nbsp;Kazunori Iwabuchi","doi":"10.1016/j.geodrs.2024.e00906","DOIUrl":"10.1016/j.geodrs.2024.e00906","url":null,"abstract":"<div><div>Recycling nutrient-rich organic waste materials in agriculture is increasingly recognized for its potential to establish sustainable systems, especially considering the diminishing availability of chemical fertilizers. However, appropriate pretreatment methods are essential for safe and efficient utilization in soil systems. In this study, we compared conventional composting (compost) with low-temperature pyrolysis (biochar) and hydrothermal carbonization (hydrochar) for conserving nutrients from chicken manure (CM) and producing stable organic fertilizer. Biochar exhibited superior nutrient recovery, with 76.4 % of N retrieved from CM compared to 37.4 % for hydrochar and 36.2 % for compost. The escape of NH<sub>3</sub> gas from deaminated hydrochar slurry and volatilization loss during composting might have caused such low N recovery in hydrochar and compost, respectively. When applied to soil, biochar released nearly 100 % of its nitrogen in phyto-available form and may satisfy 88.5 % of the N requirements for optimum sweetcorn production. Decomposition of pyridinic- and pyrrolic-N in low-temperature CM biochar might have contributed to this high N release. In contrast, compost released 85 % of its N, and hydrochar released only 33 %. Biochar also preserved the highest amount of carbon (67.6 %) during production, with a significantly higher fixed carbon content (19.2 %). Over a 140-day incubation period, while 26.6 % of compost‑carbon was emitted as CO<sub>2</sub> from soil, biochar remained significantly stable (11.5 %). These findings underscore manure biochar's potential as an effective tool for soil fertilization and carbon sequestration, surpassing compost and hydrochar in nitrogen recovery, nitrogen release, and carbon stability in soil.</div></div>","PeriodicalId":56001,"journal":{"name":"Geoderma Regional","volume":"40 ","pages":"Article e00906"},"PeriodicalIF":3.1,"publicationDate":"2024-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143145021","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mapping soil parent materials in a previously glaciated landscape: Potential for a machine learning approach for detailed nationwide mapping 测绘以前冰川景观中的土壤母质:用于详细全国测绘的机器学习方法的潜力
IF 3.1 2区 农林科学
Geoderma Regional Pub Date : 2024-12-10 DOI: 10.1016/j.geodrs.2024.e00905
Yiqi Lin , William Lidberg , Cecilia Karlsson , Gustav Sohlenius , Florian Westphal , Johannes Larson , Anneli M. Ågren
{"title":"Mapping soil parent materials in a previously glaciated landscape: Potential for a machine learning approach for detailed nationwide mapping","authors":"Yiqi Lin ,&nbsp;William Lidberg ,&nbsp;Cecilia Karlsson ,&nbsp;Gustav Sohlenius ,&nbsp;Florian Westphal ,&nbsp;Johannes Larson ,&nbsp;Anneli M. Ågren","doi":"10.1016/j.geodrs.2024.e00905","DOIUrl":"10.1016/j.geodrs.2024.e00905","url":null,"abstract":"<div><div>Reliable information on soil-forming parent materials is crucial for informed decision-making in infrastructure planning, land-use management, environmental assessments, and geohazard mitigation. In the northern landscapes previously affected by glacial processes, these parent materials are predominantly Quaternary deposits. This study explored the potential of machine learning to expedite soil parent material mapping in Sweden. Two Extreme Gradient Boosting models were trained, one using terrain and hydrological indices derived from Light Detection and Ranging data, and the other incorporating additional ancillary map data. Both models were trained on 29,588 soil observations and evaluated against a separate hold-out set of 3500 observations. As a baseline, the existing most detailed maps achieved a Matthews Correlation Coefficient of 0.36. The Extreme Gradient Boosting models achieved higher MCC values of 0.45 and 0.56, respectively. To understand spatial variations in model performance, the second model was evaluated across 28 physiographic regions in Sweden. The results revealed that model performance varied across regions and deposit types, with till and peat exhibiting better performance than sorted sediments. These findings underscore the need for region-specific analyses to optimize the application of machine learning in digital soil mapping.</div></div>","PeriodicalId":56001,"journal":{"name":"Geoderma Regional","volume":"40 ","pages":"Article e00905"},"PeriodicalIF":3.1,"publicationDate":"2024-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143145551","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
How to site grassed areas to reduce agricultural erosion efficiently? A computational analysis in Finland 如何对草地进行选址,有效减少农业水土流失?芬兰的计算分析
IF 3.1 2区 农林科学
Geoderma Regional Pub Date : 2024-12-08 DOI: 10.1016/j.geodrs.2024.e00904
M. Tähtikarhu, T.A. Räsänen, J. Uusi-Kämppä, J. Hyväluoma
{"title":"How to site grassed areas to reduce agricultural erosion efficiently? A computational analysis in Finland","authors":"M. Tähtikarhu,&nbsp;T.A. Räsänen,&nbsp;J. Uusi-Kämppä,&nbsp;J. Hyväluoma","doi":"10.1016/j.geodrs.2024.e00904","DOIUrl":"10.1016/j.geodrs.2024.e00904","url":null,"abstract":"<div><div>Spatial patterns of land-cover and agricultural operations have clear impacts on soil erosion. Allocating a portion of cultivated area for grass is a widely applied strategy to control erosion. However, it is still unclear how much and where grassed area should be spatially targeted in different landscapes to control erosion efficiently. To address this challenge, we estimate the potential of high-resolution RUSLE-based spatial targeting of grassed areas to improve erosion mitigation in two topographically different catchments in southern Finland. Erosion reductions of 1) policy-based targeting (buffer strips along main streams according to current CAP strategy) were compared with 2) RUSLE-targeted grassed areas (based on the highest computed erosion values within field parcels and sub-catchments). Furthermore, we computationally explored 3) how different rates of optimally located grass areas affected erosion and 4) how the areas could be computationally processed to continuous entities. The erosion reductions were estimated with 2 × 2 m<sup>2</sup> resolution RUSLE computations in all the scenarios. The RUSLE-targeted grassed areas demonstrated greater erosion reductions compared to the policy-based siting of grass areas along riparian fields. With optimal targeting, erosion risks could potentially be reduced up to 24 percentage points (up to 46 % erosion reduction), compared to the buffer strips. Increasing optimally targeted grassed area gradually from 0 to 100 % decreased erosion non-linearly. The largest share of erosion was generated in disproportionally small land areas (∼20 % of the land area). The location of the hotspots in relation to the streams varied between the sub-catchments and field parcels. These quantifications demonstrate the potential value of models for targeted landscape scale spatial erosion management. A more comprehensive assessment of erosion mitigation could benefit of improved empirical validation and consideration of other aspects of erosion and sediment transport, such as local drainage efficiency and reduction of erosion during flooding of rivers.</div></div>","PeriodicalId":56001,"journal":{"name":"Geoderma Regional","volume":"40 ","pages":"Article e00904"},"PeriodicalIF":3.1,"publicationDate":"2024-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143144988","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microbial necromass as a critical driver of soil organic carbon accumulation in Qinghai-Tibet Plateau under climate warming: A meta-analysis 气候变暖背景下青藏高原微生物坏死团块对土壤有机碳积累的影响:meta分析
IF 3.1 2区 农林科学
Geoderma Regional Pub Date : 2024-12-06 DOI: 10.1016/j.geodrs.2024.e00903
Yunduo Zhao , Dongsheng Li , Jinxing Zhou
{"title":"Microbial necromass as a critical driver of soil organic carbon accumulation in Qinghai-Tibet Plateau under climate warming: A meta-analysis","authors":"Yunduo Zhao ,&nbsp;Dongsheng Li ,&nbsp;Jinxing Zhou","doi":"10.1016/j.geodrs.2024.e00903","DOIUrl":"10.1016/j.geodrs.2024.e00903","url":null,"abstract":"<div><div>Microbial necromass plays a significant role in soil carbon storage under climate warming, as it is considered a crucial component of the stable carbon pool in soils. However, how the warming, including various warming patterns, affects microbial necromass and its contribution to the organic carbon pool in alpine regions remains largely unexplored. A meta-analysis was conducted utilizing data from ten publications to assess the effects of warming on microbial necromass on the Qinghai-Tibet Plateau. The findings indicated that the soil organic carbon (SOC) content did not exhibit significant changes after warming; however, microbial necromass carbon (MNC) and its ratio to SOC experienced significantly increases of 17.7 % and 52.0 %, respectively. The effect size of warming on fungal necromass carbon (FNC; +19.5 %) was larger than that of bacterial necromass carbon (BNC; +9.2 %). Furthermore, the warming patterns influenced the accumulation of microbial necromass and its ratio to SOC. The accumulation of microbial necromass and its ratio to SOC were increased (19.8 % and 63.9 %) under the low-magnitude warming and slowed down (14.0 % and 20.3 %) under the high-magnitude warming. The MNC and FNC were increased under both long-term warming (1.61 g/kg and 0.86 g/kg) and short-term warming (0.96 g/kg and 0.50 g/kg), but there was no significant change in BNC under long-term warming patterns. The effect sizes of warming on BNC, FNC and MNC were larger in the subsoil (16.3 %, 25.1 % and 24.2 %) than that in the topsoil (7.8 %, 19.1 % and 17.5 %). These results highlight the importance of warming patterns as predictors of microbial necromass. Nonetheless, these conclusions may be restricted by the insufficient sample size, and future researches should expand the sample size to reveal the threshold and mechanism underlying the effect of warming patterns on microbial necromass.</div></div>","PeriodicalId":56001,"journal":{"name":"Geoderma Regional","volume":"40 ","pages":"Article e00903"},"PeriodicalIF":3.1,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143144987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comparison of country-scale subsoil predictions between a numeric and a taxonomic soil classification system 数值土壤分类系统与分类学土壤分类系统在国家尺度下的底土预测比较
IF 3.1 2区 农林科学
Geoderma Regional Pub Date : 2024-12-02 DOI: 10.1016/j.geodrs.2024.e00902
Trevan Flynn , Catherine Clarke , Rosana Kostecki , Ansa Rebi
{"title":"A comparison of country-scale subsoil predictions between a numeric and a taxonomic soil classification system","authors":"Trevan Flynn ,&nbsp;Catherine Clarke ,&nbsp;Rosana Kostecki ,&nbsp;Ansa Rebi","doi":"10.1016/j.geodrs.2024.e00902","DOIUrl":"10.1016/j.geodrs.2024.e00902","url":null,"abstract":"<div><div>Traditional soil classification systems are designed to communicate information; however, surveyor biases and tacit knowledge can lead to subjective soil class designations. Consequently, different soil scientists may classify the same soil differently. This becomes a critical issue when mapping soil classes, as there could be multiple interpretations for the same observation. To address this problem, numerical soil classification systems have been developed. However, little is known about how well they compare to taxonomic systems when spatially predicted on a national scale. This study aimed to compare a previously developed, unsupervised numeric classification system and South Africa's taxonomic soil classification system in terms of their spatial predictions across the country. The taxonomic system of South Africa has 19 defined subsoil horizons, which were aggregated into eight horizons and compared to a nine horizon numeric classification as well as South Africa's profile (soil form) classification comprising of 73 different soil groupings, which was used as a control. The comparison was conducted from predictions through gradient tree boosting in Google Earth Engine at a 30 m resolution. The numerical system (kappa = 0.30, accuracy = 0.57) exhibited poor spatial predictions, with a kappa 22% lower and accuracy 2% lower than the control (kappa = 0.52, accuracy = 59%). On the other hand, the taxonomic system performed well, with a kappa of 0.57 and an accuracy of 67%, exhibiting a 5% increase in kappa and an 8% increase in accuracy compared to the control. It was hypothesized that the overpredictions of the predominant horizon contributed to the numeric system's poor performance. Nevertheless, both systems showed the highest maximum entropy in arid regions of the Karoo and savannah biomes, albeit in spatially distinct ecoregions. It was thought that the divergence in the two systems' maximum entropy was due to their association with precipitation differences (amount and seasonality) as well as vegetation type and cover (woodlands vs. shrublands). To map the country in more detail, further soil sampling should be conducted in arid regions and optimisation of the predictive algorithm for each soil category should be performed.</div></div>","PeriodicalId":56001,"journal":{"name":"Geoderma Regional","volume":"40 ","pages":"Article e00902"},"PeriodicalIF":3.1,"publicationDate":"2024-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143144976","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Immobilization of potentially toxic elements by grape waste biochar in contaminated soils 葡萄废生物炭在污染土壤中固定化潜在有毒元素的研究
IF 3.1 2区 农林科学
Geoderma Regional Pub Date : 2024-12-01 DOI: 10.1016/j.geodrs.2024.e00900
Fouzieh Beigmohammadi , Eisa Solgi , Ali A. Besalatpour , Mohsen Soleimani
{"title":"Immobilization of potentially toxic elements by grape waste biochar in contaminated soils","authors":"Fouzieh Beigmohammadi ,&nbsp;Eisa Solgi ,&nbsp;Ali A. Besalatpour ,&nbsp;Mohsen Soleimani","doi":"10.1016/j.geodrs.2024.e00900","DOIUrl":"10.1016/j.geodrs.2024.e00900","url":null,"abstract":"<div><div>Biochar derived from agricultural waste is recognized as an environmentally sustainable method for immobilizing potentially toxic elements (PTEs) in contaminated soils. This study investigated the efficacy of biochar produced from grape residues in immobilizing PTEs such as Pb, Ni, Mn, Cu, and Co in contaminated soils. A total of 110 surface soil samples were collected from three land-use types (agricultural, urban, and industrial) in Arak, Iran. The bioavailable fractions of PTEs were analyzed using the diethylenetriamine penta acetic acid (DTPA) extraction method. The properties of biochar were characterized through X-ray diffraction, field emission scanning electron microscopy, Fourier-transform infrared spectroscopy (FTIR), energy-dispersive X-ray spectroscopy, and Brunauer-Emmett-Teller (BET) analysis. Biochar was incorporated into the contaminated soils at a rate of 5 % (<em>w</em>/w) and incubated for two months. The results indicated that the biochar application enhanced soil properties, including pH, electrical conductivity, cation exchange capacity, organic matter, and soil microbial respiration. Simultaneously, the DTPA-extractable concentrations of Cu, Ni, Pb, and Co decreased from 7.26, 1.83, 5.82, and 0.25 mg/kg, to 5.54, 0.86, 4.06, and 0.18 mg/kg, respectively, corresponding to reductions of 24 % to 79 % in bioavailability. The reductions were attributed to the functional groups with negative charges and the high specific surface area of the biochar, as identified by FTIR and BET analyses. A random forest analysis further revealed that organic matter and soil microbial respiration were the most influential factors in in reducing the bioavailability of PTEs following biochar amendment. These findings underscore the potential of grape residue-derived biochar as an effective amendment for mitigating PTE contamination in soils.</div></div>","PeriodicalId":56001,"journal":{"name":"Geoderma Regional","volume":"39 ","pages":"Article e00900"},"PeriodicalIF":3.1,"publicationDate":"2024-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143179280","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Quantitative relationships between Munsell colour attributes and organic carbon in highly weathered tropical soils 高度风化的热带土壤中孟塞尔颜色属性与有机碳的定量关系
IF 3.1 2区 农林科学
Geoderma Regional Pub Date : 2024-12-01 DOI: 10.1016/j.geodrs.2024.e00898
Georges K. Kome , Roger K. Enang , Bernard P.K. Yerima , Eric Van Ranst
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